Description : (i) Write down the IUPAC name of the following complex : [Cr(NH3)2CI3(en)]Cl (en = ethylenediamine) (ii) Write the formula for the following complex : Pentaamminenitrito-o-Cobalt (III) -Chemistry
Last Answer : (I) [Cr(NH3)2Cl3(en)]Cl IUPAC name : Diammine dichlorido ethylenediamine chromium (III) chloride. (ii) [Co(NH3)5(ONO)]2+
Description : Using IUPAC norms write the formulae for the following: (a) Tris(ethane-1,2-diamine) chromium (III) chloride (b) Potassium tetrahydroxozincate(II) -Chemistry
Last Answer : a) [Cr(en)3] Cl3 (b) K2[Zn(OH)4]
Description : For the complex [Fe(en)2Cl2], Cl, (en = ethylene diamine), identify (i) the oxidation number of iron, (ii) the hybrid orbitals and the shape of the complex, (iii) the magnetic behaviour of the complex, (iv) ... an optical isomer also, and (vi) name of the complex. (At. no. of Fe = 26) \ -Chemistry
Last Answer : i) [Fe(en)2Cl2] Cl or x + 0 + 2 (-1) + (-1) = 0 x + (- 3) = 0 or x = + 3 ∴ Oxidation number of iron, x = + 3 (ii) The complex has two bidentate ligands and two ... )2Cl2] Cl, only cis-isomer shows optical isomerism. (vi) Name of complex: Dichloridobis (ethane-1, 2- diamine) Iron (III) chloride
Description : Using IUPAC norms write the formulae for the following: (a) Potassium trioxalatoaluminate (III) (b) Dichloridobis(ethane-l, 2-diamine) cobalt (III) -Chemistry
Last Answer : (a) K3[Al(C2O4)3] (b) [Co(Cl)2(en)2]+
Description : What is the IUPAC name of the complex [Ni(NH3)6]Cl2? -Chemistry
Last Answer : [Ni(NH3)6]Cl2 IUPAC name : Hexaamminenickel (II) chloride.
Description : Give IUPAC name of the ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry
Last Answer : IUPAC name : Triammine chlorido nickel (II) nitrate [Ni(NH3)3NO3]Cl
Description : Give IUPAC name of ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry
Last Answer : IUPAC name : Triammine nitrato nickel (III) chloride
Description : (i) Write down the IUPAC name of the following complex : [CO(NH3)5Cl]2+ (ii) Write the formula for the following complex : Potassium tetrachloridonickelate (II) -Chemistry
Last Answer : i) [CO(NH3)5Cl]2+ IUPAC name : Pentaammine chlorido cobalt (III) ion (ii) Formula of the complex potassium tetrachloridonickelate (II) K2[NiCl4]
Description : Write the IUPAC name of the following complex : [CO(NH3)6]3+ -Chemistry
Last Answer : Hexaamminecobalt (III) ion.
Description : When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex (ii) IUPAC name of the complex -Chemistry
Last Answer : i) Complex so formed is: CoCl3.6NH3 + AgNO3 → [Co(NH3)6]Cl3 (ii) IUPAC name of complex is: Hexaamminecobalt (III) chloride
Description : Which of the following is more stable complex and why? [Co(NH3)6]3+ and [Co(en)3]3+ -Chemistry
Last Answer : Co(en)3]3+ is more stable complex than [CO(NH3)6]3+ because of chelate effect.
Description : The IUPAC name of the complex `[PT(en)(NH_(3))(cl)_(2)(ONO)][Ag(CN)_(2)]` is :
Last Answer : The IUPAC name of the complex `[PT(en)(NH_(3))(cl)_(2)(ONO)][Ag(CN)_(2 ... (ethane-1,2-diammine) nitritioplatinum(IV) dicyanoargentate (I)
Description : Write the IUPAC name of the following coordination compound [NiCl4]2-. -Chemistry
Last Answer : Tetrachloridonickelate (II) ion.
Description : Write IUPAC name of the complex: [CoCl2(en)2]+ -Chemistry
Last Answer : CoCl2(en)2]+: Dichloridobis(ethylenediamine)Cobalt(III)ion.
Description : Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit? -Chemistry
Last Answer : IUPAC name : Tetraamine dichlorido chromium (III) ion. It exhibits geometrical isomerism.
Description : A complex compound in which the oxidation number of a metal is zero is - (1) K4 [Fe (CN)6] (2) K3 [Fe (CN)6] (3) [Ni (CO)4] (4) [Pl (NH3)4]Cl2
Last Answer : (3) [Ni (CO)4]
Description : How many isomers are possible for the complex `[Co(en)_(2)Cl_(2)]`(en=ethylene diamine )
Last Answer : How many isomers are possible for the complex `[Co(en)_(2)Cl_(2)]`(en=ethylene diamine ) A. 4 B. 2 C. 6 D. 3
Description : As per IUPAC nomenclature, the name of the complex `[Co(H_(2)O)_(4) (NH_(3))_(2)] Cl_(3)` is
Last Answer : As per IUPAC nomenclature, the name of the complex `[Co(H_(2)O)_(4) ( ... (III) chloride D. Diamminetetraaquacobalt (III) chloride
Description : When a co-ordination compound CrCl3.6H2O is mixed with AgNO3, 2 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex. (ii) IUPAC name of the complex. -Chemistry
Last Answer : (i) The complex formed on mixing a coordination compound CrCl3.6H2O with AgNO3 is as follows CrCl3.6H2O + AgNO3 → [Cr(H2O5)Cl]Cl2. H2O (ii) Pentaaquachloridochromium (III) chloride monohydrate
Description : Write the IUPAC name of [CO (NH3 ) 4 B12] 2 [ZnCl4 ].
Last Answer : Ans. Tetraamminedibromocobalt (III) tetrachlorozincate (II)
Description : Which is the correct order of decreasing acidity in the following compounds? A. H2O B. CH3CH3 C. NH3 D. CH2=CH2 E. HC≡CH (a) A > E > C > D > B (b) A > E > D > B > C (c) E > A > C > B > D (d) A > C > E > D > B
Last Answer : A > E > C > D > B
Description : Which of the following compounds is the strongest base? w) NH3 x) PH3 y) H2O z) H2S
Last Answer : ANSWER: W -- NH3
Description : Which of the following compounds is the strongest acid? w) NH3 x) PH3 y) H2O z) H2S
Last Answer : ANSWER: Z -- H2S
Description : Describe the shape and magnetic behaviour of following complexes : (i) [CO(NH3)6]3+ (ii) [Ni(CN)4]2- (At. No. Co = 27, Ni = 28) -Chemistry
Last Answer : (i) [CO(NH3)6]3+ : Orbitals of CO3+ ion : Hybridization : d2sp3 Shape : Octahedral Magnetic behaviour : Diamagnetic (absence of unpaired electrons) (ii) [Ni(CN)4]2-
Description : Compare the following complexes with respect to their shape, magnetic behaviour and the hybrid orbitals involved : (i) [CoF4]2- (ii) [Cr(H2O)2(C2O4)2]– (iii) [Ni(CO)4] (Atomic number : Co = 27, Cr = 24, Ni = 28) -Chemistry
Last Answer : (i) [COF4]2_ : Tetrafluorido cobalt (III) ion Coordination number = 4 Shape = Tetrahedral Hybridisation = sp3 Important Questions for Class 12 Chemistry Chapter 9 Coordination Compounds Class 12 Important Questions 7
Description : The correct IUPAC name of the compound `[Co(NH_(3))_(4)Cl(ONO)]Cl` is :
Last Answer : The correct IUPAC name of the compound `[Co(NH_(3))_(4)Cl(ONO)]Cl` is ... tetraamminecobalt(III) D. Tetraamminechloridonitrito-O-cobalt(III) chloride
Description : Give two examples of ligands which form coordination compounds useful in analytical chemistry. -Chemistry
Last Answer : Examples : (i) EDTA (Ethylene diamine tetra-acetic acid) (ii) Dimethyl glyoxime (DMG)
Description : (3) prevents freezing of petrol Explanation: Ethylene glycol (IUPAC name: ethane-1,2-diol) is an organic compound widely used as an automotive antifreeze and a precursor to polymers. In its pure form, it is ... A mixture of 60% ethylene glycol and 40% water freezes at -45 degree C (- 49 degree F).
Last Answer : Rust is - (1) A mixture of Fe₂O₃ and Fe(OH) ₂ (2) A mixture of FeO and Fe(OH)₂ (3) FeO only (4) A mixture of Fe₂O₃, 3H₂O and FeO
Description : Which type of intermolecular forces exists among the following molecules? (a) H2S molecules (b) H2O (c) Cl2 and CCl4 (d) SiH4 (e) Helium (f) He atoms and HCl molecules
Last Answer : Ans. (a) Dipole-Dipole interactions. (b)H-Bond. (c)Dispersion forces. (d)Dispersion forces. (e)Dispersion forces. (f)Induced dipole-dipole interactions.
Description : 1-Butene reacts with Cl2 in H2O to give (a) 1-Chloro-2-butanol (b) 2-Chloro-2-butanol (c) 1-Chloro-1-butanol (d) 2-Chloro-1-butanol
Last Answer : 1-Chloro-2-butanol
Description : Propene reacts with Cl2 in H2O to give (a) 1-Chloro-2-propanol (b) 2-Chloro-2-propanol (c) 1-Chloro-1-propanol (d) 2-Chloro-1-propano
Last Answer : 1-Chloro-2-propanol
Description : Which of the following molecules has a permanent electric dipole moment? w) H2O x) Cl2 y) CH4 z) N2
Last Answer : ANSWER: W -- H2O
Description : Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : [Co(NH3)6]+3, [Cr(NH3)6]3+, Ni(CO)4 (At. nos. : Co = 27, Cr = 24, Ni = 28) -Chemistry
Last Answer : (i) [Co(NH3)6]+3 → Octahedral shape, d2sp3 hybridisation, diamagnetic Formation of [Co(NH2)6]+3 → oxidation state of Co is +3.
Description : Explain why [Co(NH3)6]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital complex. (At. no. Co = 27, Ni = 28) -Chemistry
Last Answer : In [Co(NH3)6]3+, the d-electrons of Co3+ ([Ar]3d6 45°) get paired leaving behind two empty d-orbital and undergo d2sp3 hybridization and hence inner orbital complex, while in [Ni(NH3)6]2+ ... of Ni2+([Ar]3d8 45°) do not pair up and use outer 4d subshell hence outer orbital complex.
Description : Indicate the types of isomerisms exhibited by the complex [Co(NH3)5 (NO2)] (NO3)2. (At. no. Co = 27) -Chemistry
Last Answer : It shows ionisation isomerism and linkage isomerism.
Description : The IUPAC name of complex `[Cu(en)_(2)(H_(2)O)_(2)]^(22+)`
Last Answer : The IUPAC name of complex `[Cu(en)_(2)(H_(2)O)_(2)]^(22+)` A. ethylene ... C. diaquobisdietyleamineCU(II)ion D. diaquobis(ethylenediamine)cuprate(II)
Description : . Bromides contained in hot mother liquor is treated with __________ during manufacture of bromine from sea water. (A) SO3 (B) Cl2 (C) NH3 (D) SO2
Last Answer : (B) Cl2
Description : Identify the type of reaction(s) in the following equations. (i)CH4 + 2O2 CO2 + 2 H2O (ii) Pb(NO3)2 + 2KI ——–>Pbl2 + 2KNOs (iii) CaO + H2O ——–> Ca(OH)2 (iv) CuSO4 + Zn ——–> ZnSO4 + Cu -Chemistry
Last Answer : Answer. (i) Combustion reaction and oxidation reaction. (ii)Double displacement reaction and precipitation reaction. (iii) Combination reaction. (iv) Displacement reaction.
Description : Point group C2v belong to the molecule a. H2O b. BeH2 c. NH3 d. C2H2
Last Answer : a. H2O
Description : Using IUPAC norms write the formulae for the following: (i) Sodium dicyanidoaurate (I) (it) Tetraamminechloridonitrito-N-platinum (IV) sulphate -Chemistry
Last Answer : (i) Na[Au(CN)2] (ii) [Pt(NH3)4 Cl(NO2)] (SO4)
Description : Write IUPAC name of the complex: -Chemistry
Last Answer : Dichloridobis ethylenediamine cobalt (III) ion.
Description : Azo (pron: A-zo) Compounds characteristically are compounds containing the group: w) C2 x) N2 y) O2 z) Cl2
Last Answer : ANSWER: X -- N2 (N = N)
Description : What is the coordination number of an ion what is the coordination number of the cation (a) Na Cl structure and (b) Cs Cl structure explain the reason for this difference?
Last Answer : The coordination number is six for Na in NaCl.The coordination number is eight for Cs in CsCl. The accepted explanation is that the ionic radii of cesium and chloride are very similar.
Description : How many isomers are possible for a compound with formula, `[Rn(en)_(2)Cl(NO_(2))]` ?
Last Answer : How many isomers are possible for a compound with formula, `[Rn(en)_(2)Cl(NO_(2))]` ? A. 2 B. 4 C. 6 D. 8
Description : Give reasons i) H2O is a liquid but H2S a gas. ii) Ammonia has higher boiling point than phosphine ii) Krypton & xenon make compounds.
Last Answer : Ans: i) Hydrogen bond is found in H2O but not in H2S. ii) Hydrogen bond is found in NH3 but not in PH3. iii) Because they have low ionization energy.
Description : Co-ordination compounds `[Pt(NH_(3))_(3)(NCS)]` and `[Pt(NH_(3))_(2) Cl_(2)]Cl` are example of ........ Isomerism
Last Answer : Co-ordination compounds `[Pt(NH_(3))_(3)(NCS)]` and `[Pt(NH_(3))_(2) Cl_(2) ... isomerism B. linkage isomers C. optical isomerism D. hydrate isomerism
Description : Give an example of coordination isomerism. -Chemistry
Last Answer : Example : [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [CO(CN)6]
Description : CoCl2(en)2]+: Dichloridobis(ethylenediamine)Cobalt(III)ion. -Chemistry
Last Answer : Tetra amminechloridonitro cobalt (III) ion.
Description : Match each coordination compounds in List-I with an appropriate pair of characteristics from List-II and select the correct answer using the code give
Last Answer : Match each coordination compounds in List-I with an appropriate pair of characteristics from List-II and select the correct ... ,Q,R,S),(1,3,4,2):}`
Description : Identify the substances that are oxidised and the substances which are reduced in the following reactions. (i) 4Na(s) + O2(g) → 2Na2O(s) (ii) CuO (s) + H2(g) → Cu (s) + H2O(l) -Chemistry-10
Last Answer : (i) Substances oxidised is Na as it gains oxygen and oxygen is reduced. (ii) Substances reduced is Cu as hydrogen is oxidised as it gains oxygen.