In solid catalysed reactions the diffusional effects are more likely to affect the overall rate of reaction for (A) Fast reactions in catalyst of small pore diameter (B) Fast reaction in catalyst of large pore diameter (C) Slow reactions in catalyst of small pore diameter (D) Slow reactions in catalyst of large pore diameter

In solid catalysed reactions the diffusional effects are more likely to
affect the overall rate of reaction for
(A) Fast reactions in catalyst of small pore diameter
(B) Fast reaction in catalyst of large pore diameter
(C) Slow reactions in catalyst of small pore diameter
(D) Slow reactions in catalyst of large pore diameter
by

1 Answer

Answer :

(C) Slow reactions in catalyst of small pore diameter
by

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The importance of diffusion in a catalyst are increased by (A) Large catalyst particle size (B) An active surface of the catalyst (C) Small pore diameter (D) All (A), (B) and (C)

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What is the Thiele modulus of the solid catalysed first order reaction as shown in the bellow figure, if the pore diffusion offers negligible resistance to reaction? (A) < 5 (B) < 0.5(C) > 1 (D) 5

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For a solid catalysed chemical reaction, the effectiveness of solid catalyst depends upon the __________ adsorption. (A) Physical (B) Chemical (C) Both (A) and (B) (D) Neither (A) nor (B)

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The effectiveness factor for large value of Thiele modulus [L√(K/D1 )] of a solid catalysed first order reaction is equal to (where, L = length of the reactor, cm, D1 = diffusion co-efficient, cm2 /second). (A) L √(K/D1 ) (B) 1/[L√(K/D1 )] (C) 1 (D) ∞

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The Knudsen diffusivity is dependent on the (A) Molecular velocity only (B) Pore radius of the catalyst only (C) Molecular mean free path only (D) Molecular velocity and pore radius of the catalyst

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If Thiele modulus is __________, then the pore diffusion resistance in a catalyst may be considered as negligible. (A) 0 (B) ∞ (C) < 0.5 (D) > 0.5

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Helium-mercury method is used for the measurement of the __________ of the catalyst. (A) Surface area (B) Porosity (C) Pore volume (D) Both (B) & (C)

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Bulk diffusion in catalyst pore __________ with increase in pressure. (A) Increases (B) Decreases (C) Remains unchanged (D) Increases exponentially

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Brunauer, Emmet and Teller (BET) equation is used to determine the specific surface area of a porous particle but not the pore volume & the porosity of the catalyst bed. Which of the following postulates is not used to derive BET equation? (A) Langmuir's assumption applies to every adsorbed layer (B) There is no dynamic equilibrium between successive layer (C) The adsorbed layer may be polymolecular in thickness and the heat of adsorption in each layer (except the first one) is involved in each of the evaporation process (D) None of these

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Slam slam slam all day long slam slam slam some fast, some slow something solid. flat and sturdy its friend lights up the night and is sensitive to the eye slam slam slam A through Z 1,2,3 black as night. What am I? -Riddles

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