State the role of activated complex in a reaction and state the relation with energy of activation.

1 Answer

Answer :

Ans.: When the colliding reactant molecules possess the kinetic energy equal to energy of activation then the configuration of atoms of the species at this state is different from the reactants as well as the products.This state is called activated or transition state and specific configuration of this state is called activated complex.

The reactant molecules do not change directly into products, first they absorb energy equivalent to the energy of activation and form an activated complex. The activated complex formed has a very short life spam and splits into the products. The activated complex is at the top of the energy barrier graph and possess the highest energy. In this activated complex, all the bonds are in the transition state.

Low energy activation barrier means the activated complex is readily formed and it is fast reaction.

High energy of activation barrier means the activated complex is difficult to form and it is a slow reaction.

image  

Related questions

Description : Which of the following statements regarding the complement system are true? a. Complement activation yields products which are directly cytotoxic as well as products which act indirectly via activated ... and classical pathways converge proximal to generating the membrane attack complex (C5b-9)

Last Answer : Answer: a, d The complement system is composed of two different but linked sequences, the classic and alternative pathways. The pathways involve serum proteins that act to amplify the inflammatory-immune ... the C5 level proximal to generating the membrane attack complex (C5b-9) (Figure 6-3)

Description : For a heterogeneous catalytic reaction (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction (B) A relatively small amount of catalyst ... with the reactant (D) The surface of the catalyst does not play an important role during reaction

Last Answer : (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction

Description : Isoenzymes can be characterized by (A) Proteins lacking enzymatic activity that are necessary for the activation of enzymes (B) Proteolytic enzymes activated by hydrolysis (C) Enzymes with identical primary structure (D) Similar enzymes that catalyse different reaction

Last Answer : Answer : B

Description : Pick out the wrong statement. (A) Visible radiation provides the necessary activation energy in photochemical reactions (B) The order and molecularity of a complex reaction may not be the same (C) For ... rate constant (k) (D) Molecularity of the reaction is always a whole number greater than zero

Last Answer : (B) The order and molecularity of a complex reaction may not be the same

Description : The role of a catalyst in a chemical reaction is to change the (A) Equilibrium constant (B) Activation energy (C) Final products (D) Heat of reaction

Last Answer : (B) Activation energy

Description : The following are true about cell-mediated immunity: a. antigen-specific function is the role of the T-lymphocytes b. cell-mediated immunity can activate the complement system c. it is ... the delayed hypersensitivity reaction. d. Gamma interferon is an important mediator of B-cell activation.

Last Answer : cell-mediated immunity can activate the complement system

Description : The reaction step that has its transition state at the highest point on the reaction coordinate is the called the __________. (a) rate-determining step (b) activation energy (c) transition step (d) product favored step

Last Answer : rate-determining step

Description : An increase in which of the following results in a decrease in the rate of the chemical reaction? (a) temperature (b) concentration (c) collision frequency (d) energy of activation

Last Answer : energy of activation

Description : Which of the following is incorrect about heterogeneous catalysis? a. The most effective catalysts are those which have small surface area b. Seperation of catlyst is easy c. Increase in the rate of reaction is due to decrease in the activation energy d. It is based upon the phenomenon of adsorption

Last Answer : a. The most effective catalysts are those which have small surface area

Description : What happens when a catalyst is added to a system at equilibrium? A The reaction follows an alternative pathway of lower activation energy. B The heat of reaction decreases. C The potential ... decreases. D The potential energy of the products decreases. E The rate of chemical reaction decreases.

Last Answer : A The reaction follows an alternative pathway of lower activation energy.

Description : Which one of the following statements regarding a catalyst is not correct? A An enzyme is a catalyst that only binds certain substrates. B An enzyme is a protein that is a highly ... increasing the activation energy. D Catalysts do not alter the equilibrium constant for a chemical reaction.

Last Answer : C Catalysts increase the rate of a reaction by altering the mechanism, thereby increasing the activation energy.

Description : Role of an enzyme in reactions is to/as (a) decrease activation energy (b) increase activation energy (c) inorganic catalyst (d) none of the above.

Last Answer : (a) decrease activation energy

Description : __________ explains the mechanism of catalysis. (A) Activated complex theory (B) Collision theory (C) Thermodynamics (D) None of these

Last Answer : (A) Activated complex theory

Description : Fibrinolytic therapy is based on activation of plasminogen, the inactive proteolytic enzyme of plasma that binds to fibrin during the formation of thrombosis. Activation of plasminogen to plasmin results ... TPA all exceed 30 minutes d. Streptokinase is significantly cheaper than urokinase or TPA

Last Answer : Answer: a, b, d Streptokinase is a bacterial protein produced by group C b-hemolytic streptococci. It is therefore antigenic in humans and can be associated with allergic reaction in ... one agent over the other. Streptokinase however, is markedly less expensive than either urokinase or TPA

Description : The Golgi complex participates in (a) fatty acid breakdown (b) formation of secretory vesicles (c) respiration in bacteria (d) activation of amino acid

Last Answer : b) formation of secretory vesicles

Description : Dolichol phosphate is A- a complex lipid involved in docking vesicles with the plasma membrane B- the anchor on which sugars assemble before transfer to proteins C- a chaperone used in protein folding D- a product of phospholipase C activation

Last Answer : the anchor on which sugars assemble before transfer to proteins

Description : The Golgi complex participates in (1) Fatty acid breakdown (2) Formation of secretory vesicles (3) Respiration in bacteria (4) Activation of amino acid

Last Answer : (2) Formation of secretory vesicles

Description : Pick out the correct statement. (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state (C) A photochemical reaction is catalysed by ... occurs when the energy of the reacting molecule is less than the activation energy of the reaction

Last Answer : (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state

Description : If the activation energy of a biochemical reaction is lowered then?

Last Answer : What is the answer ?

Description : The energy required to start an enzymatic reaction is called (A) Chemical energy (B) Metabolic energy (C) Activation energy (D) Potential energy

Last Answer : Answer : C

Description : An enzyme brings about (A) Decrease in reaction time (B) Increase in reaction time (C) Increase in activation energy (D) Reduction in activation energy

Last Answer : Answer : D

Description : Enzymes increases the rate of reactions by (A) Increasing the free energy of activation (B) Decreasing the energy of activation (C) Changing the equilibrium constant of the reaction (D) Increasing the free energy change of the reaction

Last Answer : Answer : B

Description : An enzyme promotes a chemical reaction by (A) Lowering the energy of activation (B) Causing the release of heat which acts as a primer (C) Increasing molecular motion (D) Changing the free energy difference between substrate and product

Last Answer : Answer : A

Description : Enzymes increase the rates of reactions by (A) Increasing the free energy of activation (B) Decreasing the energy of activation (C) Changing the equilibrium constant of the reaction (D) Increasing the free energy change of the reaction

Last Answer : Answer : B

Description : Enzymes accelerate the rate of reactions by (A) Increasing the equilibrium constant of reactions (B) Increasing the energy of activation (C) Decreasing the energy of activation (D) Decreasing the free energy change of the reaction

Last Answer : Answer : C

Description : The difference between Threshold energy and average energy of the molecules is called activation energy. Ina chemical reaction lowers the rate of reaction the greater will be. The activation energy

Last Answer : How do you define the molecularity of a reaction ?

Description : The catalytic power of enzymes is due to (a) the presence of amino acids in their structures (b) their high molecular weight (c) their ability to lower the activation energy of the reaction (d) their limited solubility in water and other solvents

Last Answer : Ans:(c)

Description : A catalyst is a substance which (a) Changes the equilibrium of a reaction so that the concentration of the product increases (b) Increases the rate of reaction and increases the equilibrium concentration of products (c) Hastens the attainment of equilibrium (d) Increases the activation energy

Last Answer : Ans:(c)

Description : Which of the following step of translation does not consume a high energy phosphate bond? (a) Peptidyl transferase reaction (b) Aminoacyl tRNA binding to A-site (c) Translocation (d) Amino acid activation

Last Answer : (b) Aminoacyl tRNA binding to A-site

Description : Which of the following step of translation does not consume a high energy phosphate bond? (a) Peptidyl transferase reaction (b) Aminoacyl tRNA binding to A-site (c) Translocation (d) Amino acid activation

Last Answer : (a) Peptidyl transferase reaction

Description : When the reaction occurs in the diffusion controlled region, the apparent activation energy as measured is only __________ the true value. (A) Twice (B) Half (C) Equal (D) None of these

Last Answer : (B) Half

Description : Pick out the correct statement. (A) A lower temperature favours the reaction of lower activation energy (B) The dispersion number for a reactor/vessel is uL/D (C) The rate controlling step in ... step (D) Pore volume and porosity of a catalyst is measured by Brunauer￾Emmett-Teller (BET) technique

Last Answer : (A) A lower temperature favours the reaction of lower activation energy

Description : Enzymes (a protein) are catalysts found in organisms. Its efficiency of catalysing a reaction is due to its capacity to lower the activation energy of the reaction. The enzyme ptyalin used for food digestion is present in (A) Blood (B) Saliva (C) Intestine (D) Gland

Last Answer : (B) Saliva

Description : Pick out the wrong statement. (A) In a multistep reaction, the slowest step is the rate determining step (B) In general, the rate of a reaction becomes triple for every 10°C rise in temperature (C ... energy (D) Molecularity of a reaction cannot be zero but the order of a reaction can be zero

Last Answer : (B) In general, the rate of a reaction becomes triple for every 10°C rise in temperature

Description : In a reaction, the threshold energy is equal to (where, A = activation energy N = normal energy of reactants) (A) A (B) N (C) A + N (D) A - N

Last Answer : (C) A + N

Description : Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the ... ) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions

Last Answer : (C) The intercept of the Arrhenius plot is called the 'activation energy

Description : Photochemical reaction rate does not depend significantly on temperature, because (A) It is a reversible reaction (B) It is an exothermic reaction (C) The energy of reacting molecules exceeds the activation energy by absorption of light (D) None of these

Last Answer : (C) The energy of reacting molecules exceeds the activation energy by absorption of light

Description : Catalytic action in a catalytic chemical reaction follows from the ability of catalyst to change the (A) Activation energy (B) Equilibrium constant (C) Heat of reaction (D) None of these

Last Answer : (A) Activation energy

Description : A catalyst (A) Initiates a reaction (B) Lowers the activation energy of reacting molecules (C) Is capable of reacting with any one of the reactants (D) Cannot be recovered chemically unchanged at the end of a chemical reaction

Last Answer : (C) Is capable of reacting with any one of the reactants

Description : The reason why a catalyst increases the rate of reaction is that, it (A) Decreases the energy barrier for reaction (B) Increases the activation energy (C) Decreases the molecular collision diameter (D) None of these

Last Answer : (A) Decreases the energy barrier for reaction

Description : If the pore diffusion controls in a catalytic reaction, the apparent activation energy Ea is equal to (A) The intrinsic activation energy E (B) (E + ED) where ED is activation due to diffusion (C) (E + ED)/2 (D) ED/2

Last Answer : (D) ED/2

Description : Pick out the wrong statement: (A) Chemical reactions with high activation energy are very temperature sensitive (B) A flat velocity profile exists in a plug flow reactor (C) The residence ... D) Half life of a reaction increases with increased initial concentration for reaction orders more than one

Last Answer : (C) The residence time for all the elements of fluid in case of a P.F.R. need not be same

Description : Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to ... Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction

Last Answer : (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot

Description : Pick out the wrong statement. (A) Exit age description function (E) and internal age distribution function (I) are related as, E = -(dI/dθ) (B) Chemisorption studies are useful in the ... energy (D) A catalyst increases the potential energy barrier over which the reactants must pass to form products

Last Answer : (D) A catalyst increases the potential energy barrier over which the reactants must pass to form products

Description : The excess energy of reactants in a chemical reaction required to dissociate into products is termed as the __________ energy. (A) Activation (B) Potential (C) Binding (D) Threshold

Last Answer : (A) Activation

Description : The increase in the rate of reaction with temperature is due to (A) Increase in the number of effective collisions (B) Decrease in activation energy (C) Increase in the average kinetic energy of the reacting molecules (D) None of these

Last Answer : (B) Decrease in activation energy

Description : Pick out the wrong statement. (A) Catalytic activity of enzyme catalysed reactions which is affected by temperature, pH value & chemical agents, is maximum at a temperature of about 45°C ... in enzyme catalysed reactions can be calculated by using the thermodynamic properties of substrates & prod

Last Answer : (C) Enzymes help in increasing the activation energy of the reaction

Description : The minimum energy required to allow a chemical reaction to proceed is termed as the 'threshold energy '. Chemical reactions with low activation energy are: (A) Always irreversible (B) Insensitive to temperature changes (C) Mostly irreversible (D) Highly temperature sensitive

Last Answer : (B) Insensitive to temperature changes

Description : Threshold energy in a reaction is equal to the (A) Activation energy (B) Normal energy of reactants (C) Sum of (A) & (B) (D) Neither (A) nor (B)

Last Answer : (C) Sum of (A) & (B)