Out of benzene, m–dinitrobenzene and toluene which will undergo nitration most easily and why?

Out of benzene, m–dinitrobenzene and toluene which will undergo nitration most easily and why?
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Ans. -CH3 group is electron donating while –NO2 group is electron withdrawing. Therefore, maximum electron density will be in toluene , followed by benzene and at least in m-dinitrobenzene. Therefore, the ease of nitration decreases in the order: Toluene> benzene> m-dinitrobenzene
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Out of benzene, m–dinitrobenzene and toluene which will undergo nitration most easily and why?

Description : Out of benzene, m–dinitrobenzene and toluene which will undergo nitration most easily and why?

Last Answer : Ans. -CH3 group is electron donating while –NO2 group is electron withdrawing. Therefore, maximum electron density will be in toluene, followed by benzene and at least in m-dinitrobenzene. Therefore, the ease of nitration decreases in the order: Toluene> benzene> m-dinitrobenzene

Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.

Description : Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.

Last Answer : can be oxidized with KMnO4 to give benzoic acid

Explain the physical properties of benzene and its homologues.

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Which one is more stable structure of benzene among Kekule and Dewar’s structures?

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Compared to benzene, nitration of toluene takes place at (a) Same rate (b) Faster rate (c) Slower rate(d) Can not predict

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Last Answer : Faster rate

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Nitration of nitrobenzene with HNO3/H2SO4 gives : (a) m-dinitrobenzene (b) o-dinitrobenzene (c) p-dinitrobenzene (d) m-nitrobenzenesulfonic acid

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How will you detect the presence of unsaturation in an organic compound?

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Last Answer : Ans. Generally Unsaturated organic compound decolorize Bayer‘s reagent and Bromine water.

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Name two reagents which can be used to distinguish between ethene and ethyne.

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What are the necessary conditions for any system to be aromatic?

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Explain why Grignard reagents do not reacts with alkanes.

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What are the main constituent of LPG?

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Last Answer : Conformations are spatial arrangements which are obtained by rotation around sigma bonds.

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Resorcinol on distillation with zinc dust gives (a) Benzene (b) Cyclohexane (c) Toluene (d) m-Xylene

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Last Answer : Benzene

When propyne is passed through hot iron tube at 400°C, it gives (a) Benzene(b) Toluene(c) m-Xylene(d) Mesitylene

Description : When propyne is passed through hot iron tube at 400°C, it gives (a) Benzene (b) Toluene (c) m-Xylene (d) Mesitylene

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Which one of the following compounds would undergo nitration with greatest ease

Description : Which one of the following compounds would undergo nitration with greatest ease

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In the nitration of benzene with a mixture of conc. `HNO_(3)` and conc. `H_(2)SO_(4)`, the active species involved is :

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Nitration of benzene is:

Description : Nitration of benzene is:

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Chemical name of Gammaxane is - (1) Toluene (2) Chloro benzene (3) Aniline (4) Benzene hexachloride

Description : Chemical name of Gammaxane is - (1) Toluene (2) Chloro benzene (3) Aniline (4) Benzene hexachloride

Last Answer : (4) Benzene hexachloride Explanation: Gammexane is an insecticide that is the gamma isomer of benzene hexachloride. It is also known as lindane. Benzene hexachloride is any of several stereoisomers of 1,2,3,4,5,6- hexachlorocyclohexane formed by the lightinduced addition of chlorine to benzene.

A mixture of benzene and toluene forms (1) Non-ideal solution (2) Ideal solution (3) Emulsion (4) Suspension

Description : A mixture of benzene and toluene forms (1) Non-ideal solution (2) Ideal solution (3) Emulsion (4) Suspension

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Which of the following compounds is most readily sulfonated? (a) Benzene (b) Chlorobenzene (c) Toluene (d) Nitrobenzene

Description : Which of the following compounds is most readily sulfonated? (a) Benzene (b) Chlorobenzene (c) Toluene (d) Nitrobenzene

Last Answer : Toluene

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

Cresols on distillation with zinc dust gives (a) o-Xylene(b) Benzene(c) o- plus p-Xylene(d) Toluene

Description : Cresols on distillation with zinc dust gives (a) o-Xylene (b) Benzene (c) o- plus p-Xylene (d) Toluene

Last Answer : Toluene

Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with acidic KMnO4 solution. (c) on refluxing with concentrated H2SO4 gives a mixture of ortho and para toluenesulfonic acid. (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Description : Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with ... (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Last Answer : can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene

When acetylene is passed through hot iron tube at 400°C, it gives (a) Benzene (b) Toluene (c) o-Xylene (d) Mesitylene

Description : When acetylene is passed through hot iron tube at 400°C, it gives (a) Benzene (b) Toluene (c) o-Xylene (d) Mesitylene

Last Answer : Benzene

Chemical name of Gammaxane is (1) Toluene (2) Chloro benzene (3) Aniline (4) Benzene hexachloride

Description : Chemical name of Gammaxane is (1) Toluene (2) Chloro benzene (3) Aniline (4) Benzene hexachloride

Last Answer : Benzene hexachloride

Pick out the system with minimum boiling azeotrope at 1 atm. (A) Benzene-toluene (B) Ethyl alcohol-water (C) Hydrochloric acid-water (D) All (A), (B) and (C)

Description : Pick out the system with minimum boiling azeotrope at 1 atm. (A) Benzene-toluene (B) Ethyl alcohol-water (C) Hydrochloric acid-water (D) All (A), (B) and (C)

Last Answer : (B) Ethyl alcohol-water

Benzene cannot undergo – (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Description : Benzene cannot undergo – (1) Substitution (2) Addition (3) Elimination (4) Oxidation

Last Answer : (3) Elimination Explanation: Benzene can not undergo Elimination reaction.