How will you detect the presence of unsaturation in an organic compound?

1 Answer

Answer :

Ans. Generally Unsaturated organic compound decolorize Bayer‘s reagent and Bromine water.

Related questions

Description : Explain the physical properties of benzene and its homologues.

Last Answer : Ans: i. Benzene and its homologous upto eight carbon atoms are colourless liquids with characteristic smell. ii. Aromatic hydrocarbons are immiscible with water but soluble in organic solvents. iii. ... compounds increases with increase in molecular mass due to increase in van der waals forces.

Description : Out of benzene, m–dinitrobenzene and toluene which will undergo nitration most easily and why?

Last Answer : Ans. -CH3 group is electron donating while –NO2 group is electron withdrawing. Therefore, maximum electron density will be in toluene , followed by benzene and at least in m-dinitrobenzene. Therefore, the ease of nitration decreases in the order: Toluene> benzene> m-dinitrobenzene

Description : Which one is more stable structure of benzene among Kekule and Dewar’s structures?

Last Answer : Ans: Kekule’s structure.

Description : Define benzenoids Compounds.

Last Answer : Ans: Aromatic compounds containing benzene ring.

Description : Define Aromatic Compounds.

Last Answer : Ans: The Compounds which gives pleasant smell.

Description : What are alkanes? Why are they called paraffins?

Last Answer : Ans. Those hydrocarbons which contain single bond between carbon- carbon are called alkanes. They are called paraffins because they are very less reactive (Latin- Parum= little, affins = affinity)

Description : How will you separate propene from propyne?

Last Answer : Ans. By passing the mixture through ammonical silver nitrate solution when propyne reacts while propene passes over.

Description : How will you demonstrate that double bonds of benzene are somewhat different from that of olefins?

Last Answer : Ans. The double bonds of olefins decolorize bromine water and discharge the pink colour of Bayer‘s reagent while those of benzene not.

Description : What is Grignard reagent?

Last Answer : Ans. Alkyl magnesium halides

Description : What is meant by restricted rotation around of carbon-carbon double bond? What type of isomerism does it lead to?

Last Answer : Ans. The carbon-carbon double bond in alkene contains one sigma bond and one pi-bond. The Pibond involves the overlapping of unhybridised p orbital of two carbon atom .The rotation around the ... , the free rotation around C=C double bond is restricted, which gives rise to Geometrical Isomerism.

Description : Arrange the following in order of decreasing reactivity towards alkanes. HCl, HBr, HI, HF

Last Answer : Ans. HI> HBr> HCl >HF

Description : Name two reagents which can be used to distinguish between ethene and ethyne.

Last Answer : Ans. Tollen‘s reagent

Description : Out of ethylene and acetylene which is more acidic and why?

Last Answer : Ans. Acetylene, due to greater electonegativity of the sp hybridised carbon.

Description : Arrange the following in the increasing order of C-C bond length- C2H6 , C2H4, C2H2

Last Answer : Ans. C2H2 < C2H4 < C2H6

Description : What effect does branching of an alkane chain has on its boiling point?

Last Answer : Ans. As branching increases, the surface area of the molecule decreases which results in a small area of contact. As a result, the Van der Waals force also decreases which can be overcome at ... lower temperature. Hence, the boiling point of an alkane chain decreases with an increase in branching.

Description : What are the necessary conditions for any system to be aromatic?

Last Answer : Ans. A compound is said to be aromatic if it satisfies the following three conditions: (i) It should have a planar structure. (ii) The π-electrons of the compound are completely delocalized in the ring. (iii)The total number ... to (4n + 2), where n = 0, 1, 2 etc. This is known as Huckel s rule.

Description : Explain why Grignard reagents do not reacts with alkanes.

Last Answer : Ans. In alkanes , the C – H bond has very little polarity . The hydrogen cannot be abstracted by the Grignard reagent.

Description : What are the main constituent of LPG?

Last Answer : Ans. Butane and isobutane . Both these isomers can be easily liquified and hence can be conveniently transported in iron cylinder.

Description : Is it possible to isolate pure staggered ethane or pure eclipsed ethane at room temperature? Explain .

Last Answer : The energy differences between staggered and eclipsed forms of ethane is just 12.55 kj mol_1 which is easily met by collisions of the molecules at room temperature. Therefore, it is not possible to isolate either pure staggered or pure eclipsed ethane at room temperature.

Description : Which of the following has highest boiling point and why?(L-II) (a) 2 methylpentane (b) 2,3 dimethyl butane (c) 2,2 dimythylbutane

Last Answer : Ans. As the branching increases, surface area decreases. As a result, magnitude of Vander Waals forces of attraction decreases and hence the boiling point decreases. Thus, the overall order of decreasing boiling point is: 2 methylpentane (333k) > 2,3 dimethylbutane (331k) > 2,2 dimethylbutane(323k)

Description : Why do the C-C bonds rather than C-H bonds break during cracking of alkanes?

Last Answer : Ans. Since the bond dissociation energy of C-C bonds (348kj /mol) is lower than bond dissociation energy of C-H bonds (414kj/mol), therefore, during cracking of alkanes, C-C bonds break more early than C-H bonds.

Description : (a) What effect the branching of an alkane has on its melting point? (L-III) (b) Which of the following has highest boiling point?(L-III) (1) 2-methyl pentane. (2) 2, 3-diethyl butane. (3) 2, 2- dimethyl butane.

Last Answer : Ans.(a) In general conception, as the branching increases packing of the molecules in the crystals becomes less close and have melting point decreases accordingly. (b) As the branching increases, ... attraction decreases and hence the boiling point decreases. So, 2-methyl pentane has highest B.pt.

Description : Arrange the three isomers of pentane in increasing order of their boiling points?

Last Answer : Ans.2, 2-Dimethylpropane

Description : What do you mean by pyrolysis?

Last Answer : The decomposition of a compound by the heat is called pyrolysis. This process when applied to alkanes is known as cracking.

Description : Why are alkanes called paraffins?

Last Answer : Paraffin’s means little affinity; alkanes due to strong C-C and C-H bonds are relatively chemically inert.

Description : What are conformations?

Last Answer : Conformations are spatial arrangements which are obtained by rotation around sigma bonds.

Description : Iodine value is used to estimate – (1) Hydroxyl groups in oil (2) Alkali, content in oil (3) Unsaturation in oil (4) Carboxylic groups in oil

Last Answer : (3) Unsaturation in oil Explanation: Iodine value is used to estimate unsatwation in oil.

Description : The degree of unsaturation of a fat can be determined by means of its (a) Iodine number (b) Octane number (c) Saponification number (d) Melting point

Last Answer : Iodine number

Description : Fats differ from waxes in that fats have : (a) More unsaturation (b) Higher melting points (c) A glycerol backbone (d) Longer fatty acids

Last Answer : A glycerol backbone

Description : Iodine value is used to estimate (1) Hydroxyl groups in oil (2) Alkali content in oil (3) Unsaturation in oil (4) Carboxylic groups in oil

Last Answer : Unsaturation in oil

Description : High iodine value of a lipid indicates (A) Polymerization (B) Carboxyl groups (C) Hydroxyl groups (D) Unsaturation

Last Answer : Answer : D

Description : Iodine number denotes (A) Degree of unsaturation (B) Saponification number (C) Acid number (D) Acetyl number

Last Answer : Answer : A

Description : Saponification number indicates (A) Unsaturation in fat (B) Average M.W of fatty acid (C) Acetyl number (D) Acid number

Last Answer : Answer : B

Description : High acid value of an oil or fat is an indication of (A) Storage under improper conditions (B) Absence of unsaturation (C) Its smaller molecular weight (D) None of these

Last Answer : (A) Storage under improper conditions

Description : Pick out the wrong statement. Iodine value of an oil or fat is (A) The number of grams of iodine taken up by 100 gm of oil or fat (B) A measure of its unsaturation (C) Helpful in findings ... & its suitability for making soap (D) Independent of the type of oil, whether it is drying or non-drying

Last Answer : (D) Independent of the type of oil, whether it is drying or non-drying

Description : Saponification value/number of an oil or fat is a measure of its (A) Fatty acid content (B) Degree of unsaturation of the fatty acids present in it (C) Average molecular weight (D) Insoluble fatty acid content

Last Answer : (C) Average molecular weight

Description : Touch screen is an electronic ……….. display that can detect the presence and location of a touch within the display area. -Technology

Last Answer : Touch screen is an electronic visual display that can detect the presence and location of a touch within the display area.

Description : How could you detect the presence of Ag positive?

Last Answer : A reaction with a halide solution (ex. NaCl) is conclusive; a white precipitate of silver chloride is obtained.

Description : Radar is used for (a) Detecting objects by using light waves (b) Reflecting sound waves to detect objects (c) Determining the presence and location of objects with radio waves (d) Tracking rain-bearing clouds

Last Answer : Ans:(b)

Description : Name the solution used to detect the presence of glucose:?

Last Answer : Benedict solution

Description : An instrument used to detect and measure the presence of electrical current is generally called

Last Answer : galvanometer

Description : Intradermal drug sensitivity tests can detect the presence of following type of hypersensitivity: A. Type I (anaphylactic) B. Type II (cytolytic) C. Type III (retarded) D. All of the above

Last Answer : A. Type I (anaphylactic)

Description : Intradermal drug sensitivity tests can detect the presence of following type of hypersensitivity: A. Type I (anaphylactic) B. Type II (cytolytic) C. Type III (retarded) D. All of the above

Last Answer : A. Type I (anaphylactic)

Description : How would you detect presence of local attraction at a place ?

Last Answer : The presence of local attraction may be detected by finding difference of FB & BB of the line. If the fore bearing and back bearing difference is 1800 then there is no local attraction at both ... difference is not equal to 1800 then there is local attraction at both or any one station. 

Description : (1) the action of ultraviolet rays on oxygen Explanation: The majority of tropospheric ozone formation occurs when nitrogen oxides (NOx), carbon monoxide (CO ) and volatile organic compounds (VOCs), such as xylene, ... violet rays. NOx, CO, and VOCs are called ozone precursors. CO + 2O2 + CO2 + O3

Last Answer : Water is not effective in extinguishing a fire caused by petrol because - (1) the flame is too hot for water to cool it down (2) water and petrol react chemically (3) water and petrol are ... (4) water and petrol are immiscible with each other and petrol which forms the upper layer continues to burn

Description : What is the major organic product of the reaction between benzene and isobutyl chloride in the presence of AlCl3? (a) tert-butylbenzene (b) isobutylbenzene (c) n-butylbenzene (d) chlorobenzene

Last Answer : tert-butylbenzene

Description : What is the name of the first organic compound prepared from inorganic compounds ?

Last Answer : The first organic compound made from inorganic compound is called urea.

Description : What is Free Chain Organic Compound ?

Last Answer : Organic compounds that have free carbon atoms at the edges are called free chain organic compounds.

Description : (3) prevents freezing of petrol Explanation: Ethylene glycol (IUPAC name: ethane-1,2-diol) is an organic compound widely used as an automotive antifreeze and a precursor to polymers. In its pure form, it is ... A mixture of 60% ethylene glycol and 40% water freezes at -45 degree C (- 49 degree F).

Last Answer : Rust is - (1) A mixture of Fe₂O₃ and Fe(OH) ₂ (2) A mixture of FeO and Fe(OH)₂ (3) FeO only (4) A mixture of Fe₂O₃, 3H₂O and FeO

Description : The first organic compound synthesized in the laboratory was - (1) Urea (2) Uric acid (3) Lactic acid (4) Glucose

Last Answer : (1) Urea Explanation: In 1828, German chemist Friedrish Wohler synthesized first organic compound, urea in the laboratory by heating ammonium cyanate (an inorganic compound).