Description : The major product Y in the following sequence of reaction is: Aniline `overset((i) NaNO_(2)//HCl,273K)underset((ii)CuCN//KCN)to(X) overset((i)"DIBAL-H
Last Answer : The major product Y in the following sequence of reaction is: Aniline `overset((i) NaNO_(2)//HCl,273K)underset((ii)CuCN ... H_(2)O)to (Y)` A. B. C. D.
Description : The amount of heat liberated when one mole of `NH_(4)OH` reacts with one mole of HCl is
Last Answer : The amount of heat liberated when one mole of `NH_(4)OH` reacts with one mole of HCl is A. 13.7 ... Kcal C. Less than 13.7 Kcal D. Cannot be prodicted
Description : `Ph-NO_(2) overset(Sn//HCl)rarr underset("HCl, " 0^(@)C-5^(@)C)overset(NaNO_(2))rarr underset(Ph-OH)overset("Basic medium")rarr "Product Y"` Find the
Last Answer : `Ph-NO_(2) overset(Sn//HCl)rarr underset("HCl, " 0^(@)C-5^(@)C)overset(NaNO_(2) ... report your answer as `underset(2)overset("Molecular weight")rarr`
Description : How many N atom are present in final product `overset(Sn//HCl)rarr overset(NaNO_(2)//HCl)rarr overset(H_(3)PO_(2))rarr` Final product.
Last Answer : How many N atom are present in final product `overset(Sn//HCl)rarr overset(NaNO_(2)//HCl)rarr overset(H_(3)PO_(2))rarr` Final product.
Description : How many toluidines on reaction with `NaNO_(2)//HCl` followed by `H_(3)PO_(2)` treatment gives Toluene.
Last Answer : How many toluidines on reaction with `NaNO_(2)//HCl` followed by `H_(3)PO_(2)` treatment gives Toluene.
Description : `C_(6)H_(5)NH_(2) overset(NaNO_(2)+HCl)underset(0-5^(@)C) X overset(H_(2)O)underset(Delta)toY,` the product is :
Last Answer : `C_(6)H_(5)NH_(2) overset(NaNO_(2)+HCl)underset(0-5^(@)C) X overset(H_(2)O) ... : A. Benzenediazonium chloride B. Nitrobenzene C. Phenol D. Cresol
Description : In the reaction, `C_(6)H_(5)NH_(2)underset(0-5^(@)C)overset(NaNO_(2)+HCl)rarr(A)underset(KCN)overset(CuCN)rarr(B)overset(H^(+)//H_(2)O)rarr(C)` the pr
Last Answer : In the reaction, `C_(6)H_(5)NH_(2)underset(0-5^(@)C)overset(NaNO_(2)+HCl)rarr(A)underset(KCN)overset(CuCN ... COOH` C. `C_(6)H_(5)OH` D. none of these
Description : The product B of the following sequence of reactions is `C_(6)H_(5)CONH_(2) overset(Br_(2))underset(NaOH)toA overst(NaNO_(2)//HCl)underset(ul(" "0-5^(
Last Answer : The product B of the following sequence of reactions is `C_(6)H_(5)CONH_(2) overset(Br_(2))underset(NaOH)toA overst( ... 5^(@)C" "))toB` A. B. C. D.
Description : Which of the following compounds can form alcohol with `NaNO_(2)//HCl`?
Last Answer : Which of the following compounds can form alcohol with `NaNO_(2)//HCl`? A. B. C. `CH_(3)-CH_(2)-NH_(2)` D. All of these
Description : A liquid mixture contains 30% o-xylene, 60% p-xylene and 10%. mxylene (all percentages in w/w). Which of the following statements would be true in respect of this mixture? (A) The mixture exhibits ... : o-xylene 30, p-xylene 60 and m-xyoene 10 (D) The mixture contain optical isomers
Last Answer : (A) The mixture exhibits an azeotrope at 101.3 kPa
Description : One mole feed of a binary mixture of a given composition is flash vaporised at a fixed P and T. If Raoult's law is obeyed, then changing the feed composition would effect (A) ... The fraction vaporised but not the product composition (D) Neither the product composition nor the fraction vaporised
Last Answer : (C) The fraction vaporised but not the product composition
Description : (i) `NH_(3)` (ii) `N_(2)H_(4)` (iii) `HN_(3)` (iv) `PH_(3)` (v) `H_(2)S` (vi) `AsH_(3)` (vii) `SbH_(3)` (viii) `H_(2)Se` (ix) `H_(2)Te` Number of mole
Last Answer : (i) `NH_(3)` (ii) `N_(2)H_(4)` (iii) `HN_(3)` (iv) `PH_(3)` (v) `H_(2) ... lone pair of electrons on the central atom is present in pure s-orbital
Description : Which of the following compounds yields a yellow precipitate when warmed with a mixture of iodine in aqueous sodium hydroxide? (a) Acetophenone (b) Benzaldehyde (c) Benzophenone (d) Propanal
Last Answer : Acetophenone
Description : 1 g of complex `[Cr(H_(2)O)_(5)Cl]Cl_(2).H_(2)O` was passed through a cation exchanger to produce HCl. The acid liberated was diluted to 1 litre. What
Last Answer : 1 g of complex `[Cr(H_(2)O)_(5)Cl]Cl_(2).H_(2)O` was passed through a cation ... molarity of acid solution [Molecular weight of complex=266.5]?
Description : Componds `(A)` and `B` are treated with dilute `HCl` separately. The gases liberated are `Y` and `Z` respectively. `Y` turns acidified `K_2 Cr_2 O_7`
Last Answer : Componds `(A)` and `B` are treated with dilute `HCl` separately. The gases liberated are `Y` and `Z` ... )SO_(4)` D. `NaC1 and Na_(2)CO_(3)`
Description : Why is aniline soluble in aqueous HCl?
Last Answer : Why is aniline soluble in aqueous HCl?
Description : Which of the following reagents is used to prepare benzenediazonium chloride from aniline? (a) NaNO2 + HCl (b) LiAlH4 (c) NH2NH2 + KOH (d) NaOH
Last Answer : NaNO2 + HCl
Description : Aniline is prepared by (a) the reaction of benzene with ammonia (b) the reduction of nitrobenzene with Sn/HCl (c) the dehydrogenation of nitrobenzene (d) the reaction of nitrobenzene with I2/NaOH
Last Answer : the reduction of nitrobenzene with Sn/HCl
Description : Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl
Last Answer : It liberates nitrogen on treatment with ice-cold nitrous acid
Description : Which of the following statements is False/Incorrect about nitrobenzene? (a) is formed by nitration of benzene at temperatures below 60°C. (b) can be further nitrated to give m-dinitrobenzene. (c) can be oxidized with KMnO4 to give benzoic acid. (d) can be reduced with Sn/HCl to give aniline.
Last Answer : can be oxidized with KMnO4 to give benzoic acid
Description : Aquaregia is a mixture of the following in the ratio 1 : 3 by volume– (1) cone. HNO3 and cone. HCL (2) conc. HNO3 and conc. H2SO4 (3) dil. HCl and dil. HNO3 (4) cone. HCl and cone. HNO3
Last Answer : (3) dil. HCl and dil. HNO3 Explanation: Aqua regia or nitro-hydrochloric acid is a highly corrosive mixture of acids which is formed by freshly mixing concentrated Nitric acid (HNO3) and Hydrochloric acid (HCl), optimally in a volume ratio of 1:3. It is used in dissolving gold.
Description : Aquaregia is a mixture of the following in the ratio 1 : 3 by volume (1) conc. HNO3 and conc. HCl (2) conc. HNO3 and conc. H2 SO4 (3) dil. HCl and dil. HNO3 (4) conc. HCl and conc. HNO3
Last Answer : dil. HCl and dil. HNO3
Description : The relation among various mass transfer co-efficients (M.T.C) for ideal gases is given by (where, Kc & Km are M.T.C. for equimolar counter diffusion with concentration & mole fraction respectively as the driving ... (C) Kc = Kp . RT = Km . RT/p (D) None of these
Last Answer : (C) Kc = Kp . RT = Km . RT/p
Description : The decomposition of `N_(2)O_(5)` in chloroform was followed by measuring the volume of `O_(2)` gas evolved : `2N_(2)O_(5)(C C_(4))to2N_(2)O_(4)(C Cl_
Last Answer : The decomposition of `N_(2)O_(5)` in chloroform was followed by measuring the volume of `O_(2)` gas evolved : ... log"(90)/(100)` D. `(100)/(10xx500)`
Description : . An irreversible aqueous phase reaction, A + B → P, is carried out in an adiabatic mixed flow reactor. A feed containing 4kmole/m3 of each A and B enters the reactor at 8m3 /hr. If the temperature of ... be assumed to be independent of temperature and composition. (A) 190 (B) 290 (C) 390 (D) 490
Last Answer : (B) 290
Description : Two samples of `HCl` of `1.0 M` and `0.25 M` are mixed. Find volumes of these samples taken in order to prepare `0.75 M HCl` solution. Assume no water
Last Answer : Two samples of `HCl` of `1.0 M` and `0.25 M` are mixed. Find volumes of these samples taken in order ... B. 100mL, 50mL C. 40mL, 20mL D. 50mL, 25 mL
Description : Compound P on treatement with `CH_(2)N_(2)` (diazomethane) produces compound Q. compound Q on reaction with Hl produces two alkyl iodides R and S . Al
Last Answer : Compound P on treatement with `CH_(2)N_(2)` (diazomethane) produces compound Q. compound Q on reaction ... 2-methyl-2-propanol D. 2-methyl-1-propanol
Description : Heat engine deriving its power from the energy liberated by the explosion of a mixture of some hydrocarbon, in a gaseous or vaporized form. a. Dual Combustion Engine b. Internal Combustion Engine c. External Combustion Engine d. None of the above
Last Answer : Internal Combustion Engine
Description : Aniline reacts with mixed acid (conc. `HNO_(3)` and conc. `H_(2)SO_(4)`) at 288 K to give P (51%), Q (47%) and R(2%). The major product (s) of the fol
Last Answer : Aniline reacts with mixed acid (conc. `HNO_(3)` and conc. `H_(2)SO_(4)`) at 288 K to give P ... of the following reaction sequence is (are) B. C. D.
Description : 0.01 mole of iodoform `(CHI_(3))` reacts with Ag to produce a gas whose volume at NTP is `2CHI_(3)+6Ag to6Agl(s)+C_(2)H_(2)(g)`
Last Answer : 0.01 mole of iodoform `(CHI_(3))` reacts with Ag to produce a gas whose volume at NTP is `2CHI_(3)+6Ag ... mL B. 112 mL C. 336 mL D. None of these
Description : A batch adiabatic reactor at an initial temperature of 373°K is being used for the reaction, A → B. Assume the heat of reaction is - 1kJ/mole at 373°K and heat capacity of both A and B to be constant and equal ... rise after a conversion of 0.5 will be: (A) 5°C (B) 10°C (C) 20°C (D) 100°C
Last Answer : (B) 10°C
Description : The heat released by cooling one mole of copper from 400 K to room temperature (300 K) is (assume : Cp of copper is 23 J K-1mole-1) (A) 2300 J (B) 4600 J (C) 230 J (D) 2.3 × 106 J
Last Answer : A) 2300 J
Description : An ideal gas is heated at constant volume and then expanded isothermally. Show processes on P-V & T-S diagrams.
Last Answer : Process 1-2 : Constant volume process Process 2-3 : Constant temperature process (Isothermal process)
Description : Optically active amine having molecular formula `C_(5)H_(13)N` on reaction with `NaNO_(2)+HCI` produces, `3^(@)` optically inative alcohol. Find out s
Last Answer : Optically active amine having molecular formula `C_(5)H_(13)N` on reaction with `NaNO_(2)+HCI` produces, ` ... out structures of amines: A. B. C. D.
Description : Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and ... increases. (A) Decreases (B) Decreases exponentially (C) Increases (D) Remain constant
Last Answer : (C) Increases
Description : “The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture". This is (A) The statement as per Gibbs-Helmholtz (B) Called Lewis-Randall rule (C) Henry's law (D) None of these
Last Answer : (B) Called Lewis-Randall rule
Description : A pollutant P degrades according to first order kinetics. An aqueous stream containing P at 2 kmole/m3 and volumetric flow rate 1m3 /h requires a mixed flow reactor of volume V to bring down the pollutant level to 0.5 kmole/ ... reactor should be increased by a factor of: (A) 7 (B) 6 (C) 3 (D) 7/3
Last Answer : (A) 7
Description : The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of (A) T (B) T and P (C) T, P and Z (D) T and Z
Last Answer : (B) T and P
Description : 3, 3-Dimethyl-2-butanol no reaction with HCl yield mainly
Last Answer : 3, 3-Dimethyl-2-butanol no reaction with HCl yield mainly A. 2-Chloro-2, 3-dimethyl butane B. ... -3, 3-dimethylbutane D. 1-Chloro-3, 3-dimethylbutane
Description : Benzoic acid and diphenyl ketone are both solids insoluble in water. A mixture of these compounds can be separated if we (a) add the mixture to a solution of NaOH in water, and filter. (b) add ... benzene. (d) It is impossible to separate a mixture of two solids when both are insoluble in water.
Last Answer : add the mixture to a solution of NaOH in water, and filter
Description : Can the Percent yield be more than 100%? Why?
Last Answer : No, I will not stoop to doing your homework in exchange for lurve.
Description : Volume of `N_(2)` at 1 atm, 273 K required to form a monolayer on the surface of iron catalyst is `8.15ml//gm` of the adsorbent. What will be the surf
Last Answer : Volume of `N_(2)` at 1 atm, 273 K required to form a monolayer on the surface of iron catalyst is `8.15ml//gm` ... C. `39 m^(2)//g` D. `22400 cm^(2)`
Description : What is the yield per mole of the combustion of (algae-based) biodiesel fuel and/or how to find it?
Last Answer : answer:Welcome to Fluther. I'm not a chemist or a petroleum / fuels engineer, but it seems to me that the source of the fuel is immaterial. That is, if you have a diesel-like fuel , ... experimentally, and establish the value/s you seek on your own. Or am I missing something in your question?
Description : When equal weight of methyl alcohol and ehtyl alcohol react with excess of sodium metal, the volume of `H_(2)` liberated is more in the case of
Last Answer : When equal weight of methyl alcohol and ehtyl alcohol react with excess of sodium metal, the volume of `H_(2 ... in both D. `H_(2)` is not liberated
Description : What volume of `O_(2)` is liberated when 3 moles of `SO_(2)` reacts with sufficient volume of `O_(3)`
Last Answer : What volume of `O_(2)` is liberated when 3 moles of `SO_(2)` reacts with sufficient volume of `O_(3)` A. Zero B. 2 Vol C. 3 Vol D. `0.5` Vol
Description : Aniline point is the temperature at which (A) Equal weight of diesel & the aniline are completely miscible (B) Equal weight of aniline & the test sample are completely miscible (C) Equal volume of aniline & the test sample are completely miscible (D) Aniline vaporises
Last Answer : (C) Equal volume of aniline & the test sample are completely miscible
Description : An ideal gas of volume 1liter and pressure 10 bar undergoes a quasistatic adiabatic expansion until the pressure drops to 1 bar. Assume γ to be 1.4 what is the final volume? a. 3.18 l b. 4.18 l c. 5.18 l d. 6.18 l
Last Answer : 5.18 l
Description : For the dissociation reaction `N_(2)O_($) (g)hArr 2NO_(2)(g)`, the degree of dissociation `(alpha)`interms of `K_(p)` and total equilibrium pressure P
Last Answer : For the dissociation reaction `N_(2)O_($) (g)hArr 2NO_(2)(g)`, the degree of dissociation `(alpha)`interms ... =sqrt((K_(P))/(4P))` D. None of these
Description : p-bromoaniline is prepared from aniline via
Last Answer : p-bromoaniline is prepared from aniline via A. direct bromination of aniline in presence of Lewis ... in presence of light D. amination of bromine