Description : At a certain temperature T, the endothermic reaction `A rarr B` proceeds almost to completion.The entropy change is :
Last Answer : At a certain temperature T, the endothermic reaction `A rarr B` proceeds almost to completion.The entropy ... `Delta S gt 0` D. Cannot be predicted
Description : In which of the following reactions,standard reaction entropy change`(DeltaS^(@))`is positive and standard Gibb,s energy change`(DeltaG^(@))`decreases
Last Answer : In which of the following reactions,standard reaction entropy change`(DeltaS^(@))`is positive and standard Gibb,s ... (2)O_(2)(g)rarr CO_(2)(g)`
Description : What is meant by entropy driven reaction? How can the reaction with positive change of enthalpy and entropy be made entropy driven?
Last Answer : Ans.The free energy change of a reaction is given by ΔG = ΔH - TΔS For a reaction to be spontaneous, ΔG should be -ve. If both ΔH and ΔS are positive ΔG can be -ve if TΔS>ΔH in magnitude. Thus, entropy ... is low, TΔS should be greater than ΔH (ii) If ΔS is small, T should be so large that TΔS>ΔH.
Description : In which of the following reactions, standard reaction entropy change (S°) is positive and standard Gibb's energy change (G°) decreases sharply with increasing temperature? (1) 2 2 1 1 1 C graphite O (g) CO (g) 2 2 2 (2) 2 1 C ... CO(g) O (g) CO (g) 2 (4) 2 1 Mg(s) O (g) MgO(s) 2
Last Answer : C graphite O (g) CO(g)
Description : `CH_(3) equiv C CH_(3) overset(Na, NH_(3) (i))(rarr) Q overset("dil. Cold")underset(KMnO_(4))(rarr) R` If Q is an unsaturated hydrocarbon then product
Last Answer : `CH_(3) equiv C CH_(3) overset(Na, NH_(3) (i))(rarr) Q overset("dil. Cold")underset(KMnO_(4))(rarr) R` If ... ii & iii B. i & ii C. only v D. only iv
Description : Which of the following is NOT equivalent to `(P^^ ~ q) rarr r`
Last Answer : Which of the following is NOT equivalent to `(P^^ ~ q) rarr r` A. `~ (qv ~p) rarr r` B. `~ r rarr (~ p v q)` ... (~ p ^^ q)` D. `~((p^^(~q))^^(~r))`
Description : `(P) overset(NaH)rarr (Q) uarr overset(CuSO_(4))rarr (R) darr` black precipitate, (P) may be
Last Answer : `(P) overset(NaH)rarr (Q) uarr overset(CuSO_(4))rarr (R) darr` black precipitate, (P) may be A. `SCl_(2)` B. `PCl_(3)` C. `NCl_(3)` D. HCl
Description : `P+Q rarr Anisol e overset(HI)rarrR+S` Correct statement among the following is
Last Answer : `P+Q rarr Anisol e overset(HI)rarrR+S` Correct statement among the following is A. P and Q are `C_(6)H_(5)` ... Q are `C_(6)H_(5)C1` and `CH_(3)` Ona
Description : The Gibbs free energy change of a reaction at `27^(@)C` is -26 Kcal. and its entropy change is -60 Cals/K. `Delta H` for the reaction is :-
Last Answer : The Gibbs free energy change of a reaction at `27^(@)C` is -26 Kcal. and its entropy change is -60 Cals/K. ... Cals. C. 34 K. Cals. D. `-24` K. Cals.
Description : The enthalpy change for a given reaction at `298 K` is `-x cal mol^(-1)`. If the reaction occurs spontaneously at `298 K`, the entropy change at that
Last Answer : The enthalpy change for a given reaction at `298 K` is `-x cal mol^(-1)`. If the reaction occurs ... (-1)` C. Cannot be negative D. Cannot be positive
Description : The enthalpy and entropy change for the reaction, `Br_(2)(l)+Cl_(2)(g)rarr2BrCl(g)` are `30KJmol^(-1)` and `105JK^(-1)mol^(-1)` respectively. The temp
Last Answer : The enthalpy and entropy change for the reaction, `Br_(2)(l)+Cl_(2)(g)rarr2BrCl(g)` are `30KJmol^(-1)` and ` ... 285.7 K B. 273 K C. 450 K D. 300 K
Description : Entropy change of the reaction, H2O (liquid) → H2O (gas), is termed as the enthalpy of (A) Solution (B) Vaporisation (C) Formation (D) Sublimation
Last Answer : (B) Vaporisation
Description : What is the standard enthalpy change at 298 K for the following reaction? `CO_(2) (g)+ C("diamond") rarr 2CO(g)` Given : `DeltaH_(f)^(@)(CO,g) = - 110
Last Answer : What is the standard enthalpy change at 298 K for the following reaction? `CO_(2) (g)+ C("diamond") rarr 2CO(g ... `+172.5 kJ//mol` D. `170.5 kJ//mol`
Description : The enthalpy of formation of ammonia is `-46.0 KJ mol^(-1)` . The enthalpy change for the reaction `2NH_(3)(g)rarr N_(2)(g)+3H_(2)(g)` is :
Last Answer : The enthalpy of formation of ammonia is `-46.0 KJ mol^(-1)` . The enthalpy change for the reaction `2NH_(3)(g) ... mol^(-1)` D. `-92.0 KJ mol^(-1)`
Description : The value of enthalpy change `(DeltaH)` for the reaction `C_(2)H_(5)OH (l)+3O_(2) (g) rarr 2CO_(2) (g) +3H_(2)O (l)` at `27^(@)C` is `-1366.5 kJ mol^(
Last Answer : The value of enthalpy change `(DeltaH)` for the reaction `C_(2)H_(5)OH (l)+3O_(2) (g) rarr 2CO_(2) (g) + ... 1369. kJ` C. `-1364.0 kJ` D. `-1361.5 kJ`
Description : The enthalpy change `(Delta H)` for the reaction `N_(2) (g)+3H_(2)(g) rarr 2NH_(3)(g)` is `-92.38 kJ` at `298 K`. What is `Delta U` at `298 K`?
Last Answer : The enthalpy change `(Delta H)` for the reaction `N_(2) (g)+3H_(2)(g) rarr 2NH_(3)(g)` is `-92.38 kJ` at ` ... -87.42 kJ` C. `-97.34 kJ` D. `-89.9 kJ`
Description : A carbonyl compound (P) which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give an olefin (Q). Ozonolysis o
Last Answer : A carbonyl compound (P) which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give ... (S) is: A. B. C. D.
Last Answer : A carbonyl compound (P) which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration ... respectively, are: A. B. C. D.
Last Answer : A carbonyl compound (P) which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give ... (P) is: A. B. C. D.
Description : Assertion :- Entropy of system increases for a spontaneous reactions. Reason :- Enthalpy of reaction always decreases for spontaneous reaction.
Last Answer : Assertion :- Entropy of system increases for a spontaneous reactions. Reason :- Enthalpy of reaction ... D. If both Assertion & Reason are false.
Description : Calculate the entropy of `Br_(2)(g)` in the reaction `H_(2)(g)+Br_(2)(g)rarr2HBr(g), Delta S^(@)=20.1 JK^(-1)` given, entropy of `H_(2)` and HBr is 13
Last Answer : Calculate the entropy of `Br_(2)(g)` in the reaction `H_(2)(g)+Br_(2)(g)rarr2HBr(g), Delta S^(@)=20.1 JK^(-1 ... ` C. `24.63 JK^(-1)` D. `20 KJK^(-1)`
Description : Standard entropy of `X_(2)` , `Y_(2)` and `XY_(3)` are `60, 40 ` and `50JK^(-1)mol^(-1)` , respectively. For the reaction, `(1)/(2)X_(2)+(3)/(2)Y_(2)r
Last Answer : Standard entropy of `X_(2)` , `Y_(2)` and `XY_(3)` are `60, 40 ` and `50JK^(-1)mol^(-1)` , respectively ... be: A. 500 K B. 750 K C. 1000 K D. 1250 K
Description : What could Cause entropy to increase in a reaction?
Last Answer : Feel Free to Answer
Description : If a reaction has an enthalpy of -54.32 kJ/mol and an entropy of -354.2 J/(K*mol), what is the Gibbs free Energy at 54.3(degrees c)?
Last Answer : DeltaG = DeltaH - TDeltaS dG = -54.32 kJ/mol - (54'32+273)K(-354.2J/molK) NB Thevtemperature is quoted in Kelvin(K) and the Entropy must be converted to kJ by dividing by '1000'/ Hence dG = ... 115.94 kJ/mol dG = (+)61.61 kJ/mol Since dG is positive, the reaction is NOT thermodynamically feasible.
Description : If the rate of a chemical reaction becomes slower at a given temperature, then the (A) Initial concentration of the reactants remains constant (B) Free energy of activation is lower (C) Entropy changes (D) Free energy of activation is higher
Last Answer : (D) Free energy of activation is higher
Description : Third law of thermodynamics is helpful in (A) Prediction of the extent of a chemical reaction (B) Calculating absolute entropies of substances at different temperature (C) Evaluating entropy changes of chemical reaction (D) Both (B) and (C)
Last Answer : D) Both (B) and (C)
Description : The first law of thermodynamics is based on which of the following principles? a. Conservation of mass b. Conservation of energy c. Action and reaction d. The entropy-temperature relationship
Last Answer : Conservation of energy
Description : The first law of thermodynamics is based on which of the following principles? a. conservation of mass b. the enthalpy-entropy relationship c. action – reaction d. conservation of energy
Last Answer : conservation of energy
Description : What is the energy absorbed during chemical reaction under constant volume conditions? A. Entropy B. Ion exchange C. Enthalpy D. Enthalpy of reaction
Last Answer : Enthalpy
Description : The first law of thermodynamics is based on which of the following principles? A. Conservation of mass B. Conservation of energy C. Action and reaction D. The entropy-temperature relationship
Description : In any chemical reaction, a quantity that decrease to a minimum is: w) free energy x) entropy y) temperature z) enthalpy
Last Answer : ANSWER: W -- FREE ENERGY
Description : For the given reaction , `A(g) rarr 2B(g) , Delta_(r)H= 30 kJ//"mole" Delta_(r)S = 150 J//mol` at `300 K` If `C_(P,A) = 20 J//K mol` and `C_(P,B) = 20
Last Answer : For the given reaction , `A(g) rarr 2B(g) , Delta_(r)H= 30 kJ//"mole" Delta_(r)S = 150 J//mol` at ... G` is negative D. At `T = 200, Delta G` is zero
Description : `underset(OH^(Ɵ))overset("Conc.")rarr` Incorrect statement (s) reagarding the reaction is/are:
Last Answer : `underset(OH^(Ɵ))overset("Conc.")rarr` Incorrect statement (s) reagarding the reaction is/are: ... . D. Reaction is an example of redox reaction
Description : In the redox reaction . `MnO_(4)^(-)+C^(2)O_(4)^(2-)+H^(+) rarr Mn^(2+)+CO_(2)+H_(2)O` (Unbalance equation) 20 mL of 0.1 M `KMnO_(4)` react quantitive
Last Answer : In the redox reaction . `MnO_(4)^(-)+C^(2)O_(4)^(2-)+H^(+) rarr Mn^(2+)+CO_(2)+H_(2)O` ( ... . 40 mL of 0.1 M oxalate D. 50 mL of 0.25 M oxalate
Description : For a reaction `CH_(3)OCH_(3) (g) rarr CH_(4) (g)+H_(2) (g)+CO(g)` at 750K, the rate constant is `3.52xx10^(-3)" min"^(-1)`. Starting with a pressure
Last Answer : For a reaction `CH_(3)OCH_(3) (g) rarr CH_(4) (g)+H_(2) (g)+CO(g)` at 750K, the rate constant ... to become 760 mm Hg ? (Take log 2.25 = 0.352)
Description : Givecn that : `Zn+1//2O_(2)rarr ZnO+84000` cal ……………1 `Hg+1//2O_(2)rarr HgO+21700` cal …………2 The heat of reaction `(Delta H)` for, `Zn+HgO rarr ZnO+Hg
Last Answer : Givecn that : `Zn+1//2O_(2)rarr ZnO+84000` cal 1 `Hg+1//2O_(2)rarr HgO+21700` cal 2 ... cal B. 62300 cal C. `-105700` cal D. `-62300` cal
Description : The heat of reaction of `A+(1)/(2)O_(2)rarr AO` is -50 K call and `AO+(1)/(2)O_(2)rarr AO_(2)` is 100 Kcal. The heat of reaction for `A+O_(2)rarr AO_(
Last Answer : The heat of reaction of `A+(1)/(2)O_(2)rarr AO` is -50 K call and `AO+(1)/(2)O_(2)rarr AO_(2)` is 100 ... . B. `+50` K cal C. 100 K cal. D. 150 K cal.
Description : `Delta H` for the reaction, `I_((g))+I_((g))rarr I_(2(g))` will be :-
Last Answer : `Delta H` for the reaction, `I_((g))+I_((g))rarr I_(2(g))` will be :- A. Zero B. `-ve` C. `+ve` D. `oo`
Description : From the reaction P(White) `rarr` P(Red) `Delta H =-18.4KJ`, it follows that :-
Last Answer : From the reaction P(White) `rarr` P(Red) `Delta H =-18.4KJ`, it follows that :- A. Red P is ... P can be converted into red P and red P is more stable
Description : According to the following reaction `C(S)+1//2O_(2)(g)rarr CO(g), Delta H=-26.4` Kcal
Last Answer : According to the following reaction `C(S)+1//2O_(2)(g)rarr CO(g), Delta H=-26.4` Kcal ... compound C. The reaction is endothermic D. None of the above
Description : For the reaction `Ag_(2)O(s)rarr 2Ag(s)+1//2O_(2)(g)` the value of `Delta H=30.56 KJ mol^(_1)` and `Delta S = 66 JK^(-1)mol^(-1)`. The temperature at
Last Answer : For the reaction `Ag_(2)O(s)rarr 2Ag(s)+1//2O_(2)(g)` the value of `Delta H=30.56 KJ mol^(_1)` and `Delta ... :- A. 373 K B. 413 K C. 463 K D. 493 K
Description : The temperature at which the reaction : `Ag_(2)O(s)rarr 2Ag(s)+1//2O_(2)(g)` is at equilibrium is …….., Given `Delta H=30.5 KJ mol^(-1)` and `Delta S
Last Answer : The temperature at which the reaction : `Ag_(2)O(s)rarr 2Ag(s)+1//2O_(2)(g)` is at equilibrium is .., ... 362.12 K` C. `262.12 K` D. `562.12 K`
Description : For a reaction `2X(s)+2Y(s)rarr 2Cl(l)+D(g)` The `q_(p)` at `27^(@)C` is -28 K Cal. `mol^(-1)`. The `q_(V)` is ___________ K. Cal. `mol^(-1)` :-
Last Answer : For a reaction `2X(s)+2Y(s)rarr 2Cl(l)+D(g)` The `q_(p)` at `27^(@)C` is -28 K Cal. `mol^(-1)`. The `q_( ... . `-27.4` B. `+27.4` C. `-28.6` D. `28.6`
Description : For the reaction `CO(g)+(1)/(2)O_(2)(g)rarr CO_(2)(g)` Which one of the statement is correct at constant T and P ?
Last Answer : For the reaction `CO(g)+(1)/(2)O_(2)(g)rarr CO_(2)(g)` Which one of the statement is ... ` D. `Delta H` is independent of physical state of reactants
Description : `Delta S` for the reaction , `MgCO_(3)(s)rarr MgO(s)+CO_(2)(g)` will be :
Last Answer : `Delta S` for the reaction , `MgCO_(3)(s)rarr MgO(s)+CO_(2)(g)` will be :
Description : For the reaction `Ag_(2)O(s)rarr 2Ag(s)+1//2O_(2)(g)`, which one of the following is true :
Last Answer : For the reaction `Ag_(2)O(s)rarr 2Ag(s)+1//2O_(2)(g)`, which one of the following is true : A. ` ... . `Delta H lt Delta H` D. `Delta H gt Delta E`
Last Answer : For the reaction `CO(g)+(1)/(2)O_(2)(g)rarr CO_(2)(g)` Which one of the statement is correct at ... ` C. `Delta H lt Delta E` D. None of the above
Description : Heat of reaction for, `CO(g)+1//2O_(2)(g)rarr CO_(2)(g)` at constant V is -67.71 K cal at `17^(@)C` . The heat of reaction at constant P at `17^(@)C`
Last Answer : Heat of reaction for, `CO(g)+1//2O_(2)(g)rarr CO_(2)(g)` at constant V is -67.71 K cal at `17^(@)C` . ... B. `+68.0` K cal C. `-67.4` K cal D. None
Description : Which is the best description of the behaviour of bromine in the reaction given below `H_(2)O+Br_(2) rarr HOBr+HBr`
Last Answer : Which is the best description of the behaviour of bromine in the reaction given below `H_(2)O+ ... . Oxidized C. Reduced only D. Proton acceptor only