Description : For a gaseous reaction, `A(g)+3B(g)to3C(g)+3D(g),DeltaU` is 17 kcal at `27^(@)C`. Assuming `R=2cal" "K^(-1)mol^(-1)`, the value of `DeltaH` for the ab
Last Answer : For a gaseous reaction, `A(g)+3B(g)to3C(g)+3D(g),DeltaU` is 17 kcal at `27^(@)C`. Assuming `R=2cal" " ... Kcal B. 18.2 Kcal C. 20.0 Kcal D. 16.4 Kcal
Description : According to the following reaction `C(S)+1//2O_(2)(g)rarr CO(g), Delta H=-26.4` Kcal
Last Answer : According to the following reaction `C(S)+1//2O_(2)(g)rarr CO(g), Delta H=-26.4` Kcal ... compound C. The reaction is endothermic D. None of the above
Description : If a reaction has an enthalpy of -54.32 kJ/mol and an entropy of -354.2 J/(K*mol), what is the Gibbs free Energy at 54.3(degrees c)?
Last Answer : DeltaG = DeltaH - TDeltaS dG = -54.32 kJ/mol - (54'32+273)K(-354.2J/molK) NB Thevtemperature is quoted in Kelvin(K) and the Entropy must be converted to kJ by dividing by '1000'/ Hence dG = ... 115.94 kJ/mol dG = (+)61.61 kJ/mol Since dG is positive, the reaction is NOT thermodynamically feasible.
Description : If, `H_(2)(g)+Cl_(2)(g)rarr 2HCl(g) , Delta H^(@)=-44` Kcal `2Na(s)+2HCl(g)rarr 2NaCl(s)+H_(2)(g), Delta H=-152` Kcal Then, `Na(s)+0.5Cl_(2)(g)rarr Na
Last Answer : If, `H_(2)(g)+Cl_(2)(g)rarr 2HCl(g) , Delta H^(@)=-44` Kcal `2Na(s)+2HCl(g)rarr 2NaCl(s)+H_(2)( ... ` A. 108 Kcal B. 196 Kcal C. `-98` Kcal D. 54 Kcal
Description : Calculate the entropy of `Br_(2)(g)` in the reaction `H_(2)(g)+Br_(2)(g)rarr2HBr(g), Delta S^(@)=20.1 JK^(-1)` given, entropy of `H_(2)` and HBr is 13
Last Answer : Calculate the entropy of `Br_(2)(g)` in the reaction `H_(2)(g)+Br_(2)(g)rarr2HBr(g), Delta S^(@)=20.1 JK^(-1 ... ` C. `24.63 JK^(-1)` D. `20 KJK^(-1)`
Description : In which of the following reactions, standard reaction entropy change (S°) is positive and standard Gibb's energy change (G°) decreases sharply with increasing temperature? (1) 2 2 1 1 1 C graphite O (g) CO (g) 2 2 2 (2) 2 1 C ... CO(g) O (g) CO (g) 2 (4) 2 1 Mg(s) O (g) MgO(s) 2
Last Answer : C graphite O (g) CO(g)
Description : (∂H/∂T)P is the mathematical expression for (A) CV (B) Entropy change (C) Gibbs free energy (D) None of these
Last Answer : (D) None of these
Description : Specific __________ does not change during a phase change (e.g. sublimation, melting, vaporisation etc.). (A) Entropy (B) Internal energy (C) Enthalpy (D) Gibbs free energy
Last Answer : (D) Gibbs free energy
Description : _________ does not change during phase transformation processes like sublimation, melting & vaporisation. (A) Entropy (B) Gibbs free energy (C) Internal energy (D) All (A), (B) & (C)
Last Answer : (B) Gibbs free energy
Description : If the enthaply change for the transition of liquid water to steam is 30 KJ `"mol"^(-1)` at `27^(@)` C . The entropy change for the process would be
Last Answer : If the enthaply change for the transition of liquid water to steam is 30 KJ `"mol"^(-1)` at `27^(@)` C . The ... K^(-1)` D. `100 J mol^(-1)K^(-1)`
Description : Boiling of liquid is accompanied with increase in the (A) Vapor pressure (B) Specific Gibbs free energy (C) Specific entropy (D) All (A), (B) and (C)
Last Answer : (A) Vapor pressure
Description : Specific __________ does not change during phase change at constant temperature and pressure. (A) Entropy (B) Gibbs energy (C) Internal energy (D) Enthalpy
Last Answer : (B) Gibbs energy
Description : In which of the following reactions,standard reaction entropy change`(DeltaS^(@))`is positive and standard Gibb,s energy change`(DeltaG^(@))`decreases
Last Answer : In which of the following reactions,standard reaction entropy change`(DeltaS^(@))`is positive and standard Gibb,s ... (2)O_(2)(g)rarr CO_(2)(g)`
Description : Assertion :- At constant temp `0^(@)C` and 1 atm, the change `H_(2)O(s)rarr H_(2)O(l)Delta H` and `Delta E` both are zero. Reason :- During isothermal
Last Answer : Assertion :- At constant temp `0^(@)C` and 1 atm, the change `H_(2)O(s)rarr H_(2)O(l) ... Reason is False. D. If both Assertion & Reason are false.
Description : For a reaction `2X(s)+2Y(s)rarr 2Cl(l)+D(g)` The `q_(p)` at `27^(@)C` is -28 K Cal. `mol^(-1)`. The `q_(V)` is ___________ K. Cal. `mol^(-1)` :-
Last Answer : For a reaction `2X(s)+2Y(s)rarr 2Cl(l)+D(g)` The `q_(p)` at `27^(@)C` is -28 K Cal. `mol^(-1)`. The `q_( ... . `-27.4` B. `+27.4` C. `-28.6` D. `28.6`
Description : The enthalpy change `(Delta H)` for the reaction `N_(2) (g)+3H_(2)(g) rarr 2NH_(3)(g)` is `-92.38 kJ` at `298 K`. What is `Delta U` at `298 K`?
Last Answer : The enthalpy change `(Delta H)` for the reaction `N_(2) (g)+3H_(2)(g) rarr 2NH_(3)(g)` is `-92.38 kJ` at ` ... -87.42 kJ` C. `-97.34 kJ` D. `-89.9 kJ`
Description : Using the following thermochemical data. `C(S)+O_(2)(g)rarr CO_(2)(g), Delta H=94.0` Kcal `H_(2)(g)+1//2O_(2)(g)rarr H_(2)O(l), Delta H=-68.0` Kcal `C
Last Answer : Using the following thermochemical data. `C(S)+O_(2)(g)rarr CO_(2)(g), Delta H=94.0` Kcal `H_(2)(g)+1// ... .0` Kcal C. `-114.0` Kcal D. `+114.0` Kcal
Description : Given that standard heat enthalpy of `CH_(4), C_(2)H_(4)` and `C_(3)H_(8)` are -17.9, 12.5, -24.8 Kcal/mol. The `Delta H` for `CH_(4)+C_(2)Hrarr C_(3)
Last Answer : Given that standard heat enthalpy of `CH_(4), C_(2)H_(4)` and `C_(3)H_(8)` are -17.9, 12.5, -24.8 Kcal ... . `-30.2` Kcal C. 55.2 Kcal D. `-19.4` Kcal
Description : A solid metallic block weighing 5 kg has an initial temperature of 500°C. 40 kg of water initially at 25°C is contained in a perfectly insulated tank. The metallic block is brought into contact with water. Both of them come to equilibrium. ... .kg-1, K-1is (A) -1.87 (B) 0 (C) 1.26 (D) 3.91
Last Answer : (B) 0
Description : The difference in `Delta H` and `Delta E` for the combustion of methane at `25^(@)C` would be :-
Last Answer : The difference in `Delta H` and `Delta E` for the combustion of methane at `25^(@)C` would be :- A ... Cals C. `2xx298xx -3` Cals D. `2xx25xx -3` Cals
Last Answer : The difference in `Delta H` and `Delta E` for the combustion of methane at `25^(@)C` would be :- A ... cals C. `2xx298xx -3` cals D. `2xx25xx -3` cals
Description : For `CaCO_(3)(s)rarr CaO(s)+CO_(2)(g)` at `977^(@)C, Delta H = 174` KJ/mol , then `Delta E` is :-
Last Answer : For `CaCO_(3)(s)rarr CaO(s)+CO_(2)(g)` at `977^(@)C, Delta H = 174` KJ/mol , then `Delta E` is :- A. 160 KJ B. 163.6 KJ C. 186.4 KJ D. 180 KJ
Description : Assertion :- Catalyst change Gibbs free energy of system. Reason :- Catalyst changes preexponential factor of a chemical reaction.
Last Answer : Assertion :- Catalyst change Gibbs free energy of system. Reason :- Catalyst changes preexponential factor ... . If both Assertion & Reason are false.
Description : The standard Gibbs free energy change of a reaction depends on the equilibrium (A) Pressure (B) Temperature (C) Composition (D) All (A), (B) and (C)
Last Answer : (B) Temperature
Description : Gibbs free energy (G) is represented by, G = H - TS, whereas Helmholtz free energy, (A) is given by, A = E - TS. Which of the following is the Gibbs Helmholtz equation? (A) [∂(G/T)/∂T] = - (H/T2) (B) [∂(A/T)/∂T]V = - E/T2 (C) Both (A) and (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) and (B)
Description : The value of enthalpy change `(DeltaH)` for the reaction `C_(2)H_(5)OH (l)+3O_(2) (g) rarr 2CO_(2) (g) +3H_(2)O (l)` at `27^(@)C` is `-1366.5 kJ mol^(
Last Answer : The value of enthalpy change `(DeltaH)` for the reaction `C_(2)H_(5)OH (l)+3O_(2) (g) rarr 2CO_(2) (g) + ... 1369. kJ` C. `-1364.0 kJ` D. `-1361.5 kJ`
Description : Given that the standard free energy change (∆G°) for the hydrolysis of ATP is -7.3 K cal/mol and that for the hydrolysis of Glucose 6-phosphate is -3.3 Kcal/mol, the ∆G° for the phosphorylation of glucose is Glucose + ATP → ... -10.6 Kcal/mol (B) -7.3 Kcal/mol (C) -4.0 Kcal/mol (D) +4.0 Kcal/mol
Last Answer : Answer : C
Description : Pick out the wrong statement. (A) Cp of monatomic gases such as metallic vapor is about 5 kcal/kg.atom (B) The heat capacity of solid inorganic substance is exactly equal to the ... isolated system (D) At absolute zero temperature, the heat capacity for many pure crystalline substances is zero
Last Answer : (C) There is an increase in entropy, when a spontaneous change occurs in an isolated system
Description : A proton of mass `1.67xx10^(-27)` kg charge `1.6xx10^(-19) C` is projected in xy-plane with a speed of `2xx10^(6) m//s` at an angle of `60^(@)` to the
Last Answer : A proton of mass `1.67xx10^(-27)` kg charge `1.6xx10^(-19) C` is projected in xy-plane with a speed ... radius 0.14 m and time period `1.0xx10^(-7)s`
Description : If `Delta G^(@)gt 0` for a reaction then :
Last Answer : If `Delta G^(@)gt 0` for a reaction then : A. `K_(P) gt 1` B. `K_(P) lt 1` C. The products predominate in the equilibrium mixture D. None
Description : What are X and Y in the reaction `C_(2)H_(4) + H_(2)SO_(4) overset(80^(@)C)rarr X overset(H_(2)O//Delta)rarr Y`
Last Answer : What are X and Y in the reaction `C_(2)H_(4) + H_(2)SO_(4) overset(80^(@)C)rarr X overset(H_(2)O//Delta) ... C_(2)H_(5)OH` D. `C_(2)H_(2), CH_(3)CHO`
Description : A perfect gas has a value of R= 319.2 J/ kf.K and k= 1.26. If 120 kJ are added to 2.27 kf\g of this gas at constant pressure when the initial temp is 32.2°C? Find T2. a. 339.4 K b. 449.4 K c. 559.4K d. 669.4K formula: cp = kR/ k-1 Q= mcp(T2-T1)
Last Answer : 339.4 K
Description : A software project was estimated at 352 Function Points (FP). A four person team will be assigned to this project consisting of an architect, two programmers, and a tester. The salary of the architect is Rs.80,000 per month, the ... ) Rs.28,16,000 (2) Rs.20,90,000 (3) Rs.26,95,000 (4) Rs.27,50,000
Last Answer : (4) Rs.27,50,000
Description : What is the standard enthalpy change at 298 K for the following reaction? `CO_(2) (g)+ C("diamond") rarr 2CO(g)` Given : `DeltaH_(f)^(@)(CO,g) = - 110
Last Answer : What is the standard enthalpy change at 298 K for the following reaction? `CO_(2) (g)+ C("diamond") rarr 2CO(g ... `+172.5 kJ//mol` D. `170.5 kJ//mol`
Description : The enthalpy change for a given reaction at `298 K` is `-x cal mol^(-1)`. If the reaction occurs spontaneously at `298 K`, the entropy change at that
Last Answer : The enthalpy change for a given reaction at `298 K` is `-x cal mol^(-1)`. If the reaction occurs ... (-1)` C. Cannot be negative D. Cannot be positive
Description : If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as (A) Solubility increases as temperature ... (D) Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution
Last Answer : (B) Solubility increases as temperature decreases
Description : Specific/molar Gibbs free energy for a pure substance does not change during (A) Sublimation (B) Vaporisation (C) Melting (D) Either (A), (B) or (C)
Last Answer : (D) Either (A), (B) or (C)
Description : The change in Gibbs free energy for vaporisation of a pure substance is (A) Positive (B) Negative (C) Zero (D) May be positive or negative
Last Answer : (C) Zero
Description : The change in __________ is equal to the reversible work for compression in steady state flow process under isothermal condition. (A) Internal energy (B) Enthalpy (C) Gibbs free energy (D) Helmholtz free energy
Last Answer : (C) Gibbs free energy
Description : `C(s)+O_(2)(g)rarr CO_(2)(g)+94.0` K cal. `CO(g)+(1)/(2)O_(2)(g)rarr CO_(2)(g), Delta H=-67.7` K cal. From the above reactions find how much heat (Kca
Last Answer : `C(s)+O_(2)(g)rarr CO_(2)(g)+94.0` K cal. `CO(g)+(1)/(2)O_(2)(g)rarr CO_(2)(g), Delta H=-67.7` K cal. ... g)` A. `20.6` B. `26.3` C. `44.2` D. `161.6`
Description : For the reversible isothermal expansion of one mole of an ideal gas at 300 K, from a volume of `10 dm^(3)` to `20 dm^(3), Delta H` is -
Last Answer : For the reversible isothermal expansion of one mole of an ideal gas at 300 K, from a volume of `10 dm^(3)` to ` ... . `-1.73 KJ` C. `3.46 KJ` D. Zero
Description : The heat of reaction of `A+(1)/(2)O_(2)rarr AO` is -50 K call and `AO+(1)/(2)O_(2)rarr AO_(2)` is 100 Kcal. The heat of reaction for `A+O_(2)rarr AO_(
Last Answer : The heat of reaction of `A+(1)/(2)O_(2)rarr AO` is -50 K call and `AO+(1)/(2)O_(2)rarr AO_(2)` is 100 ... . B. `+50` K cal C. 100 K cal. D. 150 K cal.
Description : An isothermal aqueous phase reversible reaction, P ⇌ R, is to be carried out in a mixed flow reactor. The reaction rate in k.mole/m3 .h is given by, r = 0.5CP - 0.125CR. A stream containing only P enters the reactor. The ... (in hours) for 40% conversion of P is (A) 0.80 (B) 1.33 (C) 1.60 (D) 2.67
Last Answer : (C) 1.60
Description : In the reaction, `C_(6)H_(5)NH_(2)underset(0-5^(@)C)overset(NaNO_(2)+HCl)rarr(A)underset(KCN)overset(CuCN)rarr(B)overset(H^(+)//H_(2)O)rarr(C)` the pr
Last Answer : In the reaction, `C_(6)H_(5)NH_(2)underset(0-5^(@)C)overset(NaNO_(2)+HCl)rarr(A)underset(KCN)overset(CuCN ... COOH` C. `C_(6)H_(5)OH` D. none of these
Description : Identify the products in the following disproportional reaction and also mention rate determining step. `2H-overset(D)overset(|)(C)=O + overset(@)(O)H
Last Answer : Identify the products in the following disproportional reaction and also mention rate determining step. `2H-overset ... ")+underset("(Q)")("Alcohol")`
Description : For reversible melting of ice at `0^(@)C` and 1 atm. Pressure, the value of `Delta G` will be :-
Last Answer : For reversible melting of ice at `0^(@)C` and 1 atm. Pressure, the value of `Delta G` will be :- A. `lt ... 0` (zero) C. 0 (zero) D. `oo` (infinity)
Description : `C_(6)H_(5)NH_(2) overset(NaNO_(2)+HCl)underset(0-5^(@)C) X overset(H_(2)O)underset(Delta)toY,` the product is :
Last Answer : `C_(6)H_(5)NH_(2) overset(NaNO_(2)+HCl)underset(0-5^(@)C) X overset(H_(2)O) ... : A. Benzenediazonium chloride B. Nitrobenzene C. Phenol D. Cresol
Description : In the above `Delta ABC` ( not to scale ), OA is the angle bisector of `/_ BAC` . If `OB=OC,/_OAC=40^(@)` and `/_ ABO=20^(@)`. If `/_ OCB=(1)/(2) /_ A
Last Answer : In the above `Delta ABC` ( not to scale ), OA is the angle bisector of `/_ BAC` . If `OB=OC,/_OAC=40^(@) ... OCB=(1)/(2) /_ ACO,` then find `/_ BOC.`
Description : In the above figure ( not to scale ) the sides BA,BC and CA of` Delta ABC` are produced to D,F, and E respectively such that `/_ ACF= 120^(@)` and `/_
Last Answer : In the above figure ( not to scale ) the sides BA,BC and CA of` Delta ABC` are produced to D,F, and E ... /_ BAE= 150^(@)`. Then `/_ ABC = ________`.