Description : If your room has a natural tendency to become messy and disordered, it is an excellent example of: w) enthalpy x) entropy y) the Bernoulli effect z) the Haase effect
Last Answer : ANSWER: X -- ENTROPY
Description : It is a common observation that naturally occurring processes have a particular direction associated with them. For instance, heat flows from a hot body to a colder body. The property of a system ... this natural direction of events is called w) energy x) entropy y) enthalpy z) equilibrium
Description : What is the energy absorbed during chemical reaction under constant volume conditions? A. Entropy B. Ion exchange C. Enthalpy D. Enthalpy of reaction
Last Answer : Enthalpy
Description : Pick out the correct statement. (A) Like internal energy and enthalpy, the absolute value of standard entropy for elementary substances is zero (B) Melting of ice involves increase in enthalpy and ... of an ideal gas depends only on its pressure (D) Maximum work is done under reversible conditions
Last Answer : (D) Maximum work is done under reversible conditions
Description : If a reaction has an enthalpy of -54.32 kJ/mol and an entropy of -354.2 J/(K*mol), what is the Gibbs free Energy at 54.3(degrees c)?
Last Answer : DeltaG = DeltaH - TDeltaS dG = -54.32 kJ/mol - (54'32+273)K(-354.2J/molK) NB Thevtemperature is quoted in Kelvin(K) and the Entropy must be converted to kJ by dividing by '1000'/ Hence dG = ... 115.94 kJ/mol dG = (+)61.61 kJ/mol Since dG is positive, the reaction is NOT thermodynamically feasible.
Description : What American first proposed the free energy function G, which interrelates entropy and enthalpy?
Last Answer : ANSWER: J. WILLARD GIBBS
Description : (i)State why heat changes in physical and chemical processes are indicated by enthalpy changes and not by entropy changes? (ii)What are the limitations of First Law of thermodynamics?
Last Answer : (i) Most of the processes are carried out in an open system i.e, at constant pressure. (ii)(a) Can’t explain the feasibility of the reaction. (b)It poses no restriction on the direction of flow of heat. (c)Practically it is not possible to convert the heat energy into an equivalent amount of work.
Description : In the equation of a nuclear reaction, all but one of the following quantities are equal to each other on both sides of the equation. Which quantity is NOT conserved: w) the net electric charge x) the total mass-energy y) the number of protons z) the number of nucleons
Last Answer : ANSWER: Y -- THE NUMBER OF PROTONS
Description : It has been said that the universe will die an "entropy death". This means that: w) the universe will eventually explode. x) the universe will be at the same temperature everywhere. y) the universe will collapse into a black hole. z) matter and antimatter will never combine.
Last Answer : ANSWER: X -- THE UNIVERSE WILL BE AT THE SAME TEMPERATURE EVERYWHERE.
Description : Entropy is a measure of: w) magnetization x) disorder y) temperature z) heat
Last Answer : ANSWER: X -- DISORDER
Description : What is meant by entropy driven reaction? How can the reaction with positive change of enthalpy and entropy be made entropy driven?
Last Answer : Ans.The free energy change of a reaction is given by ΔG = ΔH - TΔS For a reaction to be spontaneous, ΔG should be -ve. If both ΔH and ΔS are positive ΔG can be -ve if TΔS>ΔH in magnitude. Thus, entropy ... is low, TΔS should be greater than ΔH (ii) If ΔS is small, T should be so large that TΔS>ΔH.
Description : The rate of a chemical reaction can be affected by: w) temperature x) concentration of products y) concentration of reactants z) all of the above
Last Answer : ANSWER: Z -- ALL OF THE ABOVE
Description : The first law of thermodynamics is based on which of the following principles? a. conservation of mass b. the enthalpy-entropy relationship c. action – reaction d. conservation of energy
Last Answer : conservation of energy
Description : Which of the following molecules would have the smallest molar enthalpy of vaporization? w) Water x) Formaldehyde y) Methane z) Ammonia
Last Answer : ANSWER: Y -- METHANE
Description : What two primary factors determine whether or no molecular collision leads to a chemical reaction? w) energy and volume of molecules x) energy and mass of molecules y) energy and orientation of molecules z) orientation and volume of molecules
Last Answer : ANSWER: Y -- ENERGY AND ORIENTATION OF MOLECULES
Description : The enthalpy change for a given reaction at `298 K` is `-x cal mol^(-1)`. If the reaction occurs spontaneously at `298 K`, the entropy change at that
Last Answer : The enthalpy change for a given reaction at `298 K` is `-x cal mol^(-1)`. If the reaction occurs ... (-1)` C. Cannot be negative D. Cannot be positive
Description : If the rate of a chemical reaction becomes slower at a given temperature, then the (A) Initial concentration of the reactants remains constant (B) Free energy of activation is lower (C) Entropy changes (D) Free energy of activation is higher
Last Answer : (D) Free energy of activation is higher
Description : What are the names given to constant temperature, constant pressure, constant volume, constant internal energy, constant enthalpy, and constant entropy processes.
Last Answer : Isothermal, isochroic, isobaric, free expression, throttling and adiabatic processes respectively.
Description : Mollier diagram is a plot of (A) Temperature vs. enthalpy (B) Temperature vs. enthalpy (C) Entropy vs. enthalpy (D) Temperature vs. internal energy
Last Answer : (C) Entropy vs. enthalpy
Description : Specific __________ does not change during phase change at constant temperature and pressure. (A) Entropy (B) Gibbs energy (C) Internal energy (D) Enthalpy
Last Answer : (B) Gibbs energy
Description : Joule-Thomson effect i.e., a throttling process is a constant __________ process. (A) Entropy (B) Temperature (C) Internal energy (D) Enthalpy
Last Answer : (D) Enthalpy
Description : For an incompressible fluid, the __________ is a function of both pressure as well as temperature. (A) Internal energy (B) Enthalpy (C) Entropy (D) All (A), (B) & (C)
Last Answer : (B) Enthalpy
Description : If a solid is compressed adiabatically in its elastic range, its __________ remains constant (A) Internal energy (B) Enthalpy (C) Entropy (D) Temperature
Last Answer : (C) Entropy
Description : If heat be exchanged in a reversible manner, which of the following property of the working substance will change accordingly (a) temperature (b) enthalpy (c) internal energy (d) entropy (e) all of the above.
Last Answer : Answer : d
Description : Change in enthalpy in a closed system is equal to heat transferred if the reversible process takes place at constant (a) pressure (b) temperature (c) volume (d) internal energy (e) entropy.
Last Answer : Answer : a
Description : Which of the following is the property of a system (a) pressure and temperature (b) internal energy (c) volume and density (d) enthalpy and entropy (e) all of the above.
Last Answer : Answer : e
Description : The extensive properties are (A) Volume, mass and number of moles (B) Free energy, entropy and enthalpy (C) Both (A) and (B) (D) None of these
Last Answer : (C) Both (A) and (B)
Description : Specific __________ does not change during a phase change (e.g. sublimation, melting, vaporisation etc.). (A) Entropy (B) Internal energy (C) Enthalpy (D) Gibbs free energy
Last Answer : (D) Gibbs free energy
Description : What is defined as the sum of the system’s internal energy and the product of its pressure and volume? a. Entropy. b. Enthalpy. c. Free energy. d. Potential energy.
Last Answer : b. Enthalpy.
Description : If P, Y and Z are the weights of cement, fine aggregates and coarse aggregates respectively and W/C is the water cement ratio, the minimum quantity of water to be added to first batch, is obtained by the equation (A) 0.1P + 0.3Y + 0. ... + 0.2Y + 0.01Z = W/C P (D) 0.5P + 0.3Y + 0.01Z = W/C P
Last Answer : Answer: Option B
Description : Assertion :- Entropy of system increases for a spontaneous reactions. Reason :- Enthalpy of reaction always decreases for spontaneous reaction.
Last Answer : Assertion :- Entropy of system increases for a spontaneous reactions. Reason :- Enthalpy of reaction ... D. If both Assertion & Reason are false.
Description : The enthalpy and entropy change for the reaction, `Br_(2)(l)+Cl_(2)(g)rarr2BrCl(g)` are `30KJmol^(-1)` and `105JK^(-1)mol^(-1)` respectively. The temp
Last Answer : The enthalpy and entropy change for the reaction, `Br_(2)(l)+Cl_(2)(g)rarr2BrCl(g)` are `30KJmol^(-1)` and ` ... 285.7 K B. 273 K C. 450 K D. 300 K
Description : Entropy change of the reaction, H2O (liquid) → H2O (gas), is termed as the enthalpy of (A) Solution (B) Vaporisation (C) Formation (D) Sublimation
Last Answer : (B) Vaporisation
Description : The critical temperature is the temperature: w) above which a substance cannot be vaporized x) at which the density is a minimum y) at which solid, liquid, and vapor are in equilibrium z) above which the substance cannot be liquified.
Last Answer : ANSWER: Z -- ABOVE WHICH THE SUBSTANCE CANNOT BE LIQUIFIED.
Description : Units commonly used for entropy are: w) kilograms per degree Kelvin x) Joules per degree Kelvin y) Newtons per Coulomb z) ergs
Last Answer : ANSWER: X -- JOULES PER DEGREE KELVIN
Description : Which of the following chemical reactions does not lead to formation of a salt? w) Reaction of salts with acids. x) The reaction of base anhydrides with acid anhydrides. y) Action of water on oxides of nonmetals. z) Reaction of acid with base.
Last Answer : ANSWER: Y -- ACTION OF WATER ON OXIDES OF NONMETALS. (If water reacts with oxides of nonmetals, an acid is formed.)
Description : Crude oil is separated into its components by: w) chemical reaction x) simple distillation y) fractional distillation z) settling
Last Answer : ANSWER: Y -- FRACTIONAL DISTILLATION
Description : Vertical lines on pressure-enthalpy chart show constant (a) pressure lines (b) temperature lines (c) total heat lines (d) entropy lines
Last Answer : Ans: c
Description : On the pressure-enthalpy diagram, condensation and de-superheating is represented by a horizontal line because theprocess (a) takes place at constant pressure (b) takes place at constant temperature (c) takes place at constant entropy (d) takes place at constant enthalpy
Last Answer : Ans: a
Description : Short horizontal lines on pressure-enthalpy chart show (a) constant pressure lines (b) constant temperature lines (c) constant total heat lines (d) constant entropy lines
Description : The heat content of air is called the _____ of the air. a. Temperature b. Humidity c. Enthalpy d. Psychrometry e. Entropy
Last Answer : ANSWER : C
Description : __________ decreases during adiabatic throttling of a perfect gas. (A) Entropy (B) Temperature (C) Enthalpy (D) Pressure
Last Answer : (D) Pressure
Description : During Joule-Thomson expansion of gases (A) Enthalpy remains constant (B) Entropy remains constant (C) Temperature remains constant (D) None of these
Last Answer : (A) Enthalpy remains constant
Description : Mollier chart is a __________ plot. (A) Pressure vs. enthalpy (B) Pressure vs. volume (C) Enthalpy vs. entropy (D) Temperature vs. entropy
Last Answer : (C) Enthalpy vs. entropy
Description : For a thermodynamic system undergoing a process, which of the following pairs best expresses the relationship similar to that expressed by the pressure volume plot? (A) Temperature - entropy (B) Temperature - pressure (C) Enthalpy - entropy
Last Answer : (A) Temperature - entropy
Description : Change in enthalpy of a system is the heat supplied at (a) constant pressure (b) constant temperature (c) constant volume (d) constant entropy (e) N.T.P. condition.
Description : If value of n is infinitely large in a polytropic process pV” = C, then the process is known as constant (a) volume (b) pressure (c) temperature (d) enthalpy (e) entropy
Description : Which of the following parameters is constant for a mole for most of the gases at a given temperature and pressure (a) enthalpy (b) volume (c) mass (d) entropy (e) specific volume.
Last Answer : Answer : b
Description : When the velocity of an object is tripled, another quantity which is tripled at the same time is the object's: w) momentum x) potential energy y) kinetic energy z) mass
Last Answer : ANSWER: W -- MOMENTUM
Description : Pick out the correct statement: (A) In an isothermal system, irreversible work is more than reversible work (B) Under reversible conditions, the adiabatic work is less than isothermal work (C) ... state functions' (D) Matter and energy cannot be exchanged with the surroundings in a closed system
Last Answer : (B) Under reversible conditions, the adiabatic work is less than isothermal work