Description : The catalyst in a first order chemical reaction changes the (A) Equilibrium constant (B) Activation energy (C) Heat of formation of the product (D) Heat of reaction
Last Answer : (B) Activation energy
Description : The Gibbs free energy change of a reaction at `27^(@)C` is -26 Kcal. and its entropy change is -60 Cals/K. `Delta H` for the reaction is :-
Last Answer : The Gibbs free energy change of a reaction at `27^(@)C` is -26 Kcal. and its entropy change is -60 Cals/K. ... Cals. C. 34 K. Cals. D. `-24` K. Cals.
Description : The standard Gibbs free energy change of a reaction depends on the equilibrium (A) Pressure (B) Temperature (C) Composition (D) All (A), (B) and (C)
Last Answer : (B) Temperature
Description : Assertion: Reaction of `SO_(2)` and `H_(2)S` in the presence of `Fe_(2)O_(3)` catalyst gives elemental sulphur. Reason: `SO_(2)` is a reducing agent.
Last Answer : Assertion: Reaction of `SO_(2)` and `H_(2)S` in the presence of `Fe_(2)O_(3)` catalyst gives ... is False. D. If both Assertion & Reason are False.
Description : A catalyst in a chemical reaction __________ free energy change in the reaction. (A) Increases (B) Decreases (C) Either (A) or (B); depends on the type of catalyst (D) Neither (A) nor (B)
Last Answer : (C) Either (A) or (B); depends on the type of catalyst
Description : Pick out the correct statement. (A) A catalyst does not change AH of the reaction (B) A catalyst changes the equilibrium point (C) Law of mass action was suggested by Le-Chatelier (D) The difference between the energy of reactants and that of the products is the activation energy
Last Answer : (A) A catalyst does not change AH of the reaction
Description : Assertion :- Catalyst is more effective in powdered form. Reason :- Number of free valencies increase.
Last Answer : Assertion :- Catalyst is more effective in powdered form. Reason :- Number of free valencies increase. A ... D. If both Assertion & Reason are False.
Description : Gibbs free energy per mole for a pure substance is equal to the (A) Latent heat of vaporisation (B) Chemical potential (C) Molal boiling point (D) Heat capacity
Last Answer : (B) Chemical potential
Description : If a reaction has an enthalpy of -54.32 kJ/mol and an entropy of -354.2 J/(K*mol), what is the Gibbs free Energy at 54.3(degrees c)?
Last Answer : DeltaG = DeltaH - TDeltaS dG = -54.32 kJ/mol - (54'32+273)K(-354.2J/molK) NB Thevtemperature is quoted in Kelvin(K) and the Entropy must be converted to kJ by dividing by '1000'/ Hence dG = ... 115.94 kJ/mol dG = (+)61.61 kJ/mol Since dG is positive, the reaction is NOT thermodynamically feasible.
Description : In which of the following reactions, standard reaction entropy change (S°) is positive and standard Gibb's energy change (G°) decreases sharply with increasing temperature? (1) 2 2 1 1 1 C graphite O (g) CO (g) 2 2 2 (2) 2 1 C ... CO(g) O (g) CO (g) 2 (4) 2 1 Mg(s) O (g) MgO(s) 2
Last Answer : C graphite O (g) CO(g)
Description : At the point of intersection for any two reactions for any two reactions in Ellingham diagram, the gibbs energy `(DeltaG)` changes becomes
Last Answer : At the point of intersection for any two reactions for any two reactions in Ellingham diagram, the gibbs energy `(DeltaG ... `gt1` B. 1 C. `lt0` D. 0
Description : The role of a catalyst in a chemical reaction is to change the (A) Equilibrium constant (B) Activation energy (C) Final products (D) Heat of reaction
Description : Catalytic action in a catalytic chemical reaction follows from the ability of catalyst to change the (A) Activation energy (B) Equilibrium constant (C) Heat of reaction (D) None of these
Last Answer : (A) Activation energy
Description : Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to ... Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction
Last Answer : (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot
Description : For a first order chemical reaction in a porous catalyst, the Thiele modulus is 10. The effectiveness factor is approximately equal to (A) 0 (B) 1 (C) 0.1 (D) 0.5
Last Answer : (C) 0.1
Description : Effectiveness factor of a catalyst pellet is a measure of the __________ resistance. (A) Pore diffusion (B) Gas film (C) Chemical reaction (D) None of these
Last Answer : (A) Pore diffusion
Description : For a first order isothermal chemical reaction in a porous catalyst, the effectiveness factor is 0.3. The effectiveness factor will increase if the (A) Catalyst size is reduced or the ... the catalyst diffusivity is reduced (D) Catalyst size is increased or the catalyst diffusivity is increased
Last Answer : (B) Catalyst size is reduced or the catalyst diffusivity is increased
Description : Pick out the correct statement. (A) A catalyst speeds up the forward reaction but slows shown the reverse reaction (B) Addition of catalyst changes the equilibrium constant (C) Pressure changes do not change the equilibrium concentrations (D) The composition of equilibrium is changed by catalyst
Last Answer : (C) Pressure changes do not change the equilibrium concentrations
Description : (∂H/∂T)P is the mathematical expression for (A) CV (B) Entropy change (C) Gibbs free energy (D) None of these
Last Answer : (D) None of these
Description : Specific/molar Gibbs free energy for a pure substance does not change during (A) Sublimation (B) Vaporisation (C) Melting (D) Either (A), (B) or (C)
Last Answer : (D) Either (A), (B) or (C)
Description : The change in Gibbs free energy for vaporisation of a pure substance is (A) Positive (B) Negative (C) Zero (D) May be positive or negative
Last Answer : (C) Zero
Description : If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as (A) Solubility increases as temperature ... (D) Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution
Last Answer : (B) Solubility increases as temperature decreases
Description : Specific __________ does not change during a phase change (e.g. sublimation, melting, vaporisation etc.). (A) Entropy (B) Internal energy (C) Enthalpy (D) Gibbs free energy
Last Answer : (D) Gibbs free energy
Description : The change in __________ is equal to the reversible work for compression in steady state flow process under isothermal condition. (A) Internal energy (B) Enthalpy (C) Gibbs free energy (D) Helmholtz free energy
Last Answer : (C) Gibbs free energy
Description : _________ does not change during phase transformation processes like sublimation, melting & vaporisation. (A) Entropy (B) Gibbs free energy (C) Internal energy (D) All (A), (B) & (C)
Last Answer : (B) Gibbs free energy
Description : A catalyst is a substance which (a) Changes the equilibrium of a reaction so that the concentration of the product increases (b) Increases the rate of reaction and increases the equilibrium concentration of products (c) Hastens the attainment of equilibrium (d) Increases the activation energy
Last Answer : Ans:(c)
Description : Assertion :- Zeolite is shape selective catalyst. Reason :- Size of the pores of the catalyst are such that they can trap only selective molecules.
Last Answer : Assertion :- Zeolite is shape selective catalyst. Reason :- Size of the pores of the catalyst are such ... . D. If both Assertion & Reason are False.
Description : What happens when a catalyst is added to a system at equilibrium? A The reaction follows an alternative pathway of lower activation energy. B The heat of reaction decreases. C The potential ... decreases. D The potential energy of the products decreases. E The rate of chemical reaction decreases.
Last Answer : A The reaction follows an alternative pathway of lower activation energy.
Description : Which one of the following statements regarding a catalyst is not correct? A An enzyme is a catalyst that only binds certain substrates. B An enzyme is a protein that is a highly ... increasing the activation energy. D Catalysts do not alter the equilibrium constant for a chemical reaction.
Last Answer : C Catalysts increase the rate of a reaction by altering the mechanism, thereby increasing the activation energy.
Description : _________ is a thermodynamic potential that measures the “useful” or process-initiating work obtainable from an isothermal, isobaric thermodynamic system. a. Du-Pont Potential b. Gibbs free energy c. Rabz-Eccles Energy d. Claussius Energy
Last Answer : Gibbs free energy
Description : (4) None of these Explanation: Catalysis is the change in rate of a chemical reaction due to the participation of a substance called a catalyst. Unlike other reagents that ... may participate in multiple chemical transformations. Catalysts that speed the reaction are called positive catalysts.
Last Answer : Table salt gets moist during rainy season because – (1) sodium chloride is hygroscopic (2) sodium chloride is deliquescent (3) sodium chloride contains some quantity of sodium iodide (4) sodium chloride contains hygroscopic impurities like magnesium chloride
Description : The reason why a catalyst increases the rate of reaction is that, it (A) Decreases the energy barrier for reaction (B) Increases the activation energy (C) Decreases the molecular collision diameter (D) None of these
Last Answer : (A) Decreases the energy barrier for reaction
Description : A catalyst (A) Initiates a reaction (B) Lowers the activation energy of reacting molecules (C) Is capable of reacting with any one of the reactants (D) Cannot be recovered chemically unchanged at the end of a chemical reaction
Last Answer : (C) Is capable of reacting with any one of the reactants
Description : Pick out the correct statement. (A) In catalytic reactions, the catalyst reacts with the reactants (B) A catalyst initiates a chemical reaction (C) A catalyst lowers the activation energy of ... molecules (D) A catalyst cannot be recovered chemically unchanged at the end of the chemical reaction
Last Answer : (C) A catalyst lowers the activation energy of the reacting molecules
Description : A catalyst in a chemical reaction (A) Decreases the activation energy (B) Alters the reaction mechanism (C) Increases the frequency of collisions of reacting species (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : A Catalyst (A) Increases the equilibrium concentration of the product (B) Changes the equilibrium constant of the reaction (C) Shortens the time to reach the equilibrium (D) None of these
Last Answer : (C) Shortens the time to reach the equilibrium
Description : Minimum gibbs free energy is NOT attained by a semipermeable membrane. True or false?
Last Answer : Can someone please help me with this question
Description : In what way will the gibbs free energy always be negative?
Last Answer : What is the answer ?
Description : How does the Gibbs free energy predict spontaneity?
Last Answer : If G is negative, then the answer is spontaneous
Description : Boiling of liquid is accompanied with increase in the (A) Vapor pressure (B) Specific Gibbs free energy (C) Specific entropy (D) All (A), (B) and (C)
Last Answer : (A) Vapor pressure
Description : Gibbs free energy of a pure fluid approaches __________ as the pressure tends to zero at constant temperature. (A) Infinity (B) Minus infinity (C) Zero (D) None of these
Last Answer : (B) Minus infinity
Description : Gibbs free energy at constant pressure and temperature under equilibrium conditions is (A) ∞ (B) 0 (C) Maximum (D) Minimum
Last Answer : (D) Minimum
Description : In any spontaneous process, the __________ free energy decreases. (A) Helmholtz (B) Gibbs (C) Both ‘a’ & ‘b’ (D) Neither 'a' nor 'b'
Last Answer : (C) Both ‘a’ & ‘b’
Description : Gibbs free energy of mixing at constant pressure and temperature is always (A) 0 (B) ∞ (C) + ve (D) - ve
Last Answer : (D) - ve
Description : The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1is the activity co-efficient of component 1, is (A) A . x22 (B) Ax1 (C) Ax2 (D) Ax12
Last Answer : (A) A . x22
Description : Gibbs free energy (G) is represented by, G = H - TS, whereas Helmholtz free energy, (A) is given by, A = E - TS. Which of the following is the Gibbs Helmholtz equation? (A) [∂(G/T)/∂T] = - (H/T2) (B) [∂(A/T)/∂T]V = - E/T2 (C) Both (A) and (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) and (B)
Description : Write A Short Note On Gibbs Free Energy And Derive The Equation For The Same.?
Last Answer : This thermodynamic quantity states that the decrease in value during a process is equal to the useful work done by the system. It is denoted by G and the mathematical equation is: G = H - TS Where ... of the system Thus the above equation becomes: ΔG = ΔH - TΔS is known as Gibbs-Helmoholtz equation.
Description : Specific __________ does not change during phase change at constant temperature and pressure. (A) Entropy (B) Gibbs energy (C) Internal energy (D) Enthalpy
Last Answer : (B) Gibbs energy
Description : If the rate of a chemical reaction becomes slower at a given temperature, then the (A) Initial concentration of the reactants remains constant (B) Free energy of activation is lower (C) Entropy changes (D) Free energy of activation is higher
Last Answer : (D) Free energy of activation is higher
Description : For a heterogeneous catalytic reaction (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction (B) A relatively small amount of catalyst ... with the reactant (D) The surface of the catalyst does not play an important role during reaction
Last Answer : (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction