Description : (∂E/∂T)V is the mathematical expression for (A) CV (B) Enthalpy change (C) Free energy change (D) None of these
Last Answer : (D) None of these
Description : (1/V) (∂V/∂T)Pis the mathematical expression (A) Joule-Thomson co-efficient (B) Specific heat at constant pressure (Cp) (C) co-efficient of thermal expansion (D) Specific heat at constant volume (CV)
Last Answer : (C) co-efficient of thermal expansion
Description : (∂T/∂P)H is the mathematical expression for (A) Specific heat at constant pressure (Cp) (B) Specific heat at constant volume (Cv) (C) Joule-Thompson co-efficient (D) None of these
Last Answer : (C) Joule-Thompson co-efficient
Description : Joule-Thomson co-efficient which is defined as, η = (∂T/∂P)H = 1/Cp (∂H/∂T)P, changes sign at a temperature known as inversion temperature. The value of Joule-Thomson co-efficient at inversion temperature is (A) 0 (B) ∞ (C) +ve (D) -ve
Last Answer : (A) 0
Description : Gibbs free energy (G) is represented by, G = H - TS, whereas Helmholtz free energy, (A) is given by, A = E - TS. Which of the following is the Gibbs Helmholtz equation? (A) [∂(G/T)/∂T] = - (H/T2) (B) [∂(A/T)/∂T]V = - E/T2 (C) Both (A) and (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) and (B)
Description : Gibbs-Helmholtz equation is (A) ∆F = ∆H + T [∂(∆F)/∂T]P (B) ΔF = ΔH - TΔT (C) d(E - TS) T, V < 0 (D) dP/dT = ∆Hvap/T.∆Vvap
Last Answer : (A) ∆F = ∆H + T [∂(∆F)/∂T]P
Description : The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is (A) (∂T/∂V)S = - (∂P/∂S)V (B) (∂S/∂P)T = - (∂V/∂T)P (C) (∂V/∂S)P = (∂T/∂P)S (D) (∂S/∂V)T = (∂P/∂T)V
Last Answer : (D) (∂S/∂V)T = (∂P/∂T)V
Description : Specific __________ does not change during a phase change (e.g. sublimation, melting, vaporisation etc.). (A) Entropy (B) Internal energy (C) Enthalpy (D) Gibbs free energy
Last Answer : (D) Gibbs free energy
Description : _________ does not change during phase transformation processes like sublimation, melting & vaporisation. (A) Entropy (B) Gibbs free energy (C) Internal energy (D) All (A), (B) & (C)
Last Answer : (B) Gibbs free energy
Description : The Gibbs free energy change of a reaction at `27^(@)C` is -26 Kcal. and its entropy change is -60 Cals/K. `Delta H` for the reaction is :-
Last Answer : The Gibbs free energy change of a reaction at `27^(@)C` is -26 Kcal. and its entropy change is -60 Cals/K. ... Cals. C. 34 K. Cals. D. `-24` K. Cals.
Description : Boiling of liquid is accompanied with increase in the (A) Vapor pressure (B) Specific Gibbs free energy (C) Specific entropy (D) All (A), (B) and (C)
Last Answer : (A) Vapor pressure
Description : Specific __________ does not change during phase change at constant temperature and pressure. (A) Entropy (B) Gibbs energy (C) Internal energy (D) Enthalpy
Last Answer : (B) Gibbs energy
Description : If a reaction has an enthalpy of -54.32 kJ/mol and an entropy of -354.2 J/(K*mol), what is the Gibbs free Energy at 54.3(degrees c)?
Last Answer : DeltaG = DeltaH - TDeltaS dG = -54.32 kJ/mol - (54'32+273)K(-354.2J/molK) NB Thevtemperature is quoted in Kelvin(K) and the Entropy must be converted to kJ by dividing by '1000'/ Hence dG = ... 115.94 kJ/mol dG = (+)61.61 kJ/mol Since dG is positive, the reaction is NOT thermodynamically feasible.
Description : In which of the following reactions, standard reaction entropy change (S°) is positive and standard Gibb's energy change (G°) decreases sharply with increasing temperature? (1) 2 2 1 1 1 C graphite O (g) CO (g) 2 2 2 (2) 2 1 C ... CO(g) O (g) CO (g) 2 (4) 2 1 Mg(s) O (g) MgO(s) 2
Last Answer : C graphite O (g) CO(g)
Description : The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and ... , nj (C) (∂H/∂ni)S, P, nj (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : . The entropy change in a reversible isothermal process, when an ideal gas expands to four times its initial volume is (A) R loge 4 (B) R log10 4 (C) Cv log10 4 (D) Cv loge 4
Last Answer : (A) R loge 4
Description : The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1is the activity co-efficient of component 1, is (A) A . x22 (B) Ax1 (C) Ax2 (D) Ax12
Last Answer : (A) A . x22
Description : What does mathematical expression d-p?
Last Answer : Need answer
Description : Specific/molar Gibbs free energy for a pure substance does not change during (A) Sublimation (B) Vaporisation (C) Melting (D) Either (A), (B) or (C)
Last Answer : (D) Either (A), (B) or (C)
Description : The change in Gibbs free energy for vaporisation of a pure substance is (A) Positive (B) Negative (C) Zero (D) May be positive or negative
Last Answer : (C) Zero
Description : If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as (A) Solubility increases as temperature ... (D) Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution
Last Answer : (B) Solubility increases as temperature decreases
Description : The standard Gibbs free energy change of a reaction depends on the equilibrium (A) Pressure (B) Temperature (C) Composition (D) All (A), (B) and (C)
Last Answer : (B) Temperature
Description : The change in __________ is equal to the reversible work for compression in steady state flow process under isothermal condition. (A) Internal energy (B) Enthalpy (C) Gibbs free energy (D) Helmholtz free energy
Last Answer : (C) Gibbs free energy
Description : Maxwell's relation corresponding to the identity, dH = dS = Vdp + ∑μi dni is (A) (∂T/∂V)S, ni = -(∂P/∂S)V, ni (B) (∂S/∂P)T, ni = (∂V/∂T)P, ni (C) (∂S/∂V)T, ni = (∂P/∂T)V, ni (D) (∂T/∂P)S, ni = (∂V/∂S)P, ni
Last Answer : (D) (∂T/∂P)S, ni = (∂V/∂S)P, ni
Description : Which is not constant for an ideal gas? (A) (∂P/∂V)T (B) (∂V/∂T)P (C) (∂P/∂V)V (D) All (A), (B) & (C)
Last Answer : (A) (∂P/∂V)T
Description : Pick out the Clausius-Clapeyron equation from the following: (A) dP/dT = ∆H/T∆V (B) ln P = - (∆H/RT) + constant (C) ∆F = ∆H + T [∂(∆F)/∂T]P (D) None of these
Last Answer : B) ln P = - (∆H/RT) + constant
Description : Which of the following identities can be most easily used to verify steam table data for superheated steam? (A) (∂T/∂V)S = (∂p/∂S)V (B) (∂T/∂P)S = (∂V/∂S)P (C) (∂P/∂T)V = (∂S/∂V)T (D) (∂V/∂T)P = -(∂S/∂P)T
Last Answer : D) (∂V/∂T)P = -(∂S/∂P)T
Description : Cvis given by (A) (∂E/∂T)V (B) (∂E/∂V)T (C) (∂E/∂P)V (D) (∂V/∂T)P
Last Answer : (A) (∂E/∂T)V
Description : The equation relating E, P, V and T which is true for all substances under all conditions is given by (∂E/∂V)T = T(∂P/∂T)H - P. This equation is called the (A) Maxwell's equation (B) Thermodynamic equation of state (C) Equation of state (D) Redlich-Kwong equation of state
Last Answer : (B) Thermodynamic equation of state
Description : The expression for entropy change, ΔS = n Cp. ln (T2/T1), is valid for the __________ of a substance. (A) Simultaneous pressure & temperature change (B) Heating (C) Cooling (D) Both (B) and (C)
Last Answer : (D) Both (B) and (C)
Description : The expression for entropy change given by, ΔS = - nR ln (P2/P1), holds good for (A) Expansion of a real gas (B) Reversible isothermal volume change (C) Heating of an ideal gas (D) Cooling of a real gas
Last Answer : (B) Reversible isothermal volume change
Description : The expression for entropy change given by, ΔS = nR ln (V2/V1) + nCvln (T2/T1) is valid for (A) Reversible isothermal volume change (B) Heating of a substance (C) Cooling of a substance (D) Simultaneous heating and expansion of an ideal gas
Last Answer : (D) Simultaneous heating and expansion of an ideal gas
Description : Assertion :- Catalyst change Gibbs free energy of system. Reason :- Catalyst changes preexponential factor of a chemical reaction.
Last Answer : Assertion :- Catalyst change Gibbs free energy of system. Reason :- Catalyst changes preexponential factor ... . If both Assertion & Reason are false.
Description : The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv ), depends upon its (A) Pressure (B) Volume (C) Temperature (D) All (A), (B) & (C)
Last Answer : (C) Temperature
Description : Gibbs free energy of a pure fluid approaches __________ as the pressure tends to zero at constant temperature. (A) Infinity (B) Minus infinity (C) Zero (D) None of these
Last Answer : (B) Minus infinity
Description : Gibbs free energy at constant pressure and temperature under equilibrium conditions is (A) ∞ (B) 0 (C) Maximum (D) Minimum
Last Answer : (D) Minimum
Description : In any spontaneous process, the __________ free energy decreases. (A) Helmholtz (B) Gibbs (C) Both ‘a’ & ‘b’ (D) Neither 'a' nor 'b'
Last Answer : (C) Both ‘a’ & ‘b’
Description : Gibbs free energy per mole for a pure substance is equal to the (A) Latent heat of vaporisation (B) Chemical potential (C) Molal boiling point (D) Heat capacity
Last Answer : (B) Chemical potential
Description : Gibbs free energy of mixing at constant pressure and temperature is always (A) 0 (B) ∞ (C) + ve (D) - ve
Last Answer : (D) - ve
Description : The four properties of a system viz. P, V, T, S are related by __________ equation. (A) Gibbs-Duhem (B) Gibbs-Helmholtz (C) Maxwell's (D) None of these
Last Answer : (C) Maxwell's
Description : Number of components (C), phase (P) and degrees of freedom (F) are related by Gibbs phase rule as (A) P + F - C = 2 (B) C = P - F + 2 (C) F = C - P - 2 (D) P = F - C - 2
Last Answer : A) P + F - C = 2
Description : The expression for refractive index is given by a) N = v/c b) N = c/v c) N = cv d) N = 1/cv
Last Answer : b) N = c/v
Description : Minimum gibbs free energy is NOT attained by a semipermeable membrane. True or false?
Last Answer : Can someone please help me with this question
Description : In what way will the gibbs free energy always be negative?
Last Answer : What is the answer ?
Description : How does the Gibbs free energy predict spontaneity?
Last Answer : If G is negative, then the answer is spontaneous
Description : Write A Short Note On Gibbs Free Energy And Derive The Equation For The Same.?
Last Answer : This thermodynamic quantity states that the decrease in value during a process is equal to the useful work done by the system. It is denoted by G and the mathematical equation is: G = H - TS Where ... of the system Thus the above equation becomes: ΔG = ΔH - TΔS is known as Gibbs-Helmoholtz equation.
Description : _________ is a thermodynamic potential that measures the “useful” or process-initiating work obtainable from an isothermal, isobaric thermodynamic system. a. Du-Pont Potential b. Gibbs free energy c. Rabz-Eccles Energy d. Claussius Energy
Last Answer : Gibbs free energy
Description : In a P-V diagram (for an ideal gas), an isothermal curve will coincide within adiabatic curve (through a point), when (A) Cp < Cv (B) Cp = Cv (C) Cp > Cv (D) C ≥ Cv
Last Answer : (B) Cp = Cv
Description : On a P-V diagram of an ideal gas, suppose a reversible adiabatic line intersects a reversible isothermal line at point A. Then at a point A, the slope of the reversible adiabatic line (∂P/∂V)s and the slope of the reversible isothermal line ... Y (C) (∂P/∂V)S = y(∂P/∂V)T (D) (∂P/∂V)S = 1/y(∂P/∂V)T
Last Answer : (C) (∂P/∂V)S = y(∂P/∂V)T