Give IUPAC name of the ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry

1 Answer

Answer :

IUPAC name : Triammine chlorido nickel (II) nitrate [Ni(NH3)3NO3]Cl

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Description : Give IUPAC name of ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry

Last Answer : IUPAC name : Triammine nitrato nickel (III) chloride

Description : (i) Write down the IUPAC name of the following complex : [Cr(NH3)2CI3(en)]Cl (en = ethylenediamine) (ii) Write the formula for the following complex : Pentaamminenitrito-o-Cobalt (III) -Chemistry

Last Answer : (I) [Cr(NH3)2Cl3(en)]Cl IUPAC name : Diammine dichlorido ethylenediamine chromium (III) chloride. (ii) [Co(NH3)5(ONO)]2+

Description : Name the following coordination compounds according to IUPAC system of nomenclature :(i) [Co(NH3)4 (H2O)Cl]Cl2 (ii) [CrCl2(en)2]Cl, (en = ethane – 1, 2 – diamine) -Chemistry

Last Answer : (i) [CO(NH3)4 (H2O)Cl]Cl2 Tetraammine aquachlorido cobalt (III) chloride (ii) [CrCl2(en)2]Cl Dichlorobis (ethane-1, 2-diamine) chromium (III) chloride

Description : What is the IUPAC name of the complex [Ni(NH3)6]Cl2? -Chemistry

Last Answer : [Ni(NH3)6]Cl2 IUPAC name : Hexaamminenickel (II) chloride.

Description : For the complex [Fe(en)2Cl2], Cl, (en = ethylene diamine), identify (i) the oxidation number of iron, (ii) the hybrid orbitals and the shape of the complex, (iii) the magnetic behaviour of the complex, (iv) ... an optical isomer also, and (vi) name of the complex. (At. no. of Fe = 26) \ -Chemistry

Last Answer : i) [Fe(en)2Cl2] Cl or x + 0 + 2 (-1) + (-1) = 0 x + (- 3) = 0 or x = + 3 ∴ Oxidation number of iron, x = + 3 (ii) The complex has two bidentate ligands and two ... )2Cl2] Cl, only cis-isomer shows optical isomerism. (vi) Name of complex: Dichloridobis (ethane-1, 2- diamine) Iron (III) chloride

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Last Answer : i) [CO(NH3)5Cl]2+ IUPAC name : Pentaammine chlorido cobalt (III) ion (ii) Formula of the complex potassium tetrachloridonickelate (II) K2[NiCl4]

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Last Answer : IUPAC name : Tetraamine dichlorido chromium (III) ion. It exhibits geometrical isomerism.

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Last Answer : Hexaamminecobalt (III) ion.

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Last Answer : (i) [Co(NH3)6]+3 → Octahedral shape, d2sp3 hybridisation, diamagnetic Formation of [Co(NH2)6]+3 → oxidation state of Co is +3.

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Last Answer : In [Co(NH3)6]3+, the d-electrons of Co3+ ([Ar]3d6 45°) get paired leaving behind two empty d-orbital and undergo d2sp3 hybridization and hence inner orbital complex, while in [Ni(NH3)6]2+ ... of Ni2+([Ar]3d8 45°) do not pair up and use outer 4d subshell hence outer orbital complex.

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Last Answer : (i) [CO(NH3)6]3+ : Orbitals of CO3+ ion : Hybridization : d2sp3 Shape : Octahedral Magnetic behaviour : Diamagnetic (absence of unpaired electrons) (ii) [Ni(CN)4]2-

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Last Answer : Ans. (a). The element chlorine (Cl) has the highest negative electron gain enthalpy. (b). The element cesium (Cs) has lowest ionization enthalpy. (c). The element fluorine F has lowest atomic radius. (d ... zero group (or group 18). (g). The element carbon (C) forms the largest number of compounds.

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Last Answer : The IUPAC name of the complex `[PT(en)(NH_(3))(cl)_(2)(ONO)][Ag(CN)_(2 ... (ethane-1,2-diammine) nitritioplatinum(IV) dicyanoargentate (I)

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Last Answer : Example : [Pt (NH3)5 (Br)3] SO4 and [Co (NH3)5 (SO4)] Br

Description : A complex compound in which the oxidation number of a metal is zero is - (1) K4 [Fe (CN)6] (2) K3 [Fe (CN)6] (3) [Ni (CO)4] (4) [Pl (NH3)4]Cl2

Last Answer : (3) [Ni (CO)4]

Description : The IUPAC name of `[Ni (NH_(3))_(4)] [NiCl_(4)]` is

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