How the change in pressure at equilibrium position effect the following reaction? PCl5 PCl3 + Cl2

How the change in pressure at equilibrium position effect the following reaction?  PCl5 PCl3 + Cl2
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Answer :

According to Le–chatlier’s principle, by increasing pressure the reaction will move toward less number of moles. In the above reaction, by increasing pressure the reaction will move in backward direction.
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Related questions

Consider the following gaseous equilibrium: PCl3 + Cl2 = PCl5 + heat. Which of the following changes will shift it to the right: w) lower the temperature x) remove some Cl2 y) increase the volume z) add a catalyst

Description : Consider the following gaseous equilibrium: PCl3 + Cl2 = PCl5 + heat. Which of the following changes will shift it to the right: w) lower the temperature x) remove some Cl2 y) increase the volume z) add a catalyst

Last Answer : ANSWER: W -- LOWER THE TEMPERATURE

In the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2, decrease in the pressure of the system will __________ the degree of dissociation of PCl5. (A) Increase (B) Decrease (C) Not alter (D) None of these

Description : In the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2, decrease in the pressure of the system will __________ the degree of dissociation of PCl5. (A) Increase (B) Decrease (C) Not alter (D) None of these

Last Answer : (A) Increase

Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2.Degree of dissociation of PCl5 will (A) Decrease on addition of Cl2 (B) Increase on addition of an inert gas at constant pressure (C) Decrease on increasing the pressure of the system (D) None of these

Description : Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2.Degree of dissociation of PCl5 will (A) Decrease on addition of Cl2 (B) Increase on addition of ... at constant pressure (C) Decrease on increasing the pressure of the system (D) None of these

Last Answer : (D) None of thes

A catalyst does not change the position of equilibrium but this equilibrium position approach earlier. Why?

Description : A catalyst does not change the position of equilibrium but this equilibrium position approach earlier. Why?

Last Answer : A catalyst decrease the energy of activation required by reacting substance so the position of equilibrium reaches earlier.

What is meant by state of chemical equilibrium?

Description : What is meant by state of chemical equilibrium?

Last Answer : The state of reversible reaction, in which forward and reverse rates are equal.(Rf=Rr)

What is common ion effect?

Description : What is common ion effect?

Last Answer : The decrease in ionization of a weak electrolyte by adding another strong electrolyte having common ion.e.g ionization of NaCl is decreased by passing HCl through NaCl solution.

How can you purify NaCl by common ion effect?

Description : How can you purify NaCl by common ion effect?

Last Answer : The impurities present in the common salt are CaCl2 MgCl2 and Na2SO4 in it. These impurities can be removed by common Ion effect. For this purpose a saturated solution of NaCl is prepared. Then ... electrolyte than NaCl Ionization of NaCl is suppressed by passing HCl gas and it is precipitated out.

How value of Kc can help to predict the extent to which a chemical reaction can take place?

Description : How value of Kc can help to predict the extent to which a chemical reaction can take place?

Last Answer : The extent of reaction depends upon the magnitude of Kc. i.e. (i) Very small value of Kc: when Kc is very small the forward reaction will not occur to an appreciable extent ... neither very large nor very small, the equilibrium mixture contains appreciable amounts of both reactant and products.

How Kc can be applied to calculate direction of chemical reaction?

Description : How Kc can be applied to calculate direction of chemical reaction?

Last Answer : (i) If < Kc Then the reaction will proceed in the forward direction until the equilibrium is established. (ii) If > Kc Then the reaction will proceed in the backward direction until the equilibrium is established. If = kc Then the reaction is already in equilibrium.

What are reversible reaction?

Description : What are reversible reaction?

Last Answer : Those reactions in which the reactants products are converted into each other under same set of conditions.

What is solubility product?

Description : What is solubility product?

Last Answer : The product of molar solubilities of the ions of weak electrolyte at equilibrium stage is called solubility product. It is represented by Ksp

How can you co–relate Ka with Kc?

Description : How can you co–relate Ka with Kc?

Last Answer : Ka is dissociation constant of an acid while Kc is the equilibrium constant suppose an acid HA Ionize as HA + H2O  H3O+ + A– Kc = concentration of [H2O] almost remains constant so we can write. Kc = Kc [H2O] = ka Ka =

A buffer consists of a weak acid and is salt.

Description : A buffer consists of a weak acid and is salt.

Last Answer : (i) CH3COOH + CH3COONa (ii) C6H5COOH + C6H5COONa (iii) H2CO3 + NaHCO3 (iv) H3PO3 + NaH2PO4

Prove that Kw is ionic product of water and its value is 1 x 10–14 at 25o.

Description : Prove that Kw is ionic product of water and its value is 1 x 10–14 at 25o.

Last Answer : Water undergoes self ionization as 2H2O  H3O+ + OH– or H2O  H+ + OH– Kc [H2O] = [H+] [OH–] Kw = [H+] [OH–] At 25oC the value of Kw ionic product have been measured. Its value is 1 x 10–14.

What is the relationship b/w kc, kp kc & kn?

Description : What is the relationship b/w kc, kp kc & kn?

Last Answer : These four parameters are related as. Kp = Kc (RT)n = Kx (P)n = Kn When mole of products are reactant are equal i.e. n = 0 their Kp = kc = dx = kn

What are optimum conditions for the formation of NH3 by Haber’s process?

Description : What are optimum conditions for the formation of NH3 by Haber’s process? N2(g) + 3H2(g) 2NH3(g) H = -92.46 kJ/m

Last Answer : (i) As the reaction is exothermic max yield is obtained at low temp. (ii) By applying pressure, more product is obtained. According four moles of reactants produce two moles of product so by applying ... (vi) Rate of reaction can also be increase with the help of catalyst like iron or iron oxide.

What is buffer capacity?

Description : What is buffer capacity?

Last Answer : The amount of acid or base which a buffer can absorb without significant charge in PH is called buffer capacity. Buffer capacity is the ability of buffer to resist the change in its PH value.

Discuss the factors on which buffer PH depends.

Description : Discuss the factors on which buffer PH depends.

Last Answer : PH of buffer depends upon two factors. (i) Pka or ka value of an acid (ii) Concentration of salt and acid taken for the buffer.

Why we need buffer solution in daily life?

Description : Why we need buffer solution in daily life?

Last Answer : Buffers can resist the charge of its PH value therefore they are required in chemical analysis, pharmaceuticals, electroplating, photography, beverage industry, microbiology molecular biology, soil science and in quantitative ... PH 7.35. If it decreases upto 7 or goes upto 8 death may occur.

What are conjugate acid and bases?

Description : What are conjugate acid and bases?

Last Answer : When an acid is dissolved in water it will form H3O+ ions and an anion the anion of an acid is called conjugate base and H3O+ is called conjugate acid e.g. CH3OOH + H2O H3O+ + CH3COO– Acid Base Conjugate acid Conjugate base

Define Le–Chatlier’s principle.

Description : Define Le–Chatlier’s principle.

Last Answer : If a system in equilibrium is disturbed at equilibrium it will move in that direction where change is minimized.

What is weak electrolyte?

Description : What is weak electrolyte?

Last Answer : A compound which is only partially ionized in aqueous solution is called as weak electrolyte.e.g CH3COOH(Acetic aci)

Can anyone help me with this? Chlorine and carbon monoxide gases are mixed in a 1.00L container and the following equilibrium is established: CO(g) + Cl2(g) <--> COCl2(g).. Initially 1.5 mol of chlorine was present with excess carbon monoxide. At equilibrium, 0.8 mol of COCl2(g) was found. How do you calculate the percent reaction?

Description : Can anyone help me with this? Chlorine and carbon monoxide gases are mixed in a 1.00L container and the following equilibrium is established: CO(g) + Cl2(g) COCl2(g).. Initially 1.5 mol of ... monoxide. At equilibrium, 0.8 mol of COCl2(g) was found. How do you calculate the percent reaction?

Last Answer : For a start, your equation isn't balanced; it should be Cl2 (Cl2, not 2Cl, because of HONClBrIF). Given this, if we assume the reaction goes to completion, 1.5 mol Cl2 will produce 1.5 mol ... .3% Incidentally, is that supposed to be CO or Co? It has no effect on the calculation, just curious.

For the equilibrium Cl2(g) + 2NO(g) ⇌ 2NOCl(g) the concentration of NOCl will increase if the equilibrium is disturbed by ………..

Description : For the equilibrium Cl2(g) + 2NO(g) ⇌ 2NOCl(g) the concentration of NOCl will increase if the equilibrium is disturbed by ………..

Last Answer : For the equilibrium Cl2(g) + 2NO(g) ⇌ 2NOCl(g) the concentration of NOCl will increase if the equilibrium ... NO c. adding NOCl d. removal of Cl2

Which of the following reaction mixtures will give an organic product which is ionic? (a) CH3CH2OH + PCl5 (b) CH3CH2OH + KBr + H2SO4 (c) CH3CH2OH + Na (d) CH3CH2OH + SOCl2

Description : Which of the following reaction mixtures will give an organic product which is ionic? (a) CH3CH2OH + PCl5 (b) CH3CH2OH + KBr + H2SO4 (c) CH3CH2OH + Na (d) CH3CH2OH + SOCl2

Last Answer : CH3CH2OH + Na

Is PCl3 ionic or covalent bonds?

Description : Is PCl3 ionic or covalent bonds?

Last Answer : Need answer

Which of the following species contains three bond pairs and one lone pair around the central atom? (1) PCl3 (2) H2O (3) BF3 (4) NH2

Description : Which of the following species contains three bond pairs and one lone pair around the central atom? (1) PCl3 (2) H2O (3) BF3 (4) NH2

Last Answer : PCl3

Which of the following molecules exhibit resonance w) OF3 x) HNO3 y) C2H4 z) PCl3

Description : Which of the following molecules exhibit resonance w) OF3 x) HNO3 y) C2H4 z) PCl3

Last Answer : ANSWER: X -- HNO3

Which of the following compounds has the lowest boiling points? w) CH4 x) CCl4 y) PH3 z) PCl3

Description : Which of the following compounds has the lowest boiling points? w) CH4 x) CCl4 y) PH3 z) PCl3

Last Answer : ANSWER: W -- CH4

In ammonia synthesis (N2 + 3H2 = 2NH3 ), there is a decrease in total volume, hence to get high equilibrium conversion, the reaction should becarried out at(A) Low pressure(B) High pressure(C) Very high temperature(D) Atmospheric pressure; as the pressure has no effect on conversion

Description : In ammonia synthesis (N2 + 3H2 = 2NH3 ), there is a decrease in total volume, hence to get high equilibrium conversion, the reaction should becarried out at (A) Low pressure (B) High pressure (C) Very high temperature (D) Atmospheric pressure; as the pressure has no effect on conversion

Last Answer : (B) High pressure

The effect of increasing pressure on the gaseous equilibrium of the reaction2X + 3Y ⇌ 3X + 2Y indicates that(A) Pressure has no effect(B) Backward reaction is favoured(C) Forward reaction is favoured(D) None of the

Description : The effect of increasing pressure on the gaseous equilibrium of the reaction2X + 3Y ⇌ 3X + 2Y indicates that (A) Pressure has no effect (B) Backward reaction is favoured (C) Forward reaction is favoured (D) None of the

Last Answer : (A) Pressure has no effect

In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = 0 (C) Addition of inert gas has no effect on the equilibrium constant at constant volume for any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'

Description : In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = ... any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'

Last Answer : D) All 'a', 'b' & 'c'

What of the following reactions demonstrates a synthesis reaction A) Mg plus H2SO4 and gt MgSO4 plus H2 B) 2NaCl and gt 2Na plus Cl2 C) C plus O2 and gt CO2 D) Zn plus 2HCl and gt ZnCl2 plus H2?

Description : What of the following reactions demonstrates a synthesis reaction A) Mg plus H2SO4 and gt MgSO4 plus H2 B) 2NaCl and gt 2Na plus Cl2 C) C plus O2 and gt CO2 D) Zn plus 2HCl and gt ZnCl2 plus H2?

Last Answer : C+O2 →CO2

What product is formed from the reaction of LiBr plus Cl2?

Description : What product is formed from the reaction of LiBr plus Cl2?

Last Answer : THe chemical reaction is:2 LiBr + Cl2 = 2 LiCl + Br2

Adding Cl2 to benzene in the presence of AlCl3 is an example of – (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Description : Adding Cl2 to benzene in the presence of AlCl3 is an example of – (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Last Answer : (2) Substitution reaction Explanation: The reaction between benzene and chlorine in the presence of a catalyst such as aluminium chloride gives Chlorobenzene. This reaction is an example of electrophilic substitution ... since one of the hydrogen atoms on the ring is replaced by a chlorine atom.

Which of the following statements about the reaction given below are correct? MnO2 + 4HCI → MnCl2 +2H20 + Cl2 (i) HCl is oxidized to Cl2 (ii) MnO2 is reduced to MnCl2 (iii) MnCl2 acts as an oxidizing agent (iv) HCl acts as an oxidizing agent (a) (i), (iii) and (iv) (b) (i), (ii) and (iii) (c) (i) and (ii) only (d) (iii) and (iv) only

Description : Which of the following statements about the reaction given below are correct? MnO2 + 4HCI → MnCl2 +2H20 + Cl2 (i) HCl is oxidized to Cl2 (ii) MnO2 is reduced to MnCl2 (iii) MnCl2 acts as an oxidizing agent (iv) HCl acts ... b) (i), (ii) and (iii) (c) (i) and (ii) only (d) (iii) and (iv) only

Last Answer : Answer: . (c)

What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the chain reaction. (b) It functions by destabilizing the carbocationic intermediate and thereby increases the rate of H+ loss. (c) It serves as a Lewis base catalyst by reacting with Cl2 to generate chloride ions. (d) It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Description : What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the ... by reacting with the Cl2 and thereby activates it toward attack by benzene's π electrons.

Last Answer : It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Adding Cl2 to benzene in the presence of AlCl3 is an example of : (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Description : Adding Cl2 to benzene in the presence of AlCl3 is an example of : (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Last Answer : Substitution reaction

Promoter (A) Initiates a chemical reaction and is a catalyst by itself (B) Alters the position of equilibrium in a reversible reaction (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals(D) All (A), (B) and (C)

Description : Promoter (A) Initiates a chemical reaction and is a catalyst by itself (B) Alters the position of equilibrium in a reversible reaction (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals (D) All (A), (B) and (C)

Last Answer : (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals

Pick out the wrong statement. (A) A catalyst does not alter the final position of equilibrium in a reversible reaction (B) A catalyst initiates a reaction (C) A catalyst is specific in reaction (D) A catalyst remains unchanged in chemical composition at the end the reaction

Description : Pick out the wrong statement. (A) A catalyst does not alter the final position of equilibrium in a reversible reaction (B) A catalyst initiates a reaction (C) A catalyst is specific in reaction (D) A catalyst remains unchanged in chemical composition at the end the reaction

Last Answer : (B) A catalyst initiates a reaction

"When a system in equilibrium is subjected to a change in temperature, pressure or concentration, the equilibrium is displaced in a direction which tends to undo the effect of the change." This is called the (A) Le-Chatelier principle (B) Kopp's rule (C) Law of corresponding state (D) Arrhenius hypothesis

Description : "When a system in equilibrium is subjected to a change in temperature, pressure or concentration, the equilibrium is displaced in a direction which tends to undo the effect of the change." This is ... Chatelier principle (B) Kopp's rule (C) Law of corresponding state (D) Arrhenius hypothesis

Last Answer : (A) Le-Chatelier principle

Pick out the correct statement. (A) A catalyst speeds up the forward reaction but slows shown the reverse reaction (B) Addition of catalyst changes the equilibrium constant (C) Pressure changes do not change the equilibrium concentrations (D) The composition of equilibrium is changed by catalyst

Description : Pick out the correct statement. (A) A catalyst speeds up the forward reaction but slows shown the reverse reaction (B) Addition of catalyst changes the equilibrium constant (C) Pressure changes do not change the equilibrium concentrations (D) The composition of equilibrium is changed by catalyst

Last Answer : (C) Pressure changes do not change the equilibrium concentrations

The standard Gibbs free energy change of a reaction depends on the equilibrium (A) Pressure (B) Temperature (C) Composition (D) All (A), (B) and (C)

Description : The standard Gibbs free energy change of a reaction depends on the equilibrium (A) Pressure (B) Temperature (C) Composition (D) All (A), (B) and (C)

Last Answer : (B) Temperature

In the reaction; N2 + O2 ⇌ 2NO, increasing the pressure will result in (A) Shifting the equilibrium towards right (B) Shifting the equilibrium towards left (C) No change in equilibrium condition (D) None of these

Description : In the reaction; N2 + O2 ⇌ 2NO, increasing the pressure will result in (A) Shifting the equilibrium towards right (B) Shifting the equilibrium towards left (C) No change in equilibrium condition (D) None of these

Last Answer : (C) No change in equilibrium condition

What is the name of the compound with the formula PCl5 ?

Description : What is the name of the compound with the formula PCl5 ?

Last Answer : Phosphorus pentachloride

What happens to the dissociation of PCl5 in a closed vessel if He gas is introduced into it at the same temperature?

Description : What happens to the dissociation of PCl5 in a closed vessel if He gas is introduced into it at the same temperature?

Last Answer : Ans. No effect.

Explain why PCl5 is trigonal bipyramidal and IF5is square pyramidal?

Description : Explain why PCl5 is trigonal bipyramidal and IF5is square pyramidal?

Last Answer : Ans. PCl5 has 5 bond pairs of electrons around central atom while in IF5 there are 5 bond pair & 1 lone pair of electrons around central atom.

Are all the five bonds in PCl5 molecule equivalent ?

Description : Are all the five bonds in PCl5 molecule equivalent ? 

Last Answer : Ans – PCl5 has a trigonal bipyramidal structure and the three equatorial p-cl bonds are equivalent . while trhe two axial bonds are different and longer than equatorial bonds. 

Phosphatic fertiliser is graded based on its __________ content. (A) P2O3 (B) PCl5 (C) P2O5 (D) H3PO4

Description : Phosphatic fertiliser is graded based on its __________ content. (A) P2O3 (B) PCl5 (C) P2O5 (D) H3PO4

Last Answer : (C) P2O5

Compound (A) when reacted with PCl5 and then with ammonia gave (B). Compound (B) when treated with bromine and NaOH, produced (C). Compound (C) on treatment with NaNO2/HCl at 0°C and then boiling with H2O produced ocresol. Compound (A) is (a) o-Toluic acid (b) o-Chlorotoluene (c) m-Toluic acid (d) o-Bromotoluene

Description : Compound (A) when reacted with PCl5 and then with ammonia gave (B). Compound (B) when treated with bromine and NaOH, produced (C). Compound (C) on treatment with NaNO2/HCl at 0°C and then boiling with H2O ... Compound (A) is (a) o-Toluic acid (b) o-Chlorotoluene (c) m-Toluic acid (d) o-Bromotoluene

Last Answer : o-Toluic acid