What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the chain reaction. (b) It functions by destabilizing the carbocationic intermediate and thereby increases the rate of H+ loss. (c) It serves as a Lewis base catalyst by reacting with Cl2 to generate chloride ions. (d) It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

What purpose does FeCl3 serve in the electrophilic aromatic substitution
reaction between chlorine and benzene?
(a) It serves as a radical initiator to produce the chlorine radical needed to
propagate the chain reaction.
(b) It functions by destabilizing the carbocationic intermediate and thereby
increases the rate of H+ loss.
(c) It serves as a Lewis base catalyst by reacting with Cl2 to generate chloride
ions.
(d) It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates
it toward attack by benzene’s π electrons.
by

1 Answer

Answer :

It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates
it toward attack by benzene’s π electrons.
by

Related questions

Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the rate-determining step. (c) The carbocation intermediate contains an sp3 hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Last Answer : The addition product is a frequently observed minor product.

Benzene reacts with chlorine in the presence of FeCl3 catalyst to form (a) Hexachlorobenzene (b) Chlorobenzene (c) Hexachlorocyclohexane (d) Benzyl chloride

Description : Benzene reacts with chlorine in the presence of FeCl3 catalyst to form (a) Hexachlorobenzene (b) Chlorobenzene (c) Hexachlorocyclohexane (d) Benzyl chloride

Last Answer : Chlorobenzene

How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Description : How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Last Answer : The lone pair of electrons present on oxygen atom enter into resonance with the benzene ring. As a result, the electron density becomes higher at o- and p- position and due to higher electron density, the ring gets activated towards electrophilic substitution.

Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Description : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Last Answer : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the ... D. A is incorrect but R is correct

In electrophilic aromatic substitution reactions a chlorine substituent __________. (a) is a deactivator and a m-director (b) is a deactivator and an o,p-director (c) is an activator and a m-director (d) is an activator and an o,p-director

Description : In electrophilic aromatic substitution reactions a chlorine substituent __________. (a) is a deactivator and a m-director (b) is a deactivator and an o,p-director (c) is an activator and a m-director (d) is an activator and an o,p-director

Last Answer : is a deactivator and an o,p-director

Iodobenzene can be prepared by (a) treating chlorobenzene with I2 using FeCl3 catalyst. (b) treating phenol with I2 in NaOH solution. (c) treating benzenediazonium chloride with KI (d) treating benzene with CH3I using AlCl3 catalyst

Description : Iodobenzene can be prepared by (a) treating chlorobenzene with I2 using FeCl3 catalyst. (b) treating phenol with I2 in NaOH solution. (c) treating benzenediazonium chloride with KI (d) treating benzene with CH3I using AlCl3 catalyst

Last Answer : treating benzenediazonium chloride with KI

Chain growth polymerisation is a process, in which the monomers are added in a chain fashion, and it requires an initiator to produce the free radical. An example of chain growth polymerisation products is (A) Nylon-66 (B) Teflon (C) Polyester (D) Bakelite

Description : Chain growth polymerisation is a process, in which the monomers are added in a chain fashion, and it requires an initiator to produce the free radical. An example of chain growth polymerisation products is (A) Nylon-66 (B) Teflon (C) Polyester (D) Bakelite

Last Answer : (B) Teflon

Adding Cl2 to benzene in the presence of AlCl3 is an example of – (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Description : Adding Cl2 to benzene in the presence of AlCl3 is an example of – (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Last Answer : (2) Substitution reaction Explanation: The reaction between benzene and chlorine in the presence of a catalyst such as aluminium chloride gives Chlorobenzene. This reaction is an example of electrophilic substitution ... since one of the hydrogen atoms on the ring is replaced by a chlorine atom.

Adding Cl2 to benzene in the presence of AlCl3 is an example of : (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Description : Adding Cl2 to benzene in the presence of AlCl3 is an example of : (1) Elimination reaction (2) Substitution reaction (3) None of the options (4) Addition reaction

Last Answer : Substitution reaction

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Which of the following agents is used in order to make benzene react with concentrated nitric acid to give nitrobenzene? (a) Concentrated H2SO4 (b) FeCl3 catalyst (c) Lindlar's catalyst (d) Ultraviolet light

Description : Which of the following agents is used in order to make benzene react with concentrated nitric acid to give nitrobenzene? (a) Concentrated H2SO4 (b) FeCl3 catalyst (c) Lindlar's catalyst (d) Ultraviolet light

Last Answer : Concentrated H2SO4

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ?

Description : Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ?

Last Answer : Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ? A. `A gt B gt ... A` D. `C gt B gt D gt A`

Which of the following reagents is most suitable for preparing chlorobenzene from benzene? (a) Aqueous chlorine (b) Chlorine in the presence of ultraviolet light (c) Chlorine in acetic acid (d) Chlorine in the presence of FeCl3

Description : Which of the following reagents is most suitable for preparing chlorobenzene from benzene? (a) Aqueous chlorine (b) Chlorine in the presence of ultraviolet light (c) Chlorine in acetic acid (d) Chlorine in the presence of FeCl3

Last Answer : Chlorine in the presence of FeCl3

Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Description : Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Last Answer : nucleophilic addition; free radical addition

The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

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Last Answer : a free-radical substitution

Chlorine free radicals react with methane by : (a) donating their free-radical electron to methane to form chloromethane. (b) abstracting a hydrogen atom from methane, and producing HCl and a methyl radical. (c) forming a carbanion intermediate that rapidly dissociates to produce chloromethane. (d) forming a carbonium ion intermediate that rapidly dissociates to form chloromethane

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Last Answer : abstracting a hydrogen atom from methane, and producing HCl and a methyl radical

Chlorobenzene can be prepared by treatment of aniline with (a) Cuprous chloride (b) Chlorine in the presence of UV light (c) Nitrous acid followed by treatment with CuCl (d) Chlorine in the presence of FeCl3

Description : Chlorobenzene can be prepared by treatment of aniline with (a) Cuprous chloride (b) Chlorine in the presence of UV light (c) Nitrous acid followed by treatment with CuCl (d) Chlorine in the presence of FeCl3

Last Answer : Nitrous acid followed by treatment with CuCl

Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Description : Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

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Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

Description : Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

Last Answer : Benzene + Br2/FeBr3

Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) Aldehydes are more sterically hindered than esters. (c) Once the nucleophile adds to an aldehyde, the tetrahedral intermediate is too sterically hindered to eliminate one of the attached groups. (d) Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Which halogen does not appreciably react with methane in a free-radical substitution reaction? (a) chlorine (b) bromine (c) iodine (d) fluorine

Description : Which halogen does not appreciably react with methane in a free-radical substitution reaction? (a) chlorine (b) bromine (c) iodine (d) fluorine

Last Answer : iodine

Presence of carbonaceous matter in the sewage (A) Causes reduction in its dissolved oxygen content thereby endangering the life of aquatic creatures (B) Reduces sulphate ions to sulphides causing obnoxious smell (C) Increases the quantity of chlorine used for its purification (D) All (A), (B) and (C)

Description : Presence of carbonaceous matter in the sewage (A) Causes reduction in its dissolved oxygen content thereby endangering the life of aquatic creatures (B) Reduces sulphate ions to sulphides causing obnoxious ... quantity of chlorine used for its purification (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Buffer solutions have constant acidity and alkalinity because: (1) they have fixed value of pH (2) these give unionised acid or base on reaction with added acid or alkali (3) acids and alkalies in these solutions are shielded from attack by other ions (4) they have large excess of H+ or OH– ions

Description : Buffer solutions have constant acidity and alkalinity because: (1) they have fixed value of pH (2) these give unionised acid or base on reaction with added acid or alkali (3) acids and alkalies in these solutions are shielded from attack by other ions (4) they have large excess of H+ or OH– ions

Last Answer : these give unionised acid or base on reaction with added acid or alkali

The reaction between methane and chlorine in diffused sunlight is-----? A. Oxidation B. Reduction C. Polymerisation D. Radical substitution (Answer)

Description : The reaction between methane and chlorine in diffused sunlight is-----? A. Oxidation B. Reduction C. Polymerisation D. Radical substitution (Answer)

Last Answer : D. Radical substitution (Answer)

Ammonia can be considered a Lewis base because it can donate: w) electrons x) protons y) hydronium ions z) hydroxide ions

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Last Answer : ANSWER: A -- ELECTRONS

Chlorine atom and chloride ions - (1) Have an equal number of protons (2) Have an equal number of electrons (3) Unequal number neutrons (4) reacts spontaneously with water

Description : Chlorine atom and chloride ions - (1) Have an equal number of protons (2) Have an equal number of electrons (3) Unequal number neutrons (4) reacts spontaneously with water

Last Answer : (1) Have an equal number of protons

Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

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Last Answer : there is delocalization of electrons

Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

Description : Benzene undergoes substitution reaction more easily than addition reaction because (a) it has a cyclic structure (b) it has three double bonds (c) it has six hydrogen atoms (d) there is delocalization of electrons

Last Answer : there is delocalization of electrons

Aromatic molecules contain __________ π electrons. (a) no (b) 4n + 2 (with n being an integer) (c) 4n + 2 (with n being 0.5) (d) 4n (with n an integer)

Description : Aromatic molecules contain __________ π electrons. (a) no (b) 4n + 2 (with n being an integer) (c) 4n + 2 (with n being 0.5) (d) 4n (with n an integer)

Last Answer : 4n + 2 (with n being an integer)

The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When `-NO_(2)` group is present at ortho

Description : The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When `-NO_(2)` group is present at ortho

Last Answer : The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When ` ... product (I) is : A. B. C. D.

The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When `-NO_(2)` group is present at ortho

Description : The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When `-NO_(2)` group is present at ortho

Last Answer : The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When ` ... product (H) is : A. B. C. D.

The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When `-NO_(2)` group is present at ortho

Description : The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When `-NO_(2)` group is present at ortho

Last Answer : The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When ` ... product (G) is : A. B. C. D.

Which one of the following statements regarding a catalyst is not correct? A An enzyme is a catalyst that only binds certain substrates. B An enzyme is a protein that is a highly efficient catalyst for one or more chemical reactions in a living system. C Catalysts increase the rate of a reaction by altering the mechanism, thereby increasing the activation energy. D Catalysts do not alter the equilibrium constant for a chemical reaction.

Description : Which one of the following statements regarding a catalyst is not correct? A An enzyme is a catalyst that only binds certain substrates. B An enzyme is a protein that is a highly ... increasing the activation energy. D Catalysts do not alter the equilibrium constant for a chemical reaction.

Last Answer : C Catalysts increase the rate of a reaction by altering the mechanism, thereby increasing the activation energy.

During the reaction of Benzene diazonium chloride with para-cresol the substitution occurs at_____position of p-cresol.

Description : During the reaction of Benzene diazonium chloride with para-cresol the substitution occurs at_____position of p-cresol.

Last Answer : During the reaction of Benzene diazonium chloride with para-cresol the substitution occurs at_____position of p-cresol.

The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Description : The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Last Answer : nucleophilic substitution

A catalyst in a chemical reaction (A) Decreases the activation energy (B) Alters the reaction mechanism (C) Increases the frequency of collisions of reacting species (D) All (A), (B) and (C)

Description : A catalyst in a chemical reaction (A) Decreases the activation energy (B) Alters the reaction mechanism (C) Increases the frequency of collisions of reacting species (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

"The rate at which a substance reacts is proportional to its active mass and the rate of a chemical reaction is proportional to the product of active masses of the reacting substances". This is the (A) Lewis-Randall rule (B) Statement of Van't Hoff Equation (C) Le-Chatelier's principle (D) None of these

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Last Answer : (D) None of these

If Mg Cl2 contains one Millions of Mg2+ Ions, then how many Chloride Ions are present in it?

Description : If Mg Cl2 contains one Millions of Mg2+ Ions, then how many Chloride Ions are present in it?

Last Answer : Two million

Phenol is an ortho-para director because the hydroxyl group : (a) donates electrons that increase electron density at ortho and para positions favoring nucleophilic attack. (b) donates electrons that increase electron density at ortho and para positions favoring electrophilic attack. (c) donates electrons to the ortho and para positions and attracts electrons away from meta positions favoring nucleophilic attack of the ring. (d) donates electrons to the ortho and para positions and attracts electrons away from meta positions favoring electrophilic attack on the ring.

Description : Phenol is an ortho-para director because the hydroxyl group : (a) donates electrons that increase electron density at ortho and para positions favoring nucleophilic attack. (b) donates ... para positions and attracts electrons away from meta positions favoring electrophilic attack on the ring.

Last Answer : donates electrons that increase electron density at ortho and para positions favoring electrophilic attack.

Pyridine undergoes electrophilic substitution with fuming H2SO4 at 350°C to give (a) 2-Pyridinesulfonic acid (b) 4-Pyridinesulfonic acid (c) 3-Pyridinesulfonic acid (d) None of these

Description : Pyridine undergoes electrophilic substitution with fuming H2SO4 at 350°C to give (a) 2-Pyridinesulfonic acid (b) 4-Pyridinesulfonic acid (c) 3-Pyridinesulfonic acid (d) None of these

Last Answer : 3-Pyridinesulfonic acid

A chlorine atom reacts with a sodium atom to form sodium chloride, NaCl. A chlorine atom can also react with another chlorine atom to form a chlorine molecule, Cl2. Which statement BEST explains the behavior of chlorine in these two reactions?

Description : A chlorine atom reacts with a sodium atom to form sodium chloride, NaCl. A chlorine atom can also react with another chlorine atom to form a chlorine molecule, Cl2. Which statement BEST explains the behavior of chlorine in these two reactions?

Last Answer : A chlorine atom can form ionic bonds by accepting an electron and covalent bonds by sharing electrons.

The electrophile, `E^((o+))` attacks the benzene ring to generate the intermediate `sigma`-complex. Of the following which `sigma`-complex is of lowes

Description : The electrophile, `E^((o+))` attacks the benzene ring to generate the intermediate `sigma`-complex. Of the following which `sigma`-complex is of lowes

Last Answer : The electrophile, `E^((o+))` attacks the benzene ring to generate the intermediate `sigma`-complex. Of the ... is of lowest energy? A. B. C. D.

40. Among the fo the one that is most reactive towards electrophilic nitration is: (1) Benzene (2) Benzoic acid (3) Nitrobenzene (4) Toluene

Description : 40. Among the following compounds the one that is most reactive towards electrophilic nitration is: (1) Benzene (2) Benzoic acid (3) Nitrobenzene (4) Toluene

Last Answer : Toluene

Assertion: Phenol is more reactive than benzene towards electrophilic reactions. Reason : The +R effect of OH group increases the electron density on

Description : Assertion: Phenol is more reactive than benzene towards electrophilic reactions. Reason : The +R effect of OH group increases the electron density on

Last Answer : Assertion: Phenol is more reactive than benzene towards electrophilic reactions. Reason : The +R effect of ... D. A is incorrect but R is correct

Which of the following agents is used in order to make benzene react with acetyl chloride to give acetophenone?(a) Ultraviolet light (b) AlCl3 catalyst (c) Platinum catalyst (d) Al2O3 catalyst

Description : Which of the following agents is used in order to make benzene react with acetyl chloride to give acetophenone? (a) Ultraviolet light (b) AlCl3 catalyst (c) Platinum catalyst (d) Al2O3 catalyst

Last Answer : AlCl3 catalyst

Which of the following statements are false about benzene? (a) It is a planar molecule with bond angles 120°(b) It is immiscible with water forming the lower layer. (c) It can be converted into cyclohexane by hydrogenation at 200°C in the presence of Ni catalyst. (d) It reacts with ethyl chloride in the presence of aluminium chloride to form ethylbenzene..

Description : Which of the following statements are false about benzene? (a) It is a planar molecule with bond angles 120°. (b) It is immiscible with water forming the lower layer. (c) It can be ... Ni catalyst. (d) It reacts with ethyl chloride in the presence of aluminium chloride to form ethylbenzene.

Last Answer : It is immiscible with water forming the lower layer

Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ?

Description : Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ?

Last Answer : Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ... D. Yes, in a non-polar solvent