What is meant by state of chemical equilibrium?

1 Answer

Answer :

The state of reversible reaction, in which forward and reverse rates are equal.(Rf=Rr)

Related questions

Description : How the change in pressure at equilibrium position effect the following reaction? PCl5 PCl3 + Cl2

Last Answer : According to Le–chatlier’s principle, by increasing pressure the reaction will move toward less number of moles. In the above reaction, by increasing pressure the reaction will move in backward direction.

Description : A catalyst does not change the position of equilibrium but this equilibrium position approach earlier. Why?

Last Answer : A catalyst decrease the energy of activation required by reacting substance so the position of equilibrium reaches earlier.

Description : How value of Kc can help to predict the extent to which a chemical reaction can take place?

Last Answer : The extent of reaction depends upon the magnitude of Kc. i.e. (i) Very small value of Kc: when Kc is very small the forward reaction will not occur to an appreciable extent ... neither very large nor very small, the equilibrium mixture contains appreciable amounts of both reactant and products.

Description : How Kc can be applied to calculate direction of chemical reaction?

Last Answer : (i) If < Kc Then the reaction will proceed in the forward direction until the equilibrium is established. (ii) If > Kc Then the reaction will proceed in the backward direction until the equilibrium is established. If = kc Then the reaction is already in equilibrium.

Description : What is solubility product?

Last Answer : The product of molar solubilities of the ions of weak electrolyte at equilibrium stage is called solubility product. It is represented by Ksp

Description : What is common ion effect?

Last Answer : The decrease in ionization of a weak electrolyte by adding another strong electrolyte having common ion.e.g ionization of NaCl is decreased by passing HCl through NaCl solution.

Description : How can you co–relate Ka with Kc?

Last Answer : Ka is dissociation constant of an acid while Kc is the equilibrium constant suppose an acid HA Ionize as HA + H2O  H3O+ + A– Kc = concentration of [H2O] almost remains constant so we can write. Kc = Kc [H2O] = ka Ka =

Description : A buffer consists of a weak acid and is salt.

Last Answer : (i) CH3COOH + CH3COONa (ii) C6H5COOH + C6H5COONa (iii) H2CO3 + NaHCO3 (iv) H3PO3 + NaH2PO4

Description : How can you purify NaCl by common ion effect?

Last Answer : The impurities present in the common salt are CaCl2 MgCl2 and Na2SO4 in it. These impurities can be removed by common Ion effect. For this purpose a saturated solution of NaCl is prepared. Then ... electrolyte than NaCl Ionization of NaCl is suppressed by passing HCl gas and it is precipitated out.

Description : Prove that Kw is ionic product of water and its value is 1 x 10–14 at 25o.

Last Answer : Water undergoes self ionization as 2H2O  H3O+ + OH– or H2O  H+ + OH– Kc [H2O] = [H+] [OH–] Kw = [H+] [OH–] At 25oC the value of Kw ionic product have been measured. Its value is 1 x 10–14.

Description : What is the relationship b/w kc, kp kc & kn?

Last Answer : These four parameters are related as. Kp = Kc (RT)n = Kx (P)n = Kn When mole of products are reactant are equal i.e. n = 0 their Kp = kc = dx = kn

Description : What are optimum conditions for the formation of NH3 by Haber’s process? N2(g) + 3H2(g) 2NH3(g) H = -92.46 kJ/m

Last Answer : (i) As the reaction is exothermic max yield is obtained at low temp. (ii) By applying pressure, more product is obtained. According four moles of reactants produce two moles of product so by applying ... (vi) Rate of reaction can also be increase with the help of catalyst like iron or iron oxide.

Description : What is buffer capacity?

Last Answer : The amount of acid or base which a buffer can absorb without significant charge in PH is called buffer capacity. Buffer capacity is the ability of buffer to resist the change in its PH value.

Description : Discuss the factors on which buffer PH depends.

Last Answer : PH of buffer depends upon two factors. (i) Pka or ka value of an acid (ii) Concentration of salt and acid taken for the buffer.

Description : Why we need buffer solution in daily life?

Last Answer : Buffers can resist the charge of its PH value therefore they are required in chemical analysis, pharmaceuticals, electroplating, photography, beverage industry, microbiology molecular biology, soil science and in quantitative ... PH 7.35. If it decreases upto 7 or goes upto 8 death may occur.

Description : What are conjugate acid and bases?

Last Answer : When an acid is dissolved in water it will form H3O+ ions and an anion the anion of an acid is called conjugate base and H3O+ is called conjugate acid e.g. CH3OOH + H2O H3O+ + CH3COO– Acid Base Conjugate acid Conjugate base

Description : Define Le–Chatlier’s principle.

Last Answer : If a system in equilibrium is disturbed at equilibrium it will move in that direction where change is minimized.

Description : What are reversible reaction?

Last Answer : Those reactions in which the reactants products are converted into each other under same set of conditions.

Description : What is weak electrolyte?

Last Answer : A compound which is only partially ionized in aqueous solution is called as weak electrolyte.e.g CH3COOH(Acetic aci)

Description : The chemical reaction at one time the rate of forward and backward reaction becomes equal that state is called Equilibrium state. In a chemical equilibrium, the following properties remain unchanged with time. Pressure, Temperature, density, color Pressure, Temperature, density, color

Last Answer : Who proposed law of mass action ?

Description : In an interphase heat transfer process, the equilibrium state corresponds to equality of temperature in the two phases, while the condition for equilibrium in an interphase mass transfer process is ... B) Chemical potentials (C) Activity co-efficients (D) Mass transfer co-efficients

Last Answer : (A) Concentrations

Description : Pick out the correct statement. (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state (C) A photochemical reaction is catalysed by ... occurs when the energy of the reacting molecule is less than the activation energy of the reaction

Last Answer : (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state

Description : Equilibrium of a chemical reaction as viewed by kinetics is a __________ state. (A) Dynamic steady (B) Static steady (C) Dynamic unsteady (D) None of these

Last Answer : (A) Dynamic steady

Description : Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an ... does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature

Last Answer : (C) The rate constant for a first order reaction does not change on changing the concentration units

Description : Are Chemical Equilibrium Affected by Influencers ?

Last Answer : : The equilibrium that occurs in a two-way chemical reaction in the presence of an influencer in a given experimental state is the same equilibrium that is obtained when the reaction is performed ... state . However, in the presence of catalysts, the equilibrium of the reaction is achieved quickly.

Description : What is Chemical Equilibrium ?

Last Answer : : Chemical equilibrium is when the rate of forward and backward reactions is equal in a bilateral reaction.

Description : Title is chemical equilibrium

Last Answer : given temperature pbi 2 to will be more soluble in

Description : Is chemical equilibrium reversible?

Last Answer : Need answer

Description : The function of an enzyme is to (A) Cause chemical reactions that would not otherwise take place (B) Change the rates of chemical reactions (C) Control the equilibrium points of reactions (D) Change the directions of reactions

Last Answer : Answer : B

Description : What are the consequences of shifting the chemical equilibrium of the formation of bicarbonate from carbon dioxide and water towards the consumption of products of the reverse reaction?

Last Answer : The shifting of the chemical equilibrium of the formation of bicarbonate from carbon dioxide and water into the reverse reaction (production of water and carbon dioxide) means spending of hydrogen ions and thus it increases the solution pH.

Description : What are the consequences of shifting the chemical equilibrium of the formation of bicarbonate from carbon dioxide and water towards the increase of product (bicarbonate) formation?

Last Answer : The increase in product formation in the chemical equilibrium of the formation of bicarbonate from carbon dioxide and water heightens the concentration of hydrogen ions and thus lowers the pH of the solution.

Description : Write characteristics of Chemical equilibrium.

Last Answer : Ans. (i) At equilibrium the rate of forward reaction becomes equal to rate of backward reaction. (ii) A chemical equilibrium established only if none of the products are allowed to escape out ... can be attained from either direction. (iv) Catalyst does not alter the state of equilibrium.

Description : Pick out the wrong statement (A) Co-current absorbers are usually used, when the gas to be dissolved in the liquid is a pure substance (B) In case of gas absorption, HETP is ... reaction (D) In actual practice, absorption is an endothermic process, while stripping is an exothermic process

Last Answer : (D) In actual practice, absorption is an endothermic process, while stripping is an exothermic process

Description : Supply of excess air for complete combustion of fuel is necessitated to facilitate (A) Its thorough mixing with air (B) Attainment of chemical equilibrium (C) Attainment of high temperature (D) None of these

Last Answer : (A) Its thorough mixing with air

Description : The rate of forward reaction, at chemical equilibrium is _________the rate of backward reaction. (A) More than (B) Less than (C) Equal to (D) Either (B) or (C)

Last Answer : (C) Equal to

Description : Reverse reaction in a chemical equilibrium is favoured by the (A) Removal of one of the products regularly (B) Increase in the concentration of one of the products (C) Increase in the concentration of one of the reactants (D) None of these

Last Answer : (B) Increase in the concentration of one of the products

Description : In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled, then the equilibrium constant will (A) Remain the same (B) Be halved (C) Also be doubled (D) Become one fourth

Last Answer : (A) Remain the same

Description : The role of a catalyst in a chemical reaction is to change the (A) Equilibrium constant (B) Activation energy (C) Final products (D) Heat of reaction

Last Answer : (B) Activation energy

Description : Which of the following will favour the reverse reaction in a chemical equilibrium reaction? (A) Increasing the concentration of one of the reactants (B) Increasing the concentration of one or more of the products (C) Removal of at least one of the products at regular interval (D) None of these

Last Answer : (B) Increasing the concentration of one or more of the products

Description : Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the ... ) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions

Last Answer : (C) The intercept of the Arrhenius plot is called the 'activation energy

Description : Catalytic action in a catalytic chemical reaction follows from the ability of catalyst to change the (A) Activation energy (B) Equilibrium constant (C) Heat of reaction (D) None of these

Last Answer : (A) Activation energy

Description : Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to ... Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction

Last Answer : (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot

Description : Pick out the wrong statement. (A) Catalytic activity of enzyme catalysed reactions which is affected by temperature, pH value & chemical agents, is maximum at a temperature of about 45°C ... in enzyme catalysed reactions can be calculated by using the thermodynamic properties of substrates & prod

Last Answer : (C) Enzymes help in increasing the activation energy of the reaction

Description : For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant (A) Is independent of pressure (B) Increases with pressure (C) Decreases with pressure (D) Increases /decreases with pressure depending on the stoichiometric co￾efficients of the reaction

Last Answer : (B) Increases with pressure

Description : Higher free energy of activation of a chemical reaction (at a given temperature) implies (A) Slower rate of reaction (B) Higher rate of reaction (C) Higher equilibrium conversion (D) Both (B) and (C)

Last Answer : (A) Slower rate of reaction

Description : Promoter (A) Initiates a chemical reaction and is a catalyst by itself (B) Alters the position of equilibrium in a reversible reaction (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals (D) All (A), (B) and (C)

Last Answer : (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals

Description : The catalyst in a first order chemical reaction changes the (A) Equilibrium constant (B) Activation energy (C) Heat of formation of the product (D) Heat of reaction

Last Answer : (B) Activation energy

Description : Pick out the wrong statement. (A) A catalyst does not alter the final position of equilibrium in a reversible reaction (B) A catalyst initiates a reaction (C) A catalyst is specific in reaction (D) A catalyst remains unchanged in chemical composition at the end the reaction

Last Answer : (B) A catalyst initiates a reaction

Description : The equilibrium constant ‘K’ of a chemical reaction depends on (A) Temperature only (B) Pressure only (C) Temperature and pressure (D) Ratio of reactants

Last Answer : (A) Temperature only