Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2.Degree of dissociation of PCl5 will (A) Decrease on addition of Cl2
(B) Increase on addition of an inert gas at constant pressure (C) Decrease on increasing the pressure of the system
(D) None of these

1 Answer

Answer :

(D) None of thes

Related questions

Description : In the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2, decrease in the pressure of the system will __________ the degree of dissociation of PCl5. (A) Increase (B) Decrease (C) Not alter (D) None of these

Last Answer : (A) Increase

Description : In case of the decomposition of hydroiodic acid (2HI ⇌ H2 + I2), addition of H2(at equilibrium condition) will (A) Increase the partial pressure of I2 (B) Decrease the partial pressure of HI (C) Diminish the degree of dissociation of HI (D) None of these

Last Answer : (C) Diminish the degree of dissociation of HI

Description : Consider the following gaseous equilibrium: PCl3 + Cl2 = PCl5 + heat. Which of the following changes will shift it to the right: w) lower the temperature x) remove some Cl2 y) increase the volume z) add a catalyst

Last Answer : ANSWER: W -- LOWER THE TEMPERATURE

Description : How the change in pressure at equilibrium position effect the following reaction? PCl5 PCl3 + Cl2

Last Answer : According to Le–chatlier’s principle, by increasing pressure the reaction will move toward less number of moles. In the above reaction, by increasing pressure the reaction will move in backward direction.

Description : Considering the endothermic dissociation of CaCO3 in a closed vessel (CaCO3 ⇌ CaO + CO2 ), the pressure of CO2 increases, if (A) A catalyst is added (B) The temperature is increased (C) An inert gas is pumped keeping the temperature constant (D) None of these

Last Answer : (B) The temperature is increased

Description : In the reaction, H2 +I2 ⇌ 2HI, addition of an inert gas will (A) Increase the partial pressure of H2 (B) Increase the partial pressure of I2 (C) Increase the total pressure and hence shift the equilibrium towards the right (D) Not affect the equilibrium conditions

Last Answer : (D) Not affect the equilibrium conditions Share

Description : Pick out the wrong statement pertaining to solvent extraction of oil. Rate of extraction (A) Decreases with decrease of thickness of the flakes (B) Increases with the increasing flake size ... considerably with the rise of temperature (D) Decreases as the moisture content of flakes increases

Last Answer : (D) Decreases as the moisture content of flakes increases

Description : The decomposition of A into B is represented by the exothermic reaction, A ⇌ 2B. To achieve maximum decomposition, it is desirable to carry out the reaction. (A) At high P and high T (B) At low P and high T (C) At low P and low T (D) At high P and low T

Last Answer : (C) At low P and low T

Description : Pick out the wrong statement. (A) The conversion for a gas phase reaction increases with decrease in pressure, if there is an increase in volume accompanying the reaction (B) With ... phase reaction increases with increase in pressure, if there is a decrease in volume accompanying the reaction

Last Answer : (B) With increase in temperature, the equilibrium constant increases for an exothermic reaction

Description : For the equilibrium Cl2(g) + 2NO(g) ⇌ 2NOCl(g) the concentration of NOCl will increase if the equilibrium is disturbed by ………..

Last Answer : For the equilibrium Cl2(g) + 2NO(g) ⇌ 2NOCl(g) the concentration of NOCl will increase if the equilibrium ... NO c. adding NOCl d. removal of Cl2

Description : What happens to the dissociation of PCl5 in a closed vessel if He gas is introduced into it at the same temperature?

Last Answer : Ans. No effect.

Description : Pick out the wrong statement pertaining to the cooling towers. (A) In case of induced draft cooling tower, the fan is placed at the top of the tower (B) Effectiveness of ... Effectiveness of a mechanical draft cooling tower is reduced with increase in air wet-bulb temperature

Last Answer : (D) Effectiveness of a mechanical draft cooling tower is reduced with increase in air wet-bulb temperature

Description : In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = ... any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'

Last Answer : D) All 'a', 'b' & 'c'

Description : Pick out the wrong statement. (A) Hard glass which is used for making laboratory glass wares is a mixture of sodium borosilicate and aluminium borosilicate (B) Glass is decolorized during its manufacture by ... Na2O . CaO . 6SiO2 (D) Red color is imparted to glass by addition of arsenic oxide

Last Answer : (D) Red color is imparted to glass by addition of arsenic oxide

Description : Pick out the correct statement pertaining to catalytic cracking. (A) With increase in the reactor pressure, octane number of gasoline decreases (B) With increase in the reactor temperature, gasoline yield decreases for a given ... with increase in the catalyst to oil ratio (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Description : In the reversible reaction of the type, A + B ⇌ AB, in general (A) Both forward and backward reactions will be exothermic (B) Neither of the reactions will be endothermic (C) ... will be endothermic (D) The combination reaction will be endothermic, while the dissociation reaction will be exothermic

Last Answer : (C) The combination reaction will be exothermic, while the dissociation reaction will be endothermic

Description : Pick out the wrong statement (A) A horizontal line on the humidity chart indicates the temperature changes at constant molal humidity (B) When water is cooled from 80 to 70°C by exposure ... & air cannot be increased by either reducing the mixture temperature or by increasing the total pressure

Last Answer : (D) Relative saturation of unsaturated mixture of water vapor & air cannot be increased by either reducing the mixture temperature or by increasing the total pressure

Description : Pick out the correct statement pertaining to Venturimeter. (A) A Venturimeter with a fixed pressure drop discharges more, when the flow is vertically downward, than when the flow is vertically upward (B ... , when compressibility is taken into account, than when it is neglected (D) None of these

Last Answer : (D) None of these

Description : In the reaction, represented by, 2SO2 + O2 ⇌ 2SO3; ΔH = - 42 kcal; the forward reaction will be favoured by (A) Low temperature (B) High pressure (C) Both (A) and (B) (D) Neither (A) nor (B)

Last Answer : (C) Both (A) and (B)

Description : Forward reaction will be favoured for the exothermic reaction, represented by CO + H2O ⇌ CO2 + H2, by (A) Low temperature and high pressure (B) Low temperature and low pressure (C) High temperature and high pressure (D) High temperature and low pressure

Last Answer : (A) Low temperature and high pressure

Description : Pick out the wrong statement pertaining to the roll crushers. (A) Maximum feed size determines the required roll diameter (B) For hard material's crushing, the reduction ratio should not ... ratio and differential roll speed affect production rate & energy consumed per unit of surface produced

Last Answer : (C) Both the rolls run necessarily at the same speed

Description : Pick out the wrong statement pertaining to the turbine agitator. (A) Recommended peripheral speed for the turbine agitator is 200-250 metres/minute (B) Pitched blade turbine agitator gives only radial flow with ... l/4th of agitator diameter (with central disc, it is l/8th of the agitator diameter)

Last Answer : (B) Pitched blade turbine agitator gives only radial flow with complete absence of the axial flow

Description : Pick out the wrong statement pertaining to leaching. (A) Fine solids cannot be leached in a Pachuca tank (B) Door classifier can be used for leaching of coarse solids (C) Vegetable seeds can be ... , Rotocel or Kennedy extractor (D) Very high temperature is not needed for the leaching of sugar beet

Last Answer : (A) Fine solids cannot be leached in a Pachuca tank

Description : Pick out the wrong statement pertaining to the analogy between equations of heat and mass transfer operations. (A) Sherwood number in mass transfer is analogous to Nusselt number in heat transfer ... heat transfer (D) Reynolds number remains the same in both heat and mass transfer

Last Answer : (C) Reynolds number in mass transfer is analogous to Grashoff number in heat transfer

Description : Pick out the wrong statement pertaining to fluid flow. (A) The ratio of average velocity to the maximum velocity for turbulent flow of Newtonian fluid in circular pipes is 0.5 (B) The Newtonian ... at the centre of the pipe (C) Navier-Stokes equation is applicable to the analysis of viscous flows

Last Answer : (A) The ratio of average velocity to the maximum velocity for turbulent flow of Newtonian fluid in circular pipes is 0.5

Description : Pick out the wrong statement pertaining to space velocity of flow reactors. (A) The unit of space velocity is (time) -1 (B) The space velocity of 3 hr -1 means that three reactor volumes of ... one third reactor volume of feed at specified conditions are being fed into the reactor (D) None of these

Last Answer : (C) The space velocity of 3 hr -1 means that one third reactor volume of feed at specified conditions are being fed into the reactor

Description : Pick out the wrong statement pertaining to nitric acid. (A) About 90% of nitric acid is manufactured by Ostwald's process (B) It is a strong mono basic acid which reacts with almost all the ... (mainly NO2 ) (D) Arc process of nitric acid manufacture is economical as compared to Ostwald's process

Last Answer : (D) Arc process of nitric acid manufacture is economical as compared to Ostwald's process

Description : Pick out the wrong statement pertaining to the properties of glasses. Glasses generally have (A) High electrical insulation properties (B) Sharp melting points (C) Low co-efficient of thermal expansion (D) Compressive strength much greater than their tensile strengths

Last Answer : (B) Sharp melting points

Description : Pick out the wrong statement pertaining to the soap manufacture. (A) Transparent soaps are made by cold process (B) Organic pigments are used as colouring materials in the soap manufacture (C) ... soaps are manufactured by hot process (D) Colourless rosin is used in the manufacture of laundry soaps

Last Answer : (A) Transparent soaps are made by cold process

Description : Pick out the wrong statement. (A) Angle of repose of coal increases with its increasing size (B) Specific gravity of coal increases with its increasing maturity (C) Refractive index and reflectance of ... of coal decreases with increases in the volatile matter and decrease in the C/H ratio of coal

Last Answer : (D) Specific heat of coal decreases with increases in the volatile matter and decrease in the C/H ratio of coal

Description : Pick out the wrong statement. (A) In solvent extraction, the distribution co-efficient should be as large as possible for solvent economy (B) With increase in pressure, the solubility of ... in distillation column (D) The capacity of a distillation column is maximum at total reflux

Last Answer : (D) The capacity of a distillation column is maximum at total reflux

Description : . Pick out the wrong statement. (A) The eddy viscosity is a function of the type of turbulence involved (B) The eddy viscosity is a fluid property (C) The viscosity of gas increases with increase in temperature (D) The viscosity of a liquid increases with decrease in temperature

Last Answer : (B) The eddy viscosity is a fluid property

Description : Pick out the wrong statement. (A) In drying a solid containing moisture above the critical moisture content the number of degrees of freedom is 2 (B) Sherwood number in mass transfer corresponds to ... tube heat exchangers. At higher pressure, however, it is customary to put gas in the tube side

Last Answer : (C) Forced convection is relatively more effective in increasing the rate of mass transfer, if Schmidt number is larger

Description : The effect of increasing pressure on the gaseous equilibrium of the reaction2X + 3Y ⇌ 3X + 2Y indicates that (A) Pressure has no effect (B) Backward reaction is favoured (C) Forward reaction is favoured (D) None of the

Last Answer : (A) Pressure has no effect

Description : In multistage equilibrium conversion of SO2 to SO3 (2SO2 + O2 ⇌ 2SO3 ), the reverse reaction becomes appreciable at a temperature of 550° C. The percentage equilibrium conversion of SO2 to ... some quantity of SO3 during intermediate stage (D) Maintaining low temperature & pressure in the converter

Last Answer : (C) Removing some quantity of SO3 during intermediate stage

Description : In the reaction; N2 + O2 ⇌ 2NO, increasing the pressure will result in (A) Shifting the equilibrium towards right (B) Shifting the equilibrium towards left (C) No change in equilibrium condition (D) None of these

Last Answer : (C) No change in equilibrium condition

Description : Pick out the wrong statement. (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity(B) For an ideal ... D) Reaction rate does not decrease appreciably as the reaction proceeds in case of an autocatalytic reaction

Last Answer : (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity

Description : Pick up the correct statement from the following: (A) Coefficient of compressibility is the decrease in void ratio per unit increase of pressure (B) The percent settlement at any time is called degree of consolidation (C) Time factor is a dimensionless quantity (D) All the above

Last Answer : Answer: Option D

Description : Pick out the wrong statement. (A) Addition of methane to the furnace atmosphere reduces decarburising by hydrogen (B) Nitrogen in presence of steam decor-burises high carbon steel, whereas hydrocarbon ... the metal surface) cause nitride formation with increase in surface hardness (D) None of these

Last Answer : (D) None of these

Description : Select the wrong statement pertaining to flow of an incompressible fluid through a Venturimeter. (A) For frictionless flow, the fluid pressure entering the venturi meter will be exactly equal ... than an orificemeter (D) Venturimeter incurs less power loss compared to an equivalent orificemeter

Last Answer : (C) Venturimeter occupies less space than an orificemeter

Description : The ammonia synthesis reaction represented by N2 + 3H2 ⇌ 2NH3; ΔH = - 22.4 kcal, is (A) Endothermic (B) Exothermic (C) Isothermal (D) Adiabatic

Last Answer : (B) Exothermic

Description : Pick out the wrong statement. (A) Catalytic converter is fitted in automobiles to reduce carbon monoxide concentration in exhaust emissions (B) Inhalation of pollutant carbon monoxide results ... D) Decomposition of plants containing chlorophyll is a natural source of carbon monoxide in atmosphere

Last Answer : (C) Sulphur dioxide is the main pollutant emitted from the exhaust of petrol driven automobiles

Description : Pick out the wrong statement. (A) Biological oxygen demand (BOD) is a characteristic and not a constituent of water (B) BOD is a measure of the amount of oxygen which will be demanded & used in 5 days ... BOD is expressed in mg/litre (typically, BOD=2.5 mg/litre for potable water) (D) None of these

Last Answer : (D) None of these

Description : Pick out the wrong statement. (A) Conversion of SO2 to SO3 in Monsanto-4 pass converter is about 98% (B) The chemical formula of oleum is H2S2O7 , which is formed by saturating ... but technical sulphuric acid (D) Decomposition of sulphuric acid on heating does not start before its boiling

Last Answer : (D) Decomposition of sulphuric acid on heating does not start before its boiling

Description : In the gaseous phase ammonia formation reaction (N2 + 3H2 ⇌ 2NH3 ), the value of the equilibrium constant depends on the (A) Total pressure of the system (B) Volume of the reactor (C) Temperature (D) Initial concentration of N2 and H2

Last Answer : (C) Temperature

Description : Pick out the correct statement. (A) Like internal energy and enthalpy, the absolute value of standard entropy for elementary substances is zero (B) Melting of ice involves increase in enthalpy and ... of an ideal gas depends only on its pressure (D) Maximum work is done under reversible conditions

Last Answer : (D) Maximum work is done under reversible conditions

Description : Pick out the correct statement. (A) A catalyst speeds up the forward reaction but slows shown the reverse reaction (B) Addition of catalyst changes the equilibrium constant (C) Pressure changes do not change the equilibrium concentrations (D) The composition of equilibrium is changed by catalyst

Last Answer : (C) Pressure changes do not change the equilibrium concentrations

Description : Pick out the wrong statement: (A) The expansion of a gas in vacuum is an irreversible process (B) An isometric process is a constant pressure process (C) Entropy change for a reversible adiabatic process is zero (D) Free energy change for a spontaneous process is negative

Last Answer : (B) An isometric process is a constant pressure process