o work is done by the system, when a reaction occurs at constant (A) Volume (B) Temperature (C) Pressure (D) None of these

o work is done by the system, when a reaction occurs at constant (A) Volume
(B) Temperature
(C) Pressure
(D) None of these
by

1 Answer

Answer :

(A) Volume
by

Related questions

In the gaseous phase ammonia formation reaction (N2 + 3H2 ⇌ 2NH3 ), the value of the equilibrium constant depends on the (A) Total pressure of the system (B) Volume of the reactor (C) Temperature (D) Initial concentration of N2 and H2

Description : In the gaseous phase ammonia formation reaction (N2 + 3H2 ⇌ 2NH3 ), the value of the equilibrium constant depends on the (A) Total pressure of the system (B) Volume of the reactor (C) Temperature (D) Initial concentration of N2 and H2

Last Answer : (C) Temperature

Pick out the wrong statement. (A) The conversion for a gas phase reaction increases with decrease in pressure, if there is an increase in volume accompanying the reaction (B) With increase in temperature, the equilibrium constant increases for an exothermic reaction (C) The equilibrium constant of a reaction depends upon temperature only (D) The conversion for a gas phase reaction increases with increase in pressure, if there is a decrease in volume accompanying the reaction

Description : Pick out the wrong statement. (A) The conversion for a gas phase reaction increases with decrease in pressure, if there is an increase in volume accompanying the reaction (B) With ... phase reaction increases with increase in pressure, if there is a decrease in volume accompanying the reaction

Last Answer : (B) With increase in temperature, the equilibrium constant increases for an exothermic reaction

“If the temperature o f a fixed quantity of a gas is held constant during a change of state, the volume varies inversely with the absolute pressure.  a. Charle’s Law  b. Boyle’s Law  c. Dalton’s Law  d. Amagat’s Law

Description : “If the temperature o f a fixed quantity of a gas is held constant during a change of state, the volume varies inversely with the absolute pressure.  a. Charle’s Law  b. Boyle’s Law  c. Dalton’s Law  d. Amagat’s Law

Last Answer : Boyle’s Law

A closed system receives 200kJ of heat at constant volume. It then rejects 100kJ of heat while it has 50kJ of work done on it at constant pressure. If

Description : A closed system receives 200kJ of heat at constant volume. It then rejects 100kJ of heat while it has 50kJ of work done on it at constant pressure. If

Last Answer : A closed system receives 200kJ of heat at constant volume. It then rejects 100kJ of heat while it has 50kJ of work ... kJ B. 50 kJ C. 150 kJ D. 20 kJ

Gas is enclosed in a cylinder with a weighted piston as the stop boundary. The gas is heated and expands from a volume of 0.04 m^3 to 0.10 m^3 at a constant pressure of 200kPa.Calculate the work done by the system.  A. 8 kJ  B. 10 kJ  C.12 kJ  D.14 kJ Formula: W = p(V2-V1)

Description : Gas is enclosed in a cylinder with a weighted piston as the stop boundary. The gas is heated and expands from a volume of 0.04 m^3 to 0.10 m^3 at a constant pressure of 200kPa.Calculate the work done by the system.  A. 8 kJ  B. 10 kJ  C.12 kJ  D.14 kJ Formula: W = p(V2-V1)

Last Answer : 12 kJ

A gas is enclosed in a cylinder with a weighted piston as the top boundary. The gas is heated and expands from a volume of 0.04 m3 to 0.10 m3 at a constant pressure of 200 kPa. Find the work done on the system.  a. 5 kJ  b. 15 kJ  c. 10 kJ  d. 12 kJ

Description : A gas is enclosed in a cylinder with a weighted piston as the top boundary. The gas is heated and expands from a volume of 0.04 m3 to 0.10 m3 at a constant pressure of 200 kPa. Find the work done on the system.  a. 5 kJ  b. 15 kJ  c. 10 kJ  d. 12 kJ

Last Answer : 12 kJ

Twenty grams of oxygen gas are compressed at a constant temperature of 30 ˚C to 5%of their original volume. What work is done on the system.  A.824 cal  B.924 cal  C.944 cal  D.1124 cal Formula: W = -mRTln (V2/V1) Where R = (1.98 cal/gmole·K) (32 g/gmole)

Description : Twenty grams of oxygen gas are compressed at a constant temperature of 30 ˚C to 5%of their original volume. What work is done on the system.  A.824 cal  B.924 cal  C.944 cal  D.1124 cal Formula: W = -mRTln (V2/V1) Where R = (1.98 cal/gmole·K) (32 g/gmole)

Last Answer : 1124 cal

Superheating of steam is done at constant (A) Enthalpy (B) Entropy (C) Pressure (D) Volume

Description : Superheating of steam is done at constant (A) Enthalpy (B) Entropy (C) Pressure (D) Volume

Last Answer : Option C

Assertion :- At constant pressure for the change `H_(2)O(s)rarr H_(2)O(g)` work done is nwgative. Reason :- During phase transition work done is alway

Description : Assertion :- At constant pressure for the change `H_(2)O(s)rarr H_(2)O(g)` work done is nwgative. Reason :- During phase transition work done is alway

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If a gas is heated against a pressure, keeping the volume constant, then work done will be equal to  (a) + v  (b) – ve  (c) zero  (d) pressure x volume  (e) any where between zero and infinity.

Description : If a gas is heated against a pressure, keeping the volume constant, then work done will be equal to  (a) + v  (b) – ve  (c) zero  (d) pressure x volume  (e) any where between zero and infinity.

Last Answer : Answer : c

For a constant volume process __________ by the system is used only to increase the internal energy. (A) Heat absorbed (B) Work done (C) Both (A) & (B) (D) Neither (A) nor (B)

Description : For a constant volume process __________ by the system is used only to increase the internal energy. (A) Heat absorbed (B) Work done (C) Both (A) & (B) (D) Neither (A) nor (B)

Last Answer : (B) Work done

A chemical reaction, A → 3B, is conducted in a constant pressure vessel. Starting with pure A, the volume of the reaction mixture increases 3 times in 6 minutes. The fractional conversion is (A) 0.33 (B) 0.5 (C) 1 (D) Data insufficient, can't be predicted

Description : A chemical reaction, A → 3B, is conducted in a constant pressure vessel. Starting with pure A, the volume of the reaction mixture increases 3 times in 6 minutes. The fractional conversion is (A) 0.33 (B) 0.5 (C) 1 (D) Data insufficient, can't be predicted

Last Answer : (C) 1

In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is (A) More (B) Less (C) Same (D) Unpredictable; depends on the particular reaction

Description : In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is (A) More (B) Less (C) Same (D) Unpredictable; depends on the particular reaction

Last Answer : (C) Same

In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = 0 (C) Addition of inert gas has no effect on the equilibrium constant at constant volume for any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'

Description : In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = ... any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'

Last Answer : D) All 'a', 'b' & 'c'

The work done in an adiabatic change in a particular gas depends upon changes in the __________ only. (A) Temperature (B) Specific heat (C) Volume (D) Pressure

Description : The work done in an adiabatic change in a particular gas depends upon changes in the __________ only. (A) Temperature (B) Specific heat (C) Volume (D) Pressure

Last Answer : (A) Temperature

Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is afunction of reaction temperature. In a chemical reaction, the time requiredto reduce the concentration of reactant from 100 gm moles/litre to 50 gmmoles/litre is same as that required to reduce it from 2 gm moles/litre to 1gm mole/litre in the same volume. Then the order of this reaction is:(A) 0(B) 1(C) 2(D) 3

Description : Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is afunction of reaction temperature. In a chemical reaction, the time required to ... Then the order of this reaction is: (A) 0 (B) 1 (C) 2 (D) 3

Last Answer : (B) 1

Pick out the wrong statement. (A) The controlling resistance in case of heating of air by condensing steam is in the air film (B) The log mean temperature difference (LMTD) for counter flow and parallel flow can be theoretically same when any one of the fluids (hot or cold fluid) passes through the heat exchanger at constant temperature (C) In case of a 1 - 2 shell and tube heat exchanger, the LMTD correction factor value increases sharply, when a temperature cross occurs (D) Phase change in case of a pure fluid at a given pressure from liquid to vapor or vice-versa occurs at saturation temperature

Description : Pick out the wrong statement. (A) The controlling resistance in case of heating of air by condensing steam is in the air film (B) The log mean temperature difference (LMTD) for ... a pure fluid at a given pressure from liquid to vapor or vice-versa occurs at saturation temperature

Last Answer : (C) In case of a 1 - 2 shell and tube heat exchanger, the LMTD correction factor value increases sharply, when a temperature cross occurs

What happens in a reversible adiabatic compression? (A) Heating occurs (B) Cooling occurs (C) Pressure is constant (D) Temperature is constant

Description : What happens in a reversible adiabatic compression? (A) Heating occurs (B) Cooling occurs (C) Pressure is constant (D) Temperature is constant

Last Answer : A) Heating occurs

When an isolated thermodynamic system executes a process, (A) Work is done (B) Heat transfer takes place (C) Mass flow occurs across the boundary of the system (D) No chemical reaction takes place within the system

Description : When an isolated thermodynamic system executes a process, (A) Work is done (B) Heat transfer takes place (C) Mass flow occurs across the boundary of the system (D) No chemical reaction takes place within the system

Last Answer : D) No chemical reaction takes place within the system

In case of laminar flow of fluid through a circular pipe, the (A) Shear stress over the cross-section is proportional to the distance from the surface of the pipe (B) Surface of velocity distribution is a paraboloid of revolution, whose volume equals half the volume of circumscribing cylinder (C) Velocity profile varies hyperbolically and the shear stress remains constant over the cross-section (D) Average flow occurs at a radial distance of 0.5 r from the centre of the pipe (r = pipe radius)

Description : In case of laminar flow of fluid through a circular pipe, the (A) Shear stress over the cross-section is proportional to the distance from the surface of the pipe (B) Surface of velocity distribution is a ... occurs at a radial distance of 0.5 r from the centre of the pipe (r = pipe radius)

Last Answer : (B) Surface of velocity distribution is a paraboloid of revolution, whose volume equals half the volume of circumscribing cylinder

If helium is introduced in a reactor containing O2 , SO2 and SO3 at equilibrium, so that total pressure increases while volume and temperature remains constant. In this case the dissociation of SO3 (as per Le Chatelier's principle). (A) Decreases (B) Increases (C) Remains unaltered (D) Changes unpredictably

Description : If helium is introduced in a reactor containing O2 , SO2 and SO3 at equilibrium, so that total pressure increases while volume and temperature remains constant. In this case the dissociation of SO3 ( ... 's principle). (A) Decreases (B) Increases (C) Remains unaltered (D) Changes unpredictably

Last Answer : (A) Decreases

Which of the following fixes the volume of a batch reactor for a particular conversion and production rate? (A) Operating conditions (e.g. pressure and temperature) (B) Rate constant (C) Density of mixture (D) None of these

Description : Which of the following fixes the volume of a batch reactor for a particular conversion and production rate? (A) Operating conditions (e.g. pressure and temperature) (B) Rate constant (C) Density of mixture (D) None of these

Last Answer : (C) Density of mixture

Clausius-Clapeyron Equation gives accurate result, when the (A) Vapour pressure is relatively low and the temperature does not vary over wide limits (B) Vapour obeys the ideal gas law and the latent heat of vaporisation is constant (C) Volume in the liquid state is negligible compared with that in the vapour state (D) All (A), (B) and (C)

Description : Clausius-Clapeyron Equation gives accurate result, when the (A) Vapour pressure is relatively low and the temperature does not vary over wide limits (B) Vapour obeys the ideal gas law and the latent heat of ... is negligible compared with that in the vapour state (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv ), depends upon its (A) Pressure (B) Volume (C) Temperature (D) All (A), (B) & (C)

Description : The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv ), depends upon its (A) Pressure (B) Volume (C) Temperature (D) All (A), (B) & (C)

Last Answer : (C) Temperature

Keeping the pressure constant, to double the volume of a given mass of an ideal gas at 27°C, the temperature should be raised to __________ °C. (A) 270 (B) 327 (C) 300 (D) 540

Description : Keeping the pressure constant, to double the volume of a given mass of an ideal gas at 27°C, the temperature should be raised to __________ °C. (A) 270 (B) 327 (C) 300 (D) 540

Last Answer : (B) 327

An isentropic process is carried out at constant (A) Volume (B) Pressure (C) Temperature (D) All (A), (B) and (C)

Description : An isentropic process is carried out at constant (A) Volume (B) Pressure (C) Temperature (D) All (A), (B) and (C)

Last Answer : (A) Volume

The expression, ∆G = nRT. ln(P2/P1), gives the free energy change (A) With pressure changes at constant temperature (B) Under reversible isothermal volume change (C) During heating of an ideal gas (D) During cooling of an ideal gas

Description : The expression, ∆G = nRT. ln(P2/P1), gives the free energy change (A) With pressure changes at constant temperature (B) Under reversible isothermal volume change (C) During heating of an ideal gas (D) During cooling of an ideal gas

Last Answer : (A) With pressure changes at constant temperature

Which of the following will increase the volume of a real gas by four times? (A) Doubling the absolute temperature as well as pressure of the gas (B) Reducing pressure to one fourth at constant temperature (C) Reducing temperature to one fourth at constant pressure (D) Reducing the temperature to half and doubling the pressure

Description : Which of the following will increase the volume of a real gas by four times? (A) Doubling the absolute temperature as well as pressure of the gas (B) Reducing pressure to one fourth at ... temperature to one fourth at constant pressure (D) Reducing the temperature to half and doubling the pressure

Last Answer : (B) Reducing pressure to one fourth at constant temperature

Isobaric process means a constant process. (A) Temperature (B) Pressure (C) Volume (D) Entropy

Description : Isobaric process means a constant process. (A) Temperature (B) Pressure (C) Volume (D) Entropy

Last Answer : (B) Pressure

1m3 of an ideal gas at 500 K and 1000 kPa expands reversibly to 5 times its initial volume in an insulated container. If the specific heat capacity (at constant pressure) of the gas is 21 J/mole . K, the final temperature will be (A) 35 K (B) 174 K (C) 274 K (D) 154 K

Description : 1m3 of an ideal gas at 500 K and 1000 kPa expands reversibly to 5 times its initial volume in an insulated container. If the specific heat capacity (at constant pressure) of the gas is 21 J/mole . K, the final temperature will be (A) 35 K (B) 174 K (C) 274 K (D) 154 K

Last Answer : (C) 274 K

Gas turbine normally employs a constant __________ cycle. (A) Pressure (B) Temperature (C) Volume (D) None of these

Description : Gas turbine normally employs a constant __________ cycle. (A) Pressure (B) Temperature (C) Volume (D) None of these

Last Answer : (A) Pressure

Addition of heat at constant pressure to a gas results in  (a) raising its temperature  (b) raising its pressure  (c) raising its volume  (d) raising its temperature and doing external work  (e) doing external work.

Description : Addition of heat at constant pressure to a gas results in  (a) raising its temperature  (b) raising its pressure  (c) raising its volume  (d) raising its temperature and doing external work  (e) doing external work.

Last Answer : Answer : d

The equilibrium constant for the reversible reaction as shown in the bellow figure, is affected by the (A) Temperature of the system (B) Presence or absence of inerts (C) Pressure of the system (D) Kinetics of the reaction

Description : The equilibrium constant for the reversible reaction as shown in the bellow figure, is affected by the (A) Temperature of the system (B) Presence or absence of inerts (C) Pressure of the system (D) Kinetics of the reaction

Last Answer : (C) Pressure of the system

When vapour is cooled at constant total system volume, the _______ changes. A Volume. B PRESSURE C Temperature. D None of the mentioned.

Description : When vapour is cooled at constant total system volume, the _______ changes. A Volume. B PRESSURE C Temperature. D None of the mentioned.

Last Answer : B PRESSURE

When vapour is cooled at constant total system volume, the _______ changes. A] Volume. B] Pressure C] Temperature. D] None of the mentioned

Description : When vapour is cooled at constant total system volume, the _______ changes. A] Volume. B] Pressure C] Temperature. D] None of the mentioned

Last Answer : B] Pressure

Change in internal energy in a closed system is equal to heat transferred if the reversible process takes place at constant  (a) pressure  (b) temperature  (c) volume  (d) internal energy  (e) entropy.

Description : Change in internal energy in a closed system is equal to heat transferred if the reversible process takes place at constant  (a) pressure  (b) temperature  (c) volume  (d) internal energy  (e) entropy.

Last Answer : Answer : c

Change in enthalpy in a closed system is equal to heat transferred if the reversible process takes place at constant  (a) pressure  (b) temperature  (c) volume  (d) internal energy  (e) entropy.

Description : Change in enthalpy in a closed system is equal to heat transferred if the reversible process takes place at constant  (a) pressure  (b) temperature  (c) volume  (d) internal energy  (e) entropy.

Last Answer : Answer : a

Change in enthalpy of a system is the heat supplied at  (a) constant pressure  (b) constant temperature  (c) constant volume  (d) constant entropy  (e) N.T.P. condition.

Description : Change in enthalpy of a system is the heat supplied at  (a) constant pressure  (b) constant temperature  (c) constant volume  (d) constant entropy  (e) N.T.P. condition.

Last Answer : Answer : a

Extensive property of a system is one whose value  (a) depends on the mass of the system like volume  (b) does not depend on the mass of the system, like temperature, pressure, etc.  (c) is not dependent on the path followed but on the state  (d) is dependent on the path followed and not on the state  (e) is always constant.

Description : Extensive property of a system is one whose value  (a) depends on the mass of the system like volume  (b) does not depend on the mass of the system, like temperature, pressure, etc.  (c) is not ... the state  (d) is dependent on the path followed and not on the state  (e) is always constant.

Last Answer : Answer : a

Intensive property of a system is one whose value  (a) depends on the mass of the system, like volume  (b) does not depend on the mass of the system, like temperature, pressure, etc.  (c) is not dependent on the path followed but on the state  (d) is dependent on the path followed and not on the state  (e) remains constant.

Description : Intensive property of a system is one whose value  (a) depends on the mass of the system, like volume  (b) does not depend on the mass of the system, like temperature, pressure, etc.  (c) is not ... on the state  (d) is dependent on the path followed and not on the state  (e) remains constant.

Last Answer : Answer : b

Assertion (A): For a particular reaction, heat of combustion at constant pressure `(q_(P))` is always greater than that at constant volume `(q_(V))`.

Description : Assertion (A): For a particular reaction, heat of combustion at constant pressure `(q_(P))` is always greater than that at constant volume `(q_(V))`.

Last Answer : Assertion (A): For a particular reaction, heat of combustion at constant pressure `(q_(P))` is ... False. D. If both Assertion & Reason are false.

When volume of the equilibrium reaction C(s) + H2O(g) ⇌ CO(g) + H2(g) is increased at constant temperature the equilibrium will :

Description : When volume of the equilibrium reaction C(s) + H2O(g) ⇌ CO(g) + H2(g) is increased at constant temperature the equilibrium will :

Last Answer : When volume of the equilibrium reaction C(s) + H2O(g) ⇌ CO(g) + H2(g) is increased at constant ... left c. be unaltered d. can not be predicted

Pick out the wrong statemen(A) Autocatalytic reactions are exemplified by microbial fermentation reactions (B) The slowest step has the greatest influence on the overall reaction rate in case of an irreversible series reaction (C) The fractional conversion at any time is same for both the constant as well as the variable volume system in case of an irreversible unimolecular type first order reaction (D) Hydrolysis of ester in presence of alkali or acid is a zero order reaction

Description : Pick out the wrong statemen (A) Autocatalytic reactions are exemplified by microbial fermentation reactions (B) The slowest step has the greatest influence on the overall reaction rate in case of an ... reaction (D) Hydrolysis of ester in presence of alkali or acid is a zero order reaction

Last Answer : (D) Hydrolysis of ester in presence of alkali or acid is a zero order reaction

In case of the irreversible unimolecular type, first order reaction, the fractional conversion at any time for constant volume system as compared to variable volume system is (A) More (B) Less (C) Same (D) Either (A) or (B), depends on other factors

Description : In case of the irreversible unimolecular type, first order reaction, the fractional conversion at any time for constant volume system as compared to variable volume system is (A) More (B) Less (C) Same (D) Either (A) or (B), depends on other factors

Last Answer : (C) Same

The work done by a weightless piston in causing an expansing `Delta V` (at constant temperature), when the opposing pressure P is variable, is given b

Description : The work done by a weightless piston in causing an expansing `Delta V` (at constant temperature), when the opposing pressure P is variable, is given b

Last Answer : The work done by a weightless piston in causing an expansing `Delta V` (at constant temperature), when the opposing ... 0 C. `W = -P Delta V` D. None

In ammonia synthesis (N2 + 3H2 = 2NH3 ), there is a decrease in total volume, hence to get high equilibrium conversion, the reaction should becarried out at(A) Low pressure(B) High pressure(C) Very high temperature(D) Atmospheric pressure; as the pressure has no effect on conversion

Description : In ammonia synthesis (N2 + 3H2 = 2NH3 ), there is a decrease in total volume, hence to get high equilibrium conversion, the reaction should becarried out at (A) Low pressure (B) High pressure (C) Very high temperature (D) Atmospheric pressure; as the pressure has no effect on conversion

Last Answer : (B) High pressure

The units of frequency factor in Arrhenius equation (A) Are the same as those of the rate constant (B) Depend on the order of the reaction (C) Depend on temperature, pressure etc. of the reaction (D) Are cycles per unit time

Description : The units of frequency factor in Arrhenius equation (A) Are the same as those of the rate constant (B) Depend on the order of the reaction (C) Depend on temperature, pressure etc. of the reaction (D) Are cycles per unit time

Last Answer : (A) Are the same as those of the rate constant

The rate constant of a chemical reaction decreases by decreasing the (A) Pressure (B) Concentration of reactants (C) Temperature (D) Duration of reaction

Description : The rate constant of a chemical reaction decreases by decreasing the (A) Pressure (B) Concentration of reactants (C) Temperature (D) Duration of reaction

Last Answer : (C) Temperature

The energy of activation of a chemical reaction: (A) Is same as heat of reaction at constant pressure (B) Is the minimum energy which the molecules must have before the reaction can take place (C) Varies as fifth power of the temperature (D) Both (B) and (C)

Description : The energy of activation of a chemical reaction: (A) Is same as heat of reaction at constant pressure (B) Is the minimum energy which the molecules must have before the reaction can take place (C) Varies as fifth power of the temperature (D) Both (B) and (C)

Last Answer : (B) Is the minimum energy which the molecules must have before the reaction can take place