Assertion (A): For a particular reaction, heat of combustion at constant pressure `(q_(P))` is always greater than that at constant volume `(q_(V))`.

Assertion (A): For a particular reaction, heat of combustion at constant pressure `(q_(P))` is always greater than that at constant volume `(q_(V))`.
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Assertion (A): For a particular reaction, heat of combustion at constant pressure `(q_(P))` is ... False. D. If both Assertion & Reason are false.
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For a reaction `2X(s)+2Y(s)rarr 2Cl(l)+D(g)` The `q_(p)` at `27^(@)C` is -28 K Cal. `mol^(-1)`. The `q_(V)` is ___________ K. Cal. `mol^(-1)` :-

Description : For a reaction `2X(s)+2Y(s)rarr 2Cl(l)+D(g)` The `q_(p)` at `27^(@)C` is -28 K Cal. `mol^(-1)`. The `q_(V)` is ___________ K. Cal. `mol^(-1)` :-

Last Answer : For a reaction `2X(s)+2Y(s)rarr 2Cl(l)+D(g)` The `q_(p)` at `27^(@)C` is -28 K Cal. `mol^(-1)`. The `q_( ... . `-27.4` B. `+27.4` C. `-28.6` D. `28.6`

Van der Waals derived an expression for the ‘pressure defect’, if the observed pressure is denoted as ‘p’ and volume is denoted as ‘V’, the gas pressure in the bulk of the gas is equal to: A. p + a/V; where a: constant for the particular gas B. p + a/(V²); where a: constant for the particular gas C. p + (a × V); where a: constant for the particular gas D. p + (a × V²); where a: constant for the particular gas

Description : Van der Waals derived an expression for the pressure defect', if the observed pressure is denoted as p' and volume is denoted as V', the gas pressure in the bulk of the gas is equal to: A. p + ... a: constant for the particular gas D. p + (a V²); where a: constant for the particular gas

Last Answer : p + a/(V²); where a: constant for the particular gas

Assertion :- `Q_("Surr")` is zero for adiabatic process Reason :- Final state of the system remains unchanged in adiabatic process.

Description : Assertion :- `Q_("Surr")` is zero for adiabatic process Reason :- Final state of the system remains unchanged in adiabatic process.

Last Answer : Assertion :- `Q_("Surr")` is zero for adiabatic process Reason :- Final state of the system ... False. D. If both Assertion & Reason are false.

In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is (A) More (B) Less (C) Same (D) Unpredictable; depends on the particular reaction

Description : In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is (A) More (B) Less (C) Same (D) Unpredictable; depends on the particular reaction

Last Answer : (C) Same

Pick out the wrong statement. (A) Enthalpies of all elements in their standard states are assumed to be zero (B) Combustion reactions are never endothermic in nature (C) Heat of reaction at constant volume is equal to the change in internal energy (D) Clausius-Clapeyron equation is not applicable to melting process

Description : Pick out the wrong statement. (A) Enthalpies of all elements in their standard states are assumed to be zero (B) Combustion reactions are never endothermic in nature (C) Heat of reaction ... to the change in internal energy (D) Clausius-Clapeyron equation is not applicable to melting process

Last Answer : (D) Clausius-Clapeyron equation is not applicable to melting process

`Q_(10)` of light reaction is

Description : `Q_(10)` of light reaction is

Last Answer : `Q_(10)` of light reaction is A. temperature coefficient B. water coefficient C. respiratory coefficient D. none

Change of heat content when one mole of compound is burnt in oxygen at constant pressure is called the (A) Calorific value (B) Heat of reaction (C) Heat of combustion (D) Heat of formation

Description : Change of heat content when one mole of compound is burnt in oxygen at constant pressure is called the (A) Calorific value (B) Heat of reaction (C) Heat of combustion (D) Heat of formation

Last Answer : (C) Heat of combustion

Otto cycle efficiency is higher than Diesel cycle efficiency for the same compression ratio and heat input because in Otto cycle  A. combustion is at constant volume  B. expansion and compression are isentropic  C. maximum temperature is higher  D. heat rejection is lower

Description : Otto cycle efficiency is higher than Diesel cycle efficiency for the same compression ratio and heat input because in Otto cycle  A. combustion is at constant volume  B. expansion and compression are isentropic  C. maximum temperature is higher  D. heat rejection is lower

Last Answer : Answer: D

if pressure P is inversely proportional to volume (V) at constant temperature, then PV is constant (True/False)

Description : if pressure P is inversely proportional to volume (V) at constant temperature, then PV is constant (True/False)

Last Answer : if pressure P is inversely proportional to volume (V) at constant temperature, then PV is constant (True/False)

Boyle's law states that A. pressure of a gas is inversely proportional to its volume i.e. P × V = constant B. pressure of a gas is directly proportional to its volume i.e. P⁄V = constant C. pressure of a gas is inversely proportional to the square of its volume i.e. P × V² = constant D. pressure of a gas is directly proportional to the square of its volume i.e. P ⁄ V² = constant

Description : Boyle's law states that A. pressure of a gas is inversely proportional to its volume i.e. P V = constant B. pressure of a gas is directly proportional to its volume i.e. P⁄V = constant C. ... of a gas is directly proportional to the square of its volume i.e. P ⁄ V² = constant

Last Answer : pressure of a gas is inversely proportional to its volume i.e. P × V = constant

The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv ), depends upon its (A) Pressure (B) Volume (C) Temperature (D) All (A), (B) & (C)

Description : The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv ), depends upon its (A) Pressure (B) Volume (C) Temperature (D) All (A), (B) & (C)

Last Answer : (C) Temperature

For a perfect gas, according to Boyle’s law (where p = Absolute pressure, v = Volume, and T = Absolute temperature)  A. p v = constant, if T is kept constant  B. v/T = constant, if p is kept constant  C. p/T = constant, if v is kept constant  D. T/p = constant, if v is kept constant

Description : For a perfect gas, according to Boyle’s law (where p = Absolute pressure, v = Volume, and T = Absolute temperature)  A. p v = constant, if T is kept constant  B. v/T = constant, if p is kept constant  C. p/T = constant, if v is kept constant  D. T/p = constant, if v is kept constant

Last Answer : Answer: A

The ratio of specific heat at constant pressure (Cp) and specific heat at constant volume (cv) is  A. equal to one  B. less than one  C. greater than one  D. none of these

Description : The ratio of specific heat at constant pressure (Cp) and specific heat at constant volume (cv) is  A. equal to one  B. less than one  C. greater than one  D. none of these

Last Answer : Answer: C

Heat of reaction for, `CO(g)+1//2O_(2)(g)rarr CO_(2)(g)` at constant V is -67.71 K cal at `17^(@)C` . The heat of reaction at constant P at `17^(@)C`

Description : Heat of reaction for, `CO(g)+1//2O_(2)(g)rarr CO_(2)(g)` at constant V is -67.71 K cal at `17^(@)C` . The heat of reaction at constant P at `17^(@)C`

Last Answer : Heat of reaction for, `CO(g)+1//2O_(2)(g)rarr CO_(2)(g)` at constant V is -67.71 K cal at `17^(@)C` . ... B. `+68.0` K cal C. `-67.4` K cal D. None

(1/V) (∂V/∂T)Pis the mathematical expression (A) Joule-Thomson co-efficient (B) Specific heat at constant pressure (Cp) (C) co-efficient of thermal expansion (D) Specific heat at constant volume (CV)

Description : (1/V) (∂V/∂T)Pis the mathematical expression (A) Joule-Thomson co-efficient (B) Specific heat at constant pressure (Cp) (C) co-efficient of thermal expansion (D) Specific heat at constant volume (CV)

Last Answer : (C) co-efficient of thermal expansion

The dual combustion cycle consists of one constant pressure, two constant volume and two isentropic processes.  A. Agree  B. Disagree

Description : The dual combustion cycle consists of one constant pressure, two constant volume and two isentropic processes.  A. Agree  B. Disagree

Last Answer : Answer: A

Change in enthalpy of a system is the heat supplied at  (a) constant pressure  (b) constant temperature  (c) constant volume  (d) constant entropy  (e) N.T.P. condition.

Description : Change in enthalpy of a system is the heat supplied at  (a) constant pressure  (b) constant temperature  (c) constant volume  (d) constant entropy  (e) N.T.P. condition.

Last Answer : Answer : a

For all positive reaction orders for a particular duty, (A) Mixed reactor is always larger than the plug-flow reactor (B) Ratio of the volume of the mixed reactor to that of the plug-flow reactor decreases with order (C) Reactor size is independent of the type of flow (D) Density variation during reaction affects design

Description : For all positive reaction orders for a particular duty, (A) Mixed reactor is always larger than the plug-flow reactor (B) Ratio of the volume of the mixed reactor to that of the plug-flow ... (C) Reactor size is independent of the type of flow (D) Density variation during reaction affects design

Last Answer : (A) Mixed reactor is always larger than the plug-flow reactor

. A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that __________ in the two reactors. (A) Both conversion as well as concentration are same (B) Conversion in both will be the same but concentrations will be different (C) Both the conversion as well as concentrations will be different (D) None of these

Description : . A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that __________ in the two ... be different (C) Both the conversion as well as concentrations will be different (D) None of these

Last Answer : (B) Conversion in both will be the same but concentrations will be different

Pick out the wrong statement. (A) The vessel dispersion number (D/UL) for plug flow and mixed flow approaches zero and infinity respectively (B) Space time in a flow reactor is a measure of its capacity and is equal to the residence time when the density of reaction mixture is constant (C) Mixed reactor is always smaller than the plug flow reactor for all positive reaction orders for a particular duty (D) In an ideal tubular flow reactor, mixing takes place in radial direction and there is no mixing in longitudinal direction

Description : Pick out the wrong statement. (A) The vessel dispersion number (D/UL) for plug flow and mixed flow approaches zero and infinity respectively (B) Space time in a flow reactor is a ... ideal tubular flow reactor, mixing takes place in radial direction and there is no mixing in longitudinal direction

Last Answer : (C) Mixed reactor is always smaller than the plug flow reactor for all positive reaction orders for a particular duty

Pick out the wrong statement. (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity(B) For an ideal mixed reactor at steady state, the exit stream has the samecomposition as fluid within the reactor and the space time is equivalent toholding time for constant density system(C) Plug flow reactor (PFR) is always smaller than mixed reactor for allpositive reaction orders for a particular duty(D) Reaction rate does not decrease appreciably as the reaction proceeds incase of an autocatalytic reaction

Description : Pick out the wrong statement. (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity(B) For an ideal ... D) Reaction rate does not decrease appreciably as the reaction proceeds in case of an autocatalytic reaction

Last Answer : (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity

Write the following steps in sequential order to verify the laws of reflection. (A) Draw a normal at the point where the two lines PQ and `P_(1)Q_(1)`

Description : Write the following steps in sequential order to verify the laws of reflection. (A) Draw a normal at the point where the two lines PQ and `P_(1)Q_(1)`

Last Answer : Write the following steps in sequential order to verify the laws of reflection. (A) Draw a normal at the ... A. DABECF B. ACDBFE C. DECBAF D. DBACEF

Each term of the Bernoulli's equation written in the form, (p/ρ) + (g/gc ). Z + (v 2 /2gc ) = constant, represents the total energy per unit (A) Mass (B) Volume (C) Specific weight (D) None of these

Description : Each term of the Bernoulli's equation written in the form, (p/ρ) + (g/gc ). Z + (v 2 /2gc ) = constant, represents the total energy per unit (A) Mass (B) Volume (C) Specific weight (D) None of these

Last Answer : (A) Mass

An ideal gas is heated at constant volume and then expanded isothermally. Show processes on P-V & T-S diagrams.

Description : An ideal gas is heated at constant volume and then expanded isothermally. Show processes on P-V & T-S diagrams.

Last Answer : Process 1-2 : Constant volume process Process 2-3 : Constant temperature process (Isothermal process)

Which of the following fixes the volume of a batch reactor for a particular conversion and production rate? (A) Operating conditions (e.g. pressure and temperature) (B) Rate constant (C) Density of mixture (D) None of these

Description : Which of the following fixes the volume of a batch reactor for a particular conversion and production rate? (A) Operating conditions (e.g. pressure and temperature) (B) Rate constant (C) Density of mixture (D) None of these

Last Answer : (C) Density of mixture

For series reaction, the relative yield (A) Is always greater for plug-flow reactor than for the single CSTR of the same volume (B) Statement in (A) is wrong (C) Decreases with increasing conversion (D) Both (A) and (C) hold good

Description : For series reaction, the relative yield (A) Is always greater for plug-flow reactor than for the single CSTR of the same volume (B) Statement in (A) is wrong (C) Decreases with increasing conversion (D) Both (A) and (C) hold good

Last Answer : (D) Both (A) and (C) hold good

A second order liquid phase reaction, A → B, is carried out in a mixed flow reactor operated in semi batch mode (no exit stream). The reactant A at concentration CAF is fed to the reactor at a volumetric flow rate of F. The volume of the reacting mixture is V and the density of the liquid mixture is constant. The mass balance for A is (A) d(VCA )/dt = -F (CAF - CA ) - kCA 2V (B) d(VCA )/dt = F (CAF - CA ) - kCA 2V (C) d(VCA )/dt = -FCA - kCA 2V (D) d(VCA )/dt = FCAF - kCA 2V

Description : A second order liquid phase reaction, A → B, is carried out in a mixed flow reactor operated in semi batch mode (no exit stream). The reactant A at concentration CAF is fed to the reactor at a volumetric flow rate of F. The volume ... 2V (C) d(VCA )/dt = -FCA - kCA 2V (D) d(VCA )/dt = FCAF - kCA 2V

Last Answer : (D) d(VCA )/dt = FCAF - kCA 2V

The work done in an adiabatic change in a particular gas depends upon changes in the __________ only. (A) Temperature (B) Specific heat (C) Volume (D) Pressure

Description : The work done in an adiabatic change in a particular gas depends upon changes in the __________ only. (A) Temperature (B) Specific heat (C) Volume (D) Pressure

Last Answer : (A) Temperature

Pick out the wrong statement. (A) Visible radiation provides the necessary activation energy in photochemical reactions (B) The order and molecularity of a complex reaction may not be the same (C) For a second order reaction, the slope of the graph/plot between rate and (concentration) is equal to the rate constant (k) (D) Molecularity of the reaction is always a whole number greater than zero

Description : Pick out the wrong statement. (A) Visible radiation provides the necessary activation energy in photochemical reactions (B) The order and molecularity of a complex reaction may not be the same (C) For ... rate constant (k) (D) Molecularity of the reaction is always a whole number greater than zero

Last Answer : (B) The order and molecularity of a complex reaction may not be the same

Draw P-V and T-S diagram of dual combustion cycle.

Description : Draw P-V and T-S diagram of dual combustion cycle.

Last Answer : Dual combustion cycle: 1-2 Isentropic compression of air 2-3 the combustion of fuel at constant volume. 3-4 the combustion of fuel at constant pressure 4-5 Isentropic expansion during which work is done by the system. 5-1 Heat rejection at constant volume.

Compressibility factor (i.e., the ratio of actual volume of gas to the volume predicted by ideal gas law) for all gases are (A) Always greater than one (B) Same at the same reduced temperature (C) Same at the same reduced pressure (D) Both (B) & (C)

Description : Compressibility factor (i.e., the ratio of actual volume of gas to the volume predicted by ideal gas law) for all gases are (A) Always greater than one (B) Same at the same reduced temperature (C) Same at the same reduced pressure (D) Both (B) & (C)

Last Answer : (D) Both (B) & (C)

The temperature of a gas is held constant while its volume is reduced. The pressure the gas exerts on the walls of its container increases because its molecules: w) strike the container walls more often x) strike the container walls with higher speeds y) strike the container walls with greater force z) all of the above

Description : The temperature of a gas is held constant while its volume is reduced. The pressure the gas exerts on the walls of its container increases because its molecules: w) strike the container walls more ... walls with higher speeds y) strike the container walls with greater force z) all of the above

Last Answer : ANSWER: W -- STRIKE THE CONTAINER WALLS MORE OFTEN

If a gas is heated against a pressure, keeping the volume constant, then work done will be equal to  (a) + v  (b) – ve  (c) zero  (d) pressure x volume  (e) any where between zero and infinity.

Description : If a gas is heated against a pressure, keeping the volume constant, then work done will be equal to  (a) + v  (b) – ve  (c) zero  (d) pressure x volume  (e) any where between zero and infinity.

Last Answer : Answer : c

Stack heat losses can be minimised by (A) Controlling the excess air (B) Oxygen enrichment of combustion air (C) Using low c.v. fuels (D) Maintaining proper draft in the furnace

Description : Stack heat losses can be minimised by (A) Controlling the excess air (B) Oxygen enrichment of combustion air (C) Using low c.v. fuels (D) Maintaining proper draft in the furnace

Last Answer : (A) Controlling the excess air

A 3 L gas mixture of propane `(C_(3)H_(8))` and butane `(C_(4)H_(10))` on complete combustion at 25 C produced 10 L `CO_(2.)` Assuming constant P and

Description : A 3 L gas mixture of propane `(C_(3)H_(8))` and butane `(C_(4)H_(10))` on complete combustion at 25 C produced 10 L `CO_(2.)` Assuming constant P and

Last Answer : A 3 L gas mixture of propane `(C_(3)H_(8))` and butane `(C_(4)H_(10))` on complete combustion at 25 C ... .5L` D. `C_(3)H_(8),0LandC_(4)H_(10),3L`

Pick out the correct statement. (A) If an insoluble gas is passed through a volatile liquid placed in a perfectly insulated container, the temperature of the liquid will increase (B) A process is irreversible as long as Δ S for the system is greater than zero (C) The mechanical work done by a system is always equal to∫P.dV (D) The heat of formation of a compound is defined as the heat of reaction leading to the formation of the compound from its reactants

Description : Pick out the correct statement. (A) If an insoluble gas is passed through a volatile liquid placed in a perfectly insulated container, the temperature of the liquid will increase (B) A ... compound is defined as the heat of reaction leading to the formation of the compound from its reactants

Last Answer : (D) The heat of formation of a compound is defined as the heat of reaction leading to the formation of the compound from its reactants

An adsorption isotherm equation proposed by Langmuir is of the form `V = (V_(0)bPO)/((1 + bP))` where V is the volume of gas adsorbed at pressure P. F

Description : An adsorption isotherm equation proposed by Langmuir is of the form `V = (V_(0)bPO)/((1 + bP))` where V is the volume of gas adsorbed at pressure P. F

Last Answer : An adsorption isotherm equation proposed by Langmuir is of the form `V = (V_(0)bPO)/((1 + bP))` where V is ... of V on P can be depicted as B. C. D.

The volume (V) of a mass of gas varies directly as its absulute temperature (T) and iversely as the pressure (P) applied to it. The gas occupies a vol

Description : The volume (V) of a mass of gas varies directly as its absulute temperature (T) and iversely as the pressure (P) applied to it. The gas occupies a vol

Last Answer : The volume (V) of a mass of gas varies directly as its absulute temperature (T) and iversely as ... and pressure are 250 ml and 320 Pa respectively?

The volume (V) of a mass of gas varies directly as its absolute temperature (T) and inversely as the pressure (P) applied to it. The gas occupies a vo

Description : The volume (V) of a mass of gas varies directly as its absolute temperature (T) and inversely as the pressure (P) applied to it. The gas occupies a vo

Last Answer : The volume (V) of a mass of gas varies directly as its absolute temperature (T) and inversely as ... and pressure are 200 ml and 250 Pa respectively?

For an irreversible process involving only pressure-volume work (A) (dF)T, p <0 (B) (dF)T, p = 0 (C) (dF)T, p > 0 (D) (dA)T, v >0

Description : For an irreversible process involving only pressure-volume work (A) (dF)T, p 0 (D) (dA)T, v >0

Last Answer : (A) (dF)T, p

For a reversible process involving only pressure-volume work (A) (dF)T, p < 0 (B) (dF)T, p > 0 (C) (dF)T, p = 0 (D) (dA)T, v < 0

Description : For a reversible process involving only pressure-volume work (A) (dF)T, p < 0 (B) (dF)T, p > 0 (C) (dF)T, p = 0 (D) (dA)T, v < 0

Last Answer : (C) (dF)T, p = 0

Internal energy of a gas obeying Van-Der-Waals equation of state, [p + (a/v2)] (V - b) = RT, depends upon its (A) Pressure & temperature (B) Pressure & specific volume (C) Temperature & specific volume (D) Temperature only

Description : Internal energy of a gas obeying Van-Der-Waals equation of state, [p + (a/v2)] (V - b) = RT, depends upon its (A) Pressure & temperature (B) Pressure & specific volume (C) Temperature & specific volume (D) Temperature only

Last Answer : (A) Pressure & temperature

If air is at pressure, p, of 3200 lbf/ft2 , and at a temperature, T, of 800 ˚R, what is the specific volume, v? (R=5303 ft-lbf/lbm-˚R, and air can be modeled as an ideal gas.)  A.9.8 ft^3/lbm  B.11.2 ft^3/lbm  C.13.33 ft^3/lbm  D.14.2 ft^3/lbm Formula: pv = RT v = RT / p

Description : If air is at pressure, p, of 3200 lbf/ft2 , and at a temperature, T, of 800 ˚R, what is the specific volume, v? (R=5303 ft-lbf/lbm-˚R, and air can be modeled as an ideal gas.)  A.9.8 ft^3/lbm  B.11.2 ft^3/lbm  C.13.33 ft^3/lbm  D.14.2 ft^3/lbm Formula: pv = RT v = RT / p

Last Answer : 13.33 ft^3/lbm

The sum of internal energy (U) and the product of pressure and volume (p.v) is known as  A. workdone  B. entropy  C. enthalpy  D. none of these

Description : The sum of internal energy (U) and the product of pressure and volume (p.v) is known as  A. workdone  B. entropy  C. enthalpy  D. none of these

Last Answer : Answer: C

Turndown ratio of a burner gives an idea of the __________ in the furnace. (A) Range of fuel firing rates (B) Volume of the combustion chamber (C) Maximum heat input rate only (D) Minimum heat input rate only

Description : Turndown ratio of a burner gives an idea of the __________ in the furnace. (A) Range of fuel firing rates (B) Volume of the combustion chamber (C) Maximum heat input rate only (D) Minimum heat input rate only

Last Answer : (A) Range of fuel firing rates

Pick out the wrong statement. (A) Theoretical flame temperature is the temperature attained by the products of combustion, when the fuel is burned without loss or gain of heat (B) Burning the fuel with theoretically required amount of pure oxygen results in attainment of maximum adiabatic flame temperature (C) Burning the fuel with excess pure oxygen results in maximum theoretical flame temperature (D) Adiabatic flame temperatures of actual combustions are always less than the maximum values

Description : Pick out the wrong statement. (A) Theoretical flame temperature is the temperature attained by the products of combustion, when the fuel is burned without loss or gain of heat (B) ... flame temperature (D) Adiabatic flame temperatures of actual combustions are always less than the maximum values

Last Answer : (C) Burning the fuel with excess pure oxygen results in maximum theoretical flame temperature

Actual flame temperature is always lower than the adiabatic flame temperature, because there is (A) No possibility of obtaining complete combustion at high temperature (B) Always loss of heat from the flame (C) Both (A) and (B) (D) Neither (A) nor (B)

Description : Actual flame temperature is always lower than the adiabatic flame temperature, because there is (A) No possibility of obtaining complete combustion at high temperature (B) Always loss of heat from the flame (C) Both (A) and (B) (D) Neither (A) nor (B)

Last Answer : (C) Both (A) and (B)

The work done by a weightless piston in causing an expansing `Delta V` (at constant temperature), when the opposing pressure P is variable, is given b

Description : The work done by a weightless piston in causing an expansing `Delta V` (at constant temperature), when the opposing pressure P is variable, is given b

Last Answer : The work done by a weightless piston in causing an expansing `Delta V` (at constant temperature), when the opposing ... 0 C. `W = -P Delta V` D. None