Preparation of a diazonium salt from a primary aromatic amine is known as : (a) Coupling reaction (b) Sandmeyer reaction (c) Diazotization (d) Corey-House synthesis

Preparation of a diazonium salt from a primary aromatic amine is known as :
(a) Coupling reaction
(b) Sandmeyer reaction
(c) Diazotization
(d) Corey-House synthesis
by

1 Answer

Answer :

Diazotization
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When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and the reaction is called diazo reaction.

Description : When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and the reaction is called diazo reaction.

Last Answer : When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is ... is formed which can be given as: A. B. C. D.

When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and the reaction is called diazo reaction.

Description : When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and the reaction is called diazo reaction.

Last Answer : When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt ... reaction. The final product is A. B. C. D.

When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and the reaction is called diazo reaction.

Description : When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and the reaction is called diazo reaction.

Last Answer : When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and ... gt R gt S` D. `S gt R gt Q gt P`

When aniline is heated with glycerol in the presence of sulfuric acid and nitrobenzene, it gives quinoline. This reaction in called (a) Fischer synthesis (b) Skraup synthesis (c) Diazotization (d) Corey-House synthesis

Description : When aniline is heated with glycerol in the presence of sulfuric acid and nitrobenzene, it gives quinoline. This reaction in called (a) Fischer synthesis (b) Skraup synthesis (c) Diazotization (d) Corey-House synthesis

Last Answer : Skraup synthesis

The diazonium salts are the reaction products of the reaction of nitrous acid with (a) primary aliphatic amines (b) primary aromatic amines (c) secondary aliphatic amines (d) secondary aromatic amines

Description : The diazonium salts are the reaction products of the reaction of nitrous acid with (a) primary aliphatic amines (b) primary aromatic amines (c) secondary aliphatic amines (d) secondary aromatic amines

Last Answer : primary aromatic amines

Fluorination of an aromatic ring is easily accompolished by treating a diazonium salt with `HBF_4`. Which of the following conditions is correct about

Description : Fluorination of an aromatic ring is easily accompolished by treating a diazonium salt with `HBF_4`. Which of the following conditions is correct about

Last Answer : Fluorination of an aromatic ring is easily accompolished by treating a diazonium salt with `HBF_4`. Which of the ... O //H_(2)O` D. `NaF//Cu`

Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl

Description : Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl

Last Answer : It liberates nitrogen on treatment with ice-cold nitrous acid

Coupling reaction takes place when benzene diazonium chloride is treated with :

Description : Coupling reaction takes place when benzene diazonium chloride is treated with :

Last Answer : Coupling reaction takes place when benzene diazonium chloride is treated with : A. Benzaldehyde B. `alpha`-naphthol C. N, N-dimethyl aniline D. Phenol

Which of the following compounds will not undergo azo coupling reaction with benzene diazonium chloride?

Description : Which of the following compounds will not undergo azo coupling reaction with benzene diazonium chloride?

Last Answer : Which of the following compounds will not undergo azo coupling reaction with benzene diazonium chloride? ... B. Phenol C. Anisole D. Nitrobenzene

Which of the following reactions can be used to prepare alkanes? (a) Corey-House synthesis (b) Williamson synthesis (c) Friedel-Crafts reactions (d) None of these

Description : Which of the following reactions can be used to prepare alkanes? (a) Corey-House synthesis (b) Williamson synthesis (c) Friedel-Crafts reactions (d) None of these

Last Answer : Corey-House synthesis

Consider the following diazonium ion: The order of reactivity towards diazo coupling with phenol in presence of dil. NaOH:

Description : Consider the following diazonium ion: The order of reactivity towards diazo coupling with phenol in presence of dil. NaOH:

Last Answer : Consider the following diazonium ion: The order of reactivity towards diazo coupling with phenol in presence of dil. NaOH ... ` D. `S gt R gt Q gt P`

Aromatic primary amines are not prepared by gabrial phthalimide synthesis. Why?

Description : Aromatic primary amines are not prepared by gabrial phthalimide synthesis. Why?

Last Answer : Ans:- Because aryl halides donot undergo nucleophilic substitution reaction. 

Base-catalyzed condensation of two ester molecules to form an alcohol and β-keto ester is called (a) Claisen condensation (b) Corey-House reaction (c) Aldol condensation (d) Transesterification

Description : Base-catalyzed condensation of two ester molecules to form an alcohol and β-keto ester is called (a) Claisen condensation (b) Corey-House reaction (c) Aldol condensation (d) Transesterification

Last Answer : Claisen condensation

Lassaigne’s test is not shown by diazonium Salt. Why?

Description : Lassaigne’s test is not shown by diazonium Salt. Why?

Last Answer : On heating diazonium Salts loses Nitrogen and could not fuse with the sodium metal therefore diazonium salt do not show Positive Lassaigne’s test for nitrogen.

Aniline reacts with nitrous acid at low temperatures to give (a) a N-nitrosoamine (b) a nitrile (c) a diazonium salt (d) a nitrite salt

Description : Aniline reacts with nitrous acid at low temperatures to give (a) a N-nitrosoamine (b) a nitrile (c) a diazonium salt (d) a nitrite salt

Last Answer : a diazonium salt

An aromatic amine (X) was treated with alcoholic potash and another compound (Y) when foul smelling gas was formed `C_(6)H_(5)NC`. The compound (Y) wa

Description : An aromatic amine (X) was treated with alcoholic potash and another compound (Y) when foul smelling gas was formed `C_(6)H_(5)NC`. The compound (Y) wa

Last Answer : An aromatic amine (X) was treated with alcoholic potash and another compound (Y) when foul smelling gas was formed `C_ ... 3)OH` D. `C_(6)H_(5)NH_(2)`

Aliphatic primary amines react with cold nitrous acid to form (a) Alcohols (b) Diazonium salts (c) Nitriles (d) Nitroalkanes

Description : Aliphatic primary amines react with cold nitrous acid to form (a) Alcohols (b) Diazonium salts (c) Nitriles (d) Nitroalkanes

Last Answer : Alcohols

The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating amide is known as Hofmann-Bromoamide

Description : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating amide is known as Hofmann-Bromoamide

Last Answer : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the ... ` Mechanism: A. B. C. D. all of these

The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating amide is known as Hofmann-Bromoamide

Description : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating amide is known as Hofmann-Bromoamide

Last Answer : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating ... : Find X and Y: A. B. C. D.

The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating amide is known as Hofmann-Bromoamide

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Last Answer : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating ... reaction: A. 1 B. 2 C. 3 D. 4

Alkaline hydrolysis of oils (or fats) is called : (a) Saponification (b) Fermentation (c) Diazotization (d) Rancidification

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Diazotization is carried out by… a. HNO3 b. H2SO4 c. HNO2 d. NO

Description : Diazotization is carried out by… a. HNO3 b. H2SO4 c. HNO2 d. NO

Last Answer : c. HNO2

Which of the following reactions is suitable for the preparation of α-amino acids? (a) Schmidt reaction (b) Hofmann's degradation of amides (c) Strecker's synthesis (b) Reduction of nitro compounds

Description : Which of the following reactions is suitable for the preparation of α-amino acids? (a) Schmidt reaction (b) Hofmann's degradation of amides (c) Strecker's synthesis (b) Reduction of nitro compounds

Last Answer : Strecker's synthesis

Which filler can NOT be used for the preparation of tablets for amine containing basic drugs to avoid discoloration of the tablets? (A) Dicalcium phosphate (B) Microcrystalline cellulose (C) Starch (D) Lactose

Description : Which filler can NOT be used for the preparation of tablets for amine containing basic drugs to avoid discoloration of the tablets? (A) Dicalcium phosphate (B) Microcrystalline cellulose (C) Starch (D) Lactose

Last Answer : (D) Lactose

Assuming roughly equivalent molecular weights, which of the following would have the highest boiling point? (a) a tertiary amine (b) a quaternary ammonium salt (c) an alcohol (d) an ether

Description : Assuming roughly equivalent molecular weights, which of the following would have the highest boiling point? (a) a tertiary amine (b) a quaternary ammonium salt (c) an alcohol (d) an ether

Last Answer : a quaternary ammonium salt

The presence of primary amine can be confirmed by its reaction with:

Description : The presence of primary amine can be confirmed by its reaction with:

Last Answer : The presence of primary amine can be confirmed by its reaction with: A. `HNO_(2)` B. `CHCI_(3) +NaOH` C. `CS_(2)` and `HgCI_(2)` D. `H_(2)SO_(4)`

Soap is (a) a mixture of salts of fatty acids (b) a salt of glycerol (c) a mixture of ethers (d) a mixture of aromatic ethers

Description : Soap is (a) a mixture of salts of fatty acids (b) a salt of glycerol (c) a mixture of ethers (d) a mixture of aromatic ethers

Last Answer : a mixture of salts of fatty acids

During the reaction of Benzene diazonium chloride with para-cresol the substitution occurs at_____position of p-cresol.

Description : During the reaction of Benzene diazonium chloride with para-cresol the substitution occurs at_____position of p-cresol.

Last Answer : During the reaction of Benzene diazonium chloride with para-cresol the substitution occurs at_____position of p-cresol.

Benzene diazonium chloride on reaction with phenol in a basic medium gives:

Description : Benzene diazonium chloride on reaction with phenol in a basic medium gives:

Last Answer : Benzene diazonium chloride on reaction with phenol in a basic medium gives: A. benzene B. chlorobenzene C. diphenyl ether D. p-hydroxy azobenzene

A primary amine can be identified by using (a) HCl (b) CHCl3 (c) NaOH (d) CHCl3 + KOH

Description : A primary amine can be identified by using (a) HCl (b) CHCl3 (c) NaOH (d) CHCl3 + KOH

Last Answer : CHCl3 + KOH

Which type of amine produces N2 when treated with HONO? (a) Primary (b) Secondary (c) Tertiary (d) Quaternary

Description : Which type of amine produces N2 when treated with HONO? (a) Primary (b) Secondary (c) Tertiary (d) Quaternary

Last Answer : Primary

Carbylamine test involves heating a mixture of (a) alcoholic KOH, methyl iodide, and sodium metal (b) alcoholic KOH, methyl iodide, and primary amine (c) alcoholic KOH, chloroform, and primary amine (d) alcoholic KOH, methyl alcohol, and primary amine

Description : Carbylamine test involves heating a mixture of (a) alcoholic KOH, methyl iodide, and sodium metal (b) alcoholic KOH, methyl iodide, and primary amine (c) alcoholic KOH, chloroform, and primary amine (d) alcoholic KOH, methyl alcohol, and primary amine

Last Answer : alcoholic KOH, chloroform, and primary amine

Alkyl cyanide on reduction gives….. a. primary amine b. secondary amine c. amide d. carboxylic acid

Description : Alkyl cyanide on reduction gives….. a. primary amine b. secondary amine c. amide d. carboxylic acid

Last Answer : a. primary amine

The increasing order of diazotization of the following compound is :

Description : The increasing order of diazotization of the following compound is :

Last Answer : The increasing order of diazotization of the following compound is : A. `(a) lt (b) lt (c) lt (d)` B. `(a) lt ( ... b)` D. `(d) lt (c) lt (b) lt (a)`

In Gabriel synthesis, amine is always:

Description : In Gabriel synthesis, amine is always:

Last Answer : In Gabriel synthesis, amine is always: A. alphatic primary amine B. aliphatic secondary amine C. aromatic primary amine D. aromatic secondary amine

Corey-House is related to?

Description : Corey-House is related to?

Last Answer : Alkane

. Amount of 2,4-D amine salt at 10 ppm for a pond measuring 40mx20mx5m a). 0.4 kg b). 400 kg c). 40 kg d). 4 kg

Description : . Amount of 2,4-D amine salt at 10 ppm for a pond measuring 40mx20mx5m a). 0.4 kg b). 400 kg c). 40 kg d). 4 kg

Last Answer : c). 40 kg

What is carbil amine reaction ?

Description : What is carbil amine reaction ?

Last Answer : The primary or 1 degree amine ( CH3-NH2 and aniline) reacts with chloroform and alcoholic caustic potash ( KOH) to produce methyl carbil amine ( CH3-NC) . This reaction is called carbil amine reaction.

The substance that gives a primary amine on hydrolysis is

Description : The substance that gives a primary amine on hydrolysis is

Last Answer : The substance that gives a primary amine on hydrolysis is A. nitroparaffin B. alkyl cyanide C. oxime D. alkyl isocyanide

Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to give a primary amine that ha

Description : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to give a primary amine that ha

Last Answer : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to ... . `II gt I gt IV gt III`

Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to give a primary amine that ha

Description : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to give a primary amine that ha

Last Answer : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to ... O)overset(||)(C)-NH_(2)`

Give 3 methods to distinguish primary amine from secondary and tertiary.

Description : Give 3 methods to distinguish primary amine from secondary and tertiary.

Last Answer : Give 3 methods to distinguish primary amine from secondary and tertiary.

What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the chain reaction. (b) It functions by destabilizing the carbocationic intermediate and thereby increases the rate of H+ loss. (c) It serves as a Lewis base catalyst by reacting with Cl2 to generate chloride ions. (d) It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Description : What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the ... by reacting with the Cl2 and thereby activates it toward attack by benzene's π electrons.

Last Answer : It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Conversion of benzene diazonium chloride to chloro benzene is an example of which of the following reactions ?

Description : Conversion of benzene diazonium chloride to chloro benzene is an example of which of the following reactions ?

Last Answer : Conversion of benzene diazonium chloride to chloro benzene is an example of which of the following ... Friedel-Crafts acylation C. Sandmeyer D. Wurtz

Complete reduction of benzene-diazonium chloride with Zn/HCl gives :

Description : Complete reduction of benzene-diazonium chloride with Zn/HCl gives :

Last Answer : Complete reduction of benzene-diazonium chloride with Zn/HCl gives : A. Aniline B. Phenylhydrazine C. Azobenzene D. Hydrazobenzene

A solution contains 1g mol. Each of p-toluene diazonium chloride and p-nitrophenyl diazonium cholride. To this 1g mol.of alkaline solution of phenol i

Description : A solution contains 1g mol. Each of p-toluene diazonium chloride and p-nitrophenyl diazonium cholride. To this 1g mol.of alkaline solution of phenol i

Last Answer : A solution contains 1g mol. Each of p-toluene diazonium chloride and p-nitrophenyl diazonium ... Predict the major product. Explain your answer.

Benzene diazonium chloride on hydrolysis gives

Description : Benzene diazonium chloride on hydrolysis gives

Last Answer : Benzene diazonium chloride on hydrolysis gives A. Benzene B. Benzyl alcohol C. Phenol D. Chlorobenzene

What is a coupling reaction ?

Description : What is a coupling reaction ?

Last Answer : : An oxidation reaction in which two or more chemicals combine to form a single product is called a coupling reaction. For example, ferrous chloride combines with chlorine to produce ferric ... Thus the process of producing ammonia gas is considered as either a coupling or synthesis reaction.

What is the coupling reaction ?

Description : What is the coupling reaction ?

Last Answer : : Benzene diazonium chloride ( C6H5N2Cl) reacts with phenol in mild alkaline solution ( NaOH) to form yellow azo compound. This reaction is called coupling reaction.