What is carbil amine reaction ?

What is carbil amine reaction ?
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Answer :

The primary or 1 degree amine ( CH3-NH2 and aniline) reacts with chloroform and alcoholic caustic potash ( KOH) to produce methyl carbil amine ( CH3-NC) . This reaction is called carbil amine reaction.
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Preparation of a diazonium salt from a primary aromatic amine is known as : (a) Coupling reaction (b) Sandmeyer reaction (c) Diazotization (d) Corey-House synthesis

Description : Preparation of a diazonium salt from a primary aromatic amine is known as : (a) Coupling reaction (b) Sandmeyer reaction (c) Diazotization (d) Corey-House synthesis

Last Answer : Diazotization

In the hofmann-bromamide degradation reaction, the number of moles of NaOH and `Br_(2)` used per mole of amine produced are

Description : In the hofmann-bromamide degradation reaction, the number of moles of NaOH and `Br_(2)` used per mole of amine produced are

Last Answer : In the hofmann-bromamide degradation reaction, the number of moles of NaOH and `Br_(2)` used per mole of ... moles of NaOH and one mole of `Br_(2)`

Of the following amines how many can give carbyl amine reaction?

Description : Of the following amines how many can give carbyl amine reaction?

Last Answer : Of the following amines how many can give carbyl amine reaction?

When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and the reaction is called diazo reaction.

Description : When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and the reaction is called diazo reaction.

Last Answer : When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is ... is formed which can be given as: A. B. C. D.

When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and the reaction is called diazo reaction.

Description : When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and the reaction is called diazo reaction.

Last Answer : When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt ... reaction. The final product is A. B. C. D.

When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and the reaction is called diazo reaction.

Description : When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and the reaction is called diazo reaction.

Last Answer : When an primary aromatic amine is treated with `NaNO_(2)+HCI` at `0^(@)-5^(@)C`, a diazonium salt is formed and ... gt R gt S` D. `S gt R gt Q gt P`

The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating amide is known as Hofmann-Bromoamide

Description : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating amide is known as Hofmann-Bromoamide

Last Answer : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the ... ` Mechanism: A. B. C. D. all of these

The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating amide is known as Hofmann-Bromoamide

Description : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating amide is known as Hofmann-Bromoamide

Last Answer : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating ... : Find X and Y: A. B. C. D.

The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating amide is known as Hofmann-Bromoamide

Description : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating amide is known as Hofmann-Bromoamide

Last Answer : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating ... reaction: A. 1 B. 2 C. 3 D. 4

Optically active amine having molecular formula `C_(5)H_(13)N` on reaction with `NaNO_(2)+HCI` produces, `3^(@)` optically inative alcohol. Find out s

Description : Optically active amine having molecular formula `C_(5)H_(13)N` on reaction with `NaNO_(2)+HCI` produces, `3^(@)` optically inative alcohol. Find out s

Last Answer : Optically active amine having molecular formula `C_(5)H_(13)N` on reaction with `NaNO_(2)+HCI` produces, ` ... out structures of amines: A. B. C. D.

The presence of primary amine can be confirmed by its reaction with:

Description : The presence of primary amine can be confirmed by its reaction with:

Last Answer : The presence of primary amine can be confirmed by its reaction with: A. `HNO_(2)` B. `CHCI_(3) +NaOH` C. `CS_(2)` and `HgCI_(2)` D. `H_(2)SO_(4)`

Trimetyl amine is pyramidal while trisilyl amine is trigonal planer . explain ?

Description : Trimetyl amine is pyramidal while trisilyl amine is trigonal planer . explain ?

Last Answer : Ans. In tri silylamine N is sp2 hybridised and pπ-dπ bonding take place while In trimethyl amine N is SP3 hybridised and No pπ-dπ bonding .

How would you remove nonpolar impurities from an amine ?

Description : How would you remove nonpolar impurities from an amine ?

Last Answer : Ans.--- Adding HCl , amine will form salt whereas nonpolar impurities will not react . Amines can be regenerated by adding NaOH . 

Why is amide more acidic than an amine ?

Description : Why is amide more acidic than an amine ?

Last Answer : Ans.—In amide there is C=O group attached NH2 , electron withdrawing & increases acidic nature of amide whereas in amines there is alkyl group which is electron releasing and makes it more basic & hence less acidic.

Pkb of aniline is more than that of methyl amine.

Description : Pkb of aniline is more than that of methyl amine.

Last Answer : In aniline, the lone pair of electrons on the N-atom are delocalized over the benzene ring. As a result electron density on the nitrogen decreases. In contrast in CH2NH2 , + I effect of CH3 ... , aniline is a weaker base than methylamine and hence its Pkb value is higher than that of methylamine.

Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl

Description : Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl

Last Answer : It liberates nitrogen on treatment with ice-cold nitrous acid

A primary amine can be identified by using (a) HCl (b) CHCl3 (c) NaOH (d) CHCl3 + KOH

Description : A primary amine can be identified by using (a) HCl (b) CHCl3 (c) NaOH (d) CHCl3 + KOH

Last Answer : CHCl3 + KOH

Which of the following does not react with acyl chlorides to form amides : (a) ammonia (b) 1° amine (c) 2° amine (d) 3° amine

Description : Which of the following does not react with acyl chlorides to form amides : (a) ammonia (b) 1° amine (c) 2° amine (d) 3° amine

Last Answer : 3° amine

Which type of amine produces N2 when treated with HONO? (a) Primary (b) Secondary (c) Tertiary (d) Quaternary

Description : Which type of amine produces N2 when treated with HONO? (a) Primary (b) Secondary (c) Tertiary (d) Quaternary

Last Answer : Primary

. Reduction of an imine will give an (a) Acid (b) Amide (c) Amine (d) Alcohol

Description : Reduction of an imine will give an (a) Acid (b) Amide (c) Amine (d) Alcohol

Last Answer : Amine

Consider a 1°, 2° and 3° amine, all of equivalent molecular weight. Which amine is most likely to have the lowest boiling point? (a) 1° amine (b) 2° amine (c) 3° amine (d) Not enough information to determine

Description : Consider a 1°, 2° and 3° amine, all of equivalent molecular weight. Which amine is most likely to have the lowest boiling point? (a) 1° amine (b) 2° amine (c) 3° amine (d) Not enough information to determine

Last Answer : 3° amine

Which amine is NOT soluble in water? (a) Methylamine (b) Dimethylamine (c) Trimethylamine (d) All are water-soluble

Description : Which amine is NOT soluble in water? (a) Methylamine (b) Dimethylamine (c) Trimethylamine (d) All are water-soluble

Last Answer : All are water-soluble

A sample of pure amine molecules is found to possess no intermolecular Hbonding. This sample is most likely : (a) 1° amine (b) 2° amine (c) 3° amine (d) all of these

Description : A sample of pure amine molecules is found to possess no intermolecular Hbonding. This sample is most likely : (a) 1° amine (b) 2° amine (c) 3° amine (d) all of these

Last Answer : 3° amine

The hybridization of nitrogen in an amine is (a) sp (b) sp3 (c) sp2 (d) sp4

Description : The hybridization of nitrogen in an amine is (a) sp (b) sp3 (c) sp2 (d) sp4

Last Answer : sp3

Assuming roughly equivalent molecular weights, which of the following would have the highest boiling point? (a) a tertiary amine (b) a quaternary ammonium salt (c) an alcohol (d) an ether

Description : Assuming roughly equivalent molecular weights, which of the following would have the highest boiling point? (a) a tertiary amine (b) a quaternary ammonium salt (c) an alcohol (d) an ether

Last Answer : a quaternary ammonium salt

Amides undergo hydrolysis under acidic conditions to give (a) Carboxylic acid and amine (b) Carboxylic acid and ammonium ion (c) Carboxylate ion and ammonium ion (d) Carboxylate ion and amine

Description : Amides undergo hydrolysis under acidic conditions to give (a) Carboxylic acid and amine (b) Carboxylic acid and ammonium ion (c) Carboxylate ion and ammonium ion (d) Carboxylate ion and amine

Last Answer : Carboxylic acid and ammonium ion

Consider a small aliphatic 1° amine, 1° alcohol, ester, carboxylic acid, and amide, all of similar molecular weight. Which one is most likely to have thehighest boiling point?(a) The amide(b) The alcohol(c) The ester(d) The carboxylic acid

Description : Consider a small aliphatic 1° amine, 1° alcohol, ester, carboxylic acid, and amide, all of similar molecular weight. Which one is most likely to have the highest boiling point? (a) The amide (b) The alcohol (c) The ester (d) The carboxylic acid

Last Answer : The amide

Which of the following statements is False about acetamide? (a) reacts with Br2/NaOH to form tertiary amine (b) undergoes acid-hydrolysis to form acetic acid (c) undergoes dehydration with P2O5 to form a nitrile (d) is a white crystalline solid, soluble in water

Description : Which of the following statements is False about acetamide? (a) reacts with Br2/NaOH to form tertiary amine (b) undergoes acid-hydrolysis to form acetic acid (c) undergoes dehydration with P2O5 to form a nitrile (d) is a white crystalline solid, soluble in water

Last Answer : reacts with Br2/NaOH to form tertiary amine

Carbylamine test involves heating a mixture of (a) alcoholic KOH, methyl iodide, and sodium metal (b) alcoholic KOH, methyl iodide, and primary amine (c) alcoholic KOH, chloroform, and primary amine (d) alcoholic KOH, methyl alcohol, and primary amine

Description : Carbylamine test involves heating a mixture of (a) alcoholic KOH, methyl iodide, and sodium metal (b) alcoholic KOH, methyl iodide, and primary amine (c) alcoholic KOH, chloroform, and primary amine (d) alcoholic KOH, methyl alcohol, and primary amine

Last Answer : alcoholic KOH, chloroform, and primary amine

Alkyl cyanide on reduction gives….. a. primary amine b. secondary amine c. amide d. carboxylic acid

Description : Alkyl cyanide on reduction gives….. a. primary amine b. secondary amine c. amide d. carboxylic acid

Last Answer : a. primary amine

Based on the intermolecular forces involved, which of the following molecules will have the lowest boiling point? w) ethane x) methyl alcohol y) methyl amine z) methyl fluoride

Description : Based on the intermolecular forces involved, which of the following molecules will have the lowest boiling point? w) ethane x) methyl alcohol y) methyl amine z) methyl fluoride

Last Answer : ANSWER: W -- ethane

An amine contains which one of the following functional groups? w) NO2 x) NOH y) NH2 z) N2

Description : An amine contains which one of the following functional groups? w) NO2 x) NOH y) NH2 z) N2

Last Answer : ANSWER: Y -- NH2

Which of the following would be most acidic? w) phenol x) methanol y) acetic acid z) methyl amine

Description : Which of the following would be most acidic? w) phenol x) methanol y) acetic acid z) methyl amine

Last Answer : ANSWER: C -- ACETIC ACID

In the following reactions `2X+B_(2)H_(6) to [BH_(2)(X)_(2)]^(+){BH_(4)]^(-)` The amine X will not be -

Description : In the following reactions `2X+B_(2)H_(6) to [BH_(2)(X)_(2)]^(+){BH_(4)]^(-)` The amine X will not be -

Last Answer : In the following reactions `2X+B_(2)H_(6) to [BH_(2)(X)_(2)]^(+){BH_(4)]^(-)` The amine X will not be - A. ... C. `(CH_(3))_(2)NH` D. `(CH_(3))_(3)N`

Tertiary butyl amine is a-

Description : Tertiary butyl amine is a-

Last Answer : Tertiary butyl amine is a- A. `1^(@)` Amine B. `2^(@)` Amine C. `3^(@)` Amine D. Quaternary salt

The substance that gives a primary amine on hydrolysis is

Description : The substance that gives a primary amine on hydrolysis is

Last Answer : The substance that gives a primary amine on hydrolysis is A. nitroparaffin B. alkyl cyanide C. oxime D. alkyl isocyanide

Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to give a primary amine that ha

Description : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to give a primary amine that ha

Last Answer : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to ... . `II gt I gt IV gt III`

Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to give a primary amine that ha

Description : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to give a primary amine that ha

Last Answer : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to ... O)overset(||)(C)-NH_(2)`

Which of the following reduction reactions does not give an amine as product?

Description : Which of the following reduction reactions does not give an amine as product?

Last Answer : Which of the following reduction reactions does not give an amine as product? A. `R-NO_(2) underset(" ... (2)underset(Delta)overset(Zn//NH_(4)Cl)rarr`

In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the carbon chain, the reagent used as sou

Description : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the carbon chain, the reagent used as sou

Last Answer : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the ... C_(6)H_(4)(CO)_(2)N^(-)K^(+)`

An aromatic amine (X) was treated with alcoholic potash and another compound (Y) when foul smelling gas was formed `C_(6)H_(5)NC`. The compound (Y) wa

Description : An aromatic amine (X) was treated with alcoholic potash and another compound (Y) when foul smelling gas was formed `C_(6)H_(5)NC`. The compound (Y) wa

Last Answer : An aromatic amine (X) was treated with alcoholic potash and another compound (Y) when foul smelling gas was formed `C_ ... 3)OH` D. `C_(6)H_(5)NH_(2)`

Give 3 methods to distinguish primary amine from secondary and tertiary.

Description : Give 3 methods to distinguish primary amine from secondary and tertiary.

Last Answer : Give 3 methods to distinguish primary amine from secondary and tertiary.

Which of the following amine is optically active?1

Description : Which of the following amine is optically active?1

Last Answer : Which of the following amine is optically active?1 A. `CH_(3)NH_(2)` B. `CH_(3)NHC_(2)H_(5)` C. D. sec-Butylamine

In the path I, if then the amine finally formed is :

Description : In the path I, if then the amine finally formed is :

Last Answer : In the path I, if then the amine finally formed is : A. B. C. racemic mixture of a and b D. none of these

Which of the following can give `1^(@)` amine?

Description : Which of the following can give `1^(@)` amine?

Last Answer : Which of the following can give `1^(@)` amine? A. `Ph-overset(CH_(3))overset(|)(CH)-OH ... overset(NaN_(3))underset(Delta)rarr overset(LiAIH_(4))rarr`

What set of conditions would be useful for preparing a `2^(@)` amine?

Description : What set of conditions would be useful for preparing a `2^(@)` amine?

Last Answer : What set of conditions would be useful for preparing a `2^(@)` amine? A. `2^(@)R-Br +NaNH_(2)` B. `2^(2)R ... (@)R-NH_(2)+1^(@)RCHO,H_(2)` and `Pt` D.

The nitrogan atom in each of the following tertiary amines may be removed as trimethyl amine by repeated Hoffmann elimination. Which of the following

Description : The nitrogan atom in each of the following tertiary amines may be removed as trimethyl amine by repeated Hoffmann elimination. Which of the following

Last Answer : The nitrogan atom in each of the following tertiary amines may be removed as trimethyl amine by repeated Hoffmann ... to accomplish this? A. B. C. D.

Only one of the following amines will lose its nitrogen atom as trimethyl amine by repeated Hofmann elimination reactions:

Description : Only one of the following amines will lose its nitrogen atom as trimethyl amine by repeated Hofmann elimination reactions:

Last Answer : Only one of the following amines will lose its nitrogen atom as trimethyl amine by repeated Hofmann elimination reactions: A. B. C. D.

In which of the following reactions does the amine behaves as an acid ?

Description : In which of the following reactions does the amine behaves as an acid ?

Last Answer : In which of the following reactions does the amine behaves as an acid ? A. `(C_(2)H_(5))_(2)NH +H_(2) PtCI_ ... (C_(2)H_(5))_(3)overset(..)(N)+BF_(3)`

Which of the following compounds is an amine?

Description : Which of the following compounds is an amine?

Last Answer : Which of the following compounds is an amine? A. B. C. D.