Description : Consider a small aliphatic 1° amine, 1° alcohol, ester, carboxylic acid, and amide, all of similar molecular weight. Which one is most likely to have the highest boiling point? (a) The amide (b) The alcohol (c) The ester (d) The carboxylic acid
Last Answer : The amide
Description : The reduction of a ketone (a) always gives a primary alcohol (b) always gives a secondary alcohol (c) always gives a carboxylic acid (d) always gives a ketal
Last Answer : always gives a secondary alcoho
Description : Reduction of an imine will give an (a) Acid (b) Amide (c) Amine (d) Alcohol
Last Answer : Amine
Description : Which of the following is the correct ranking in decreasing order of relative Boiling Point of carbonyl containing compounds? (a) primary amide > carboxylic acid >> ester ~ acyl chloride ~ aldehyde ~ ketone ... chloride ~ amide (d) carboxylic acid > amide >> ester ~ acyl chloride ~ aldehyde ~ ketone
Last Answer : primary amide > carboxylic acid >> ester ~ acyl chloride ~ aldehyde ~ ketone
Description : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to give a primary amine that ha
Last Answer : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to ... . `II gt I gt IV gt III`
Last Answer : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to ... O)overset(||)(C)-NH_(2)`
Description : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating amide is known as Hofmann-Bromoamide
Last Answer : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the ... ` Mechanism: A. B. C. D. all of these
Last Answer : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating ... : Find X and Y: A. B. C. D.
Last Answer : The conversion of an amide by reaction `NaOH` and `Br_(2)` to primary amine that has one carbon than the strating ... reaction: A. 1 B. 2 C. 3 D. 4
Description : Which reaction does not yield an ester as one of the products? (a) A carboxylic acid is heated with an alcohol (b) A Grignard reagent is added to a carboxylic acid (c) An acid halide is treated with an alcohol (d) An alkyl halide is heated with the salt of a carboxylic acid
Last Answer : A Grignard reagent is added to a carboxylic acid
Description : Amides undergo hydrolysis under acidic conditions to give (a) Carboxylic acid and amine (b) Carboxylic acid and ammonium ion (c) Carboxylate ion and ammonium ion (d) Carboxylate ion and amine
Last Answer : Carboxylic acid and ammonium ion
Description : Why is amide more acidic than an amine ?
Last Answer : Ans.—In amide there is C=O group attached NH2 , electron withdrawing & increases acidic nature of amide whereas in amines there is alkyl group which is electron releasing and makes it more basic & hence less acidic.
Description : Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl
Last Answer : It liberates nitrogen on treatment with ice-cold nitrous acid
Description : A nitrile can be made by dehydrating an amide. However, for this reaction to occur, the amide must be : (a) primary (b) secondary (c) tertiary (d) N-methylated
Last Answer : primary
Description : How should CH3CHClCH2CH3 be classified? (a) primary alkyl halide (b) secondary alkyl halide (c) tertiary alkyl halide (d) quarternary alkyl halide
Last Answer : secondary alkyl halide
Description : 2-Methyl-2-butene reacts with HBr in the presence of peroxide to give (a) A primary alkyl bromide (b) A secondary alkyl bromide (c) A tertiary alkyl bromide (d) A vicinal dibromide
Last Answer : A secondary alkyl bromide
Description : 2-Methylpropene reacts with HBr in the presence of peroxide to give (a) A primary alkyl bromide (b) A secondary alkyl bromide (c) A tertiary alkyl bromide (d) A vicinal dibromide
Last Answer : A primary alkyl bromide
Description : What type of an alkyl group is an isobutyl group? (a) primary (b) secondary (c) tertiary (d) none of these
Last Answer : none of these
Description : In an alkyl halide substitution of hydrogen by deuterium results in slow formation of ion pair. This is known as? a. Ortho effect b. Mesomeric effect c. Secondary kinetic isotope effect d. Primary kinetic isotope effect
Last Answer : c. Secondary kinetic isotope effect
Description : Which type of amine produces N2 when treated with HONO? (a) Primary (b) Secondary (c) Tertiary (d) Quaternary
Last Answer : Primary
Description : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the carbon chain, the reagent used as sou
Last Answer : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the ... C_(6)H_(4)(CO)_(2)N^(-)K^(+)`
Description : A compound undergoes reduction with LiAlH4. It also dissolves in aqueous NaOH from which it can be recovered by addition of HCl. The compound is (a) a carboxylic acid (b) an ester (c) an acid anhydride (d) an alcohol
Last Answer : a carboxylic acid
Description : Ethyl cyanide (A) can be converted to ethyl amine (B) by:
Last Answer : Ethyl cyanide (A) can be converted to ethyl amine (B) by: A. `A overset(Sn //HCI)rarr B` B. `A ... LiAIH_(4))rarr B` D. both (a),(c) are correct
Description : Oxidation of a secondary alcohol with K2Cr2O7/H+ produces (a) a carboxylic acid (b) a ketone (c) an aldehyde (d) an ester
Last Answer : a ketone
Description : An organic compound (A), C3H8O, on oxidation gives (B), C3H6O. The compound (B) could be (a) a carbonyl compound (b) an alcohol (c) a carboxylic acid (d) an ether
Last Answer : a carbonyl compound
Description : Give 3 methods to distinguish primary amine from secondary and tertiary.
Last Answer : Give 3 methods to distinguish primary amine from secondary and tertiary.
Description : The substance that gives a primary amine on hydrolysis is
Last Answer : The substance that gives a primary amine on hydrolysis is A. nitroparaffin B. alkyl cyanide C. oxime D. alkyl isocyanide
Description : Oxidation of a primary alcohol with produces (a) a carboxylic acid (b) an ether (c) a ketone (d) an ester
Description : Decomposition of the acetyl salicylic acid at room temperature most likely would occur by (a) Oxidation of the ester (b) Reduction of the carboxylic acid (c) Hydrolysis of the ester
Last Answer : Ans: C
Description : Which of the following is a secondary alkyl halide? (a) CH3Br (b) (CH3)3CBr (c) (CH3)2CHBr (d) (CH3)2CHCH2Br
Last Answer : (CH3)2CHBr
Description : Acetamide on heating with P2O5 gives : (a) Methylamine (b) Ethylamine (c) Methyl cyanide (d) None of these
Last Answer : Methyl cyanide
Description : The conversion of aldehyde having no alpha hydrogen to a mixture to a mixture of carboxylic acid and primary alcohol is known as cannizzaro reaction.
Last Answer : The conversion of aldehyde having no alpha hydrogen to a mixture to a mixture of carboxylic acid and primary ... final product is A. B. C. D.
Last Answer : The conversion of aldehyde having no alpha hydrogen to a mixture to a mixture of carboxylic acid and primary ... C. step III D. step I and II both
Description : When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form
Last Answer : primary amines form
Description : Alkyl halides react with ammonia in the presence of base to form : (a) primary amines (b) nitrated alkyl halides (c) amides (d) quaternary ammonium salts
Last Answer : primary amines
Description : Preparation of a diazonium salt from a primary aromatic amine is known as : (a) Coupling reaction (b) Sandmeyer reaction (c) Diazotization (d) Corey-House synthesis
Last Answer : Diazotization
Description : A primary amine can be identified by using (a) HCl (b) CHCl3 (c) NaOH (d) CHCl3 + KOH
Last Answer : CHCl3 + KOH
Description : Carbylamine test involves heating a mixture of (a) alcoholic KOH, methyl iodide, and sodium metal (b) alcoholic KOH, methyl iodide, and primary amine (c) alcoholic KOH, chloroform, and primary amine (d) alcoholic KOH, methyl alcohol, and primary amine
Last Answer : alcoholic KOH, chloroform, and primary amine
Description : Ketones react with Grignard reagents to form an addition product which on hydrolysis gives a (a) Primary alcohol (b) Tertiary alcohol (c) Secondary alcohol (d) Ketal
Last Answer : Tertiary alcohol
Description : Which of the following reduction reactions does not give an amine as product?
Last Answer : Which of the following reduction reactions does not give an amine as product? A. `R-NO_(2) underset(" ... (2)underset(Delta)overset(Zn//NH_(4)Cl)rarr`
Description : Which of the following statements is false about secondary amines? (a) They react with chloroform and NaOH to form isocyanides. (b) They can be prepared by reduction of isocyanides. (c) They react ... give substituted amides. (d) They react with ice-cold nitrous acid to give nitrosamine (yellow oil)
Last Answer : They react with chloroform and NaOH to form isocyanides.
Description : In a size reduction crushing operation, the feed size is 10 to 50 mm, while the product size is 2 to 10 mm. This is a case of __________ crushing. (A) Primary (B) Secondary (C) Fine
Last Answer : (C) Fine
Description : In a size reduction crushing operation, feed size is 100 to 300 mm. while the product size is 10 to 50 mm. This is a case of the __________ crushing. (A) Primary (B) Secondary (C) Fine (D) Ultrafine
Last Answer : (B) Secondary
Description : In a size reduction crushing operation, feed size is 300 to 1500 mm while the product size is 100 to 300 mm. This is a case of the __________ crushing. (A) Secondary (B) Fine (C) Primary (D) Ultrafine
Last Answer : (C) Primary
Description : The junction between primary and secondary dentine is,*** A. A reversal line B. Sharp curvature C. A resting line D. A reduction in the number of tubules
Last Answer : B. Sharp curvature
Description : Synthetic detergents are made from – (1) Sodium stearate (2) Sodium salt of benzene sulphonic acid (3) Sodium salt of benzene carboxylic acid (4) Sodium palmitate
Last Answer : (2) Sodium salt of benzene sulphonic acid Explanation: Synthetic detergents are made from sodium salt of benezene sulphonic acid.
Description : Why does solubility decreases with increasing molecular mass in carboxylic acid ?
Last Answer : Ans. Because of increase in alkyl chain length which is hydrophobic in nature.
Description : During preparation of esters from a carboxylic acid and an alcohol in the presence of an acid catalyst, water or the ester formed should be removed as soon as it is formed.
Last Answer : Ans. The formation of esters from a carboxylic acid and an alcohol in the presence of acid catalyst in a reversible reaction. To shift the equilibrium in the forward direction, the water or ester formed should be removed as fast as it is formed.