The relative volatility of a binary mixture at the Azeotropic composition is (A) 1 (B) > 1 (C) 0 (D) ∞

The relative volatility of a binary mixture at the Azeotropic composition

is

(A) 1

(B) > 1

(C) 0

(D) ∞

by

1 Answer

Answer :

(D) ∞

by

Related questions

Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is nonlinear in the case of steady state unimolal unidirectional diffusion (C) Azeotropes obey Raoult's law at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1

Description : Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial ... at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1

Last Answer : (C) Azeotropes obey Raoult's law at all temperature

Pick out the wrong statement. (A) Constant pressure distillation cannot separate an Azeotropic mixture (B) Relative volatility of a binary mixture changes appreciably with the minor change in temperature (C) The relative volatility of a binary mixture at Azeotropic composition is unity (D) Flash distillation is practised on wide spread scale in petroleum refinery

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Last Answer : (B) Relative volatility of a binary mixture changes appreciably with the minor change in temperature

Entrainer used in Azeotropic distillation should (A) Form a low boiling azeotrope with one of the constituents of the mixture (B) Form a new azeotrope of low relative volatility with one of the constituents of the mixture (C) Have high latent heat of vaporisation (D) Have high viscosity to provide high tray efficiency

Description : Entrainer used in Azeotropic distillation should (A) Form a low boiling azeotrope with one of the constituents of the mixture (B) Form a new azeotrope of low relative volatility with one of the ... (C) Have high latent heat of vaporisation (D) Have high viscosity to provide high tray efficiency

Last Answer : (A) Form a low boiling azeotrope with one of the constituents of the mixture

In case of __________ distillation, a solvent is added to alter the relative volatility of the mixture to be separated. (A) Molecular (B) Azeotropic (C) Extractive

Description : In case of __________ distillation, a solvent is added to alter the relative volatility of the mixture to be separated. (A) Molecular (B) Azeotropic (C) Extractive

Last Answer : (C) Extractive

The-relative volatility for separation of a non-ideal binary mixture by distillation should be (A) 0 (B) 1 (C) > 1 (D) < 1

Description : The-relative volatility for separation of a non-ideal binary mixture by distillation should be (A) 0 (B) 1 (C) > 1 (D) < 1

Last Answer : (C) > 1

For a binary mixture with low relative volatility, continuous rectification to get pure products will require (A) Low reflux ratio (B) Less number of trays (C) Small cross-section column (D) High reflux ratio

Description : For a binary mixture with low relative volatility, continuous rectification to get pure products will require (A) Low reflux ratio (B) Less number of trays (C) Small cross-section column (D) High reflux ratio

Last Answer : (D) High reflux ratio

For a binary mixture with low relative volatility, (A) Use steam distillation (B) Use molecular distillation (C) Use high pressure distillation (D) An azeotrope may be formed during distillation

Description : For a binary mixture with low relative volatility, (A) Use steam distillation (B) Use molecular distillation (C) Use high pressure distillation (D) An azeotrope may be formed during distillation

Last Answer : (D) An azeotrope may be formed during distillation

Relative volatility varies with the concentration of component for an ideal solution. The relative volatility of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when (A) Only vapor phase follows Raoult's law (B) Only liquid phase obeys Dalton's law (C) Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

Description : Relative volatility varies with the concentration of component for an ideal solution. The relative volatility of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of ... law (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

Last Answer : (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

The relative volatility of a binary mixture at constant temperature __________ the total pressure. (A) Decreases with increase in(B) Increases with increase in(C) Is independent of(D) None of these

Description : The relative volatility of a binary mixture at constant temperature __________ the total pressure. (A) Decreases with increase in (B) Increases with increase in (C) Is independent of (D) None of these

Last Answer : (A) Decreases with increase in

According to the Fenske equation, what will be the minimum number of plates required in a distillation column to separate an equimolar binary mixture of components A and B into an overhead fraction containing 99 mol% A and a bottom fraction containing 98 mol% B ? Assume that relative volatility (αAB = 2) does not change appreciably in the column. (A) 5 (B) 9 (C) 12 (D) 28

Description : According to the Fenske equation, what will be the minimum number of plates required in a distillation column to separate an equimolar binary mixture of components A and B into an overhead fraction containing 99 mol% A and a ... in the column. (A) 5 (B) 9 (C) 12 (D) 28

Last Answer : (C) 12

The equilibrium liquid composition compared to the vapor composition in case of Azeotropic mixture is (A) More (B) Less (C) Same (D) Either more or less; depends on the system

Description : The equilibrium liquid composition compared to the vapor composition in case of Azeotropic mixture is (A) More (B) Less (C) Same (D) Either more or less; depends on the system

Last Answer : (C) Same

In Azeotropic mixture, the equilibrium vapour composition is (A) More than liquid composition (B) Less than liquid composition (C) Same as liquid composition (D) Independent of pressure

Description : In Azeotropic mixture, the equilibrium vapour composition is (A) More than liquid composition (B) Less than liquid composition (C) Same as liquid composition (D) Independent of pressure

Last Answer : (C) Same as liquid composition

An Azeotropic mixture is a __________ mixture. (A) Binary (B) Ternary (C) Constant boiling point (D) None of these

Description : An Azeotropic mixture is a __________ mixture. (A) Binary (B) Ternary (C) Constant boiling point (D) None of these

Last Answer : (C) Constant boiling point

Van Laar equation deals with the activity co-efficients in (A) Binary solutions (B) Ternary solutions (C) Azeotropic mixture only (D) None of these

Description : Van Laar equation deals with the activity co-efficients in (A) Binary solutions (B) Ternary solutions (C) Azeotropic mixture only (D) None of these

Last Answer : (A) Binary solutions

In a binary system, separation is very efficient, when the relative volatility is (A) 1 (B) > 1 (C) < 1 (D) 0.5

Description : In a binary system, separation is very efficient, when the relative volatility is (A) 1 (B) > 1 (C) < 1 (D) 0.5

Last Answer : (B) > 1

With increase in pressure, the relative volatility for a binary system (A) Increases (B) Decreases (C) Remains same

Description : With increase in pressure, the relative volatility for a binary system (A) Increases (B) Decreases (C) Remains same

Last Answer : (B) Decreases

When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of (A) Vapour pressure of component A to that of component B (B) Vapour pressure of component A to the total pressure (C) Vapour pressure of component A to the partial pressure of A (D) Partial pressure of component A to the total pressure

Description : When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of (A) Vapour pressure of component A to that of ... to the partial pressure of A (D) Partial pressure of component A to the total pressure

Last Answer : (A) Vapour pressure of component A to that of component B

In extractive distillation, solvent is (A) Added to alter the relative volatility of the mixture (B) Of high volatility (C) Present in overhead stream (D) Of high viscosity to give high tray efficiency

Description : In extractive distillation, solvent is (A) Added to alter the relative volatility of the mixture (B) Of high volatility (C) Present in overhead stream (D) Of high viscosity to give high tray efficiency

Last Answer : (A) Added to alter the relative volatility of the mixture

Fenske equation for determining the minimum number of theoretical stages in distillation column holds good, when the (A) Relative volatility is reasonably constant (B) Mixture (to be separated) shows negative deviation from ideality (C) Mixture (to be separated) shows positive deviation from ideality (D) Multi-component distillation is involved

Description : Fenske equation for determining the minimum number of theoretical stages in distillation column holds good, when the (A) Relative volatility is reasonably constant (B) Mixture (to be separated) ... (to be separated) shows positive deviation from ideality (D) Multi-component distillation is involved

Last Answer : (A) Relative volatility is reasonably constant

Separation of a mixture of two gases by absorption in the liquid solvent depends upon the difference in their (A) Viscosity (B) Density (C) Solubility (D) Relative volatility

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Fugacity is a measure of the (A) Escaping tendencies of the same substance in different phases of a system (B) Relative volatility of a mixture of two miscible liquids (C) Behaviour of ideal gases (D) None of these

Description : Fugacity is a measure of the (A) Escaping tendencies of the same substance in different phases of a system (B) Relative volatility of a mixture of two miscible liquids (C) Behaviour of ideal gases (D) None of these

Last Answer : (A) Escaping tendencies of the same substance in different phases of a system

The number of degree of freedom for an Azeotropic mixture of ethanol and water in vapour-liquid equilibrium, is (A) 3 (B) 1 (C) 2 (D) 0

Description : The number of degree of freedom for an Azeotropic mixture of ethanol and water in vapour-liquid equilibrium, is (A) 3 (B) 1 (C) 2 (D) 0

Last Answer : B) 1

Steam distillation is not recommended to be used, if the (A) Azeotropic mixture is to be separated and the final product is miscible with water (B) Liquids decompose, if distilled directly at atmospheric pressure (C) Material cannot be distilled by indirect heating even under low pressure, because of the high boiling temperature (D) Material to be distilled is thermally unstable or has the tendency to react with other components associated with it, at the boiling temperature

Description : Steam distillation is not recommended to be used, if the (A) Azeotropic mixture is to be separated and the final product is miscible with water (B) Liquids decompose, if ... unstable or has the tendency to react with other components associated with it, at the boiling temperature

Last Answer : (A) Azeotropic mixture is to be separated and the final product is miscible with water

When the mixture to be distilled has a very high boiling point and the product material is heat sensitive, the separation technique to be used is __________ distillation. (A) Continuous (B) Steam (C) Azeotropic (D) None of these

Description : When the mixture to be distilled has a very high boiling point and the product material is heat sensitive, the separation technique to be used is __________ distillation. (A) Continuous (B) Steam (C) Azeotropic (D) None of these

Last Answer : (B) Steam

One mole feed of a binary mixture of a given composition is flash vaporised at a fixed P and T. If Raoult's law is obeyed, then changing the feed composition would effect (A) The product composition but not the fraction vaporised (B) The product composition as well as the fraction vaporised (C) The fraction vaporised but not the product composition (D) Neither the product composition nor the fraction vaporised

Description : One mole feed of a binary mixture of a given composition is flash vaporised at a fixed P and T. If Raoult's law is obeyed, then changing the feed composition would effect (A) ... The fraction vaporised but not the product composition (D) Neither the product composition nor the fraction vaporised

Last Answer : (C) The fraction vaporised but not the product composition

The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of (A) T (B) T and P (C) T, P and Z (D) T and Z

Description : The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of (A) T (B) T and P (C) T, P and Z (D) T and Z

Last Answer : (B) T and P

The ratio of volume of mixed reactor to the volume of P.F.R. (for identical flow rate, feed composition and conversion) for zero order reaction is: (A) ∞(B) 0 (C) 1 (D) > 1

Description : The ratio of volume of mixed reactor to the volume of P.F.R. (for identical flow rate, feed composition and conversion) for zero order reaction is: (A) ∞ (B) 0 (C) 1 (D) > 1

Last Answer : (C) 1

The relative saturation of an unsaturated mixture of gas and vapor is independent of the (A) Nature of the vapor (B) Temperature of the mixture (C) Composition of the mixture (D) None of these

Description : The relative saturation of an unsaturated mixture of gas and vapor is independent of the (A) Nature of the vapor (B) Temperature of the mixture (C) Composition of the mixture (D) None of these

Last Answer : (D) None of these

In case of an unsaturated mixture of gas and vapor, the percentage saturation is __________ its relative saturation. (A) Lower than (B) Higher than (C) Equal to (D) Either (A) or (B), depends on the mixture composition

Description : In case of an unsaturated mixture of gas and vapor, the percentage saturation is __________ its relative saturation. (A) Lower than (B) Higher than (C) Equal to (D) Either (A) or (B), depends on the mixture composition

Last Answer : (A) Lower than

Pick out the correct statement. (A) Ponchan-Savarit method is more accurate than McCabe-Thiele method to determine the number of theoretical stages required for the separation of non￾ideal binary system by distillation (B) A sharp decrease in pressure drop is an indication of flooding in a distillation coloumn (C) Solvent used in extractive distillation should be of high volatility (D) Flash distillation is suitable for separating components which have very close boiling temperature

Description : Pick out the correct statement. (A) Ponchan-Savarit method is more accurate than McCabe-Thiele method to determine the number of theoretical stages required for the separation of ... Flash distillation is suitable for separating components which have very close boiling temperature

Last Answer : (A) Ponchan-Savarit method is more accurate than McCabe-Thiele method to determine the number of theoretical stages required for the separation of non￾ideal binary system by distillation

Solvent used in extractive distillation (A) Changes the relative volatility of the original components (B) Should be of high volatility (C) Should form azeotropes with the original components (D) All (A), (B) and (C)

Description : Solvent used in extractive distillation (A) Changes the relative volatility of the original components (B) Should be of high volatility (C) Should form azeotropes with the original components (D) All (A), (B) and (C)

Last Answer : (A) Changes the relative volatility of the original components

Solvent used in extractive distillation (A) Is of low volatility (B) Forms a low boiling azeotrope (C) Forms a high boiling azeotrope (D) Does not alter the relative volatility of the original components

Description : Solvent used in extractive distillation (A) Is of low volatility (B) Forms a low boiling azeotrope (C) Forms a high boiling azeotrope (D) Does not alter the relative volatility of the original components

Last Answer : (B) Forms a low boiling azeotrope

Fenske-Underwood equation used for calculating the minimum number of theoretical plates in distillation column is valid for (A) Constant molal overflow (B) Total reflux (C) Constant relative volatility (D) All (A), (B) and (C)

Description : Fenske-Underwood equation used for calculating the minimum number of theoretical plates in distillation column is valid for (A) Constant molal overflow (B) Total reflux (C) Constant relative volatility (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

If the amount of the steam used in steam distillation is increased, the temperature of distillation (A) Increases (B) Decreases (C) Remains unchanged (D) Depends on relative volatility

Description : If the amount of the steam used in steam distillation is increased, the temperature of distillation (A) Increases (B) Decreases (C) Remains unchanged (D) Depends on relative volatility

Last Answer : (B) Decreases

Relative volatility does not change appreciably with the change in (A) Temperature (B) Vapour pressure of either component (C) Total pressure (D) None of these

Description : Relative volatility does not change appreciably with the change in (A) Temperature (B) Vapour pressure of either component (C) Total pressure (D) None of these

Last Answer : (A) Temperature

The reciprocal of stripping factor is termed as (A) Selectivity index (B) Relative volatility (C) Absorption factor (D) Murphree efficiency

Description : The reciprocal of stripping factor is termed as (A) Selectivity index (B) Relative volatility (C) Absorption factor (D) Murphree efficiency

Last Answer : (C) Absorption factor

The expression, y(1 - x)/x(1 - y) is for (A) Absorption factor (B) Relative volatility (C) Selectivity (D) Murphree efficiency

Description : The expression, y(1 - x)/x(1 - y) is for (A) Absorption factor (B) Relative volatility (C) Selectivity (D) Murphree efficiency

Last Answer : (B) Relative volatility

High pressure at the bottom of a distillation tower handling heat sensitive materials results in (A) Thermal decomposition of bottoms (B) Increased relative volatility (C) Erosion of the tower (D) Very efficient operation

Description : High pressure at the bottom of a distillation tower handling heat sensitive materials results in (A) Thermal decomposition of bottoms (B) Increased relative volatility (C) Erosion of the tower (D) Very efficient operation

Last Answer : (A) Thermal decomposition of bottoms

Separation of two volatile liquids by distillation makes use of their (A) Selectivity (B) Relative volatility (C) Solubility (D) Density difference

Description : Separation of two volatile liquids by distillation makes use of their (A) Selectivity (B) Relative volatility (C) Solubility (D) Density difference

Last Answer : (B) Relative volatility

The slope of 9-line is determined by the (A) Reflux ratio (B) Plate efficiency to be achieved (C) Thermal condition of the feed (D) Relative volatility

Description : The slope of 9-line is determined by the (A) Reflux ratio (B) Plate efficiency to be achieved (C) Thermal condition of the feed (D) Relative volatility

Last Answer : (C) Thermal condition of the feed

Gibbs-Duhem equation (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure (B) Applies only to binary systems (C) Finds no application in gas-liquid equilibria involved in distillation (D) None of these

Description : Gibbs-Duhem equation (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure (B) Applies only to binary systems (C) Finds no application in gas-liquid equilibria involved in distillation (D) None of these

Last Answer : (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure

Alcohol is dehydrated using __________ distillation. (A) Extractive (B) Azeotropic (C) Steam (D) Molecular

Description : Alcohol is dehydrated using __________ distillation. (A) Extractive (B) Azeotropic (C) Steam (D) Molecular

Last Answer : (B) Azeotropic

Polar organic compounds are normally used as separating agents for the azeotropic and extractive distillation. Which of the following is the most important factor to be considered for the choice of the separating agent for extractive distillation? (A) Cost (B) Availability(C) Toxicity(D) Selectivity

Description : Polar organic compounds are normally used as separating agents for the azeotropic and extractive distillation. Which of the following is the most important factor to be considered for the choice of the separating agent ... ? (A) Cost (B) Availability (C) Toxicity (D) Selectivity

Last Answer : (D) Selectivity

Penicillin is separated from fermented broth by (A) Extraction with amyl or butyl acetate (B) Ternary Azeotropic distillation (C) Evaporator in calandria (D) Extractive distillation

Description : Penicillin is separated from fermented broth by (A) Extraction with amyl or butyl acetate (B) Ternary Azeotropic distillation (C) Evaporator in calandria (D) Extractive distillation

Last Answer : (A) Extraction with amyl or butyl acetate

The diffusivity (D) in a binary gas mixture is related to the temperature (T) as (A) D ∝ T (B) D ∝ T 0.5 (C) D ∝ T 1.5 (D) D ∝ T

Description : The diffusivity (D) in a binary gas mixture is related to the temperature (T) as (A) D ∝ T (B) D ∝ T 0.5 (C) D ∝ T 1.5 (D) D ∝ T

Last Answer : (C) D ∝ T 1.5

For a binary mixture distillation process, the degree of freedom is 2. However, if the pressure is fixed in this process, the number of independent variables in this process will be (A) 1 (B) 0 (C) 2 (D) 3

Description : For a binary mixture distillation process, the degree of freedom is 2. However, if the pressure is fixed in this process, the number of independent variables in this process will be (A) 1 (B) 0 (C) 2 (D) 3

Last Answer : (A) 1

Smoke volatility index is equal to smoke point plus (A) 0.42 × (% distilled at 204°C) (B) 5 mm (C) 0.84 × (% distilled at 204°C) (D) 10 mm approximately

Description : Smoke volatility index is equal to smoke point plus (A) 0.42 × (% distilled at 204°C) (B) 5 mm (C) 0.84 × (% distilled at 204°C) (D) 10 mm approximately

Last Answer : (A) 0.42 × (% distilled at 204°C)

A liquid mixture contains 30% o-xylene, 60% p-xylene and 10%. m￾xylene (all percentages in w/w). Which of the following statements would be true in respect of this mixture? (A) The mixture exhibits an azeotrope at 101.3 kPa (B) The composition of the mixture, in percent by volume is: o-xylene 30, p￾xylene 60. and m-xylene 10 (C) The composition of the mixture in mole percent is: o-xylene 30, p-xylene 60 and m-xyoene 10 (D) The mixture contain optical isomers

Description : A liquid mixture contains 30% o-xylene, 60% p-xylene and 10%. m￾xylene (all percentages in w/w). Which of the following statements would be true in respect of this mixture? (A) The mixture exhibits ... : o-xylene 30, p-xylene 60 and m-xyoene 10 (D) The mixture contain optical isomers

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The dew point of an unsaturated gas-vapor mixture does not depend upon the __________ of the mixture. (A) Composition (B) Temperature (C) Total pressure (D) All (A), (B) and (C)

Description : The dew point of an unsaturated gas-vapor mixture does not depend upon the __________ of the mixture. (A) Composition (B) Temperature (C) Total pressure (D) All (A), (B) and (C)

Last Answer : (B) Temperature