In Azeotropic mixture, the equilibrium vapour composition is
(A) More than liquid composition
(B) Less than liquid composition
(C) Same as liquid composition
(D) Independent of pressure
Description : The equilibrium liquid composition compared to the vapor composition in case of Azeotropic mixture is (A) More (B) Less (C) Same (D) Either more or less; depends on the system
Last Answer : (C) Same
Description : The number of degree of freedom for an Azeotropic mixture of ethanol and water in vapour-liquid equilibrium, is (A) 3 (B) 1 (C) 2 (D) 0
Last Answer : B) 1
Description : Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial ... at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1
Last Answer : (C) Azeotropes obey Raoult's law at all temperature
Description : Pick out the wrong statement. (A) Constant pressure distillation cannot separate an Azeotropic mixture (B) Relative volatility of a binary mixture changes appreciably with the minor change in ... unity (D) Flash distillation is practised on wide spread scale in petroleum refinery
Last Answer : (B) Relative volatility of a binary mixture changes appreciably with the minor change in temperature
Description : A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co- ... and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi
Last Answer : (C) Temperature, pressure and liquid composition xi only
Description : The relative volatility of a binary mixture at the Azeotropic composition is (A) 1 (B) > 1 (C) 0 (D) ∞
Last Answer : (D) ∞
Description : Moisture in a substance exerting an equilibrium vapour pressure less than that of pure liquid at the same temperature is called the __________ moisture. (A) Bound (B) Unbound (C) Critical (D) None of these
Last Answer : (A) Bound
Description : In case of steam distillation, the steam leaving the liquid is not completely saturated with distillate vapour, because (A) Temperature is less (B) Total pressure is less (C) Mixing of steam ... not so intimate as to result in equilibrium condition (D) Saturated steam is used for steam distillation
Last Answer : (C) Mixing of steam with the material being vaporised is not so intimate as to result in equilibrium condition
Description : When liquid and vapour phase of multi-component system are in equilibrium (at a given temperature and pressure), then chemical potential of each component is (A) Same in both the phases (B) Zero in both the phases (C) More in vapour phase (D) More in liquid phase
Last Answer : (A) Same in both the phases
Description : When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is (A) More in vapour phase (B) More in liquid phase (C) Same in both the phases (D) Replaced by chemical potential which is more in vapour phase
Last Answer : (C) Same in both the phases
Description : Steam distillation is not recommended to be used, if the (A) Azeotropic mixture is to be separated and the final product is miscible with water (B) Liquids decompose, if ... unstable or has the tendency to react with other components associated with it, at the boiling temperature
Last Answer : (A) Azeotropic mixture is to be separated and the final product is miscible with water
Description : Moisture in a solid exerting an equilibrium vapour pressure equal to that of the pure liquid at the same temperature is called the __________ moisture. (A) Unbound (B) Critical (C) Free (D) Bound
Last Answer : (A) Unbound
Description : In saturated gas, the (A) Vapour is in equilibrium with the liquid at the gas temperature (B) Vapour is in equilibrium with the liquid at the room temperature (C) Partial pressure of vapour equals the vapour pressure of the liquid at room temperature (D) None of these
Last Answer : (A) Vapour is in equilibrium with the liquid at the gas temperature
Description : If the vapour pressure at two temperatures of a solid phase in equilibrium with its liquid phase are known, then the latent heat of fusion can be calculated by the (A) Maxwell's equation (B) Clausius-Clapeyron Equation (C) Van Laar equation (D) Nernst Heat Theorem
Last Answer : B) Clausius-Clapeyron Equation
Description : For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant (A) Is independent of pressure (B) Increases with pressure (C) Decreases with pressure (D) Increases /decreases with pressure depending on the stoichiometric coefficients of the reaction
Last Answer : (B) Increases with pressure
Description : An Azeotropic mixture is a __________ mixture. (A) Binary (B) Ternary (C) Constant boiling point (D) None of these
Last Answer : (C) Constant boiling point
Description : Entrainer used in Azeotropic distillation should (A) Form a low boiling azeotrope with one of the constituents of the mixture (B) Form a new azeotrope of low relative volatility with one of the ... (C) Have high latent heat of vaporisation (D) Have high viscosity to provide high tray efficiency
Last Answer : (A) Form a low boiling azeotrope with one of the constituents of the mixture
Description : In case of __________ distillation, a solvent is added to alter the relative volatility of the mixture to be separated. (A) Molecular (B) Azeotropic (C) Extractive
Last Answer : (C) Extractive
Description : When the mixture to be distilled has a very high boiling point and the product material is heat sensitive, the separation technique to be used is __________ distillation. (A) Continuous (B) Steam (C) Azeotropic (D) None of these
Last Answer : (B) Steam
Description : Van Laar equation deals with the activity co-efficients in (A) Binary solutions (B) Ternary solutions (C) Azeotropic mixture only (D) None of these
Last Answer : (A) Binary solutions
Description : McCabe-Thiele method (A) Uses molal units for material and energy balance (B) Uses weight fractions to express liquid and vapour composition (C) Can use any type of units (D) Is more accurate than Ponchon-Savarit method
Last Answer : (A) Uses molal units for material and energy balance
Description : Condensation of a vapour-gas mixture just begins, when (where, p = partial pressure of the vapour P = vapour pressure of the liquid). (A) p = P (B) p >>P (C) p < P (D) p
Last Answer : (A) p = P
Description : At triple point (for one component system), vapour pressure of solid as compared to that of liquid will be (A) More (B) Less (C) Same (D) More or less; depending on the system
Description : A standard ice point temperature corresponds to the temperature of (a) water at 0°C (b) ice at - 4°C (c) mixture of ice, water and vapour under equilibrium conditions under NTP conditions (d) mixture of ice and water Under equilibrium conditions.
Last Answer : Ans: D
Description : The relative saturation of an unsaturated mixture of gas and vapor is independent of the (A) Nature of the vapor (B) Temperature of the mixture (C) Composition of the mixture (D) None of these
Last Answer : (D) None of these
Description : . An irreversible aqueous phase reaction, A + B → P, is carried out in an adiabatic mixed flow reactor. A feed containing 4kmole/m3 of each A and B enters the reactor at 8m3 /hr. If the temperature of ... be assumed to be independent of temperature and composition. (A) 190 (B) 290 (C) 390 (D) 490
Last Answer : (B) 290
Description : The condition of refrigerant before entering the expansion or throttle valve, in a vapour compression system (a) dry vapour (b) wet vapour (c)liquid-vapour mixture (d) high pressure saturated liquid
Last Answer : Ans: d
Description : Reboiler is considered as one theoretical plate, because (A) Of the assumption that vapour and liquid leaving the reboiler are in equilibrium (B) Vapour is recycled to the column (C) Reboiler itself contains one plate (D) None of these
Last Answer : (A) Of the assumption that vapour and liquid leaving the reboiler are in equilibrium
Description : What is the degree of freedom for a system comprising liquid water equilibrium with its vapour? (A) 0 (B) 1 (C) 2 (D) 3
Description : Net positive suction head (NPSH) of a centrifugal pump must be (A) Greater than the vapour pressure of the liquid (B) Less than the vapour pressure of the liquid (C) Equal to the vapour pressure of the liquid (D) Less than barometric pressure
Last Answer : (A) Greater than the vapour pressure of the liquid
Description : Cavitation occurs in a centrifugal pump when the suction pressure is (A) Less than the vapour pressure of the liquid at that temperature (B) Greater than the vapour pressure of the liquid at that temperature (C) Equal to the vapour pressure (D) Equal to the developed head
Last Answer : (A) Less than the vapour pressure of the liquid at that temperature
Description : Steady state temperature reached by a small amount of liquid evaporating into a large amount of unsaturated vapour-gas mixture is called the __________ temperature. (A) Dry-bulb (B) Wet-bulb (C) Dew point (D) Adiabatic saturation
Last Answer : (B) Wet-bulb
Description : To obtain integrated form of Clausius-Clapeyron equation, ln (P2/P1) = (∆HV/R) (1/T1- 1/T2) from the exact Clapeyron equation, it is assumed that the (A) Volume of the liquid phase is negligible compared to ... gas (C) Heat of vaporisation is independent of temperature (D) All (A), (B) & (C)
Last Answer : (D) All (A), (B) & (C)
Description : A liquid mixture contains 30% o-xylene, 60% p-xylene and 10%. mxylene (all percentages in w/w). Which of the following statements would be true in respect of this mixture? (A) The mixture exhibits ... : o-xylene 30, p-xylene 60 and m-xyoene 10 (D) The mixture contain optical isomers
Last Answer : (A) The mixture exhibits an azeotrope at 101.3 kPa
Description : Bound moisture is that liquid which exerts an equilibrium vapor pressure __________ that of the pure liquid at the given temperature. (A) Less than (B) More than (C) Equal to (D) Either (A) or (B); depends on the solid
Last Answer : (A) Less than
Description : Moisture content of a substance when at equilibrium with a given partial pressure of the vapour is called the __________ moisture. (A) Free (B) Unbound (C) Equilibrium (D) Bound
Last Answer : (C) Equilibrium
Description : Pick out the wrong statement. (A) The integral method of analysing kinetic data is used when the data is scattered (B) The differential method of analysing kinetic data requires more accurate ... less than one for identical feed composition, flow rate, conversion and for all positive reaction orders
Last Answer : (C) When the reaction rate is independent of temperature, the reaction is said to be of zero order
Description : The siphon will work satisfactorily, if the minimum pressure in the pipe is __________ vapour pressure of liquid. (A) Equal to (B) Less than (C) More than (D) None of these
Last Answer : Answer: Option C
Description : The individual mass transfer co-efficients (moles/m2s) for absorption of a solute from a gas mixture into a liquid solvent are, KL = 4.5 and KG = 1.5. The slope of the equilibrium line is 3. Which of ... A) Liquid side (B) Gas side (C) Interfacial (D) Both liquid and gas side
Last Answer : (B) Gas side
Description : What is the number of degrees of freedom for liquid water in equilibrium with a mixture of nitrogen and water vapor? (A) 2 (B) 0 (C) 3 (D) 1
Last Answer : (A) 2
Description : Pick out the correct statement. (A) A catalyst speeds up the forward reaction but slows shown the reverse reaction (B) Addition of catalyst changes the equilibrium constant (C) Pressure changes do not change the equilibrium concentrations (D) The composition of equilibrium is changed by catalyst
Last Answer : (C) Pressure changes do not change the equilibrium concentrations
Description : The standard Gibbs free energy change of a reaction depends on the equilibrium (A) Pressure (B) Temperature (C) Composition (D) All (A), (B) and (C)
Last Answer : (B) Temperature
Description : The ratio of partial pressure of water vapour in a mixture to the saturation pressure of water at the same temperature of the mixture is called as A. humidity B. partial humidity C. specific humidity D. relative humidity
Last Answer : ANSWER : D
Description : At a fixed total pressure, humidity depends only on the (A) Partial pressure of vapour in the mixture (B) Heat capacity of the vapour (C) Density of the vapour (D) None of these
Last Answer : (A) Partial pressure of vapour in the mixture
Description : Dew point of a gas-vapour mixture (A) Increases with temperature rise (B) Decreases with temperature rise (C) Decreases with decrease in pressure (D) Increases with increase in pressure
Last Answer : (C) Decreases with decrease in pressure
Description : An air-water vapour mixture has a dry bulb temperature of 60°C and a dew point temperature of 40°C. The total pressure is 101.3 kPa and the vapour pressure of water at 40°C and 60°C are 7.30 kPa and 19.91 kPa respectively ... air is: (A) 0.048 (B) 0.079 (C) 0.122 (D) 0.152
Last Answer : (D) 0.152
Description : The relative saturation of a partially saturated mixture of vapour and gas can be increased by __________ of the mixture. (A) Reducing the total pressure (B) Increasing the total pressure (C) Reducing the temperature (D) Both (B) and (C)
Last Answer : (D) Both (B) and (C)
Description : At a fixed pressure, the humidity depends upon the partial pressure of vapor in the mixture. Humidity of a vapour free gas is __________ percent. (A) 100 (B) 0 (C) 50 (D) Between 0 and 100
Last Answer : (B) 0
Description : The wet and 'dry bulb temperature for a vapour-gas mixture are 25°C and 30°C respectively. If the mixture is heated to 45°C at constant pressure, the wet bulb temperature will be __________ °C. (A) 25 (B) > 25 (C) < 25 (D) - 25
Last Answer : (B) > 25
Description : When an unsaturated air-water mixture is heated at constant pressure, then (A) The partial pressure of water vapour increases (B) The specific humidity decreases (C) The relative humidity increases (D) The relative humidity decreases
Last Answer : D) The relative humidity decreases