When liquid and vapour phase of multi-component system are in equilibrium (at a given temperature and pressure), then chemical potential of each component is (A) Same in both the phases (B) Zero in both the phases (C) More in vapour phase (D) More in liquid phase

When liquid and vapour phase of multi-component system are in
equilibrium (at a given temperature and pressure), then chemical potential
of each component is
(A) Same in both the phases
(B) Zero in both the phases
(C) More in vapour phase
(D) More in liquid phase
by

1 Answer

Answer :

(A) Same in both the phases
by

Related questions

When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is (A) More in vapour phase (B) More in liquid phase (C) Same in both the phases (D) Replaced by chemical potential which is more in vapour phase

Description : When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is (A) More in vapour phase (B) More in liquid phase (C) Same in both the phases (D) Replaced by chemical potential which is more in vapour phase

Last Answer : (C) Same in both the phases

For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the __________ of each component must be same in all phases. (A) Chemical potential (B) Fugacity (C) Both (A) and (B) (D) Neither (A) nor (B)

Description : For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the __________ of each component must be same in all phases. (A) Chemical potential (B) Fugacity (C) Both (A) and (B) (D) Neither (A) nor (B)

Last Answer : (C) Both (A) and (B)

The necessary and sufficient condition for equilibrium between two phases is (A) The concentration of each component should be same in the two phases (B) The temperature of each phase should be same (C) The pressure should be same in the two phases (D) The chemical potential of each component should be same in the two phases

Description : The necessary and sufficient condition for equilibrium between two phases is (A) The concentration of each component should be same in the two phases (B) The temperature of each phase should be same ( ... the two phases (D) The chemical potential of each component should be same in the two phases

Last Answer : (D) The chemical potential of each component should be same in the two phases

The necessary condition for phase equilibrium in a multiphase system of N components is that the (A) Chemical potentials of a given component should be equal in all phases (B) Chemical potentials of all components should be same in a particular phase (C) Sum of the chemical potentials of any given component in all the phases should be the same (D) None of these

Description : The necessary condition for phase equilibrium in a multiphase system of N components is that the (A) Chemical potentials of a given component should be equal in all phases (B) Chemical potentials of all ... potentials of any given component in all the phases should be the same (D) None of these

Last Answer : (A) Chemical potentials of a given component should be equal in all phases

A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of (A) Temperature only (B) Temperature and pressure only (C) Temperature, pressure and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Description : A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co- ... and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Last Answer : (C) Temperature, pressure and liquid composition xi only

If a two phase system is in physical equilibrium; then it means that, the(A) Escaping tendency of each component from the liquid phase to the vaporphase is exactly equal to that from vapor phase to liquid phase(B) Temperature of the liquid phase is equal to that of the vapor phase(C) Total pressure throughout the liquid phase is equal to that throughout thevapor phase(D) All (A), (B) and (C)

Description : If a two phase system is in physical equilibrium; then it means that, the (A) Escaping tendency of each component from the liquid phase to the vapor phase is exactly equal to that from vapor phase to liquid phase ... liquid phase is equal to that throughout the vapor phase (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.) (A) μ° + RT ln f (B) μ°+ R ln f (C) μ° + T ln f (D) μ° + R/T ln f

Description : At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm. ... (B) μ°+ R ln f (C) μ° + T ln f (D) μ° + R/T ln f

Last Answer : (A) μ° + RT ln f

In case of absorption & stripping, the interface of the liquid & gas phases are present in equilibrium, when the diffusional resistance of __________ is zero. (A) Interface (B) Gas phase (C) Liquid phase (D) All 'a', 'b' & 'c'

Description : In case of absorption & stripping, the interface of the liquid & gas phases are present in equilibrium, when the diffusional resistance of __________ is zero. (A) Interface (B) Gas phase (C) Liquid phase (D) All 'a', 'b' & 'c'

Last Answer : (A) Interface

If the vapour pressure at two temperatures of a solid phase in equilibrium with its liquid phase are known, then the latent heat of fusion can be calculated by the (A) Maxwell's equation (B) Clausius-Clapeyron Equation (C) Van Laar equation (D) Nernst Heat Theorem

Description : If the vapour pressure at two temperatures of a solid phase in equilibrium with its liquid phase are known, then the latent heat of fusion can be calculated by the (A) Maxwell's equation (B) Clausius-Clapeyron Equation (C) Van Laar equation (D) Nernst Heat Theorem

Last Answer : B) Clausius-Clapeyron Equation

The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and pressure. It is given by (A) (∂E/∂ni)S, v, nj (B) (∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj (C) (∂H/∂ni)S, P, nj (D) All (A), (B) and (C)

Description : The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and ... , nj (C) (∂H/∂ni)S, P, nj (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of (A) Vapour pressure of component A to that of component B (B) Vapour pressure of component A to the total pressure (C) Vapour pressure of component A to the partial pressure of A (D) Partial pressure of component A to the total pressure

Description : When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of (A) Vapour pressure of component A to that of ... to the partial pressure of A (D) Partial pressure of component A to the total pressure

Last Answer : (A) Vapour pressure of component A to that of component B

If a system involves two phases, it is in ______ equilibrium when the mass of each phase reaches an equilibrium level and stays there.  A. Chemical  B. Thermal  C. Mechanical  D. Phase

Description : If a system involves two phases, it is in ______ equilibrium when the mass of each phase reaches an equilibrium level and stays there.  A. Chemical  B. Thermal  C. Mechanical  D. Phase

Last Answer : Phase

Moisture in a substance exerting an equilibrium vapour pressure less than that of pure liquid at the same temperature is called the __________ moisture. (A) Bound (B) Unbound (C) Critical (D) None of these

Description : Moisture in a substance exerting an equilibrium vapour pressure less than that of pure liquid at the same temperature is called the __________ moisture. (A) Bound (B) Unbound (C) Critical (D) None of these

Last Answer : (A) Bound

Moisture in a solid exerting an equilibrium vapour pressure equal to that of the pure liquid at the same temperature is called the __________ moisture. (A) Unbound (B) Critical (C) Free (D) Bound

Description : Moisture in a solid exerting an equilibrium vapour pressure equal to that of the pure liquid at the same temperature is called the __________ moisture. (A) Unbound (B) Critical (C) Free (D) Bound

Last Answer : (A) Unbound

The reaction A (l) → R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The numbers of degrees of freedom are: (A) 1 (B) 2 (C) 3 (D) 0

Description : The reaction A (l) → R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The numbers of degrees of freedom are: (A) 1 (B) 2 (C) 3 (D) 0

Last Answer : (B) 2

Solid and liquid phases of a substance are in equilibrium at the (A) Critical temperature (B) Melting point (C) Freezing point (D) Both (B) and (C)

Description : Solid and liquid phases of a substance are in equilibrium at the (A) Critical temperature (B) Melting point (C) Freezing point (D) Both (B) and (C)

Last Answer : D) Both (B) and (C)

In saturated gas, the (A) Vapour is in equilibrium with the liquid at the gas temperature (B) Vapour is in equilibrium with the liquid at the room temperature (C) Partial pressure of vapour equals the vapour pressure of the liquid at room temperature (D) None of these

Description : In saturated gas, the (A) Vapour is in equilibrium with the liquid at the gas temperature (B) Vapour is in equilibrium with the liquid at the room temperature (C) Partial pressure of vapour equals the vapour pressure of the liquid at room temperature (D) None of these

Last Answer : (A) Vapour is in equilibrium with the liquid at the gas temperature

In case of steam distillation, the steam leaving the liquid is not completely saturated with distillate vapour, because(A) Temperature is less(B) Total pressure is less(C) Mixing of steam with the material being vaporised is not so intimate asto result in equilibrium condition(D) Saturated steam is used for steam distillation

Description : In case of steam distillation, the steam leaving the liquid is not completely saturated with distillate vapour, because (A) Temperature is less (B) Total pressure is less (C) Mixing of steam ... not so intimate as to result in equilibrium condition (D) Saturated steam is used for steam distillation

Last Answer : (C) Mixing of steam with the material being vaporised is not so intimate as to result in equilibrium condition

At triple point (for one component system), vapour pressure of solid as compared to that of liquid will be (A) More (B) Less (C) Same (D) More or less; depending on the system

Description : At triple point (for one component system), vapour pressure of solid as compared to that of liquid will be (A) More (B) Less (C) Same (D) More or less; depending on the system

Last Answer : (C) Same

In Azeotropic mixture, the equilibrium vapour composition is (A) More than liquid composition (B) Less than liquid composition (C) Same as liquid composition (D) Independent of pressure

Description : In Azeotropic mixture, the equilibrium vapour composition is (A) More than liquid composition (B) Less than liquid composition (C) Same as liquid composition (D) Independent of pressure

Last Answer : (C) Same as liquid composition

For a multi-component system, the term chemical potential is equivalent to the (A) Molal concentration difference (B) Molar free energy (C) Partial molar free energy (D) Molar free energy change

Description : For a multi-component system, the term chemical potential is equivalent to the (A) Molal concentration difference (B) Molar free energy (C) Partial molar free energy (D) Molar free energy change

Last Answer : (C) Partial molar free energy

At the critical point of a substance (A) The surface tension vanishes (B) Liquid and vapour have the same density (C) There is no distinction between liquid and vapour phases (D) All (A), (B) and (C)

Description : At the critical point of a substance (A) The surface tension vanishes (B) Liquid and vapour have the same density (C) There is no distinction between liquid and vapour phases (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the __________ equation. (A) Gibbs-Duhem (B) Maxwell's (C) Clapeyron (D) None of these

Description : Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the __________ equation. (A) Gibbs-Duhem (B) Maxwell's (C) Clapeyron (D) None of these

Last Answer : (C) Clapeyron

Pick out the wrong statement. (A) Surface tension of a substance vanishes at critical point, as there is no distinction between liquid and vapour phases at its critical point (B) Entropy of a system decreases with the evolution of heat (C) Change of internal energy is negative for exothermic reactions (D) The eccentric factor for all materials is always more than one

Description : Pick out the wrong statement. (A) Surface tension of a substance vanishes at critical point, as there is no distinction between liquid and vapour phases at its critical point (B) Entropy of ... is negative for exothermic reactions (D) The eccentric factor for all materials is always more than one

Last Answer : (D) The eccentric factor for all materials is always more than one

In an interphase heat transfer process, the equilibrium state corresponds to equality of temperature in the two phases, while the condition for equilibrium in an interphase mass transfer process is equality of (A) Concentrations (B) Chemical potentials (C) Activity co-efficients (D) Mass transfer co-efficients

Description : In an interphase heat transfer process, the equilibrium state corresponds to equality of temperature in the two phases, while the condition for equilibrium in an interphase mass transfer process is ... B) Chemical potentials (C) Activity co-efficients (D) Mass transfer co-efficients

Last Answer : (A) Concentrations

Which of the following unit operations makes use of Thiele-Geddes equation? (A) Liquid-liquid extraction (B) Solid-liquid extraction (C) Multi-component absorption with chemical reaction (D) Multi-component distillation

Description : Which of the following unit operations makes use of Thiele-Geddes equation? (A) Liquid-liquid extraction (B) Solid-liquid extraction (C) Multi-component absorption with chemical reaction (D) Multi-component distillation

Last Answer : (D) Multi-component distillation

Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance at constant temperature and pressure is (A) 0 (B) 1 (C) ∞ (D) None of these

Description : Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance ... temperature and pressure is (A) 0 (B) 1 (C) ∞ (D) None of these

Last Answer : (B) 1

At equilibrium the concentration of water in vapour phase (C* ) in kg/m3 of air space and the amount of water (m) adsorbed per kg of dry silica gel are related by, C* = 0.0667m. To maintain dry conditions in a room of air space 100m3 containing 2.2 kg of water vapour initially, 10 kg of dry silica gel is kept in the room. The fraction of initial water remaining in the air space after a long time (during which the temperature is maintained constant) is (A) 0.0 (B) 0.2 (C) 0.4 (D) 1.0

Description : At equilibrium the concentration of water in vapour phase (C* ) in kg/m3 of air space and the amount of water (m) adsorbed per kg of dry silica gel are related by, C* = 0.0667m. To maintain dry conditions in a room ... which the temperature is maintained constant) is (A) 0.0 (B) 0.2 (C) 0.4 (D) 1.0

Last Answer : (C) 0.4

Urea is formed only (A) In liquid phase (B) In vapour phase (C) At very high temperature (D) At very low pressure (vacuum)

Description : Urea is formed only (A) In liquid phase (B) In vapour phase (C) At very high temperature (D) At very low pressure (vacuum)

Last Answer : (A) In liquid phase

Henry's law states that the (A) Partial pressure of a component over a solution is proportional to its mole fraction in the liquid (B) Partial pressure of a component over a solution is proportional to the mole fraction in the vapour (C) Vapour pressure is equal to the product of the mole fraction and total pressure (D) Partial pressure is equal to the product of the mole fraction and total pressure

Description : Henry's law states that the (A) Partial pressure of a component over a solution is proportional to its mole fraction in the liquid (B) Partial pressure of a component over a solution ... pressure (D) Partial pressure is equal to the product of the mole fraction and total pressure

Last Answer : (A) Partial pressure of a component over a solution is proportional to its mole fraction in the liquid

For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system __________ as its mole fraction increases. (A) Decreases (B) Increases (C) Remain same (D) Decreases linearly

Description : For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system __________ as its mole fraction increases. (A) Decreases (B) Increases (C) Remain same (D) Decreases linearly

Last Answer : (B) Increases

What is the degree of freedom for a system comprising liquid water equilibrium with its vapour? (A) 0 (B) 1 (C) 2 (D) 3

Description : What is the degree of freedom for a system comprising liquid water equilibrium with its vapour? (A) 0 (B) 1 (C) 2 (D) 3

Last Answer : B) 1

For the gaseous phase chemical reaction, C2H4(g) + H2O(g) ↔ C2H5OH(g), the equilibrium conversion does not depend on the (A) Steam to ethylene ratio (B) Temperature (C) Pressure (D) None of these

Description : For the gaseous phase chemical reaction, C2H4(g) + H2O(g) ↔ C2H5OH(g), the equilibrium conversion does not depend on the (A) Steam to ethylene ratio (B) Temperature (C) Pressure (D) None of these

Last Answer : (D) None of these

Moisture content of a substance when at equilibrium with a given partial pressure of the vapour is called the __________ moisture. (A) Free (B) Unbound (C) Equilibrium (D) Bound

Description : Moisture content of a substance when at equilibrium with a given partial pressure of the vapour is called the __________ moisture. (A) Free (B) Unbound (C) Equilibrium (D) Bound

Last Answer : (C) Equilibrium

Reboiler is considered as one theoretical plate, because (A) Of the assumption that vapour and liquid leaving the reboiler are in equilibrium (B) Vapour is recycled to the column (C) Reboiler itself contains one plate (D) None of these

Description : Reboiler is considered as one theoretical plate, because (A) Of the assumption that vapour and liquid leaving the reboiler are in equilibrium (B) Vapour is recycled to the column (C) Reboiler itself contains one plate (D) None of these

Last Answer : (A) Of the assumption that vapour and liquid leaving the reboiler are in equilibrium

The number of degree of freedom for an Azeotropic mixture of ethanol and water in vapour-liquid equilibrium, is (A) 3 (B) 1 (C) 2 (D) 0

Description : The number of degree of freedom for an Azeotropic mixture of ethanol and water in vapour-liquid equilibrium, is (A) 3 (B) 1 (C) 2 (D) 0

Last Answer : B) 1

A plot of pressure vs. temperature for a given substance showing the various phases possible for that particular substance.  a. Phase diagram  b. P-T diagram  c. Wein Diagram  d. Histogram

Description : A plot of pressure vs. temperature for a given substance showing the various phases possible for that particular substance.  a. Phase diagram  b. P-T diagram  c. Wein Diagram  d. Histogram

Last Answer : Phase diagram

At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is (A) 1.572 (B) 1.9398 (C) 3.389

Description : At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole ... respectively. Activity co-efficient of methanol is (A) 1.572 (B) 1.9398 (C) 3.389

Last Answer : (A) 1.572

For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm3 and that in vapour phase in 391.1 cm3.Fugacity of water (in kPa) at 9000 kPa will be (A) 6738.9 (B) 6753.5 (C) 7058.3 (D) 9000

Description : For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm3 and that in vapour phase in 391.1 cm3.Fugacity of water (in kPa) at 9000 kPa will be (A) 6738.9 (B) 6753.5 (C) 7058.3 (D) 9000

Last Answer : (B) 6753.5

Activity co-efficient is a measure of the (A) Departure from ideal solution behaviour (B) Departure of gas phase from ideal gas law (C) Vapour pressure of liquid (D) None of these

Description : Activity co-efficient is a measure of the (A) Departure from ideal solution behaviour (B) Departure of gas phase from ideal gas law (C) Vapour pressure of liquid (D) None of these

Last Answer : (A) Departure from ideal solution behaviour

What is the state at which all three phases of water coexist in equilibrium?  A. Tripoint of water  B. Triple point of water  C. Triple phase point of water  D. Phase point of water

Description : What is the state at which all three phases of water coexist in equilibrium?  A. Tripoint of water  B. Triple point of water  C. Triple phase point of water  D. Phase point of water

Last Answer : Triple point of water

To obtain integrated form of Clausius-Clapeyron equation, ln (P2/P1) = (∆HV/R) (1/T1- 1/T2) from the exact Clapeyron equation, it is assumed that the (A) Volume of the liquid phase is negligible compared to that of vapour phase (B) Vapour phase behaves as an ideal gas (C) Heat of vaporisation is independent of temperature (D) All (A), (B) & (C)

Description : To obtain integrated form of Clausius-Clapeyron equation, ln (P2/P1) = (∆HV/R) (1/T1- 1/T2) from the exact Clapeyron equation, it is assumed that the (A) Volume of the liquid phase is negligible compared to ... gas (C) Heat of vaporisation is independent of temperature (D) All (A), (B) & (C)

Last Answer : (D) All (A), (B) & (C)

Relative volatility does not change appreciably with the change in (A) Temperature (B) Vapour pressure of either component (C) Total pressure (D) None of these

Description : Relative volatility does not change appreciably with the change in (A) Temperature (B) Vapour pressure of either component (C) Total pressure (D) None of these

Last Answer : (A) Temperature

Bound moisture is that liquid which exerts an equilibrium vapor pressure __________ that of the pure liquid at the given temperature. (A) Less than (B) More than (C) Equal to (D) Either (A) or (B); depends on the solid

Description : Bound moisture is that liquid which exerts an equilibrium vapor pressure __________ that of the pure liquid at the given temperature. (A) Less than (B) More than (C) Equal to (D) Either (A) or (B); depends on the solid

Last Answer : (A) Less than

An ideal liquid refrigerant should (A) Not have a sub-atmospheric vapour pressure at the temperature in the refrigerator coils (B) Not have unduly high vapour pressure at the condenser temperature (C) Both (A) and (B) (D) Have low specific heat

Description : An ideal liquid refrigerant should (A) Not have a sub-atmospheric vapour pressure at the temperature in the refrigerator coils (B) Not have unduly high vapour pressure at the condenser temperature (C) Both (A) and (B) (D) Have low specific heat

Last Answer : (C) Both (A) and (B)

At constant temperature and pressure, for one mole of a pure substance, the ratio of the free energy to the chemical potential is (A) Zero (B) One (C) Infinity (D) Negative

Description : At constant temperature and pressure, for one mole of a pure substance, the ratio of the free energy to the chemical potential is (A) Zero (B) One (C) Infinity (D) Negative

Last Answer : (B) One

Chemical potential of ith component of a system is given by (A) µi = (∂F/∂ni)T, P, ni (B) µi = (∂A/∂ni)T, P, ni (C) µi = (∂F/∂ni)T, P (D) µi = (∂A/∂ni)T, P

Description : Chemical potential of ith component of a system is given by (A) µi = (∂F/∂ni)T, P, ni (B) µi = (∂A/∂ni)T, P, ni (C) µi = (∂F/∂ni)T, P (D) µi = (∂A/∂ni)T, P

Last Answer : A) µi = (∂F/∂ni)T, P, ni

Pick out the wrong statement. (A) The operating line always lies above the equilibrium solubility curve in case of a single component absorber (B) The operating line always lies below the equilibrium solubility curve in case of a single component stripper (C) The operating pressure in solvent extraction system should be below vapor pressures of all components (D) The solubility of a particular gas in ideal solution in any solvent is always the same

Description : Pick out the wrong statement. (A) The operating line always lies above the equilibrium solubility curve in case of a single component absorber (B) The operating line always lies below the equilibrium ... (D) The solubility of a particular gas in ideal solution in any solvent is always the same

Last Answer : (C) The operating pressure in solvent extraction system should be below vapor pressures of all components