Consider the following statements. 1. Ozone is an allotropic form of oxygen 2. Phosphorus is present in DNA and RNA 3. Halogens occur in free state in nature. 4. The compounds of chlorine are used as cooling agents. The correct statements are: (a) 1 and 4 (b) 2 and 4 (c) 3 and 4 (d) 1 and 2