Write an expression for equilibrium constant with respect to concerntration.

Write an expression for equilibrium constant with respect to concerntration.
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Write an expression for equilibrium constant with respect to concerntration.
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When did the concerntration camp start?

Description : When did the concerntration camp start?

Last Answer : The first concentration camp was started in 1933.

The rate expression for a heterogeneous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + KR.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A) (A) E (B) E + ΔHA (C) E + ΔHA - ΔHR ) (D) ΔHA + ΔHR

Description : The rate expression for a heterogeneous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + KR.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR ... R and A) (A) E (B) E + ΔHA (C) E + ΔHA - ΔHR ) (D) ΔHA + ΔHR

Last Answer : (C) E + ΔHA - ΔHR )

Which of the following expression is not applicable on the hydrolysis equilibrium : `CN^(-)H_(2)OrArrHCN+OH^(-)`

Description : Which of the following expression is not applicable on the hydrolysis equilibrium : `CN^(-)H_(2)OrArrHCN+OH^(-)`

Last Answer : Which of the following expression is not applicable on the hydrolysis equilibrium : `CN^(-)H_(2)OrArrHCN+OH^(-)` A. ... H+] =sqrt((K_(w).K_(a))/(C))`

A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of (A) Temperature only (B) Temperature and pressure only (C) Temperature, pressure and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Description : A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co- ... and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Last Answer : (C) Temperature, pressure and liquid composition xi only

Write the effect of temperature on Equilibrium constant.

Description : Write the effect of temperature on Equilibrium constant.

Last Answer : Ans. The value of Equilibrium constant changes with the temperature. The increase in rate depends upon activation energy .As the activation energy are different for forward & backward direction .So temperature will ... & backward direction. As K= Kf/ Kb ,so the state of equilibrium will be altered.

Write the significance of equilibrium constant?

Description : Write the significance of equilibrium constant?

Last Answer : Ans.The numerical value of equilibrium constant is a measure of the extent to which the reactants have been converted into products. A large value of K indicates large amount of ... its low value indicates less amount of reactants converted into products before achieving the equilibrium state.

Write Application of Equilibrium constant?

Description : Write Application of Equilibrium constant?

Last Answer : Ans. (i) To predict the extent of the reaction. (ii) To predict the direction of the reaction. (iii) To calculate the equilibrium concentration.

The best statement of the responsibility of the auditor with respect to audited financial statement is: a. The auditor's responsibility on fair presentation of financial statements is limited only up to the date of the audit report. b. The auditor's responsibility is confined to the expression of opinion on the financial statements audited. c. The responsibility over the financial statements rests with the management and the auditor assumes responsibility with respect to the notes of financial statements. d. The auditor is responsible only to his qualified opinion but not for any other type of opinion.

Description : The best statement of the responsibility of the auditor with respect to audited financial statement is: a. The auditor's responsibility on fair presentation of financial statements is limited only up to ... auditor is responsible only to his qualified opinion but not for any other type of opinion.

Last Answer : The auditor's responsibility is confined to the expression of opinion on the financial statements audited

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Description : Mark correct option a) The expression postage means the duty chargeable for the transmission by post of postal articles b) The expression postage stamps means any stamp provided by the [Central Government] ... room, carriage or place used for the purposes of the Post Office. d) All the above

Last Answer : d) All the above

Determine the values of equilibrium constant (Kc) and ΔG° for the following reaction : Ni(s) + 2Ag+ (aq) → Ni2+ (aq) + 2Ag(s), E° = 1.05 V (1F = 96500 C mol-1 -Chemistry

Description : Determine the values of equilibrium constant (Kc) and ΔG° for the following reaction : Ni(s) + 2Ag+ (aq) → Ni2+ (aq) + 2Ag(s), E° = 1.05 V (1F = 96500 C mol-1 -Chemistry

Last Answer : According to the formula ΔG° = -nFE° = – 2 × 96500 ×1.05 or ΔG° = -202650 J mol-1 = -202.65 KJ mol-1 Now ΔG° ⇒ -202650 J Mol-1 R = 8.314 J/Mol/K, T = 298 K

Equilibrium constant of a reaction is elated to :

Description : Equilibrium constant of a reaction is elated to :

Last Answer : Equilibrium constant of a reaction is elated to : A. Standard free energy change `Delta G^(@)` B. ... change `Delta G` C. Entropy change D. None

The equilibrium constant for : `PClrArrPCl_(3)+Cl_(2)` is 0.5 at 500 K. What is the state of vessel shown below ?

Description : The equilibrium constant for : `PClrArrPCl_(3)+Cl_(2)` is 0.5 at 500 K. What is the state of vessel shown below ?

Last Answer : The equilibrium constant for : `PClrArrPCl_(3)+Cl_(2)` is 0.5 at 500 K. What is ... regarding the equilibrium just from the diagram given above.

For a reaction `H_(2(g))+I_(2(g))rArr2HI_((g))at 721^(@)C` the value of equilibrium constant is 50 . If 0.5 moles each of `H_(2)` & `I(2)` is added to

Description : For a reaction `H_(2(g))+I_(2(g))rArr2HI_((g))at 721^(@)C` the value of equilibrium constant is 50 . If 0.5 moles each of `H_(2)` & `I(2)` is added to

Last Answer : For a reaction `H_(2(g))+I_(2(g))rArr2HI_((g))at 721^(@)C` the value of equilibrium constant is 50 . ... constant will be . A. 100 B. 25 C. 50 D. 200

One mole of A reacts with one mole of B to form 0.1 mole of C and 0.1 mole of D . What will be the value of the equilibrium constant ? `A+BrArrC+D`

Description : One mole of A reacts with one mole of B to form 0.1 mole of C and 0.1 mole of D . What will be the value of the equilibrium constant ? `A+BrArrC+D`

Last Answer : One mole of A reacts with one mole of B to form 0.1 mole of C and 0.1 mole of D . What will be the value of the ... A. 0.1 B. 100 C. `(1)/(81)` D. 81

When volume of the equilibrium reaction C(s) + H2O(g) ⇌ CO(g) + H2(g) is increased at constant temperature the equilibrium will :

Description : When volume of the equilibrium reaction C(s) + H2O(g) ⇌ CO(g) + H2(g) is increased at constant temperature the equilibrium will :

Last Answer : When volume of the equilibrium reaction C(s) + H2O(g) ⇌ CO(g) + H2(g) is increased at constant ... left c. be unaltered d. can not be predicted

What is the equilibrium constant or a reaction?

Description : What is the equilibrium constant or a reaction?

Last Answer : Feel Free to Answer

Enzymes increases the rate of reactions by (A) Increasing the free energy of activation (B) Decreasing the energy of activation (C) Changing the equilibrium constant of the reaction (D) Increasing the free energy change of the reaction

Description : Enzymes increases the rate of reactions by (A) Increasing the free energy of activation (B) Decreasing the energy of activation (C) Changing the equilibrium constant of the reaction (D) Increasing the free energy change of the reaction

Last Answer : Answer : B

Enzymes increase the rates of reactions by (A) Increasing the free energy of activation (B) Decreasing the energy of activation (C) Changing the equilibrium constant of the reaction (D) Increasing the free energy change of the reaction

Description : Enzymes increase the rates of reactions by (A) Increasing the free energy of activation (B) Decreasing the energy of activation (C) Changing the equilibrium constant of the reaction (D) Increasing the free energy change of the reaction

Last Answer : Answer : B

Enzymes accelerate the rate of reactions by (A) Increasing the equilibrium constant of reactions (B) Increasing the energy of activation (C) Decreasing the energy of activation (D) Decreasing the free energy change of the reaction

Description : Enzymes accelerate the rate of reactions by (A) Increasing the equilibrium constant of reactions (B) Increasing the energy of activation (C) Decreasing the energy of activation (D) Decreasing the free energy change of the reaction

Last Answer : Answer : C

At equilibrium the concentration of water in vapour phase (C* ) in kg/m3 of air space and the amount of water (m) adsorbed per kg of dry silica gel are related by, C* = 0.0667m. To maintain dry conditions in a room of air space 100m3 containing 2.2 kg of water vapour initially, 10 kg of dry silica gel is kept in the room. The fraction of initial water remaining in the air space after a long time (during which the temperature is maintained constant) is (A) 0.0 (B) 0.2 (C) 0.4 (D) 1.0

Description : At equilibrium the concentration of water in vapour phase (C* ) in kg/m3 of air space and the amount of water (m) adsorbed per kg of dry silica gel are related by, C* = 0.0667m. To maintain dry conditions in a room ... which the temperature is maintained constant) is (A) 0.0 (B) 0.2 (C) 0.4 (D) 1.0

Last Answer : (C) 0.4

Why the Equilibrium constant is taken as dimensionless?

Description : Why the Equilibrium constant is taken as dimensionless?

Last Answer : Ans. Activities are used in place of molar Conc. These represent the concentration or pressure with respect to standard state.

What will be the effect on equilibrium if (i) a catalyst is added to it (ii) An inert gas is added at constant volume

Description : What will be the effect on equilibrium if (i) a catalyst is added to it (ii) An inert gas is added at constant volume

Last Answer : Ans. (i) The state of equilibrium is not disturbed on adding catalyst rather it is attained quickly. (ii) No effect on state of equilibrium

if the equilibrium constant for the reaction is 4.0, what will be the equilibrium constant for the reverse reaction.

Description : if the equilibrium constant for the reaction is 4.0, what will be the equilibrium constant for the reverse reaction.

Last Answer : Ans. Kc=1/4

Which measurable property become constant in Water Water vapors equilibrium at constant temperature

Description : Which measurable property become constant in Water Water vapors equilibrium at constant temperature

Last Answer : Ans. Vapour pressure.

Pick out the wrong statement. (A) Different solids have different equilibrium moisture curves (B) Total condenser or reboiler is considered equivalent to one theoretical plate in McCabe-Thiele method of theoretical plate calculation for distillation column (C) Heat removal load on cooler remains constant, even with increase of the reflux ratio in a distillation column (D) Even a forced draft cooling tower cannot cool water below the wet bulb temperature

Description : Pick out the wrong statement. (A) Different solids have different equilibrium moisture curves (B) Total condenser or reboiler is considered equivalent to one theoretical plate in McCabe-Thiele method of ... (D) Even a forced draft cooling tower cannot cool water below the wet bulb temperature

Last Answer : (C) Heat removal load on cooler remains constant, even with increase of the reflux ratio in a distillation column

Pick out the correct statement. (A) Bound moisture is removed during constant rate drying period (B) Free moisture is removed during falling rate drying period (C) The sum of free moisture and equilibrium moisture in a solid is called the critical moisture (D) The driving force for mass transfer in a wet solid is its free moisture content

Description : Pick out the correct statement. (A) Bound moisture is removed during constant rate drying period (B) Free moisture is removed during falling rate drying period (C) The sum of free moisture and ... (D) The driving force for mass transfer in a wet solid is its free moisture content

Last Answer : (D) The driving force for mass transfer in a wet solid is its free moisture content

Why is the equilibrium constant K, related to only E°cell and not Ecell ?

Description : Why is the equilibrium constant K, related to only E°cell and not Ecell ?

Last Answer : Ans. This is because Ecell is zero at equilibrium. 

Pick out the wrong statement: (A) Absorption factor is constant, when the equilibrium and operating lines are straight (B) In case of a stripper, the equilibrium curve is always below the operating line (C) In case of an absorber, the operating line is always above the equilibrium curve (D) In the absorption of low solubility gases, the liquid film is the controlling resistance

Description : Pick out the wrong statement: (A) Absorption factor is constant, when the equilibrium and operating lines are straight (B) In case of a stripper, the equilibrium curve is always below ... (D) In the absorption of low solubility gases, the liquid film is the controlling resistance

Last Answer : (B) In case of a stripper, the equilibrium curve is always below the operating line

Object is in equilibrium if resultant force acting on it is A. increasing B. decreasing C. zero D. becomes constant

Description : Object is in equilibrium if resultant force acting on it is A. increasing B. decreasing C. zero D. becomes constant

Last Answer : zero

Object moving along a circular path is A. in equilibrium B. not in equilibrium C. not moving with constant speed D. in random motion

Description : Object moving along a circular path is A. in equilibrium B. not in equilibrium C. not moving with constant speed D. in random motion

Last Answer : not in equilibrium

During ecological succession (a) the numbers and types of animals remain constant (b) the changes lead to a community that is in near equilibrium with the environment and is called pioneer community (c) the gradual and predictable change in species composition occurs in a given area (d) the establishment of a new biotic community is very fast in its primary phase.

Description : During ecological succession (a) the numbers and types of animals remain constant (b) the changes lead to a community that is in near equilibrium with the environment and is called pioneer community ( ... area (d) the establishment of a new biotic community is very fast in its primary phase.

Last Answer : (c) the gradual and predictable change in species composition occurs in a given area

Thermodynamic equilibrium constant in a system is affected by (A) Inerts (B) Pressure (C) Temperature (D) All (A), (B) & (C)

Description : Thermodynamic equilibrium constant in a system is affected by (A) Inerts (B) Pressure (C) Temperature (D) All (A), (B) & (C)

Last Answer : (C) Temperature

With increase in temperature, the equilibrium __________ rises in case of endothermic reaction. (A) Constant (B) Conversion (C) Both (A) & (B) (D) Neither (A) nor (B)

Description : With increase in temperature, the equilibrium __________ rises in case of endothermic reaction. (A) Constant (B) Conversion (C) Both (A) & (B) (D) Neither (A) nor (B)

Last Answer : (B) Conversion

In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled, then the equilibrium constant will (A) Remain the same (B) Be halved (C) Also be doubled (D) Become one fourth

Description : In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled, then the equilibrium constant will (A) Remain the same (B) Be halved (C) Also be doubled (D) Become one fourth

Last Answer : (A) Remain the same

The role of a catalyst in a chemical reaction is to change the (A) Equilibrium constant (B) Activation energy (C) Final products (D) Heat of reaction

Description : The role of a catalyst in a chemical reaction is to change the (A) Equilibrium constant (B) Activation energy (C) Final products (D) Heat of reaction

Last Answer : (B) Activation energy

The equilibrium constant for the reversible reaction as shown in the bellow figure, is affected by the (A) Temperature of the system (B) Presence or absence of inerts (C) Pressure of the system (D) Kinetics of the reaction

Description : The equilibrium constant for the reversible reaction as shown in the bellow figure, is affected by the (A) Temperature of the system (B) Presence or absence of inerts (C) Pressure of the system (D) Kinetics of the reaction

Last Answer : (C) Pressure of the system

Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the reaction is practically irreversible in nature (C) The intercept of the Arrhenius plot is called the 'activation energy' (D) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions

Description : Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the ... ) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions

Last Answer : (C) The intercept of the Arrhenius plot is called the 'activation energy

In the gaseous phase ammonia formation reaction (N2 + 3H2 ⇌ 2NH3 ), the value of the equilibrium constant depends on the (A) Total pressure of the system (B) Volume of the reactor (C) Temperature (D) Initial concentration of N2 and H2

Description : In the gaseous phase ammonia formation reaction (N2 + 3H2 ⇌ 2NH3 ), the value of the equilibrium constant depends on the (A) Total pressure of the system (B) Volume of the reactor (C) Temperature (D) Initial concentration of N2 and H2

Last Answer : (C) Temperature

Catalytic action in a catalytic chemical reaction follows from the ability of catalyst to change the (A) Activation energy (B) Equilibrium constant (C) Heat of reaction (D) None of these

Description : Catalytic action in a catalytic chemical reaction follows from the ability of catalyst to change the (A) Activation energy (B) Equilibrium constant (C) Heat of reaction (D) None of these

Last Answer : (A) Activation energy

A Catalyst (A) Increases the equilibrium concentration of the product (B) Changes the equilibrium constant of the reaction (C) Shortens the time to reach the equilibrium (D) None of these

Description : A Catalyst (A) Increases the equilibrium concentration of the product (B) Changes the equilibrium constant of the reaction (C) Shortens the time to reach the equilibrium (D) None of these

Last Answer : (C) Shortens the time to reach the equilibrium

If helium is introduced in a reactor containing O2 , SO2 and SO3 at equilibrium, so that total pressure increases while volume and temperature remains constant. In this case the dissociation of SO3 (as per Le Chatelier's principle). (A) Decreases (B) Increases (C) Remains unaltered (D) Changes unpredictably

Description : If helium is introduced in a reactor containing O2 , SO2 and SO3 at equilibrium, so that total pressure increases while volume and temperature remains constant. In this case the dissociation of SO3 ( ... 's principle). (A) Decreases (B) Increases (C) Remains unaltered (D) Changes unpredictably

Last Answer : (A) Decreases

The irreversible reaction is a special case of reversible reaction, if the(A) Equilibrium constant is 1(B) Conversion of the reactant at equilibrium condition is zero(C) Reactant concentration at equilibrium condition is zero(D) All (A), (B) and (C)

Description : The irreversible reaction is a special case of reversible reaction, if the(A) Equilibrium constant is 1 (B) Conversion of the reactant at equilibrium condition is zero (C) Reactant concentration at equilibrium condition is zero (D) All (A), (B) and (C)

Last Answer : (C) Reactant concentration at equilibrium condition is zero

A catalyst is said to be a negative catalyst, if it (A) Retards the rate of reaction (B) Reduces the value of equilibrium constant (C) Does not initiate the reaction (D) All (A), (B) and (C)

Description : A catalyst is said to be a negative catalyst, if it (A) Retards the rate of reaction (B) Reduces the value of equilibrium constant (C) Does not initiate the reaction (D) All (A), (B) and (C)

Last Answer : (A) Retards the rate of reaction

For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant(A) Is independent of pressure(B) Increases with pressure(C) Decreases with pressure(D) Increases /decreases with pressure depending on the stoichiometric co￾efficients of the reaction

Description : For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant (A) Is independent of pressure (B) Increases with pressure (C) Decreases with pressure (D) Increases /decreases with pressure depending on the stoichiometric co￾efficients of the reaction

Last Answer : (B) Increases with pressure

According to the 'law of mass action', the rate of reaction is directlyproportional to the (A) Equilibrium constant (B) Volume of the reaction vessel (C) Nature of the reactants (D) Molar concentration of the reactants

Description : According to the 'law of mass action', the rate of reaction is directlyproportional to the (A) Equilibrium constant (B) Volume of the reaction vessel (C) Nature of the reactants (D) Molar concentration of the reactants

Last Answer : (D) Molar concentration of the reactants

Pick out the correct statement. (A) A catalyst speeds up the forward reaction but slows shown the reverse reaction (B) Addition of catalyst changes the equilibrium constant (C) Pressure changes do not change the equilibrium concentrations (D) The composition of equilibrium is changed by catalyst

Description : Pick out the correct statement. (A) A catalyst speeds up the forward reaction but slows shown the reverse reaction (B) Addition of catalyst changes the equilibrium constant (C) Pressure changes do not change the equilibrium concentrations (D) The composition of equilibrium is changed by catalyst

Last Answer : (C) Pressure changes do not change the equilibrium concentrations

Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an endothermic reaction (C) The rate constant for a first order reaction does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature

Description : Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an ... does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature

Last Answer : (C) The rate constant for a first order reaction does not change on changing the concentration units

The catalyst in a first order chemical reaction changes the (A) Equilibrium constant(B) Activation energy(C) Heat of formation of the product(D) Heat of reaction

Description : The catalyst in a first order chemical reaction changes the (A) Equilibrium constant (B) Activation energy (C) Heat of formation of the product (D) Heat of reaction

Last Answer : (B) Activation energy

The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)

Description : The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

For the reversible reaction A ⇌ 2B, if the equilibrium constant K is 0.05 mole/litre; starting from initially 2 moles of A and zero moles of B, how many moles will be formed at equilibrium? (A) 0.253 (B) 0.338 (C) 0.152 (D) 0.637

Description : For the reversible reaction A ⇌ 2B, if the equilibrium constant K is 0.05 mole/litre; starting from initially 2 moles of A and zero moles of B, how many moles will be formed at equilibrium? (A) 0.253 (B) 0.338 (C) 0.152 (D) 0.637

Last Answer : (B) 0.338