Determine the values of equilibrium constant (Kc) and ΔG° for the following reaction : Ni(s) + 2Ag+ (aq) → Ni2+ (aq) + 2Ag(s), E° = 1.05 V (1F = 96500 C mol-1 -Chemistry

Determine the values of equilibrium constant (Kc) and ΔG° for the following reaction : Ni(s) + 2Ag+ (aq) → Ni2+ (aq) + 2Ag(s), E° = 1.05 V (1F = 96500 C mol-1 -Chemistry
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Answer :

According to the formula ΔG° = -nFE° = – 2 × 96500 ×1.05 or ΔG° = -202650 J mol-1 = -202.65 KJ mol-1 Now ΔG° ⇒ -202650 J Mol-1 R = 8.314 J/Mol/K, T = 298 K
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Describe the shape and magnetic behaviour of following complexes : (i) [CO(NH3)6]3+ (ii) [Ni(CN)4]2- (At. No. Co = 27, Ni = 28) -Chemistry

Description : Describe the shape and magnetic behaviour of following complexes : (i) [CO(NH3)6]3+ (ii) [Ni(CN)4]2- (At. No. Co = 27, Ni = 28) -Chemistry

Last Answer : (i) [CO(NH3)6]3+ : Orbitals of CO3+ ion : Hybridization : d2sp3 Shape : Octahedral Magnetic behaviour : Diamagnetic (absence of unpaired electrons) (ii) [Ni(CN)4]2-

What is the IUPAC name of the complex [Ni(NH3)6]Cl2? -Chemistry

Description : What is the IUPAC name of the complex [Ni(NH3)6]Cl2? -Chemistry

Last Answer : [Ni(NH3)6]Cl2 IUPAC name : Hexaamminenickel (II) chloride.

Give IUPAC name of the ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry

Description : Give IUPAC name of the ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry

Last Answer : IUPAC name : Triammine chlorido nickel (II) nitrate [Ni(NH3)3NO3]Cl

Give IUPAC name of ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry

Description : Give IUPAC name of ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry

Last Answer : IUPAC name : Triammine nitrato nickel (III) chloride

The relation between Kc and Kp for the reaction A(g) + B(g) ⇌ 2C(g) + D(g) is :

Description : The relation between Kc and Kp for the reaction A(g) + B(g) ⇌ 2C(g) + D(g) is :

Last Answer : The relation between Kc and Kp for the reaction A(g) + B(g) ⇌ 2C(g) + D(g) is : a. Kc = Kp/RT b. Kp ... Kc = \(\frac{1}{\sqrt{Kp}}\) d. Kp/Kc = 1

How value of Kc can help to predict the extent to which a chemical reaction can take place?

Description : How value of Kc can help to predict the extent to which a chemical reaction can take place?

Last Answer : The extent of reaction depends upon the magnitude of Kc. i.e. (i) Very small value of Kc: when Kc is very small the forward reaction will not occur to an appreciable extent ... neither very large nor very small, the equilibrium mixture contains appreciable amounts of both reactant and products.

How Kc can be applied to calculate direction of chemical reaction?

Description : How Kc can be applied to calculate direction of chemical reaction?

Last Answer : (i) If < Kc Then the reaction will proceed in the forward direction until the equilibrium is established. (ii) If > Kc Then the reaction will proceed in the backward direction until the equilibrium is established. If = kc Then the reaction is already in equilibrium.

The dimensions of rate constant for reaction 3A → B are (l/gm mole)/min. Therefore the reaction order is (A) 0 (B) 1 (C) 2 (D) 3

Description : The dimensions of rate constant for reaction 3A → B are (l/gm mole)/min. Therefore the reaction order is (A) 0 (B) 1 (C) 2 (D) 3

Last Answer : (C) 2

A batch adiabatic reactor at an initial temperature of 373°K is being used for the reaction, A → B. Assume the heat of reaction is - 1kJ/mole at 373°K and heat capacity of both A and B to be constant and equal to 50J/mole.K. The temperature rise after a conversion of 0.5 will be: (A) 5°C (B) 10°C (C) 20°C (D) 100°C

Description : A batch adiabatic reactor at an initial temperature of 373°K is being used for the reaction, A → B. Assume the heat of reaction is - 1kJ/mole at 373°K and heat capacity of both A and B to be constant and equal ... rise after a conversion of 0.5 will be: (A) 5°C (B) 10°C (C) 20°C (D) 100°C

Last Answer : (B) 10°C