Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds:

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Identify the correct order of reactivity in electrophilic substitution reactions of the following ... C. `IIgtIgtIIIgtIV` D. `IIgtIIIgtIgtIV`

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Description : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds :

Last Answer : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds : ... ` C. `2gt1gt3gt4` D. `2gt3gt1gt4`

Description : Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is :

Last Answer : Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is : ... C. `IVgtIgtIIgtIII` D. `IIIgtIgtIIgtIV`

Description : Which of the following compounds reacts least rapidly in electrophilic substitution reactions? (a) Nitrobenzene (b) Phenol (c) Bromobenzene (d) Toluene

Last Answer : Nitrobenzene

Description : Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ?

Last Answer : Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ? A. `A gt B gt ... A` D. `C gt B gt D gt A`

Description : The reactivity of compound `Z` with different halogens under appropriate conditions is gives below- The observed pattern of electrophilic substitution

Last Answer : The reactivity of compound `Z` with different halogens under appropriate conditions is gives below- ... the electronic effect of the tert-butyl group

Description : Which of the following statements correctly describes the general reactivity of alkynes? (a) An alkyne is an electron-rich molecule and therefore reacts as a nucleophile. (b) The σ bonds ... fail to undergo electrophilic addition reactions. (d) Alkynes are generally more reactive than alkenes.

Last Answer : Alkynes are generally more reactive than alkenes.

Description : Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Last Answer : Ans. Due to the presence of an electron cloud containing 6 pi electrons above and below the plane of the ring, benzene is a source of electrons. Consequently, it attracts ... . As a result, benzene undergoes electrophilic substitution reactions easily and nucleophilic substitution with difficulty.

Description : Anthracene undergoes electrophilic substitution reactions mainly at (a) C-1 (b) C-2 (c) C-9 (d) C-1 and C-2

Last Answer : C-9

Description : Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

Last Answer : Benzene + Br2/FeBr3

Description : In electrophilic aromatic substitution reactions a chlorine substituent __________. (a) is a deactivator and a m-director (b) is a deactivator and an o,p-director (c) is an activator and a m-director (d) is an activator and an o,p-director

Last Answer : is a deactivator and an o,p-director

Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Description : Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Last Answer : nucleophilic addition; free radical addition

Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Last Answer : Nucleophilic substitution reactions

Description : Arrange the following carboxyl compounds in increasing order of their reactivity in nucleophilic addition reactions. Explain with proper reasoning : Benzaldehyde. p-tolualdeyde, p-nitrobenzaldehyde, Acetophenone.

Last Answer : Ans. Acetophenone is a ketone while all others are aldehydes, therefore it is least reactive. In p-tolualdehyde, there is methyl group (CH3 ) at para position w.r.t. to the ... overall order of increasing reactivity : acetophenone < p-tolualdehyde < benzaldehyde < p-nitrobenzaldehyde. 

Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Last Answer : The addition product is a frequently observed minor product.

Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)

Last Answer : (a) and (b)

Description : Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ?

Last Answer : Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ... D. Yes, in a non-polar solvent

Description : Toluene o/p orienting with respect to an electrophilic substitution reaction due to

Last Answer : Toluene o/p orienting with respect to an electrophilic substitution reaction due to A. `+I` effect of the ... ring D. `+M` effect to the methyl group.

Description : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Last Answer : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the ... D. A is incorrect but R is correct

Description : Give the example for electrophilic substitution reaction ?

Last Answer : The species, which accepts the electrons, are called Electrophilles (or) Electrophilic reagents. When the atom (or) group of atoms present in the organic compound is replaced by another atom (or) group of atoms (electrophilic) is called electrophilic substitution reaction.

Description : How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Last Answer : The lone pair of electrons present on oxygen atom enter into resonance with the benzene ring. As a result, the electron density becomes higher at o- and p- position and due to higher electron density, the ring gets activated towards electrophilic substitution.

Description : Pyridine undergoes electrophilic substitution with fuming H2SO4 at 350°C to give (a) 2-Pyridinesulfonic acid (b) 4-Pyridinesulfonic acid (c) 3-Pyridinesulfonic acid (d) None of these

Last Answer : 3-Pyridinesulfonic acid

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Description : What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the ... by reacting with the Cl2 and thereby activates it toward attack by benzene's π electrons.

Last Answer : It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Description : The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Last Answer : nucleophilic substitution

Description : Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition (d) Nucleophilic substitution

Last Answer : Nucleophilic addition

Description : Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution

Last Answer : Electrophilic addition

Description : The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Last Answer : a free-radical substitution

Description : Arrange the following compounds in decreasing order of reactivity for EAR :- (I) `CH_(2)=CH_(2)` (II) `CH_(3)-CH=CH_(2)` (III) `Ph_(2)C=CH-CH_(3)` (IV

Last Answer : Arrange the following compounds in decreasing order of reactivity for EAR :- (I) `CH_(2)=CH_(2)` (II) `CH_(3)- ... I gt IV` D. `II gt III gt IV gt I`

Description : Assertion: Phenol is more reactive than benzene towards electrophilic reactions. Reason : The +R effect of OH group increases the electron density on

Last Answer : Assertion: Phenol is more reactive than benzene towards electrophilic reactions. Reason : The +R effect of ... D. A is incorrect but R is correct

Description : The chemical reactivity of noble gases involves the loss of electrons and hence it can form compounds with highly electronegative elements like F and

Last Answer : The chemical reactivity of noble gases involves the loss of electrons and hence it can form compounds with ... )d` and linear D. `sp` and linear

Description : The chemical reactivity of noble gases involves the loss of electrons and hence it can form compounds with highly electronegative elements like F and

Last Answer : The chemical reactivity of noble gases involves the loss of electrons and hence it can form compounds with highly ... D. `sp^(3)d^(2)` & 2

Description : The chemical reactivity of noble gases involves the loss of electrons and hence it can form compounds with highly electronegative elements like F and

Last Answer : The chemical reactivity of noble gases involves the loss of electrons and hence it can form compounds with highly ... A. zero B. 2 C. 6 D. 8

Description : The catalytic activity of transition metals and their compounds is ascribed mainly to (1) their chemical reactivity (2) their magnetic behaviour (3) their unfilled d-orbitals (4) their ability to adopt variable oxidation states

Last Answer : (4) their ability to adopt variable oxidation states

Description : Arrange the following in correct order of reactivity towards `Cl_(2)//hupsilon` (A) `CH_(4)` (B) `CH_(3)CH_(3)` (C ) `CH_(3)CH_(2)CH_(3)` (D) `CH_(3)-

Last Answer : Arrange the following in correct order of reactivity towards `Cl_(2)//hupsilon` (A) `CH_(4)` (B) `CH_(3)CH_(3)` ( ... gt A gt D` D. `C gt B gt D gt A`

Description : Which of the following is the correct order of decreasing `S_(N^(2))` reactivity ?

Last Answer : Which of the following is the correct order of decreasing `S_(N^(2))` reactivity ? A. `R_(2)CHXgtR_(3) ... 3)CXgtR_(2)CHXgtRCH_(2)X("X is a halogen")`

Description : The correct increasing order of the reactivity of halides for `S_(N^(1))` reaction is:

Last Answer : The correct increasing order of the reactivity of halides for `S_(N^(1))` reaction is: A. `CH_(3)CH_(2)-Xlt( ... -Xlt(CH_(3))_(2)CH-XltCH_(3)CH_(2)-X`

Description : Consider the following bromides: The correct order of `S_(N^(1))` reactivity is :

Last Answer : Consider the following bromides: The correct order of `S_(N^(1))` reactivity is : A. `IgtIIgtIII` B. `IIgtIIIgtI` C. `IIgtIgtIII` D. `IIIgtIIgtI`

Description : Which of the following is the correct arrangement of the given metals in ascending order of their reactivity? Zinc, Iron, Magnesium, Sodium A) Zinc > Iron > Magnesium > Sodium B) Sodium > Magnesium > Iron > Zinc C) Sodium > Zinc > Magnesium > Iron D) sodium > Magnesium > Zinc > Iron

Last Answer : D) sodium > Magnesium > Zinc > Iron

Description : Explain why nucleophilic substitution reactions are not very common in phenols.

Last Answer : Explain why nucleophilic substitution reactions are not very common in phenols.

Description : (A) Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution reactions. (R) Vinyl chloride is `+I` electron pushing group

Last Answer : (A) Ethyl chloride is more reactive than vinyl chloride towards nucleophilic substitution reactions. (R) Vinyl ... A) is incorrect but (R) is correct.

Description : Give reason: Alkanes undergo only substitution reactions but alkenes and alkynes undergo both substitution and addition reactions.

Last Answer : Alkenes and alkynes have double and triple bonds, which on breaking can add hydrogen atoms to satisfy the valency.

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

Description : Esters can be formed by nucleophilic substitution reactions of : (a) carboxylic acids and alcohols ; acid-catalyzed (b) acid chlorides and alcohols (c) both of the above (d) neither of the above

Last Answer : both of the above

Description : Esters and amides are most easily made by nucleophilic acyl substitution reactions on : (a) acid anhydrides (b) carboxylates (c) carboxylic acids (d) acid chlorides

Last Answer : acid chlorides

Description : Which statement about the carbonyl group of ketones and aldehydes is true? I. It can attract nucleophiles. II. It can attract electrophiles. III. It tends to undergo addition reactions. IV. It tends to undergo substitution reactions. (a) I and III (b) II and IV (c) I, II, and III (d) I, III, and IV

Last Answer : I, II, and III

Description : Which of the following compounds undergoes mucleophilic substitution reaction most easily?

Last Answer : Which of the following compounds undergoes mucleophilic substitution reaction most easily? A. B. C. D.

Description : Reactivity order of the following alkenes for hydrochlorination (HCl) is (I) `CH_(2) = CH - Cl` (II) `(CH_(3))_(2)C=CH_(2)` (III) `CH_(2) = CH - CHO`

Last Answer : Reactivity order of the following alkenes for hydrochlorination (HCl) is (I) `CH_(2) = CH - Cl` (II) `(CH_(3) ... `II gt I gt III` D. `III gt I gt II`