The reactivity of compound `Z` with different halogens under appropriate conditions is gives below- The observed pattern of electrophilic substitution

1 Answer

Answer :

The reactivity of compound `Z` with different halogens under appropriate conditions is gives below- ... the electronic effect of the tert-butyl group

Related questions

Description : Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ?

Last Answer : Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ? A. `A gt B gt ... A` D. `C gt B gt D gt A`

Description : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds:

Last Answer : Identify the correct order of reactivity in electrophilic substitution reactions of the following ... C. `IIgtIgtIIIgtIV` D. `IIgtIIIgtIgtIV`

Description : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds :

Last Answer : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds : ... ` C. `2gt1gt3gt4` D. `2gt3gt1gt4`

Description : Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is :

Last Answer : Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is : ... C. `IVgtIgtIIgtIII` D. `IIIgtIgtIIgtIV`

Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Last Answer : The addition product is a frequently observed minor product.

Description : Which of the following statements correctly describes the general reactivity of alkynes? (a) An alkyne is an electron-rich molecule and therefore reacts as a nucleophile. (b) The σ bonds ... fail to undergo electrophilic addition reactions. (d) Alkynes are generally more reactive than alkenes.

Last Answer : Alkynes are generally more reactive than alkenes.

Description : Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ?

Last Answer : Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ... D. Yes, in a non-polar solvent

Description : Toluene o/p orienting with respect to an electrophilic substitution reaction due to

Last Answer : Toluene o/p orienting with respect to an electrophilic substitution reaction due to A. `+I` effect of the ... ring D. `+M` effect to the methyl group.

Description : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Last Answer : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the ... D. A is incorrect but R is correct

Description : Give the example for electrophilic substitution reaction ?

Last Answer : The species, which accepts the electrons, are called Electrophilles (or) Electrophilic reagents. When the atom (or) group of atoms present in the organic compound is replaced by another atom (or) group of atoms (electrophilic) is called electrophilic substitution reaction.

Description : Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Last Answer : Ans. Due to the presence of an electron cloud containing 6 pi electrons above and below the plane of the ring, benzene is a source of electrons. Consequently, it attracts ... . As a result, benzene undergoes electrophilic substitution reactions easily and nucleophilic substitution with difficulty.

Description : How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Last Answer : The lone pair of electrons present on oxygen atom enter into resonance with the benzene ring. As a result, the electron density becomes higher at o- and p- position and due to higher electron density, the ring gets activated towards electrophilic substitution.

Description : Pyridine undergoes electrophilic substitution with fuming H2SO4 at 350°C to give (a) 2-Pyridinesulfonic acid (b) 4-Pyridinesulfonic acid (c) 3-Pyridinesulfonic acid (d) None of these

Last Answer : 3-Pyridinesulfonic acid

Description : Anthracene undergoes electrophilic substitution reactions mainly at (a) C-1 (b) C-2 (c) C-9 (d) C-1 and C-2

Last Answer : C-9

Description : Which of the following compounds reacts least rapidly in electrophilic substitution reactions? (a) Nitrobenzene (b) Phenol (c) Bromobenzene (d) Toluene

Last Answer : Nitrobenzene

Description : Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

Last Answer : Benzene + Br2/FeBr3

Description : In electrophilic aromatic substitution reactions a chlorine substituent __________. (a) is a deactivator and a m-director (b) is a deactivator and an o,p-director (c) is an activator and a m-director (d) is an activator and an o,p-director

Last Answer : is a deactivator and an o,p-director

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Description : What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the ... by reacting with the Cl2 and thereby activates it toward attack by benzene's π electrons.

Last Answer : It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Description : The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Last Answer : nucleophilic substitution

Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Description : Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Last Answer : nucleophilic addition; free radical addition

Description : Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition (d) Nucleophilic substitution

Last Answer : Nucleophilic addition

Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Last Answer : Nucleophilic substitution reactions

Description : Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution

Last Answer : Electrophilic addition

Description : The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Last Answer : a free-radical substitution

Description : Which of the following phrases is NOT appropriate for a description of benzene? w) characteristic reactivity of an alkene x) volatile liquid y) aromatic hydrocarbon z) resonance hybridization

Last Answer : ANSWER: W -- CHARACTERISTIC REACTIVITY OF AN ALKENE

Description : Consider a compound `CsXY_2` where X and Y are halogens. Which of the following statements is /are correct ? (i)X and Y have different oxidation state

Last Answer : Consider a compound `CsXY_2` where X and Y are halogens. Which of the following statements is /are correct ? (i)X ... ) C. Only (ii) D. (i) and (iii)

Description : Which of the following can undergo nucleophilic substitution under ordinary conditions? I Allyl chloride II Benzyl chloride III n-Propyl chloride IV V

Last Answer : Which of the following can undergo nucleophilic substitution under ordinary conditions? I Allyl chloride II ... are correct D. I and III are correct

Description : The given graph/data I, II, III and IV represent general trends observed for different physisorption and chemisorption processes under mild conditions

Last Answer : The given graph/data I, II, III and IV represent general trends observed for different ... D. IV is chemisorption and III is chemisorption

Description : In organic compound, halogens are estimated by which method? -General Knowledge

Last Answer : The answer is 'Carius method'

Description : In organic compound, halogens are estimated by which method? -General Knowledge

Last Answer : answer:

Description : In organic compound, halogens are estimated by which method?

Last Answer : Carius method

Description : Why is an organic compound fused with Sodium for testing nitrogen,halogens and sulphur ?

Last Answer : On fusing with sodium metal the elements presents in an organic compounds are converted in to ionic compounds of sodium which are water soluble which can be filtered and detected by the respective tests.

Description : With respect to halogens, four statements are given below: (P) The bond dissociation energies for halogens are in the order: `I_(2) lt F_(2) lt Br_(2)

Last Answer : With respect to halogens, four statements are given below: (P) The bond dissociation energies for halogens are in ... ,III,IV C. II,III,IV D. I,III

Description : The reactivity of an ionic compound element is explained as its tendency to attain noble gas configuration. How do the elements do so? (1) Lose electrons (2) Gain electrons (3) Both are correct (4) Both are incorrect

Last Answer : (3) Both are correct Explanation: The reactivity of elements is explained as their tendency to attain a completely filled outer shell. This is called as having attained noble gas configuration. Once noble gas configuration is reached, the elements lose their reactivity.

Description : The boiling points of the halogens increase going from F2 to I2. What type of intermolecular forces are responsible for this trend? w) permanent dipole x) hydrogen bonding y) ion-ion attraction z) London dispersion forces

Last Answer : ANSWER: Z -- LONDON DISPERSION FORCES

Description : AS A GROUP, the halogens have the largest: w) atomic radii x) Boiling points y) electronegativities z) ionization energies

Last Answer : ANSWER: Y -- ELECTRONEGATIVITIES

Description : Which of the following groups of elements have an OUTER ELECTRONIC configuration of S-2-P-2? w) halogens x) Nitrogen-Phosphorus Group y) Carbon-Silicon Group z) Boron-Aluminum Group

Last Answer : ANSWER: Y -- CARBON-SILICON GROUP

Description : The elements that have an outer electron configuration ns2 (read: n - s - 2) are called: w) halogens x) transition metals y) alkaline earths z) noble gases

Last Answer : ANSWER: Y -- ALKALINE EARTHS

Description : Which of the following halogens does NOT replace the other halogens from their compounds? w) fluorine x) iodine y) bromine z) chlorine

Last Answer : ANSWER: X -- IODINE

Description : The elements in group 1A of the periodic table are called: w) halogens x) alkaline earths y) alkali metals z) rare earths

Last Answer : ANSWER: Y -- ALKALI METALS

Description : Boundary layer separation is characterised by one of the conditions given below, where 'Re' is the Reynolds number for the flow. Select the appropriate conditions. (A) Re > 1, accelerating flow (C) Re >1, decelerating flow

Last Answer : (D) Re >>1, decelerating flow

Description : (A) In allylic substitution propene gives allyl bromide. (R) NBS is a selective brominating agent and gives substitution at the alpha carbon with resp

Last Answer : (A) In allylic substitution propene gives allyl bromide. (R) NBS is a selective brominating agent and gives ... (A) is incorrect but (R) is correct.

Description : A fast reactor uses: w) an extremely short time to get to the maximum operating reactivity. x) uranium-235 as fuel. y) heavy water as a coolant. z) essentially unmoderated neutrons.

Last Answer : ANSWER: Z -- ESSENTIALLY UNMODERATED NEUTRONS.

Description : Refractory metals are known for which of the following properties: w) lack of chemical reactivity x) low density y) high melting point z) high thermal conductivity

Last Answer : ANSWER: Y -- HIGH MELTING POINT

Description : Energy is described as the capacity for: w) reactivity x) combustion y) transformation z) doing work

Last Answer : ANSWER: Z -- DOING WORK 

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene