Toluene o/p orienting with respect to an electrophilic substitution reaction due to

Toluene o/p orienting with respect to an electrophilic substitution reaction due to
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Toluene o/p orienting with respect to an electrophilic substitution reaction due to A. `+I` effect of the ... ring D. `+M` effect to the methyl group.
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Related questions

Which of the following compounds reacts least rapidly in electrophilic substitution reactions? (a) Nitrobenzene (b) Phenol (c) Bromobenzene (d) Toluene

Description : Which of the following compounds reacts least rapidly in electrophilic substitution reactions? (a) Nitrobenzene (b) Phenol (c) Bromobenzene (d) Toluene

Last Answer : Nitrobenzene

In electrophilic aromatic substitution reactions a chlorine substituent __________. (a) is a deactivator and a m-director (b) is a deactivator and an o,p-director (c) is an activator and a m-director (d) is an activator and an o,p-director

Description : In electrophilic aromatic substitution reactions a chlorine substituent __________. (a) is a deactivator and a m-director (b) is a deactivator and an o,p-director (c) is an activator and a m-director (d) is an activator and an o,p-director

Last Answer : is a deactivator and an o,p-director

Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ?

Description : Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ?

Last Answer : Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ? A. `A gt B gt ... A` D. `C gt B gt D gt A`

Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ?

Description : Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ?

Last Answer : Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ... D. Yes, in a non-polar solvent

Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Description : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Last Answer : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the ... D. A is incorrect but R is correct

Give the example for electrophilic substitution reaction ?

Description : Give the example for electrophilic substitution reaction ?

Last Answer : The species, which accepts the electrons, are called Electrophilles (or) Electrophilic reagents. When the atom (or) group of atoms present in the organic compound is replaced by another atom (or) group of atoms (electrophilic) is called electrophilic substitution reaction.

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Description : Benzene reacts with concentrated HNO3 in the presence of concentrated H2SO4 to give nitrobenzene. This reaction is an example of (a) Electrophilic addition (b) Nucleophilic addition (c) Electrophilic substitution (d) Nucleophilic substitution

Last Answer : Electrophilic substitution

What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the chain reaction. (b) It functions by destabilizing the carbocationic intermediate and thereby increases the rate of H+ loss. (c) It serves as a Lewis base catalyst by reacting with Cl2 to generate chloride ions. (d) It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Description : What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the ... by reacting with the Cl2 and thereby activates it toward attack by benzene's π electrons.

Last Answer : It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Description : The characteristic reaction of carboxylic acids is : (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic addition (d) nucleophilic substitution

Last Answer : nucleophilic substitution

40. Among the fo the one that is most reactive towards electrophilic nitration is: (1) Benzene (2) Benzoic acid (3) Nitrobenzene (4) Toluene

Description : 40. Among the following compounds the one that is most reactive towards electrophilic nitration is: (1) Benzene (2) Benzoic acid (3) Nitrobenzene (4) Toluene

Last Answer : Toluene

The reactivity of compound `Z` with different halogens under appropriate conditions is gives below- The observed pattern of electrophilic substitution

Description : The reactivity of compound `Z` with different halogens under appropriate conditions is gives below- The observed pattern of electrophilic substitution

Last Answer : The reactivity of compound `Z` with different halogens under appropriate conditions is gives below- ... the electronic effect of the tert-butyl group

Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds:

Description : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds:

Last Answer : Identify the correct order of reactivity in electrophilic substitution reactions of the following ... C. `IIgtIgtIIIgtIV` D. `IIgtIIIgtIgtIV`

Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds :

Description : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds :

Last Answer : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds : ... ` C. `2gt1gt3gt4` D. `2gt3gt1gt4`

Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is :

Description : Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is :

Last Answer : Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is : ... C. `IVgtIgtIIgtIII` D. `IIIgtIgtIIgtIV`

Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Description : Why does benzene undergo electrophilic substitution reactions easily and nucleophilic substitutions with difficulty?

Last Answer : Ans. Due to the presence of an electron cloud containing 6 pi electrons above and below the plane of the ring, benzene is a source of electrons. Consequently, it attracts ... . As a result, benzene undergoes electrophilic substitution reactions easily and nucleophilic substitution with difficulty.

How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Description : How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Last Answer : The lone pair of electrons present on oxygen atom enter into resonance with the benzene ring. As a result, the electron density becomes higher at o- and p- position and due to higher electron density, the ring gets activated towards electrophilic substitution.

Pyridine undergoes electrophilic substitution with fuming H2SO4 at 350°C to give (a) 2-Pyridinesulfonic acid (b) 4-Pyridinesulfonic acid (c) 3-Pyridinesulfonic acid (d) None of these

Description : Pyridine undergoes electrophilic substitution with fuming H2SO4 at 350°C to give (a) 2-Pyridinesulfonic acid (b) 4-Pyridinesulfonic acid (c) 3-Pyridinesulfonic acid (d) None of these

Last Answer : 3-Pyridinesulfonic acid

Anthracene undergoes electrophilic substitution reactions mainly at (a) C-1 (b) C-2 (c) C-9 (d) C-1 and C-2

Description : Anthracene undergoes electrophilic substitution reactions mainly at (a) C-1 (b) C-2 (c) C-9 (d) C-1 and C-2

Last Answer : C-9

Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

Description : Which of the reactions between the following pairs of reagents proceeds by a mechanism that may be described as an electrophilic substitution? (a) Benzene + Br2/FeBr3 (b) Propene + Br2 (c) Acetone + NH2NH2 (d) Ethyl bromide + aq KOH

Last Answer : Benzene + Br2/FeBr3

Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the rate-determining step. (c) The carbocation intermediate contains an sp3 hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Last Answer : The addition product is a frequently observed minor product.

Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) Aldehydes are more sterically hindered than esters. (c) Once the nucleophile adds to an aldehyde, the tetrahedral intermediate is too sterically hindered to eliminate one of the attached groups. (d) Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Description : Why do aldehydes undergo nucleophilic addition reactions while esters undergo nucleophilic acyl substitution reactions? (a) The carbonyl carbon of an ester is more electrophilic than that of an aldehyde. (b) ... adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Last Answer : Once the nucleophile adds to an aldehyde, neither H− nor R− can be eliminated since they are strongly basic

Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Description : Which of the following characterizes the reactions of aldehydes and ketones? (a) electrophilic addition (b) electrophilic substitution (c) nucleophilic acyl substitution (d) nucleophilic addition; free radical addition

Last Answer : nucleophilic addition; free radical addition

Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition(d) Nucleophilic substitution

Description : Acetone reacts with HCN to form a cyanohydrin. It is an example of (a) Electrophilic addition (b) Electrophilic substitution (c) Nucleophilic addition (d) Nucleophilic substitution

Last Answer : Nucleophilic addition

Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions

Last Answer : Nucleophilic substitution reactions

Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution

Description : Propene reacts with bromine to form 1,2-dibromopropane. This is an example of (a) Nucleophilic addition (b) Electrophilic addition (c) Nucleophilic substitution (d) Electrophilic substitution

Last Answer : Electrophilic addition

The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Description : The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Last Answer : a free-radical substitution

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

Cresols on distillation with zinc dust gives (a) o-Xylene(b) Benzene(c) o- plus p-Xylene(d) Toluene

Description : Cresols on distillation with zinc dust gives (a) o-Xylene (b) Benzene (c) o- plus p-Xylene (d) Toluene

Last Answer : Toluene

Toluene reacts with chlorine in the presence of AlCl3 to give (a) o-Chlorotoluene (b) o- plus p-Chlorotoluene (c) m-Chlorotoluene (d) o- plus m-Chlorotoluene

Description : Toluene reacts with chlorine in the presence of AlCl3 to give (a) o-Chlorotoluene (b) o- plus p-Chlorotoluene (c) m-Chlorotoluene (d) o- plus m-Chlorotoluene

Last Answer : o- plus p-Chlorotoluene

(A) Cation carriers, e.g., `H-Br,Cl-OH` and `Br-Br` and oxidising agents such as `O_(3)` and `R-O-O-R`, etc. act as electrophilic reagents. (R) Electr

Description : (A) Cation carriers, e.g., `H-Br,Cl-OH` and `Br-Br` and oxidising agents such as `O_(3)` and `R-O-O-R`, etc. act as electrophilic reagents. (R) Electr

Last Answer : (A) Cation carriers, e.g., `H-Br,Cl-OH` and `Br-Br` and oxidising agents such as `O_(3)` and ... incorrect. D. IF (A) is incorrect but (R) is correct.

During the reaction of Benzene diazonium chloride with para-cresol the substitution occurs at_____position of p-cresol.

Description : During the reaction of Benzene diazonium chloride with para-cresol the substitution occurs at_____position of p-cresol.

Last Answer : During the reaction of Benzene diazonium chloride with para-cresol the substitution occurs at_____position of p-cresol.

Which of the following solutions will follow Raoult's law most closely? (A) A solution of benzene, toluene and o-xylene (B) 35% solution of camphor in water (C) 35% solution of NH3 in water (D) A solution of polar organic compounds (not of homologue of a series)

Description : Which of the following solutions will follow Raoult's law most closely? (A) A solution of benzene, toluene and o-xylene (B) 35% solution of camphor in water (C) 35% solution of NH3 in water (D) A solution of polar organic compounds (not of homologue of a series)

Last Answer : (A) A solution of benzene, toluene and o-xylene

Toluene reacts with bromine in the presence of uv light to give (a) m-Bromotoluene (b) Benzyl bromide (c) o-Bromotoluene (d) Benzoyl bromide

Description : Toluene reacts with bromine in the presence of uv light to give (a) m-Bromotoluene (b) Benzyl bromide (c) o-Bromotoluene (d) Benzoyl bromide

Last Answer : Benzyl bromide

When acetylene is passed through hot iron tube at 400°C, it gives (a) Benzene (b) Toluene (c) o-Xylene (d) Mesitylene

Description : When acetylene is passed through hot iron tube at 400°C, it gives (a) Benzene (b) Toluene (c) o-Xylene (d) Mesitylene

Last Answer : Benzene

What is electrophilic addition reaction ?

Description : What is electrophilic addition reaction ?

Last Answer : When the attacking species during the addition reaction is Electrophile, it is called electrophilic addition reaction. Ex; (+) (-) (+) (-) (+) (-) CH2Br-CH2BràH2C-CH2+BrBr-àH2C=CH2+Br2-

A solution contains 1g mol. Each of p-toluene diazonium chloride and p-nitrophenyl diazonium cholride. To this 1g mol.of alkaline solution of phenol i

Description : A solution contains 1g mol. Each of p-toluene diazonium chloride and p-nitrophenyl diazonium cholride. To this 1g mol.of alkaline solution of phenol i

Last Answer : A solution contains 1g mol. Each of p-toluene diazonium chloride and p-nitrophenyl diazonium ... Predict the major product. Explain your answer.

Toluene when treated with `Br_(2)//Fe,` give p-bromotoluene as the major product because of the `-CH_(3)` group:

Description : Toluene when treated with `Br_(2)//Fe,` give p-bromotoluene as the major product because of the `-CH_(3)` group:

Last Answer : Toluene when treated with `Br_(2)//Fe,` give p-bromotoluene as the major product because ... is m-directing D. activates the ring by hyperconjugation

Reduction of p-nitrotoluene with Sn + HCl gives : (a) p-methylaniline (b) Toluene (c) m-methylaniline (d) N-Methylaniline

Description : Reduction of p-nitrotoluene with Sn + HCl gives : (a) p-methylaniline (b) Toluene (c) m-methylaniline (d) N-Methylaniline

Last Answer : p-methylaniline

How many toluidines on reaction with `NaNO_(2)//HCl` followed by `H_(3)PO_(2)` treatment gives Toluene.

Description : How many toluidines on reaction with `NaNO_(2)//HCl` followed by `H_(3)PO_(2)` treatment gives Toluene.

Last Answer : How many toluidines on reaction with `NaNO_(2)//HCl` followed by `H_(3)PO_(2)` treatment gives Toluene.

Why does dichloromethane have no reaction with toluene?

Description : Why does dichloromethane have no reaction with toluene?

Last Answer : Need answer

Oxidation of toluene with chromyl chloride gives benzaldehyde. This reaction is known as (a) Perkin reaction (b) Benzoin condensation (c) Etard's reaction (d) Ozonolysis

Description : Oxidation of toluene with chromyl chloride gives benzaldehyde. This reaction is known as (a) Perkin reaction (b) Benzoin condensation (c) Etard's reaction (d) Ozonolysis

Last Answer : Etard's reaction

A liquid mixture contains 30% o-xylene, 60% p-xylene and 10%. m￾xylene (all percentages in w/w). Which of the following statements would be true in respect of this mixture? (A) The mixture exhibits an azeotrope at 101.3 kPa (B) The composition of the mixture, in percent by volume is: o-xylene 30, p￾xylene 60. and m-xylene 10 (C) The composition of the mixture in mole percent is: o-xylene 30, p-xylene 60 and m-xyoene 10 (D) The mixture contain optical isomers

Description : A liquid mixture contains 30% o-xylene, 60% p-xylene and 10%. m￾xylene (all percentages in w/w). Which of the following statements would be true in respect of this mixture? (A) The mixture exhibits ... : o-xylene 30, p-xylene 60 and m-xyoene 10 (D) The mixture contain optical isomers

Last Answer : (A) The mixture exhibits an azeotrope at 101.3 kPa

A solution of (-l)- chloro -1 phenyletane in toluene recemises slowly in the presence of a small amunt of `SbCI_(5)` due to the formation of .

Description : A solution of (-l)- chloro -1 phenyletane in toluene recemises slowly in the presence of a small amunt of `SbCI_(5)` due to the formation of .

Last Answer : A solution of (-l)- chloro -1 phenyletane in toluene recemises slowly in the presence of a ... free radical B. carbanion C. carbene D. carbocation

A solution of `(+)`-2-chloro-2-phenyl ethane in toluene racemises slowly in the presence of small amount of `SbCl_(5)`, due to the formation of:

Description : A solution of `(+)`-2-chloro-2-phenyl ethane in toluene racemises slowly in the presence of small amount of `SbCl_(5)`, due to the formation of:

Last Answer : A solution of `(+)`-2-chloro-2-phenyl ethane in toluene racemises slowly in the presence of ... carbanion B. carbene C. free radical D. carbocation

In a `S_(N^(2))` substitution reaction of the type `R-Br+Cl^(-)overset("DMF")rarrR-Cl+Br^(-)` Which one of the following has the highest relative rate

Description : In a `S_(N^(2))` substitution reaction of the type `R-Br+Cl^(-)overset("DMF")rarrR-Cl+Br^(-)` Which one of the following has the highest relative rate

Last Answer : In a `S_(N^(2))` substitution reaction of the type `R-Br+Cl^(-)overset("DMF")rarrR-Cl+Br^(-)` Which one of ... CH_(2)Br` D. `(CH_(3))_(2)CH-CH_(2)Br`

Which of the following is a free radical substitution reaction?

Description : Which of the following is a free radical substitution reaction?

Last Answer : Which of the following is a free radical substitution reaction? A. `CH_(3)CHO+HCNrarrCH_(3)CH(OH)CN` B. C. D.

Which one of the following is most reactive towards nucleophilic substitution reaction ?

Description : Which one of the following is most reactive towards nucleophilic substitution reaction ?

Last Answer : Which one of the following is most reactive towards nucleophilic substitution reaction ? A. `H_(2)C=CH-Cl` B. ` ... 3)CH=CHCl` D. `ClCH_(2)-CH=CH_(2)`

Which of the following is least reactive in a nucleophilic substitution reaction?

Description : Which of the following is least reactive in a nucleophilic substitution reaction?

Last Answer : Which of the following is least reactive in a nucleophilic substitution reaction? A. `(CH_(3))_(3)C-Cl` B. `CH_ ... 3)CH_(2)Cl` D. `CH_(2)=CHCH_(2)Cl`