Write the IUPAC name of the following complex : [CO(NH3)6]3+ -Chemistry

1 Answer

Answer :

Hexaamminecobalt (III) ion.

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Description : (i) Write down the IUPAC name of the following complex : [CO(NH3)5Cl]2+ (ii) Write the formula for the following complex : Potassium tetrachloridonickelate (II) -Chemistry

Last Answer : i) [CO(NH3)5Cl]2+ IUPAC name : Pentaammine chlorido cobalt (III) ion (ii) Formula of the complex potassium tetrachloridonickelate (II) K2[NiCl4]

Description : (i) Write down the IUPAC name of the following complex : [Cr(NH3)2CI3(en)]Cl (en = ethylenediamine) (ii) Write the formula for the following complex : Pentaamminenitrito-o-Cobalt (III) -Chemistry

Last Answer : (I) [Cr(NH3)2Cl3(en)]Cl IUPAC name : Diammine dichlorido ethylenediamine chromium (III) chloride. (ii) [Co(NH3)5(ONO)]2+

Description : Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit? -Chemistry

Last Answer : IUPAC name : Tetraamine dichlorido chromium (III) ion. It exhibits geometrical isomerism.

Description : What is the IUPAC name of the complex [Ni(NH3)6]Cl2? -Chemistry

Last Answer : [Ni(NH3)6]Cl2 IUPAC name : Hexaamminenickel (II) chloride.

Description : Name the following coordination compounds according to IUPAC system of nomenclature :(i) [Co(NH3)4 (H2O)Cl]Cl2 (ii) [CrCl2(en)2]Cl, (en = ethane – 1, 2 – diamine) -Chemistry

Last Answer : (i) [CO(NH3)4 (H2O)Cl]Cl2 Tetraammine aquachlorido cobalt (III) chloride (ii) [CrCl2(en)2]Cl Dichlorobis (ethane-1, 2-diamine) chromium (III) chloride

Description : When a co-ordination compound CrCl3.6H2O is mixed with AgNO3, 2 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex. (ii) IUPAC name of the complex. -Chemistry

Last Answer : (i) The complex formed on mixing a coordination compound CrCl3.6H2O with AgNO3 is as follows CrCl3.6H2O + AgNO3 → [Cr(H2O5)Cl]Cl2. H2O (ii) Pentaaquachloridochromium (III) chloride monohydrate

Description : Explain why [Co(NH3)6]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital complex. (At. no. Co = 27, Ni = 28) -Chemistry

Last Answer : In [Co(NH3)6]3+, the d-electrons of Co3+ ([Ar]3d6 45°) get paired leaving behind two empty d-orbital and undergo d2sp3 hybridization and hence inner orbital complex, while in [Ni(NH3)6]2+ ... of Ni2+([Ar]3d8 45°) do not pair up and use outer 4d subshell hence outer orbital complex.

Description : Which of the following is more stable complex and why? [Co(NH3)6]3+ and [Co(en)3]3+ -Chemistry

Last Answer : Co(en)3]3+ is more stable complex than [CO(NH3)6]3+ because of chelate effect.

Description : Write the IUPAC name of [CO (NH3 ) 4 B12] 2 [ZnCl4 ].

Last Answer : Ans. Tetraamminedibromocobalt (III) tetrachlorozincate (II) 

Description : Give IUPAC name of the ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry

Last Answer : IUPAC name : Triammine chlorido nickel (II) nitrate [Ni(NH3)3NO3]Cl

Description : Give IUPAC name of ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry

Last Answer : IUPAC name : Triammine nitrato nickel (III) chloride

Description : Indicate the types of isomerisms exhibited by the complex [Co(NH3)5 (NO2)] (NO3)2. (At. no. Co = 27) -Chemistry

Last Answer : It shows ionisation isomerism and linkage isomerism.

Description : When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex (ii) IUPAC name of the complex -Chemistry

Last Answer : i) Complex so formed is: CoCl3.6NH3 + AgNO3 → [Co(NH3)6]Cl3 (ii) IUPAC name of complex is: Hexaamminecobalt (III) chloride

Description : Write IUPAC name of the complex: -Chemistry

Last Answer : Dichloridobis ethylenediamine cobalt (III) ion.

Description : Write IUPAC name of the complex: [CoCl2(en)2]+ -Chemistry

Last Answer : CoCl2(en)2]+: Dichloridobis(ethylenediamine)Cobalt(III)ion.

Description : Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : [Co(NH3)6]+3, [Cr(NH3)6]3+, Ni(CO)4 (At. nos. : Co = 27, Cr = 24, Ni = 28) -Chemistry

Last Answer : (i) [Co(NH3)6]+3 → Octahedral shape, d2sp3 hybridisation, diamagnetic Formation of [Co(NH2)6]+3 → oxidation state of Co is +3.

Description : Describe the shape and magnetic behaviour of following complexes : (i) [CO(NH3)6]3+ (ii) [Ni(CN)4]2- (At. No. Co = 27, Ni = 28) -Chemistry

Last Answer : (i) [CO(NH3)6]3+ : Orbitals of CO3+ ion : Hybridization : d2sp3 Shape : Octahedral Magnetic behaviour : Diamagnetic (absence of unpaired electrons) (ii) [Ni(CN)4]2-

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Last Answer : (3) [Ni (CO)4]

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Last Answer : (a) K3[Al(C2O4)3] (b) [Co(Cl)2(en)2]+

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Last Answer : a) [Cr(en)3] Cl3 (b) K2[Zn(OH)4]

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Last Answer : (i) Na[Au(CN)2] (ii) [Pt(NH3)4 Cl(NO2)] (SO4)

Description : Write the IUPAC name of the following coordination compound [NiCl4]2-. -Chemistry

Last Answer : Tetrachloridonickelate (II) ion.

Description : As per IUPAC nomenclature, the name of the complex `[Co(H_(2)O)_(4) (NH_(3))_(2)] Cl_(3)` is

Last Answer : As per IUPAC nomenclature, the name of the complex `[Co(H_(2)O)_(4) ( ... (III) chloride D. Diamminetetraaquacobalt (III) chloride

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Last Answer : Stability of a complex in solution means the measure of resistance to the replacement of a ligand by some other ligand. This stablility can be expressed in terms of equilibrium constant. Let the ... is its tendency to donate electron pair and therefore, more is the stability of the complex.

Description : The IUPAC name of `[Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)]` is :

Last Answer : The IUPAC name of `[Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)]` is : A. ... (II) tris(oxalato)chromium(III) D. Hexaamminecobalt(III)trioxalatechromium(III)

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Description : IUPAC name `[Co(NH_(3))_(5)(NO_(2))]Cl_(2)` is

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Last Answer : i) [Fe(en)2Cl2] Cl or x + 0 + 2 (-1) + (-1) = 0 x + (- 3) = 0 or x = + 3 ∴ Oxidation number of iron, x = + 3 (ii) The complex has two bidentate ligands and two ... )2Cl2] Cl, only cis-isomer shows optical isomerism. (vi) Name of complex: Dichloridobis (ethane-1, 2- diamine) Iron (III) chloride

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