Write the IUPAC name of [CO (NH3 ) 4 B12] 2 [ZnCl4 ].

1 Answer

Answer :

Ans. Tetraamminedibromocobalt (III) tetrachlorozincate (II) 

Related questions

Description : A cationic complex has two isomers A & B. Each has one Co3+, five NH3 , one Br and one SO4 2 . A gives a white precipitate with BaCl2 solution while B gives a yellow precipitate with AgNO3 ... are the possible structures of the complexes A and B ? (a) Will the two complexes have same colour ?

Last Answer : (a) [CO (NH3 ) 5 Br] SO4 and [CO (NH3 ) 5 SO4 ] Br  (b) NO

Description : Mention any four characteristics of Co- Ordination Compound

Last Answer : (1) Hard ness of water is estimated by simple titration with Na2 EDTA.  (2) Extraction of metals like Ag and Au make use of complex formation .  (3) Purification of ... compounds  (4) Biological application like pigment formation photosynthesis, Chloropyll.  Haemoglobin pigment of blood . 

Description : What are difference between double salt and a complex salt.

Last Answer : (1) both double salts as well as complex are formed by the combination of two or more stable compounds in stiochometric ratio (2) They differ in the fact that double salts such as carnallite -KCl. MgCl2. 6H20 , Mohr's ... as [Fe (CN) 6]4 of K4 Fe (CN) 6 do not dissociate into Fe2+ and CN- ions 

Description : What is meant by unidentate , didentate and ambidentate ligands . give two example of each

Last Answer : When a legend is bound to a metal ion through a single diner atom, is said to be unidentate for ex- Cl- , H2O & NH3 When a legande can bound through two donor atoms as in H2N ... is said to be polydentate ligand which can ligate through two different atoms is called ambidenate ligand Ex-NO2, SCN 

Description : Which vitamin is a complex compound of cobalt ? 

Last Answer : Ans. Vitamin B12 is a complex compound in which central metal atom is cobalt. 

Description : What is the hybridisation of central metal ion and shape of Wilkinson’s catalyst ?

Last Answer : Wilkinson’s catalyst is (PH3 P)3 RhCl. In this Rh has dsp² hybridisation and square planar shape.

Description : How many EDTA (lethylendiamine tetra acetic acid) molecules are required to make an octahedral complex with a Ca2+ ion.

Last Answer : EDTA is a hexadentate ligand therefore only one EDTA molecule is required to form octahedral complex. 

Description : Explain the reason behind a colour of some gem stone with the help of example.

Last Answer : The colours of many gem stones are due to the presence of transition metal ions & colour are produced due to d-d transition. For example the mineral corundum Al2O3 is colourless when pure but when ... in trace amounts various gem stones are formed. Ruby is Al2O3 containing about 0.5 - 1% Cr3+ .

Description : FeSO4 solution mixed with (NH4 ) 2 SO4 solution in 1 : 1 molar ratio gives the test of Fe2+ ion but CuSO4 solution mixed with aqueous ammonia in 1 : 4 molar ratio does not give the test of Cu2+ ion. Explain why ?

Last Answer : When FeSO4 and (NH4 ) 2 SO4 solution are mixed in 1 : 1 molar ratio, a double salt is formed. It has the formula FeSO4 (NH4 ) 2 SO4 . 6 H2O. In aqueous solution, the salt dissociates. When CuSO4 and NH3 are mixed in the molar ratio of 1 : 4 in solution, a complex [Cu (NH3 ) 4 ] SO4 is formed.

Description : (i) Write down the IUPAC name of the following complex : [CO(NH3)5Cl]2+ (ii) Write the formula for the following complex : Potassium tetrachloridonickelate (II) -Chemistry

Last Answer : i) [CO(NH3)5Cl]2+ IUPAC name : Pentaammine chlorido cobalt (III) ion (ii) Formula of the complex potassium tetrachloridonickelate (II) K2[NiCl4]

Description : Write the IUPAC name of the following complex : [CO(NH3)6]3+ -Chemistry

Last Answer : Hexaamminecobalt (III) ion.

Description : Name the following coordination compounds according to IUPAC system of nomenclature :(i) [Co(NH3)4 (H2O)Cl]Cl2 (ii) [CrCl2(en)2]Cl, (en = ethane – 1, 2 – diamine) -Chemistry

Last Answer : (i) [CO(NH3)4 (H2O)Cl]Cl2 Tetraammine aquachlorido cobalt (III) chloride (ii) [CrCl2(en)2]Cl Dichlorobis (ethane-1, 2-diamine) chromium (III) chloride

Description : (i) Write down the IUPAC name of the following complex : [Cr(NH3)2CI3(en)]Cl (en = ethylenediamine) (ii) Write the formula for the following complex : Pentaamminenitrito-o-Cobalt (III) -Chemistry

Last Answer : (I) [Cr(NH3)2Cl3(en)]Cl IUPAC name : Diammine dichlorido ethylenediamine chromium (III) chloride. (ii) [Co(NH3)5(ONO)]2+

Description : Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit? -Chemistry

Last Answer : IUPAC name : Tetraamine dichlorido chromium (III) ion. It exhibits geometrical isomerism.

Description : What is the IUPAC name of the complex [Ni(NH3)6]Cl2? -Chemistry

Last Answer : [Ni(NH3)6]Cl2 IUPAC name : Hexaamminenickel (II) chloride.

Description : Give IUPAC name of the ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry

Last Answer : IUPAC name : Triammine chlorido nickel (II) nitrate [Ni(NH3)3NO3]Cl

Description : Give IUPAC name of ionization isomer of [Ni(NH3)3NO3]Cl. -Chemistry

Last Answer : IUPAC name : Triammine nitrato nickel (III) chloride

Description : When a co-ordination compound CrCl3.6H2O is mixed with AgNO3, 2 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex. (ii) IUPAC name of the complex. -Chemistry

Last Answer : (i) The complex formed on mixing a coordination compound CrCl3.6H2O with AgNO3 is as follows CrCl3.6H2O + AgNO3 → [Cr(H2O5)Cl]Cl2. H2O (ii) Pentaaquachloridochromium (III) chloride monohydrate

Description : Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : [Co(NH3)6]+3, [Cr(NH3)6]3+, Ni(CO)4 (At. nos. : Co = 27, Cr = 24, Ni = 28) -Chemistry

Last Answer : (i) [Co(NH3)6]+3 → Octahedral shape, d2sp3 hybridisation, diamagnetic Formation of [Co(NH2)6]+3 → oxidation state of Co is +3.

Description : Explain why [Co(NH3)6]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital complex. (At. no. Co = 27, Ni = 28) -Chemistry

Last Answer : In [Co(NH3)6]3+, the d-electrons of Co3+ ([Ar]3d6 45°) get paired leaving behind two empty d-orbital and undergo d2sp3 hybridization and hence inner orbital complex, while in [Ni(NH3)6]2+ ... of Ni2+([Ar]3d8 45°) do not pair up and use outer 4d subshell hence outer orbital complex.

Description : Describe the shape and magnetic behaviour of following complexes : (i) [CO(NH3)6]3+ (ii) [Ni(CN)4]2- (At. No. Co = 27, Ni = 28) -Chemistry

Last Answer : (i) [CO(NH3)6]3+ : Orbitals of CO3+ ion : Hybridization : d2sp3 Shape : Octahedral Magnetic behaviour : Diamagnetic (absence of unpaired electrons) (ii) [Ni(CN)4]2-

Description : Which of the following is more stable complex and why? [Co(NH3)6]3+ and [Co(en)3]3+ -Chemistry

Last Answer : Co(en)3]3+ is more stable complex than [CO(NH3)6]3+ because of chelate effect.

Description : Indicate the types of isomerisms exhibited by the complex [Co(NH3)5 (NO2)] (NO3)2. (At. no. Co = 27) -Chemistry

Last Answer : It shows ionisation isomerism and linkage isomerism.

Description : A complex compound in which the oxidation number of a metal is zero is - (1) K4 [Fe (CN)6] (2) K3 [Fe (CN)6] (3) [Ni (CO)4] (4) [Pl (NH3)4]Cl2

Last Answer : (3) [Ni (CO)4]

Description : Out of CO and NH3 which is adsorbed on activated charcoal to a large extent and why ?

Last Answer : Ans. Ammonia; because more easily liquefiable gas undergoes adsorption to a greater extent.

Description : IUPAC name of `|Co(ONO)(NH_(3))_(5)Cl_(2)|` is

Last Answer : IUPAC name of `|Co(ONO)(NH_(3))_(5)Cl_(2)|` is A. ... pentamminenitritocobalt(III)chloride D. pentammineoxo-nitrocobalt(III)chloride

Description : The IUPAC name of `[Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)]` is :

Last Answer : The IUPAC name of `[Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)]` is : A. ... (II) tris(oxalato)chromium(III) D. Hexaamminecobalt(III)trioxalatechromium(III)

Description : IUPAC name `[Co(NH_(3))_(5)(NO_(2))]Cl_(2)` is

Last Answer : IUPAC name `[Co(NH_(3))_(5)(NO_(2))]Cl_(2)` is A. Nitrito-N-pentaamminecobalt( ... -cobalt(II)chloride D. Pentaamminenitrito-N-cobalt (III) chloride

Description : As per IUPAC nomenclature, the name of the complex `[Co(H_(2)O)_(4) (NH_(3))_(2)] Cl_(3)` is

Last Answer : As per IUPAC nomenclature, the name of the complex `[Co(H_(2)O)_(4) ( ... (III) chloride D. Diamminetetraaquacobalt (III) chloride

Description : The correct IUPAC name of the compound `[Co(NH_(3))_(4)Cl(ONO)]Cl` is :

Last Answer : The correct IUPAC name of the compound `[Co(NH_(3))_(4)Cl(ONO)]Cl` is ... tetraamminecobalt(III) D. Tetraamminechloridonitrito-O-cobalt(III) chloride

Description : Using IUPAC norms write the formulae for the following: (a) Potassium trioxalatoaluminate (III) (b) Dichloridobis(ethane-l, 2-diamine) cobalt (III) -Chemistry

Last Answer : (a) K3[Al(C2O4)3] (b) [Co(Cl)2(en)2]+

Description : Using IUPAC norms write the formulae for the following: (a) Tris(ethane-1,2-diamine) chromium (III) chloride (b) Potassium tetrahydroxozincate(II) -Chemistry

Last Answer : a) [Cr(en)3] Cl3 (b) K2[Zn(OH)4]

Description : Using IUPAC norms write the formulae for the following: (i) Sodium dicyanidoaurate (I) (it) Tetraamminechloridonitrito-N-platinum (IV) sulphate -Chemistry

Last Answer : (i) Na[Au(CN)2] (ii) [Pt(NH3)4 Cl(NO2)] (SO4)

Description : When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex (ii) IUPAC name of the complex -Chemistry

Last Answer : i) Complex so formed is: CoCl3.6NH3 + AgNO3 → [Co(NH3)6]Cl3 (ii) IUPAC name of complex is: Hexaamminecobalt (III) chloride

Description : Write IUPAC name of the complex: -Chemistry

Last Answer : Dichloridobis ethylenediamine cobalt (III) ion.

Description : Write IUPAC name of the complex: [CoCl2(en)2]+ -Chemistry

Last Answer : CoCl2(en)2]+: Dichloridobis(ethylenediamine)Cobalt(III)ion.

Description : Write the IUPAC name of the following coordination compound [NiCl4]2-. -Chemistry

Last Answer : Tetrachloridonickelate (II) ion.

Description : Write the metamer of diethyl ether. What is its IUPAC name?

Last Answer : Ans.1-methoxypropane, CH3OCH2CH2CH3 or 2-methoxypropane,CH3OCH(CH3)2

Description : Write the IUPAC name for: (CH3)2CHCH(OH)CH2C(CH3)3,identify the functional group and type of compound.

Last Answer : Ans. 2,5,5-trimethylhexan-3-ol, alcohol, secondary alcohol

Description : Write the IUPAC of molecule with the formula C3 H8?

Last Answer : Ans. propane

Description : Acid rains are due to which of the following gases? (a) CO2 and CO (b) Ozone and CO2(c) NO2 and SO2 (d) NH3 and CO2

Last Answer : (c) NO2 and SO2

Description : Raw materials for urea production are (A) CO2 and N2 (B) CO2 , H2 and N2 (C) NH3 and CO (D) HNO3 and CaCO3

Last Answer : (B) CO2 , H2 and N2

Description : Urea is represented as (A) NH2 .CO.NH2 (B) NH3CO.CH3 (C) NH.CO2 .NH (D) NH3 .CO2 .NH3

Last Answer : (A) NH2 .CO.NH2

Description : . Chemical formula of biuret is (A) NH2 .CO.NH2 (B) NH3 .COO.NH3 (C) NH2CONHCONH2 (D) NH4COONH2

Last Answer : (C) NH2CONHCONH2

Description : Automobile exhaust is passed through two compartments catalytic converter employing platinum as catalyst for (A) Conversion of CO into CO2 in the second compartment (B) Conversion of NOx into N2 and NH3 in the first ... of unburnt hydrocarbon fuel in the second compartment (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Description : Which of the following pollutants is absent in the emissions from a fertiliser plant? (A) SO2 & SO3 (B) NO2 (C) NH3 (D) CO

Last Answer : (D) CO

Description : . Shift conversion reaction (A) Converts N2 and H2 into NH3 (B) Converts CO to CO2 with steam (C) Is non-catalytic (D) Is highly exothermic

Last Answer : (B) Converts CO to CO2 with steam

Description : The worst enemy of ozone is a) Liquid NH3 b) SO2 c) CH4 d) CO.

Last Answer : c) CH4

Description : Acid rain is caused by a) SO2 and NO2 b) SO2 and CO c) NH3 and CO d) SO2 and NH3.

Last Answer : a) SO2

Description : Write down the IUPAC names of the following compounds :- (A) `CH_(3)-underset(C_(2)H_(5))underset(|)(CH)-overset(CH_(3))overset(|)(CH)-underset(OH)und

Last Answer : Write down the IUPAC names of the following compounds :- (A) `CH_(3)-underset(C_(2)H_(5))underset(|)( ... )=CH-underset(CH_(3))underset(|)(CH)-C-=CH`