Description : Pick out the wrong statement: (A) The expansion of a gas in vacuum is an irreversible process (B) An isometric process is a constant pressure process (C) Entropy change for a reversible adiabatic process is zero (D) Free energy change for a spontaneous process is negative
Last Answer : (B) An isometric process is a constant pressure process
Description : Assertion :- Entropy of system increases for a spontaneous reactions. Reason :- Enthalpy of reaction always decreases for spontaneous reaction.
Last Answer : Assertion :- Entropy of system increases for a spontaneous reactions. Reason :- Enthalpy of reaction ... D. If both Assertion & Reason are false.
Description : For a spontaneous natural process at constant temperature and pressure, the free energy of the system always (A) Increases (B) Decreases (C) Remain constant (D) Increases to a maximum before decreasing
Last Answer : : Option A
Description : When ice cubes are made, the entropy of water – (1) does not change (2) decreases (3) increases (4) may either increase or decrease depending on the process used
Last Answer : (2) decreases Explanation: When water is frozen into ice, the temperature drops below 0°C. Since the entropy of the solid is less than that of the liquid, the entropy of the water (the system ... decrease is found by dividing the heat of fusion of ice by the temperature for the reversible pathway.
Description : When ice cubes are made, the entropy of water (1) does not change (2) decreases (3) increases (4) may either increase or decrease depending on the process used
Last Answer : decreases
Description : A change in state involving a decrease in entropy can be spontaneous, only if (A) It is exothermic (B) It is isenthalpic (C) It takes place isothermally (D) It takes place at constant volume
Last Answer : (A) It is exothermic
Description : Pick out the wrong statement. (A) Cp of monatomic gases such as metallic vapor is about 5 kcal/kg.atom (B) The heat capacity of solid inorganic substance is exactly equal to the ... isolated system (D) At absolute zero temperature, the heat capacity for many pure crystalline substances is zero
Last Answer : (C) There is an increase in entropy, when a spontaneous change occurs in an isolated system
Description : In any spontaneous process, the __________ free energy decreases. (A) Helmholtz (B) Gibbs (C) Both ‘a’ & ‘b’ (D) Neither 'a' nor 'b'
Last Answer : (C) Both ‘a’ & ‘b’
Description : Spontaneous change is one in there is: (1) A lowering of entropy (2) A lowering of free energy (3) Increase in free energy (4) An increase in Internal energy
Last Answer : (2) A lowering of free energy Explanation: Entropy and enthalpy together make a new quantity, the Free Energy which, under conditions of constant temperature and pressure, determines the direction of spontaneous change. All spontaneous processes have a negative change in free energy.
Last Answer : A lowering of free energy
Description : A closed system is cooled reversibly from 100°C to 50°C. If no work is done on the system (A) its internal energy (U) decreases and its entropy (S) increases (B) U and S both decreases (C) U decreases but S is constant (D) U is constant but S decreases
Last Answer : (B) U and S both decreases
Description : When a salt dissolves in water (a) Entropy decreases (b) Entropy increases (c) Free energy increases (d) Heat is liberated
Last Answer : Ans:(b)
Description : Pick out the correct statement. (A) Like internal energy and enthalpy, the absolute value of standard entropy for elementary substances is zero (B) Melting of ice involves increase in enthalpy and ... of an ideal gas depends only on its pressure (D) Maximum work is done under reversible conditions
Last Answer : (D) Maximum work is done under reversible conditions
Description : In a spontaneous irreversible process the total entropy of the system and surroundings
Last Answer : In a spontaneous irreversible process the total entropy of the system and surroundings A. Remains constant B. Increases C. Decreases D. Zero
Description : Pick out the wrong statement. (A) The net change in entropy in any reversible cycle is always zero (B) The entropy of the system as a whole in an irreversible process increases (C) The ... to a maximum (D) The entropy of a substance does not remain constant during a reversible adiabatic change
Last Answer : (D) The entropy of a substance does not remain constant during a reversible adiabatic change
Description : The entropy __________ in an irreversible cyclic process. A. remains constant B. decreases C. increases
Last Answer : Answer: C
Description : In any spontaneous process, (A) Only F decreases (B) Only A decreases (C) Both F and A decreases (D) Both F and A increase
Last Answer : (C) Both F and A decreases
Description : For spontaneous changes in an isolated system (S = entropy) (A) ds = 0 (B) ds 0 (D) ds = Constant
Last Answer : (C) ds > 0
Description : A 47-year-old patient undergoing a complicated laparotomy for bowel obstruction develops a postoperative enterocutaneous fistula. Which of the following statement(s) is/are true concerning parenteral ... use of TPN better prepares the patient for surgery if surgical intervention proves necessary
Last Answer : Answer: a, b, d Patients with gastrointestinal-cutaneous fistulas represent the classical indication for TPN. In such patients, oral intake of food almost invariably results in increased ... treated more aggressively surgically after a defined period of nutritional support (unless closure occurs)
Description : In a free expansion process (a) work done is zero (b) heat transfer is zero (c) both (a) and (b) above (d) work done is zero but heat increases (e) work done is zero but heat decreases.
Last Answer : Answer : c
Description : Pick out the wrong statement. (A) A refrigeration cycle violates the second law of thermodynamics (B) Refrigeration cycle is normally represented by a temperature vs. entropy plot (C) In a refrigerator, ... (D) One ton of refrigeration is equivalent to the rate of heat absorption equal to 3.53 kW
Last Answer : (A) A refrigeration cycle violates the second law of thermodynamics
Description : In an isothermal process, the internal energy of gas molecules (a) increases (b) decreases (c) remains constant (d) may increase/decrease depending on the properties of gas (e) shows unpredictable behaviour.
Description : Assertion (A): May endothermic reactions that are not spontaneous at room temperature become spontaneous at high temperature. Reason (R ) : Entropy of
Last Answer : Assertion (A): May endothermic reactions that are not spontaneous at room temperature become spontaneous ... . If both Assertion & Reason are false.
Description : Pick out the wrong statement. (A) When the concentration difference for the mass transfer becomes zero at the bottom of the gas absorption tower, then the upper end of the operating line touches the ... fixed gas flow rate, the slope of the operating line decreases, in case of gas absorption process
Last Answer : (C) The operating line lies above the equilibrium curve in case of a gas desorber
Description : When liquid water is converted to steam at 100˚C, the entropy of water a. increases b. decreases c. remains the same d. none of the above
Last Answer : increases
Description : Production rate __________ with increased fineness, with a given energy input to the size reduction machine. (A) Decreases (B) Increases (C) Remains unchanged (D) May increase or decrease; depends on the machine
Last Answer : (A) Decreases
Description : With increase in temperature, the internal energy of a substance (A) Increases (B) Decreases (C) Remains unchanged (D) May increase or decrease; depends on the substance
Last Answer : (A) Increases
Description : With the increase in the amount of compaction energy (A) Optimum water content increases but maximum dry density decreases (B) Optimum water content decreases but maximum dry density increases ( ... and maximum dry density increase (D) Both optimum water content and maximum dry density decrease
Last Answer : Answer: Option B
Description : When the compaction energy increases the compaction of soils: (a) Both of OMC and maximum dry density decrease (b) Both of OMC and maximum dry density increase (c) OMC decreases but maximum dry density decrease (c) OMC increases but maximum dry density increase
Last Answer : (c) OMC decreases but maximum dry density decrease
Description : During throttling process (a) heat exchange does not take place (b) no work is done by expanding steam (c) there is no change of internal energy of steam (d) all of the above (e) entropy decreases.
Last Answer : Answer : d
Description : In any chemical reaction, a quantity that decrease to a minimum is: w) free energy x) entropy y) temperature z) enthalpy
Last Answer : ANSWER: W -- FREE ENERGY
Description : If the internal energy of an ideal gas decreases by the same amount as the work done by the system, then the (A) Process must be isobaric (B) Temperature must decrease (C) Process must be adiabatic (D) Both (B) and (C)
Last Answer : (D) Both (B) and (C)
Description : Pick out the wrong statement. (A) Surface tension of a substance vanishes at critical point, as there is no distinction between liquid and vapour phases at its critical point (B) Entropy of ... is negative for exothermic reactions (D) The eccentric factor for all materials is always more than one
Last Answer : (D) The eccentric factor for all materials is always more than one
Description : Pick out the correct statement. (A) The available energy in an isolated system for all irreversible (real) processes decreases (B) The efficiency of a Carnot engine increases, if the sink temperature is decreased ... condition is the change in Helmholtz free energy (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : Increase in the entropy of a system represents the (A) Degradation of energy (B) Decrease in system pressure (C) Increase in the availability of energy (D) Increase in the temperature
Last Answer : Option A
Description : When amount of free energy increases entropy?
Last Answer : Need answer
Description : Entropy of the system decreases, when (A) Snow melts into water (B) A gas expands spontaneously from high pressure to low pressure (C) Water is converted into ice (D) Both (B) & (C)
Last Answer : (D) Both (B) & (C)
Description : Entropy change in case of reversible adiabatic process is (A) Minimum (B) Zero (C) Maximum (D) Indeterminate
Last Answer : (B) Zero
Description : In β-decay of radioactive material, the ratio of neutron to proton (A) Increases (B) Remain same (C) Decreases (D) Is unpredictable; may increase or decrease
Last Answer : (C) Decreases
Description : The disintegration rate of a radioactive element (A) Progressively increases (B) Progressively decreases (C) Remains constant throughout (D) May increase or decrease depending on the material
Last Answer : (B) Progressively decreases
Description : Temperature of the product during ultrafine grinding (A) Increases (B) Decreases (C) Remain constant (D) May increase or decrease; depends on the material being ground
Description : The filtrate flow rate in constant pressure filtration (A) Continuously increases (B) Continuously decreases (C) Remain constant throughout (D) May increase or decrease; depends on the pressure
Last Answer : (B) Continuously decreases
Description : As the impurities are oxidised, the melting point of iron (A) Decreases (B) Remains unchanged (C) Increases (D) May increase or decrease; unpredictable
Last Answer : (C) Increases
Description : Dew point of a gas-vapour mixture (A) Increases with temperature rise (B) Decreases with temperature rise (C) Decreases with decrease in pressure (D) Increases with increase in pressure
Last Answer : (C) Decreases with decrease in pressure
Description : In batch distillation with constant reflux, overhead product composition __________ with time. (A) Increases (B) Decreases (C) Does not vary (D) May increase on decrease, depends on the system
Last Answer : (B) Decreases
Description : With increase in the concentration of the adsorbate, the integral heat of adsorption (A) Increases (B) Decreases (C) Remains unchanged (D) May increase or decrease; depends on the type of adsorbate
Description : With lapse of time, the overhead composition of light component in case of batch distillation with constant reflux (A) Increases (B) Decreases (C) Remain same (D) May increase or decrease; depends on system
Description : Molecular diffusivity of a liquid (A) Increases with temperature (B) Decreases with temperature (C) May increase or decrease with temperature (D) Is independent of temperature
Last Answer : (A) Increases with temperature
Description : The boiling points of pure components of a binary system __________ with increase in total pressure of the system. (A) Decreases (B) Increases (C) Remains unchanged (D) May increase or decrease, depends on the system
Last Answer : (B) Increases