Description : Pick out the wrong statement: (A) The expansion of a gas in vacuum is an irreversible process (B) An isometric process is a constant pressure process (C) Entropy change for a reversible adiabatic process is zero (D) Free energy change for a spontaneous process is negative
Last Answer : (B) An isometric process is a constant pressure process
Description : Pick out the correct statement: (A) In an isothermal system, irreversible work is more than reversible work (B) Under reversible conditions, the adiabatic work is less than isothermal work (C) ... state functions' (D) Matter and energy cannot be exchanged with the surroundings in a closed system
Last Answer : (B) Under reversible conditions, the adiabatic work is less than isothermal work
Description : The total entropy change for a system and its surroundings increases, if the process is
Last Answer : The total entropy change for a system and its surroundings increases, if the process is A. Reversible B. Irreversible C. Exothermic D. Endothermic
Description : A system undergoes a change from a given initial state to a given final state either by an irreversible process or by a reversible process, then (where, Δ S1 and Δ SR are the entropy changes of the system for the ... S1is sometimes > Δ SR (C) Δ S1is always > Δ SR (D) Δ S1is always = Δ SR
Last Answer : (C) Δ S1is always > Δ SR
Description : Pick out the wrong statement. (A) The net change in entropy in any reversible cycle is always zero (B) The entropy of the system as a whole in an irreversible process increases (C) The ... to a maximum (D) The entropy of a substance does not remain constant during a reversible adiabatic change
Last Answer : (D) The entropy of a substance does not remain constant during a reversible adiabatic change
Description : Entropy change for an irreversible process taking system and surrounding together is (A) 0 (B) > 0 (C) < 0 (D) None of these
Last Answer : (B) > 0
Description : For a spontaneous process, free energy (A) Is zero (B) Increases (C) Decreases whereas the entropy increases (D) And entropy both decrease
Last Answer : C) Decreases whereas the entropy increases
Description : Throttling process is a/an __________ process. (A) Reversible and isothermal (B) Irreversible and constant enthalpy (C) Reversible and constant entropy (D) Reversible and constant enthalpy
Last Answer : (B) Irreversible and constant enthalpy
Description : The entropy __________ in an irreversible cyclic process. A. remains constant B. decreases C. increases
Last Answer : Answer: C
Description : Assertion :- Entropy of system increases for a spontaneous reactions. Reason :- Enthalpy of reaction always decreases for spontaneous reaction.
Last Answer : Assertion :- Entropy of system increases for a spontaneous reactions. Reason :- Enthalpy of reaction ... D. If both Assertion & Reason are false.
Description : Pick out the wrong statement. (A) Cp of monatomic gases such as metallic vapor is about 5 kcal/kg.atom (B) The heat capacity of solid inorganic substance is exactly equal to the ... isolated system (D) At absolute zero temperature, the heat capacity for many pure crystalline substances is zero
Last Answer : (C) There is an increase in entropy, when a spontaneous change occurs in an isolated system
Description : For spontaneous changes in an isolated system (S = entropy) (A) ds = 0 (B) ds 0 (D) ds = Constant
Last Answer : (C) ds > 0
Description : Entropy change for an irreversible isolated system is (A) ∞ (B) 0 (C) < 0 (D) > 0
Last Answer : (D) > 0
Description : Assertion (A): May endothermic reactions that are not spontaneous at room temperature become spontaneous at high temperature. Reason (R ) : Entropy of
Last Answer : Assertion (A): May endothermic reactions that are not spontaneous at room temperature become spontaneous ... . If both Assertion & Reason are false.
Description : Spontaneous change is one in there is: (1) A lowering of entropy (2) A lowering of free energy (3) Increase in free energy (4) An increase in Internal energy
Last Answer : (2) A lowering of free energy Explanation: Entropy and enthalpy together make a new quantity, the Free Energy which, under conditions of constant temperature and pressure, determines the direction of spontaneous change. All spontaneous processes have a negative change in free energy.
Description : A change in state involving a decrease in entropy can be spontaneous, only if (A) It is exothermic (B) It is isenthalpic (C) It takes place isothermally (D) It takes place at constant volume
Last Answer : (A) It is exothermic
Last Answer : A lowering of free energy
Description : Entropy of a substance remains constant during a/an __________ change. (A) Reversible isothermal (B) Irreversible isothermal (C) Reversible adiabatic (D) None of these
Last Answer : (C) Reversible adiabatic
Description : According to first law of thermodynamics (a) work done by a system is equal to heat transferred by the system (b) total internal energy of a system during a process remains constant ( ... , enthalpy and entropy during a process remain constant (d) total energy of a system remains constant
Last Answer : Answer : d
Description : Requisites of a reversible process is that the (A) System and surroundings pressure be equal (B) Friction in the system should be absent (C) System and surroundings temperature be equal (D) None of these
Last Answer : B) Friction in the system should be absent
Description : What is the thermodynamic STATE function that is directly associated with a constant pressure process in which heat is exchanged between system and surroundings?
Last Answer : ANSWER: DELTA H
Description : A 47-year-old patient undergoing a complicated laparotomy for bowel obstruction develops a postoperative enterocutaneous fistula. Which of the following statement(s) is/are true concerning parenteral ... use of TPN better prepares the patient for surgery if surgical intervention proves necessary
Last Answer : Answer: a, b, d Patients with gastrointestinal-cutaneous fistulas represent the classical indication for TPN. In such patients, oral intake of food almost invariably results in increased ... treated more aggressively surgically after a defined period of nutritional support (unless closure occurs)
Description : The process of damage of metals by the action of any medium from its surroundings is called?
Last Answer : Corrosion of metals
Description : For a spontaneous natural process at constant temperature and pressure, the free energy of the system always (A) Increases (B) Decreases (C) Remain constant (D) Increases to a maximum before decreasing
Last Answer : : Option A
Description : Pick out the correct statement. (A) The available energy in an isolated system for all irreversible (real) processes decreases (B) The efficiency of a Carnot engine increases, if the sink temperature is decreased ... condition is the change in Helmholtz free energy (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : Pick out the correct statement. (A) If an insoluble gas is passed through a volatile liquid placed in a perfectly insulated container, the temperature of the liquid will increase (B) A ... compound is defined as the heat of reaction leading to the formation of the compound from its reactants
Last Answer : (D) The heat of formation of a compound is defined as the heat of reaction leading to the formation of the compound from its reactants
Description : An irreversible process (A) Is the analog of linear frictionless motion in machines (B) Is an idealised visualisation of behaviour of a system (C) Yields the maximum amount of work (D) Yields an amount of work less than that of a reversible process
Last Answer : (D) Yields an amount of work less than that of a reversible process
Description : Identify the correct statement regarding a spontaneous process:
Last Answer : Identify the correct statement regarding a spontaneous process: A. For a spontaneous process in ... process is the only criterion for spontaneity
Description : For a spontaneous process the correct statement is -
Last Answer : For a spontaneous process the correct statement is - A. Entropy of the system always increase ... negative D. Total entropy change is always positive
Description : Assertion : Reduction of ZnO with carbon is done at `1100^(@)C`. Reason : At this temperature, `DeltaG^(@)` is negative and the process is spontaneous
Last Answer : Assertion : Reduction of ZnO with carbon is done at `1100^(@)C`. Reason : At this temperature, ... ^(@)` is negative and the process is spontaneous.
Description : Go through the following graph and answer the following questions. To make the following reduction process spontaneous, temprature should be : `ZnO+C
Last Answer : Go through the following graph and answer the following questions. To make the following reduction process spontaneous, ... )C " but " lt 1000^(@)C`
Description : What process was studied by Redi and Spaltanzani? a. Spontaneous generation b. Fermentation c. Variolation d. Antisepsis
Last Answer : a. Spontaneous generation
Description : _________ law of thermodynamics ascertains the direction of a particular spontaneous process. (A) Zeroth (B) First (C) Second (D) Third
Last Answer : (C) Second
Description : In any spontaneous process, (A) Only F decreases (B) Only A decreases (C) Both F and A decreases (D) Both F and A increase
Last Answer : (C) Both F and A decreases
Description : In any spontaneous process, the __________ free energy decreases. (A) Helmholtz (B) Gibbs (C) Both ‘a’ & ‘b’ (D) Neither 'a' nor 'b'
Last Answer : (C) Both ‘a’ & ‘b’
Description : The process of moving from one energy level to another is called ____________. ∙ A. Spontaneous emission ∙ B. Excited emission ∙ C. Absorption ∙ D. Spontaneous decay
Last Answer : C. Absorption
Description : The process of decaying from one energy level to another energy level is called __________. ∙ A. Spontaneous emission ∙ B. Excited emission ∙ C. Absorption ∙ D. Any of these
Last Answer : A. Spontaneous emission
Description : What is the irreversible process ?
Last Answer : The process that cannot be reversed, that is, the results of heat and work are not equal and opposite in each step of reversal and reversal , is called irreversible process.
Description : A liquid which is confined inside an adiabatic piston is suddently taken from state `-1` to state `-2` by a single stage irreversible process. If the
Last Answer : A liquid which is confined inside an adiabatic piston is suddently taken from state `-1` to state `-2` by a single ... (0)` D. `DeltaU = -3P_(0)V_(0)`
Description : Transamination is a (A) Irreversible process(B) Reversible process (C) Both (A) and (B) (D) None of these
Last Answer : Answer : B
Description : Catalytic ammonia synthesis reaction as in Haber's process is (A) Endothermic (B) Exothermic (C) Irreversible (D) None of these
Last Answer : (B) Exothermic
Description : When a gas in a vessel expands, its internal energy decreases. The process involved is (A) Reversible (B) Irreversible (C) Isothermal (D) Adiabatic
Last Answer : (A) Reversible
Description : In an irreversible process (A) Tds = dE - dW = 0 (B) dE - dW - Tds = 0 (C) Tds - dE + dW < 0 (D) Tds - dT + dW < 0
Last Answer : (C) Tds - dE + dW < 0
Description : For an irreversible process involving only pressure-volume work (A) (dF)T, p 0 (D) (dA)T, v >0
Last Answer : (A) (dF)T, p
Description : PVy = constant, holds good for an isentropic process, which is (A) Reversible and isothermal (B) Isothermal and irreversible (C) Reversible and adiabatic (D) Adiabatic and irreversible
Last Answer : C) Reversible and adiabatic
Description : In a totally irreversible isothermal expansion process for an ideal gas, ΔE = 0, ΔH = 0. Then ΔQ and ΔS will be (A) ΔQ = 0, ΔS=0 (B) ΔQ = 0, ΔS = +ve (C) ΔQ = 0, ΔS = -ve (D) ΔQ = +ve, ΔS= +ve
Last Answer : (B) ΔQ = 0, ΔS = +ve
Description : Ideal process are ________ process a. Irreversible b. Reversible c. Isothermal d. Isometric
Last Answer : Reversible
Description : The term “isentropic process” used in thermodynamics implies what? A. Reversible adiabatic process B. Externally reversible, adiabatic process C. Internally reversible, adiabatic process D. Irreversible adiabatic process
Last Answer : Internally reversible, adiabatic process
Description : How does an adiabatic process compare to an isentropic process? A. Adiabatic heat transfer is not equal to zero; isentropic heat transfer is zero B. Both heat transfer = 0; isentropic: reversible ... is not equal to zero D. Both heat transfer is not equal to zero; isentropic: irreversible
Last Answer : Both heat transfer = 0; isentropic: reversible