Description : Which of the following is least soluble in water? (a) Methylamine (b) Trimethylamine (c) Dimethylamine (d) Aniline
Last Answer : Methylamine
Description : Which of the following compounds does not react with acetyl chloride? (a) Methylamine (b) Dimethylamine (c) Aniline (d) Trimethylamine
Last Answer : Trimethylamine
Description : Which of the following is most basic? (a) Ammonia (b) Methylamine (c) Dimethylamine (d) Trimethylamine
Last Answer : Dimethylamine
Description : Acetonitrile undergoes reduction with LiAlH4 to form : (a) Methylamine (b) Dimethylamine (c) Ethylamine (d) Trimethylamine
Last Answer : Ethylamine
Description : Which of the following statements is False about acetamide? (a) reacts with Br2/NaOH to form tertiary amine (b) undergoes acid-hydrolysis to form acetic acid (c) undergoes dehydration with P2O5 to form a nitrile (d) is a white crystalline solid, soluble in water
Last Answer : reacts with Br2/NaOH to form tertiary amine
Description : Pyridine is less basic than trimethylamine because the lone-pair of electrons on N-atom in pyridine resides in (a) sp2 hybrid orbital (b) sp hybrid orbital (c) sp3 hybrid orbital (d) p-orbital
Last Answer : sp2 hybrid orbita
Description : Which formulation of 2,4-D has fastest ab sorption by crop plants? a). Ethyl ester b). Dimethylamine c). Na salt d). All
Last Answer : a). Ethyl ester
Description : Phenol is (a) stronger acid than acetic acid (b) weaker acid than acetic acid (c) stronger base than methylamine (d) weaker base than methylamine
Last Answer : weaker acid than acetic acid
Description : Glycine reacts with nitrous acid to form : (a) Glycollic acid (b) Diketopiperazine (c) Methylamine (d) Ethyl alcoho
Last Answer : Glycollic acid
Description : Methylamine reacts with nitrous acid to form (a) CH3CH3 (b) CH3OH (c) CH3NO2 (d) CH3CH2OH
Last Answer : CH3OH
Description : Acetamide reacts with Br2/NaOH to give (a) Methylamine (b) Urea (c) Ethylamine (d) Acetyl bromide
Description : Which of the following will have the highest boiling point? (a) Methylamine (b) Diethylamine (c) Ethylamine (d) Triethylamine
Last Answer : Triethylamine
Description : The compound methylamine, H3C–NH2, contains a C–N bond. In this bond, which of the following best describes the charge on the nitrogen atom? (a) slightly positive (b) uncharged (c) slightly negative (d) –1
Last Answer : slightly negative
Description : Which of the following reagents will react with acetamide to form methylamine? (a) LiAlH4 (b) Br2/NaOH (c) PCl5 (d) H2/Ni
Last Answer : Br2/NaOH
Description : Acetamide on reduction with LiAlH4 gives (a) Acetaldehyde (b) Ethylamine (c) Acetone (d) Methylamine
Description : Acetamide can be converted into methylamine by (a) P2O5 (b) Br2/NaOH (c) PCl5 (d) LiAlH4
Description : Acetamide on heating with P2O5 gives : (a) Methylamine (b) Ethylamine (c) Methyl cyanide (d) None of these
Last Answer : Methyl cyanide
Description : The nitrogen atom in the following cyclic compounds can be removed as trimethylamine by successive Hoffmann eliminations (involving exhaustive methyla
Last Answer : The nitrogen atom in the following cyclic compounds can be removed as trimethylamine by successive Hoffmann eliminations ... is : A. B. C. D.
Description : Acetamide is treated separately with the following reagens. Which one of these given methylamine?
Last Answer : Acetamide is treated separately with the following reagens. Which one of these given methylamine? A. `PCI_(5)` ... ` D. Hot concentrated `H_(2)SO_(4)`
Description : What is carbil amine reaction ?
Last Answer : The primary or 1 degree amine ( CH3-NH2 and aniline) reacts with chloroform and alcoholic caustic potash ( KOH) to produce methyl carbil amine ( CH3-NC) . This reaction is called carbil amine reaction.
Description : Trimetyl amine is pyramidal while trisilyl amine is trigonal planer . explain ?
Last Answer : Ans. In tri silylamine N is sp2 hybridised and pπ-dπ bonding take place while In trimethyl amine N is SP3 hybridised and No pπ-dπ bonding .
Description : How would you remove nonpolar impurities from an amine ?
Last Answer : Ans.--- Adding HCl , amine will form salt whereas nonpolar impurities will not react . Amines can be regenerated by adding NaOH .
Description : Why is amide more acidic than an amine ?
Last Answer : Ans.—In amide there is C=O group attached NH2 , electron withdrawing & increases acidic nature of amide whereas in amines there is alkyl group which is electron releasing and makes it more basic & hence less acidic.
Description : Pkb of aniline is more than that of methyl amine.
Last Answer : In aniline, the lone pair of electrons on the N-atom are delocalized over the benzene ring. As a result electron density on the nitrogen decreases. In contrast in CH2NH2 , + I effect of CH3 ... , aniline is a weaker base than methylamine and hence its Pkb value is higher than that of methylamine.
Description : Preparation of a diazonium salt from a primary aromatic amine is known as : (a) Coupling reaction (b) Sandmeyer reaction (c) Diazotization (d) Corey-House synthesis
Last Answer : Diazotization
Description : Which of the following statements is false about aniline? (a) It is a primary aromatic amine. (b) It is a weak base which forms salts with acids. (c) It liberates nitrogen on treatment with ice-cold nitrous acid. (d) It can be prepared by the reduction of nitrobenzene with tin and HCl
Last Answer : It liberates nitrogen on treatment with ice-cold nitrous acid
Description : A primary amine can be identified by using (a) HCl (b) CHCl3 (c) NaOH (d) CHCl3 + KOH
Last Answer : CHCl3 + KOH
Description : Which of the following does not react with acyl chlorides to form amides : (a) ammonia (b) 1° amine (c) 2° amine (d) 3° amine
Last Answer : 3° amine
Description : Which type of amine produces N2 when treated with HONO? (a) Primary (b) Secondary (c) Tertiary (d) Quaternary
Last Answer : Primary
Description : Reduction of an imine will give an (a) Acid (b) Amide (c) Amine (d) Alcohol
Last Answer : Amine
Description : Consider a 1°, 2° and 3° amine, all of equivalent molecular weight. Which amine is most likely to have the lowest boiling point? (a) 1° amine (b) 2° amine (c) 3° amine (d) Not enough information to determine
Description : A sample of pure amine molecules is found to possess no intermolecular Hbonding. This sample is most likely : (a) 1° amine (b) 2° amine (c) 3° amine (d) all of these
Description : The hybridization of nitrogen in an amine is (a) sp (b) sp3 (c) sp2 (d) sp4
Last Answer : sp3
Description : Assuming roughly equivalent molecular weights, which of the following would have the highest boiling point? (a) a tertiary amine (b) a quaternary ammonium salt (c) an alcohol (d) an ether
Last Answer : a quaternary ammonium salt
Description : Amides undergo hydrolysis under acidic conditions to give (a) Carboxylic acid and amine (b) Carboxylic acid and ammonium ion (c) Carboxylate ion and ammonium ion (d) Carboxylate ion and amine
Last Answer : Carboxylic acid and ammonium ion
Description : Consider a small aliphatic 1° amine, 1° alcohol, ester, carboxylic acid, and amide, all of similar molecular weight. Which one is most likely to have the highest boiling point? (a) The amide (b) The alcohol (c) The ester (d) The carboxylic acid
Last Answer : The amide
Description : Carbylamine test involves heating a mixture of (a) alcoholic KOH, methyl iodide, and sodium metal (b) alcoholic KOH, methyl iodide, and primary amine (c) alcoholic KOH, chloroform, and primary amine (d) alcoholic KOH, methyl alcohol, and primary amine
Last Answer : alcoholic KOH, chloroform, and primary amine
Description : Alkyl cyanide on reduction gives….. a. primary amine b. secondary amine c. amide d. carboxylic acid
Last Answer : a. primary amine
Description : Based on the intermolecular forces involved, which of the following molecules will have the lowest boiling point? w) ethane x) methyl alcohol y) methyl amine z) methyl fluoride
Last Answer : ANSWER: W -- ethane
Description : An amine contains which one of the following functional groups? w) NO2 x) NOH y) NH2 z) N2
Last Answer : ANSWER: Y -- NH2
Description : Which of the following would be most acidic? w) phenol x) methanol y) acetic acid z) methyl amine
Last Answer : ANSWER: C -- ACETIC ACID
Description : H2S is scrubbed from refinery gases by absorption using (A) Dilute H2SO4 (B) Ethanol amine (C) Chilled water (D) Tri-butyl phosphate
Last Answer : (B) Ethanol amine
Description : In the following reactions `2X+B_(2)H_(6) to [BH_(2)(X)_(2)]^(+){BH_(4)]^(-)` The amine X will not be -
Last Answer : In the following reactions `2X+B_(2)H_(6) to [BH_(2)(X)_(2)]^(+){BH_(4)]^(-)` The amine X will not be - A. ... C. `(CH_(3))_(2)NH` D. `(CH_(3))_(3)N`
Description : Tertiary butyl amine is a-
Last Answer : Tertiary butyl amine is a- A. `1^(@)` Amine B. `2^(@)` Amine C. `3^(@)` Amine D. Quaternary salt
Description : The substance that gives a primary amine on hydrolysis is
Last Answer : The substance that gives a primary amine on hydrolysis is A. nitroparaffin B. alkyl cyanide C. oxime D. alkyl isocyanide
Description : In the hofmann-bromamide degradation reaction, the number of moles of NaOH and `Br_(2)` used per mole of amine produced are
Last Answer : In the hofmann-bromamide degradation reaction, the number of moles of NaOH and `Br_(2)` used per mole of ... moles of NaOH and one mole of `Br_(2)`
Description : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to give a primary amine that ha
Last Answer : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to ... . `II gt I gt IV gt III`
Last Answer : Hofmann rearrangement In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromide to ... O)overset(||)(C)-NH_(2)`
Description : Which of the following reduction reactions does not give an amine as product?
Last Answer : Which of the following reduction reactions does not give an amine as product? A. `R-NO_(2) underset(" ... (2)underset(Delta)overset(Zn//NH_(4)Cl)rarr`
Description : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the carbon chain, the reagent used as sou
Last Answer : In order to prepare a `1^(@)` amine from an alkyl halide with simultaneous addition of one `CH_(2)` group in the ... C_(6)H_(4)(CO)_(2)N^(-)K^(+)`