Description : Which of the following statements is correct for a saturated alkyl halide? (a) the C-X bond results from overlap of the s orbital of carbon and the p orbital of the halogen (X) (b) the C-X bond ... the C-X bond results from overlap of the sp2 orbital of carbon and the p orbital of the halogen (X)
Last Answer : the C–X bond results from overlap of the sp3 orbital of carbon and the p orbital of the halogen (X)
Description : Which of the following cofactors or their derivatives must be present for the conversion of acetyl CoA to malonyl CoA extramitochondrial fatty acid synthesis? (A) Biotin (B) FAD (C) FMN (D) ACP
Last Answer : Answer : A
Description : Identify the group in which all the polymers mentioned can be used to make fibres. (A) Butadiene copolymers, Polyamides, Urea-formaldehyde (B) Cellulose derivatives, Polyisoprene, Polyethylene (C) Cellulose derivatives, Polyamides, Polyurethane (D) Polypropylene, Poly vinyl chloride, Silicon
Last Answer : (B) Cellulose derivatives, Polyisoprene, Polyethylene
Description : Acetamide reacts with Br2/NaOH to give (a) Methylamine (b) Urea (c) Ethylamine (d) Acetyl bromide
Last Answer : Methylamine
Description : The metabolite which sustains urea cycle is (A) Ornithine (B) Citrulline (C) Carbamoyl phosphate (D) n-acetyl glutamate
Last Answer : Answer : C
Description : In urea synthesis, the amino acid functioning solely as an enzyme activator: (A) N-acetyl glutamate(B) Ornithine (C) Citrulline (D) Arginine
Description : Although — NH2 gp is an ortho and para directing gp, nitration of aniline gives along with ortho and para, meta derivatives also.
Last Answer : Nitration is carried out with a mixture of Conc. NO3 + Conc. H2 SO4 (nitrating mix). In the presence of these acids, most of aniline gets protonated to form anilinium ion. Therefore, in the ... is m-directing and deactivating hence a mixture of all three-ortho, para and meta derivatives is formed.
Description : Which of the following acid-derivatives are most stable? (a) Acid chlorides (b) Esters (c) Amides (d) Anhydrides
Last Answer : Amides
Description : What is the hybridization and geometry of the carbonyl carbon in carboxylic acids and their derivatives? (a) sp3, tetrahedral (b) sp2, trigonal planar (c) sp2, tetrahedral (d) sp3, trigonal planar
Last Answer : sp2, trigonal planar
Description : Why the presence of a base is essential in the ammonolysis of alkyl halides ?
Last Answer : During ammonolysis of alkyl halides, the acid liberated during the reaction combines with the amine formed to form amine salt. To liberate free amine from the amine salt, a base is needed.
Description : When ammonia is added to an alkyl halide, in the presence of base : (a) primary amines form (b) amides form (c) nitrated alkyl halides form (d) quaternary ammonium salts form
Last Answer : primary amines form
Description : Aryl halides are less reactive towards nucleophilic substitution as compared to alkyl halides due to (a) Inductive effect (b) Resonance stabilization (c) Tautomerism (d) Stereoisomerism
Last Answer : Resonance stabilization
Description : Which of the following is not a correct statement concerning the FriedelCrafts acylation of benzene? (a) An alkyl group substitutes for a hydrogen. (b) The benzene ring attacks an acylium ion. (c) The acylium ion is resonance stabilized. (d) The acylium ion is often produced from an acyl chloride.
Last Answer : An alkyl group substitutes for a hydrogen
Description : Alkyl halides react with ammonia in the presence of base to form : (a) primary amines (b) nitrated alkyl halides (c) amides (d) quaternary ammonium salts
Last Answer : primary amines
Description : . Hunsdiecker reaction is used for the preparation of (a) Alkyl chlorides and bromides (b) Alkyl nitrates and nitrites (c) Ketenes (d) Alcohols
Last Answer : Alkyl chlorides and bromides
Description : Which reaction does not yield an ester as one of the products? (a) A carboxylic acid is heated with an alcohol (b) A Grignard reagent is added to a carboxylic acid (c) An acid halide is treated with an alcohol (d) An alkyl halide is heated with the salt of a carboxylic acid
Last Answer : A Grignard reagent is added to a carboxylic acid
Description : The reaction of a sodium alkoxide with an alkyl halide is called (a) Wurtz-Fittig reaction (b) Perkin reaction (c) Williamson's synthesis (d) Aldol condensation
Last Answer : Williamson's synthesis
Description : Grignard reagents do not show any reaction with (a) Alkoxyalkanes (b) Alkanones (c) Alkyl alkanoates (d) Acyl halides
Last Answer : Alkoxyalkanes
Description : Which of the alkyl chlorides listed below undergoes dehydrohalogenation in the presence of a strong base to give 2-pentene as the only alkene product? (a) 1-chloropentane (b) 2-chloropentane (c) 3-chloropentane (d) 1-chloro-2-methylbutane
Last Answer : 3-chloropentane
Description : Which is the most reactive alkyl halide in a SN1 reaction? (a) CH3F (b) CH3Br (c) CH3I (d) CH3Cl
Last Answer : CH3I
Description : Which of the following factors has no effect on the rate of SN1 reactions? (a) the nature of the alkyl halide (b) the nature of the leaving group (c) the concentration of the alkyl halide (d) the concentration of the nucleophile
Last Answer : the concentration of the nucleophile
Description : Which of the following is the rate law for SN1 mechanisms? (a) Rate = k[Alkyl Halide] [Nucleophile] (b) Rate = k[Nucleophile] (c) Rate = k[Alkyl Halide] (d) Rate = k1[Alkyl Halide] + k2[Nucleophile]
Last Answer : Rate = k[Alkyl Halide]
Description : Which of the following statements concerning SN2 reactions of alkyl halides is not correct? (a) The rate of reaction depends on the concentration of the nucleophile. (b) The rate of reaction depends on the ... carbon of the C-Br bond. (d) All alkyl iodides react more rapidly than all alkyl chlorides
Last Answer : All alkyl iodides react more rapidly than all alkyl chlorides
Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)
Last Answer : (a) and (b)
Description : How should CH3CHClCH2CH3 be classified? (a) primary alkyl halide (b) secondary alkyl halide (c) tertiary alkyl halide (d) quarternary alkyl halide
Last Answer : secondary alkyl halide
Description : Which of the following is a secondary alkyl halide? (a) CH3Br (b) (CH3)3CBr (c) (CH3)2CHBr (d) (CH3)2CHCH2Br
Last Answer : (CH3)2CHBr
Description : Which of the following best describes the carbon-chlorine bond of an alkyl chloride? (a) nonpolar; no dipole (b) polar; δ+ at carbon and δ– at chlorine (c) polar; δ– at carbon and δ+ at chlorine (d) ionic
Last Answer : polar; δ+ at carbon and δ– at chlorine
Description : There are 8 isomers that have the molecular formula C5H11Br. How many of these are tertiary alkyl bromides? (a) 1 (b) 2 (c) 3 (d) 8
Last Answer : 1
Description : Which of the following factors influence whether a reaction will proceed by an SN1, SN2, E1, or E2 mechanism? (a) Structure of the alkyl halide (b) Solvent (c) Concentration of reagents (d) Nature of the nucleophile (e) All of these
Last Answer : All of these
Description : Which alkyl halides react most readily by nucleophilic substitution? (a) CH3CH2Cl (b) CH3CH2I (c) CH3CH2Br (d) CH3CH2F
Last Answer : CH3CH2I
Description : Alkyl halides undergo (a) Electrophilic substitution reactions (b) Electrophilic addition reactions (c) Nucleophilic substitution reactions (d) Nucleophilic addition reactions
Last Answer : Nucleophilic substitution reactions
Description : Which of the following reagents cannot be used to prepare an alkyl chloride from an alcohol? (a) HCl + ZnCl2 (b) SOCl2 (c) NaCl (d) PCl5
Last Answer : NaCl
Description : Which of the following has two equatorial alkyl substituents in its most stable conformation? (a) 1,1-dimethylcyclohexane (b) cis-1,2-dimethylcyclohexane (c) cis-1,3-diethylcyclohexane (d) cis-1,4-diethylcyclohexane
Last Answer : cis-1,3-diethylcyclohexane
Description : 2-Methyl-2-butene reacts with HBr in the presence of peroxide to give (a) A primary alkyl bromide (b) A secondary alkyl bromide (c) A tertiary alkyl bromide (d) A vicinal dibromide
Last Answer : A secondary alkyl bromide
Description : 2-Methylpropene reacts with HBr in the presence of peroxide to give (a) A primary alkyl bromide (b) A secondary alkyl bromide (c) A tertiary alkyl bromide (d) A vicinal dibromide
Last Answer : A primary alkyl bromide
Description : The major carbon compound formed from the incomplete combustion of a hydrocarbon in air is (a) carbon dioxide (b) carbon monoxide (c) water (d) alkyl chains
Last Answer : carbon monoxide
Description : What type of an alkyl group is an isobutyl group? (a) primary (b) secondary (c) tertiary (d) none of these
Last Answer : none of these
Description : Alkyl cyanide on reduction gives….. a. primary amine b. secondary amine c. amide d. carboxylic acid
Last Answer : a. primary amine
Description : In an alkyl halide substitution of hydrogen by deuterium results in slow formation of ion pair. This is known as? a. Ortho effect b. Mesomeric effect c. Secondary kinetic isotope effect d. Primary kinetic isotope effect
Last Answer : c. Secondary kinetic isotope effect
Description : What class of organic compounds is characterized by an -OH group bonded to an alkyl group?
Last Answer : ANSWER: ALCOHOL
Description : What is a halogen element ?
Last Answer : The cunt elements in the seventh class of the periodic table (16th class according to the modern periodic table) are called halogen.
Description : (3) They are not easily combustible Explanation: Typical organic compounds are combustible by nature as they contain carbon. Organic compounds mostly consist of carbon, hydrogen, halogen, and phosphorus.
Last Answer : Which of the process is known as nitrification? (1) Reaction of Nitrogen Monoxide with oxygen to form nitric acid (2) Reaction of nitrogen dioxide with water to form nitric acid (3) Conversion of ammonia to nitrites (4) Conversion of nitrite to nitric oxide
Description : An element with an atomic number of 17 is - (1) an alkali metal (2) a rare gas (3) a halogen gas (4) a transition metal
Last Answer : (3) a halogen gas Explanation: Chlorine has atomic number of 17. It is a halogen gas along with fluorine (F), bromine (Br), iodine (I), and astatine (At).
Description : Which of the following reagents will replace –OH group by a halogen atom? (a) HOCl (b) Br2 (c) SOCl2 (d) I2
Last Answer : SOCl2
Description : Which halogen does not appreciably react with methane in a free-radical substitution reaction? (a) chlorine (b) bromine (c) iodine (d) fluorine
Last Answer : iodine
Description : Carboxylic acid reacts with halogen in presence of red P to gives__________ a) α-halogen acids b) β-halogen acid c) Acid halide d) Dicarboxylic acid
Last Answer : a) α-halogen acids
Description : Within a given period of the periodic table, the element with the lowest ionization energy is: w) transition metal x) alkali metal y) halogen z) noble gas
Last Answer : ANSWER: X -- ALKALI METAL
Description : What halogen is a liquid at room temperature?
Last Answer : ANSWER: BROMINE
Description : I will be describing a chemical element. Try to identify it with the fewest number of clues. This element is a halogen wh is a liquid at standard conditions. The element volatilizes readily at ro ... . The atomic number of this element is 35 and its chemical symbol is Br. Name this element.