The rate of a homogeneous reaction is a function of (A) Temperature and pressure only(B) Temperature and composition only(C) Pressure and composition only(D) All temperature, pressure and composition

The rate of a homogeneous reaction is a function of
(A) Temperature and pressure only
(B) Temperature and composition only
(C) Pressure and composition only
(D) All temperature, pressure and composition
by

1 Answer

Answer :

(D) All temperature, pressure and composition
by

Related questions

Variables affecting the rate of homogeneous reactions are (A) Pressure and temperature only (B) Temperature and composition only (C) Pressure and composition only (D) Pressure, temperature and composition

Description : Variables affecting the rate of homogeneous reactions are (A) Pressure and temperature only (B) Temperature and composition only (C) Pressure and composition only (D) Pressure, temperature and composition

Last Answer : (D) Pressure, temperature and composition

Rate of an autocatalytic chemical reaction is a function of (A) Temperature only (B) Pressure only (C) Composition only (D) All (A), (B) and (C)

Description : Rate of an autocatalytic chemical reaction is a function of (A) Temperature only (B) Pressure only (C) Composition only (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

In a homogeneous solution, the activity co-efficient of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Description : In a homogeneous solution, the activity co-efficient of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

In a homogeneous solution, the fugacity of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Description : In a homogeneous solution, the fugacity of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Chemical reaction rate of a component depends upon the (A) Composition of the component only (B) Temperature of the system (C) Pressure of the system (D) All (A), (B) and (C)

Description : Chemical reaction rate of a component depends upon the (A) Composition of the component only (B) Temperature of the system (C) Pressure of the system (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of (A) Temperature only (B) Temperature and pressure only (C) Temperature, pressure and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Description : A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co- ... and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Last Answer : (C) Temperature, pressure and liquid composition xi only

The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of (A) T (B) T and P (C) T, P and Z (D) T and Z

Description : The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of (A) T (B) T and P (C) T, P and Z (D) T and Z

Last Answer : (B) T and P

Pick out the wrong statement. (A) The integral method of analysing kinetic data is used when the data is scattered (B) The differential method of analysing kinetic data requires more accurate or larger amounts of data (C) When the reaction rate is independent of temperature, the reaction is said to be of zero order (D) The ratio of volumes of plug flow reactor to that of mixed reactor is always less than one for identical feed composition, flow rate, conversion and for all positive reaction orders

Description : Pick out the wrong statement. (A) The integral method of analysing kinetic data is used when the data is scattered (B) The differential method of analysing kinetic data requires more accurate ... less than one for identical feed composition, flow rate, conversion and for all positive reaction orders

Last Answer : (C) When the reaction rate is independent of temperature, the reaction is said to be of zero order

Which of the following is a controlling factor in very fast heterogeneous reaction? (A) Heat and mass transfer effects (B) Pressure (C) Temperature (D) Composition of reactant

Description : Which of the following is a controlling factor in very fast heterogeneous reaction? (A) Heat and mass transfer effects (B) Pressure (C) Temperature (D) Composition of reactant

Last Answer : (A) Heat and mass transfer effects

The standard Gibbs free energy change of a reaction depends on the equilibrium (A) Pressure (B) Temperature (C) Composition (D) All (A), (B) and (C)

Description : The standard Gibbs free energy change of a reaction depends on the equilibrium (A) Pressure (B) Temperature (C) Composition (D) All (A), (B) and (C)

Last Answer : (B) Temperature

A substance that has a fixed chemical composition is known as ______ substance.  A. Monoatomic  B. Heterogeneous  C. Homogeneous  D. Pure

Description : A substance that has a fixed chemical composition is known as ______ substance.  A. Monoatomic  B. Heterogeneous  C. Homogeneous  D. Pure

Last Answer : Pure

During metamorphonism, changes in the bulk composition of a rock occur primarily as a result of _____? a) Increase in pressure b) Increases in temperature c) Reaction with hydrothermal fluids d) All of these

Description : During metamorphonism, changes in the bulk composition of a rock occur primarily as a result of _____? a) Increase in pressure b) Increases in temperature c) Reaction with hydrothermal fluids d) All of these

Last Answer : Increase in pressure

Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature __________ as its mole fraction increases. (A) Decreases (B) Decreases exponentially (C) Increases (D) Remain constant

Description : Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and ... increases. (A) Decreases (B) Decreases exponentially (C) Increases (D) Remain constant

Last Answer : (C) Increases

Gibbs-Duhem equation (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure (B) Applies only to binary systems (C) Finds no application in gas-liquid equilibria involved in distillation (D) None of these

Description : Gibbs-Duhem equation (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure (B) Applies only to binary systems (C) Finds no application in gas-liquid equilibria involved in distillation (D) None of these

Last Answer : (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure

The ratio of volume of mixed reactor to the volume of P.F.R. (for identical flow rate, feed composition and conversion) for zero order reaction is: (A) ∞(B) 0 (C) 1 (D) > 1

Description : The ratio of volume of mixed reactor to the volume of P.F.R. (for identical flow rate, feed composition and conversion) for zero order reaction is: (A) ∞ (B) 0 (C) 1 (D) > 1

Last Answer : (C) 1

With increase in the order of reaction (for all positive reaction orders), the ratio of the volume of mixed reactor to the volume of plug flow reactor (for identical feed composition, flow rate and conversion). (A) Increases (B) Decreases (C) Remain same (D) Increases linearly

Description : With increase in the order of reaction (for all positive reaction orders), the ratio of the volume of mixed reactor to the volume of plug flow reactor (for identical feed composition, flow rate and conversion). (A) Increases (B) Decreases (C) Remain same (D) Increases linearly

Last Answer : (A) Increases

Pick out the correct statement. (A) A catalyst speeds up the forward reaction but slows shown the reverse reaction (B) Addition of catalyst changes the equilibrium constant (C) Pressure changes do not change the equilibrium concentrations (D) The composition of equilibrium is changed by catalyst

Description : Pick out the correct statement. (A) A catalyst speeds up the forward reaction but slows shown the reverse reaction (B) Addition of catalyst changes the equilibrium constant (C) Pressure changes do not change the equilibrium concentrations (D) The composition of equilibrium is changed by catalyst

Last Answer : (C) Pressure changes do not change the equilibrium concentrations

A plug-flow reactor is characterised by (A) High capacity (B) Presence of axial mixing (C) Presence of lateral mixing (D) Constant composition and temperature of reaction mixture

Description : A plug-flow reactor is characterised by (A) High capacity (B) Presence of axial mixing (C) Presence of lateral mixing (D) Constant composition and temperature of reaction mixture

Last Answer : (C) Presence of lateral mixing

When dilute aqueous solutions of two salts are mixed, the process is associated with (A) Decrease in temperature (B) Increase in temperature (C) No change in temperature (D) Change in temperature which is a function of composition

Description : When dilute aqueous solutions of two salts are mixed, the process is associated with (A) Decrease in temperature (B) Increase in temperature (C) No change in temperature (D) Change in temperature which is a function of composition

Last Answer : B) Increase in temperature

In chamber process of sulphuric acid manufacture in industry, the gas phase oxidation of SO2 to SO3 is accomplished by a __________ reaction. (A) Non-catalytic homogeneous (B) Non-catalytic heterogeneous (C) Catalytic homogenous (D) Catalytic heterogeneous

Description : In chamber process of sulphuric acid manufacture in industry, the gas phase oxidation of SO2 to SO3 is accomplished by a __________ reaction. (A) Non-catalytic homogeneous (B) Non-catalytic heterogeneous (C) Catalytic homogenous (D) Catalytic heterogeneous

Last Answer : (C) Catalytic homogenous

__________ catalytic reaction is involved in the thermal cracking of gas oil. (A) Homogeneous (B) Non-Homogeneous (C) Heterogeneous (D) Non-Heterogeneous

Description : __________ catalytic reaction is involved in the thermal cracking of gas oil. (A) Homogeneous (B) Non-Homogeneous (C) Heterogeneous (D) Non-Heterogeneous

Last Answer : (A) Homogeneous

Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is nonlinear in the case of steady state unimolal unidirectional diffusion (C) Azeotropes obey Raoult's law at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1

Description : Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial ... at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1

Last Answer : (C) Azeotropes obey Raoult's law at all temperature

Pick out the wrong statement. (A) Constant pressure distillation cannot separate an Azeotropic mixture (B) Relative volatility of a binary mixture changes appreciably with the minor change in temperature (C) The relative volatility of a binary mixture at Azeotropic composition is unity (D) Flash distillation is practised on wide spread scale in petroleum refinery

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Last Answer : (B) Relative volatility of a binary mixture changes appreciably with the minor change in temperature

The dew point of an unsaturated gas-vapor mixture does not depend upon the __________ of the mixture. (A) Composition (B) Temperature (C) Total pressure (D) All (A), (B) and (C)

Description : The dew point of an unsaturated gas-vapor mixture does not depend upon the __________ of the mixture. (A) Composition (B) Temperature (C) Total pressure (D) All (A), (B) and (C)

Last Answer : (B) Temperature

The composition of fresh feed to the high temperature, high pressure urea autoclave is (A) Excess liquid ammonia and liquefied CO2 (B) Excess liquid ammonia and compressed CO2 gas (C) Liquid ammonia and excess compressed CO2 (D) Compressed ammonia gas and excess compressed CO2

Description : The composition of fresh feed to the high temperature, high pressure urea autoclave is (A) Excess liquid ammonia and liquefied CO2 (B) Excess liquid ammonia and compressed CO2 gas (C) Liquid ammonia and excess compressed CO2 (D) Compressed ammonia gas and excess compressed CO2

Last Answer : (B) Excess liquid ammonia and compressed CO2 gas

Pick out the wrong statement. (A) In a batch reactor, which is exclusively used for liquid phase reactions; temperature pressure and composition may vary with time (B) In a semi-batch reactor, one reactant is charged batch wise, while the other reactant is fed continuously (C) In a continuous flow reactor, uniform concentration cannot be maintained throughout the vessel even in a well agitated system (D) In a continuous flow reactor, both the reactants and the products flow out continuously

Description : Pick out the wrong statement. (A) In a batch reactor, which is exclusively used for liquid phase reactions; temperature pressure and composition may vary with time (B) In a semi-batch reactor, ... system (D) In a continuous flow reactor, both the reactants and the products flow out continuously

Last Answer : (C) In a continuous flow reactor, uniform concentration cannot be maintained throughout the vessel even in a well agitated system

The relation connecting the fugacities of various components in a solution with one another and to composition at constant temperature and pressure is called the __________ equation. (A) Gibbs-Duhem (B) Van Laar (C) Gibbs-Helmholtz (D) Margules

Description : The relation connecting the fugacities of various components in a solution with one another and to composition at constant temperature and pressure is called the __________ equation. (A) Gibbs-Duhem (B) Van Laar (C) Gibbs-Helmholtz (D) Margules

Last Answer : (A) Gibbs-Duhem

The chemical potential of any constituent of an ideal solution depends on the __________ of the solution. (A) Temperature (B) Pressure (C) Composition (D) All (A), (B) and (C)

Description : The chemical potential of any constituent of an ideal solution depends on the __________ of the solution. (A) Temperature (B) Pressure (C) Composition (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)

Description : Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)

Last Answer : (D) All (A), (B), and (C)

Critical solution temperature (or the con-solute temperature) for partially miscible liquids (e.g., phenol-water) is the minimum temperature at which (A) A homogeneous solution (say of phenol water) is formed (B) Mutual solubility of the two liquids shows a decreasing trend (C) Two liquids are completely separated into two layers (D) None of these

Description : Critical solution temperature (or the con-solute temperature) for partially miscible liquids (e.g., phenol-water) is the minimum temperature at which (A) A homogeneous solution (say of phenol water) is ... a decreasing trend (C) Two liquids are completely separated into two layers (D) None of these

Last Answer : (A) A homogeneous solution (say of phenol water) is formed

The rate constant of a reaction is a function of the (A) Time of reaction (B) Temperature of the system (C) Extent of reaction (D) Initial concentration of the reactants

Description : The rate constant of a reaction is a function of the (A) Time of reaction (B) Temperature of the system (C) Extent of reaction (D) Initial concentration of the reactants

Last Answer : (B) Temperature of the system

In Dumas’ method for estimation of nitrogen, 0.3g of an organic compound gave 50mL of nitrogen collected at 300K temperature and 715mm pressure. Calculate the percentage composition of nitrogen in the compound. (Aqueous tension at 300K=15 mm).

Description : In Dumas’ method for estimation of nitrogen, 0.3g of an organic compound gave 50mL of nitrogen collected at 300K temperature and 715mm pressure. Calculate the percentage composition of nitrogen in the compound. (Aqueous tension at 300K=15 mm).

Last Answer : Volume of nitrogen collected at 300K and 715mm pressure is 50 mL Actual pressure = 715-15 =700 mm Volume of Nitrogen at STP=273*700*50/300*760 =41.9 ml 22400 ml of Nitrogen at STP weighs = 28 g 41.9 ml of Nitrogen weighs = 28*41.9/22400 g % of Nitrogen = 28*41.9*100/22400*0.3 = 17.45 %

Resistivity of conductors is most affected by (A) composition. (B) temperature. (C) pressure. (D) current.

Description : Resistivity of conductors is most affected by (A) composition. (B) temperature. (C) pressure. (D) current.

Last Answer : (B) temperature.

Pick out the correct statement. (A) Reaction of NH3 with HNO3 to produce (NH4 )2NO3 is endothermic (B) With increase in NH3 /CO2 ratio, urea yield decreases for a given temperature, pressure and total feed rate (C) Biuret (an intermediate during urea manufacture) is toxic to seeds and animals (D) Both (B) and (C)

Description : Pick out the correct statement. (A) Reaction of NH3 with HNO3 to produce (NH4 )2NO3 is endothermic (B) With increase in NH3 /CO2 ratio, urea yield decreases for a given temperature, pressure and total ... (an intermediate during urea manufacture) is toxic to seeds and animals (D) Both (B) and (C)

Last Answer : (B) With increase in NH3 /CO2 ratio, urea yield decreases for a given temperature, pressure and total feed rate

Though kinetics of ammonia synthesis dictates the use of low temperature for high equilibrium conversion, yet it is kept moderately high (550°C), because at low temperature (A) Rate of reaction is very low (B) Very high pressure is required resulting in costly pressure vessel (C) Space velocity of gas is very low resulting in decreased conversion (D) None of these

Description : Though kinetics of ammonia synthesis dictates the use of low temperature for high equilibrium conversion, yet it is kept moderately high (550°C), because at low temperature (A) Rate of reaction is very low ... (C) Space velocity of gas is very low resulting in decreased conversion (D) None of these

Last Answer : (A) Rate of reaction is very low

The units of frequency factor in Arrhenius equation (A) Are the same as those of the rate constant (B) Depend on the order of the reaction (C) Depend on temperature, pressure etc. of the reaction (D) Are cycles per unit time

Description : The units of frequency factor in Arrhenius equation (A) Are the same as those of the rate constant (B) Depend on the order of the reaction (C) Depend on temperature, pressure etc. of the reaction (D) Are cycles per unit time

Last Answer : (A) Are the same as those of the rate constant

The rate constant of a chemical reaction decreases by decreasing the (A) Pressure (B) Concentration of reactants (C) Temperature (D) Duration of reaction

Description : The rate constant of a chemical reaction decreases by decreasing the (A) Pressure (B) Concentration of reactants (C) Temperature (D) Duration of reaction

Last Answer : (C) Temperature

Which of the following does not produce a change in the value of rate constant of a reaction? (A) Pressure (B) Temperature (C) Concentration and catalyst (D) None of these

Description : Which of the following does not produce a change in the value of rate constant of a reaction? (A) Pressure (B) Temperature (C) Concentration and catalyst (D) None of these

Last Answer : (C) Concentration and catalyst

Mean residence time is equal to the space time, when (A) The feed rate is measured at temperature and pressure in the reactor (B) The temperature, pressure and the density of reaction mixture remains constant throughout the reactor (C) There is no change in number of moles in gaseous reaction (D) All (A), (B) and (C)

Description : Mean residence time is equal to the space time, when (A) The feed rate is measured at temperature and pressure in the reactor (B) The temperature, pressure and the density of reaction mixture remains constant throughout ... no change in number of moles in gaseous reaction (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

The rate constant of a chemical reaction increases by increasing the (A) Temperature (B) Pressure (C) Reactant's concentration (D) None of these

Description : The rate constant of a chemical reaction increases by increasing the (A) Temperature (B) Pressure (C) Reactant's concentration (D) None of these

Last Answer : (A) Temperature

Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to iron catalyst in ammonia synthesis reaction (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction

Description : Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to ... Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction

Last Answer : (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot

Pick out the wrong statement. (A) A catalyst does not alter the final position of equilibrium in a reversible reaction (B) A catalyst initiates a reaction (C) A catalyst is specific in reaction (D) A catalyst remains unchanged in chemical composition at the end the reaction

Description : Pick out the wrong statement. (A) A catalyst does not alter the final position of equilibrium in a reversible reaction (B) A catalyst initiates a reaction (C) A catalyst is specific in reaction (D) A catalyst remains unchanged in chemical composition at the end the reaction

Last Answer : (B) A catalyst initiates a reaction

Which of the following is not fixed by the process requirements, in the design of absorbers? (A) Flow rate of the entering gas (B) Composition of the entering liquid (C) Terminal concentrations of gas stream (D) None of these

Description : Which of the following is not fixed by the process requirements, in the design of absorbers? (A) Flow rate of the entering gas (B) Composition of the entering liquid (C) Terminal concentrations of gas stream (D) None of these

Last Answer : (D) None of these

In a continuous flow stirred tank reactor, the composition of the exit stream (A) Is same as that in the reactor (B) Is different than that in the reactor (C) Depends upon the flow rate of inlet stream (D) None of these

Description : In a continuous flow stirred tank reactor, the composition of the exit stream (A) Is same as that in the reactor (B) Is different than that in the reactor (C) Depends upon the flow rate of inlet stream (D) None of these

Last Answer : (A) Is same as that in the reactor

For identical flow rate and feed composition, X plug flow reactors (PER) in series with a total volume V gives the same conversion as single (A) CSTR of volume V (B) PFR of volume V (C) CSTR of volume V/X (D) PFR of volume V/X

Description : For identical flow rate and feed composition, X plug flow reactors (PER) in series with a total volume V gives the same conversion as single (A) CSTR of volume V (B) PFR of volume V (C) CSTR of volume V/X (D) PFR of volume V/X

Last Answer : (B) PFR of volume V

A pycnometer is used for the measurement of (A) Flow rate of molten metal (B) Specific gravity of a liquid (C) Composition of alloys (D) Concentration of a solution

Description : A pycnometer is used for the measurement of (A) Flow rate of molten metal (B) Specific gravity of a liquid (C) Composition of alloys (D) Concentration of a solution

Last Answer : Option B

For a homogeneous & isotropic body under hydrostatic pressure, which theory of elastic failure does not fail (a) Firstly Maximum Principal Theory (b) Secondly Maximum Shear Stress Theory (c) Thirdly Maximum Principal Energy Theory (d) None

Description : For a homogeneous & isotropic body under hydrostatic pressure, which theory of elastic failure does not fail (a) Firstly Maximum Principal Theory (b) Secondly Maximum Shear Stress Theory (c) Thirdly Maximum Principal Energy Theory (d) None

Last Answer : (a) Firstly Maximum Principal Theory

For a homogeneous & isotropic body under hydrostatic pressure, which theory of elastic failure fails (a) Firstly Maximum Principal Theory (b) Secondly Maximum Principal strain Theory (c) Thirdly Maximum Principal Energy Theory (d) None

Description : For a homogeneous & isotropic body under hydrostatic pressure, which theory of elastic failure fails (a) Firstly Maximum Principal Theory (b) Secondly Maximum Principal strain Theory (c) Thirdly Maximum Principal Energy Theory (d) None

Last Answer : (c) Thirdly Maximum Principal Energy Theory

Coulomb's wedge theory assumes that (A) Back fill is dry, cohesionless, homogeneous and isotropic (B) Slip surface is the plane which passes through the heel of the wall (C) Position and direction of the resultant earth pressure are known (D) All the above

Description : Coulomb's wedge theory assumes that (A) Back fill is dry, cohesionless, homogeneous and isotropic (B) Slip surface is the plane which passes through the heel of the wall (C) Position and direction of the resultant earth pressure are known (D) All the above

Last Answer : (D) All the above