Description : At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm. ... (B) μ°+ R ln f (C) μ° + T ln f (D) μ° + R/T ln f
Last Answer : (A) μ° + RT ln f
Description : The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1is the activity co-efficient of component 1, is (A) A . x22 (B) Ax1 (C) Ax2 (D) Ax12
Last Answer : (A) A . x22
Description : For an ideal gas, the chemical potential is given by (A) RT d ln P (B) R d ln P (C) R d ln f (D) None of these
Last Answer : (A) RT d ln P
Description : For a real gas, the chemical potential is given by (A) RT d ln P (B) RT d ln f (C) R d ln f (D) None of these
Last Answer : (B) RT d ln f
Description : Pick out the Clausius-Clapeyron equation from the following: (A) dP/dT = ∆H/T∆V (B) ln P = - (∆H/RT) + constant (C) ∆F = ∆H + T [∂(∆F)/∂T]P (D) None of these
Last Answer : B) ln P = - (∆H/RT) + constant
Description : According to Arrhenius equation of temperature dependency of rate constant for an elementary reaction (A) k ∝ √T (B) k ∝ e -E/RT (C) k ∝ T e -E/RT (D) None of these
Last Answer : (B) k ∝ e -E/RT
Description : The rate expression for a heterogeneous catalytic reaction is given by, - rA = K.KA PA(1 + KA.PA + KR.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR ... R and A) (A) E (B) E + ΔHA (C) E + ΔHA - ΔHR ) (D) ΔHA + ΔHR
Last Answer : (C) E + ΔHA - ΔHR )
Description : Concentration of the limiting reactant (with initial concentration of a moles/litre) after time t is (a-x). Then 't' for a first order reaction is given by (A) k. t = ln a/(a - x) (B) k. t = x/a (a - x) (C) k. t = ln (a - x)/a (D) k. t = ln a (a - x)/x
Last Answer : (A) k. t = ln a/(a - x)
Description : Helium ( R= 0.4698 BTU/lbm-˚R ) is compressed isothermally from 14.7 psia and 68 ˚F. The compression ratio is 1:4. Calculate the work done by the gas. A. –1454 BTU/lbm B. -364 BTU/lbm C.-187BTU/lbm D.46.7 BTU/lbm Formula: W = RT ln (V2/V1)
Last Answer : -364 BTU/lbm
Description : What is the equation for the work done by a constant temperature system? A. W = mRTln(V2-V1) B. W = mR( T2-T1 ) ln( V2/V1) C. W = mRTln (V2/V1) D. W = RT ln (V2/V1) Formula : W=∫ pdV lim1,2 ∫ = mRT / V
Last Answer : W = mRTln (V2/V1)
Description : Rate constant 'k' and absolute temperature 'T' are related by collision theory (for bimolecular) as (A) k ∝ T 1.5 (B) k ∝ exp(-E/RT) (C) k ∝ √T (D) k ∝ T
Last Answer : (C) k ∝ √T
Description : Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the ... ) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions
Last Answer : (C) The intercept of the Arrhenius plot is called the 'activation energy
Description : The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n octane into pure compounds each at 1 atm is (A) -2 RT ln 0.5 (B) -RT ln 0.5 (C) 0.5 RT (D) 2 RT
Last Answer : (B) -RT ln 0.5
Description : The equilibrium constant for a chemical reaction at two different temperatures is given by (A) Kp2/Kp1 = - (∆H/R) (1/T2- 1/T1) (B) Kp2/Kp1 = (∆H/R) (1/T2- 1/T1) (C) Kp2/Kp1 = ∆H (1/T2- 1/T1) (D) Kp2/Kp1 = - (1/R) (1/T2- 1/T1)
Last Answer : (A) Kp2/Kp1 = - (∆H/R) (1/T2- 1/T1)
Description : Collision theory gives the rate constant for bimolecular reaction as (A) K α √T.e -E/RT (B) K α e E/RT (C) K α e -E/RT (D) None of these
Last Answer : (C) K α e -E/RT
Description : The free energy change, AG (A) Is directly proportional to the standard free energy change, AG (B) Is equal to zero at equilibrium (C) Can only be calculated when the reactants and products are present at 1mol/1 concentrations (D) Is equal to –RT in keq
Last Answer : B
Description : From collision theory, the reaction rate constant is proportional to (A) exp (-E/RT) (B) exp (-E/2RT) (C) √T (D) T m exp (-E/RT)
Last Answer : (D) T m exp (-E/RT)
Description : The expression, ∆G = nRT. ln(P2/P1), gives the free energy change (A) With pressure changes at constant temperature (B) Under reversible isothermal volume change (C) During heating of an ideal gas (D) During cooling of an ideal gas
Last Answer : (A) With pressure changes at constant temperature
Description : The equilibrium constant ‘K’ of a chemical reaction depends on (A) Temperature only (B) Pressure only (C) Temperature and pressure (D) Ratio of reactants
Last Answer : (A) Temperature only
Description : The role of a catalyst in a chemical reaction is to change the (A) Equilibrium constant (B) Activation energy (C) Final products (D) Heat of reaction
Last Answer : (B) Activation energy
Description : Catalytic action in a catalytic chemical reaction follows from the ability of catalyst to change the (A) Activation energy (B) Equilibrium constant (C) Heat of reaction (D) None of these
Last Answer : (A) Activation energy
Description : . Which of the following equations is Rittinger's crushing law? (Where P = power required by the machine, m = feed rate, k = a constant, Ds̅a & D̅sb = volume surface mean diameter of feed & product respectively.) (A) P/m = K/ ... K . ln D̅sa /D̅sb (C) P/m = K . (1/ D̅sb - 1/Ds̅a ) (D) None of these
Last Answer : (C) P/m = K . (1/ D̅sb - 1/Ds̅a )
Description : The compressibility factor, x, is used for predicting the behavior of nonideal gases. How is the compressibility ty factor defined relative to an ideal gas? (subscript c refers to critical value) A. ... compressibility factor, x, is an dimensionless constant given by pV=zRT. Therefore z = pV / RT
Last Answer : z = pV/ RT
Description : Transition state theory relates the above quantities as (A) k ∝ e -E/RT (B) k ∝ T.e E/RT (C) k ∝ √T (D) k ∝ T 1.5
Last Answer : (B) k ∝ T.e E/RT
Description : Half life period of a first order irreversible reaction A → B is (A) k/2 (B) ln k/2 (C) ln 2/k (D) ln 0.5/k
Last Answer : (C) ln 2/k
Description : Higher free energy of activation of a chemical reaction (at a given temperature) implies (A) Slower rate of reaction (B) Higher rate of reaction (C) Higher equilibrium conversion (D) Both (B) and (C)
Last Answer : (A) Slower rate of reaction
Description : Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an ... does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature
Last Answer : (C) The rate constant for a first order reaction does not change on changing the concentration units
Description : The catalyst in a first order chemical reaction changes the (A) Equilibrium constant (B) Activation energy (C) Heat of formation of the product (D) Heat of reaction
Description : The unit of equilibrium constant of a chemical reaction is the same as that of (A) Molar concentration (B) Temperature (C) Internal energy (D) None of these
Last Answer : (D) None of these
Description : Pick out the correct statement. (A) Plastic chips are called non-cohesive solids (B) Kick's crushing law is, P/m = K . ln (D̅sa /Ds̅b ) (C) Communition is a generic term for size enlargement ... per ton of product, such that 80% of it passes through a 200 mesh screen, is called 'Work index'
Last Answer : (B) Kick's crushing law is, P/m = K . ln (D̅sa /Ds̅b )
Description : For the reversible reaction A ⇌ 2B, if the equilibrium constant K is 0.05 mole/litre; starting from initially 2 moles of A and zero moles of B, how many moles will be formed at equilibrium? (A) 0.253 (B) 0.338 (C) 0.152 (D) 0.637
Last Answer : (B) 0.338
Description : The thickness of oxide film is y at time t. If K1, K2 and K3 are the temperature dependent constants, the parabolic law of oxidation is given by (A) y2 = 2k1t + k2 (B) y = k1 ln (k2t + k3) (C) y = k1 t + k2 (D) y = k1t3 + k2
Last Answer : Option A
Description : Enzymes increases the rate of reactions by (A) Increasing the free energy of activation (B) Decreasing the energy of activation (C) Changing the equilibrium constant of the reaction (D) Increasing the free energy change of the reaction
Last Answer : Answer : B
Description : Enzymes increase the rates of reactions by (A) Increasing the free energy of activation (B) Decreasing the energy of activation (C) Changing the equilibrium constant of the reaction (D) Increasing the free energy change of the reaction
Description : Enzymes accelerate the rate of reactions by (A) Increasing the equilibrium constant of reactions (B) Increasing the energy of activation (C) Decreasing the energy of activation (D) Decreasing the free energy change of the reaction
Last Answer : Answer : C
Description : Arrhenius equation K = Ae-E a / R T In some reactions, Rate of reaction is directly proportional to. Concentration of catalyst Catalyst used in Bio-Chemical reactions is called. Enzymes Reactions catalyzed by light are called as. Photo catalyzed or Photosensitised reactions
Last Answer : Define order of reaction
Description : Out of the following four assumptions used in the derivation of theequation for LMTD [LMTD = (∆t1 - ∆t2 )/ln(∆t1 /∆t2 )], which one is subject to the largest deviation in practice ? (A) Constant ... (B) Constant rate of fluid flow (C) Constant specific heat (D) No partial phase change in the system
Last Answer : (B) Constant rate of fluid flow
Description : Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance ... temperature and pressure is (A) 0 (B) 1 (C) ∞ (D) None of these
Last Answer : (B) 1
Description : If air is at pressure, p, of 3200 lbf/ft2 , and at a temperature, T, of 800 ˚R, what is the specific volume, v? (R=5303 ft-lbf/lbm-˚R, and air can be modeled as an ideal gas.) A.9.8 ft^3/lbm B.11.2 ft^3/lbm C.13.33 ft^3/lbm D.14.2 ft^3/lbm Formula: pv = RT v = RT / p
Last Answer : 13.33 ft^3/lbm
Description : In the equation Pv = RT, the constant of proportionality R is known as ______. A. Universal gas constant B. Gas constant C. Ideal gas factor D. Gas index
Last Answer : Gas constant
Description : Which one of the following statements regarding a catalyst is not correct? A An enzyme is a catalyst that only binds certain substrates. B An enzyme is a protein that is a highly ... increasing the activation energy. D Catalysts do not alter the equilibrium constant for a chemical reaction.
Last Answer : C Catalysts increase the rate of a reaction by altering the mechanism, thereby increasing the activation energy.
Description : The relation among various mass transfer co-efficients (M.T.C) for ideal gases is given by (where, Kc & Km are M.T.C. for equimolar counter diffusion with concentration & mole fraction respectively as the driving ... (C) Kc = Kp . RT = Km . RT/p (D) None of these
Last Answer : (C) Kc = Kp . RT = Km . RT/p
Description : In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled, then the equilibrium constant will (A) Remain the same (B) Be halved (C) Also be doubled (D) Become one fourth
Last Answer : (A) Remain the same
Description : For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant (A) Is independent of pressure (B) Increases with pressure (C) Decreases with pressure (D) Increases /decreases with pressure depending on the stoichiometric coefficients of the reaction
Last Answer : (B) Increases with pressure
Description : Limiting reactant in a chemical reaction decides the (A) Rate constant (B) Conversion (C) Reaction speed (D) Equilibrium constant
Last Answer : (B) Conversion
Description : Catalyst is a substance, which __________ chemical reaction. (A) Increases the speed of a (B) Decreases the speed of a (C) Can either increase or decrease the speed of a (D) Alters the value of equilibrium constant in a reversible
Last Answer : (C) Can either increase or decrease the speed of a
Description : The equilibrium constant of a catalytic chemical reaction __________ due to the presence of a catalyst. (A) Increases (B) Decreases (C) Remain unaffected (D) Unpredictable from the data
Last Answer : (C) Remain unaffected
Description : The equilibrium constant of chemical reaction __________ in the presence of catalyst. (A) Increases (B) Decreases (C) Remain unaffected (D) Can either increase or decrease (depends on the type of catalyst)
Description : Two substances are in equilibrium in a reversible chemical reaction. If the concentration of each substance is doubled, then the value of the equilibrium constant will be (A) Same (B) Doubled (C) Halved (D) One fourth of its original value
Last Answer : (A) Same
Description : In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = ... any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'
Last Answer : D) All 'a', 'b' & 'c'