Considering the endothermic dissociation of CaCO3 in a closed vessel (CaCO3 ⇌ CaO + CO2 ), the pressure of CO2 increases, if (A) A catalyst is added (B) The temperature is increased (C) An inert gas is pumped keeping the temperature constant (D) None of these

Considering the endothermic dissociation of CaCO3
in a closed vessel
(CaCO3 ⇌ CaO + CO2
), the pressure of CO2
increases, if
(A) A catalyst is added
(B) The temperature is increased
(C) An inert gas is pumped keeping the temperature constant
(D) None of these
by

1 Answer

Answer :

(B) The temperature is increased
by

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Pick out the endothermic reaction out of the following. (A) C+ ½O2 = CO (B) CO + 3H2 = CH4 + H2O (C) CaCO3 = CaO + CO2 (D) CO + ½O2 = CO2

Description : Pick out the endothermic reaction out of the following. (A) C+ ½O2 = CO (B) CO + 3H2 = CH4 + H2O (C) CaCO3 = CaO + CO2 (D) CO + ½O2 = CO2

Last Answer : (C) CaCO3 = CaO + CO2

Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2.Degree of dissociation of PCl5 will (A) Decrease on addition of Cl2 (B) Increase on addition of an inert gas at constant pressure (C) Decrease on increasing the pressure of the system (D) None of these

Description : Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2.Degree of dissociation of PCl5 will (A) Decrease on addition of Cl2 (B) Increase on addition of ... at constant pressure (C) Decrease on increasing the pressure of the system (D) None of these

Last Answer : (D) None of thes

Calcination reaction of limestone (CaCO3 → CaO + CO2 ) goes to completion in the rotary kiln, because (A) CaO is not dissociated (B) CO2 escapes continuously (C) Of high calcination temperature (D) CaO is more stable than CaCO3

Description : Calcination reaction of limestone (CaCO3 → CaO + CO2 ) goes to completion in the rotary kiln, because (A) CaO is not dissociated (B) CO2 escapes continuously (C) Of high calcination temperature (D) CaO is more stable than CaCO3

Last Answer : (B) CO2 escapes continuously

In the reversible reaction of the type, A + B ⇌ AB, in general (A) Both forward and backward reactions will be exothermic (B) Neither of the reactions will be endothermic (C) The combination reaction will be exothermic, while the dissociation reaction will be endothermic (D) The combination reaction will be endothermic, while the dissociation reaction will be exothermic

Description : In the reversible reaction of the type, A + B ⇌ AB, in general (A) Both forward and backward reactions will be exothermic (B) Neither of the reactions will be endothermic (C) ... will be endothermic (D) The combination reaction will be endothermic, while the dissociation reaction will be exothermic

Last Answer : (C) The combination reaction will be exothermic, while the dissociation reaction will be endothermic

In case of calcination of limestone, CaCO3 CaO + CO2 , the addition of more of CaO will result in __________ in the concentration of CO2 . (A) No change (B) Increase (C) Decrease (D) Unpredictable from the data

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Last Answer : (A) No change

In multistage equilibrium conversion of SO2 to SO3 (2SO2 + O2 ⇌ 2SO3 ), the reverse reaction becomes appreciable at a temperature of 550° C. The percentage equilibrium conversion of SO2 to SO3 can be increased by (A) Increasing the oxygen concentration (B) Putting more quantity of V2O5 catalyst in the converter (C) Removing some quantity of SO3 during intermediate stage (D) Maintaining low temperature & pressure in the converter

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What will be the effect on equilibrium if (i) a catalyst is added to it (ii) An inert gas is added at constant volume

Description : What will be the effect on equilibrium if (i) a catalyst is added to it (ii) An inert gas is added at constant volume

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What happens to the dissociation of PCl5 in a closed vessel if He gas is introduced into it at the same temperature?

Description : What happens to the dissociation of PCl5 in a closed vessel if He gas is introduced into it at the same temperature?

Last Answer : Ans. No effect.

In the reaction, H2 +I2 ⇌ 2HI, addition of an inert gas will (A) Increase the partial pressure of H2 (B) Increase the partial pressure of I2 (C) Increase the total pressure and hence shift the equilibrium towards the right (D) Not affect the equilibrium conditions

Description : In the reaction, H2 +I2 ⇌ 2HI, addition of an inert gas will (A) Increase the partial pressure of H2 (B) Increase the partial pressure of I2 (C) Increase the total pressure and hence shift the equilibrium towards the right (D) Not affect the equilibrium conditions

Last Answer : (D) Not affect the equilibrium conditions Share

In the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2, decrease in the pressure of the system will __________ the degree of dissociation of PCl5. (A) Increase (B) Decrease (C) Not alter (D) None of these

Description : In the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2, decrease in the pressure of the system will __________ the degree of dissociation of PCl5. (A) Increase (B) Decrease (C) Not alter (D) None of these

Last Answer : (A) Increase

In case of the decomposition of hydroiodic acid (2HI ⇌ H2 + I2), addition of H2(at equilibrium condition) will (A) Increase the partial pressure of I2 (B) Decrease the partial pressure of HI (C) Diminish the degree of dissociation of HI (D) None of these

Description : In case of the decomposition of hydroiodic acid (2HI ⇌ H2 + I2), addition of H2(at equilibrium condition) will (A) Increase the partial pressure of I2 (B) Decrease the partial pressure of HI (C) Diminish the degree of dissociation of HI (D) None of these

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Last Answer : (A) Low temperature and high pressure

If helium is introduced in a reactor containing O2 , SO2 and SO3 at equilibrium, so that total pressure increases while volume and temperature remains constant. In this case the dissociation of SO3 (as per Le Chatelier's principle). (A) Decreases (B) Increases (C) Remains unaltered (D) Changes unpredictably

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The ammonia synthesis reaction represented by N2 + 3H2 ⇌ 2NH3; ΔH = - 22.4 kcal, is (A) Endothermic (B) Exothermic (C) Isothermal (D) Adiabatic

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During manufacture of H2SO4 , the oxidation of SO2 to SO3 by oxygen is an endothermic reaction. The yield of SO3 will be maximised, if the (A) Temperature is increased (B) Pressure is reduced (C) Temperature is increased and pressure is reduced (D) Temperature is reduced and pressure is increased

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Consider the reaction, C + O2 ⇌ CO2; ΔH = - 94 kcal. What will be the value of ΔH for the reaction CO2 → C + O2? (A) -94 kcal (B) +94 kcal (C) > 94 kcal (D) < -94 kcal

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Last Answer : (B) +94 kcal

Fractional conversion __________ with increase in pressure for ammonia synthesis reaction i.e., N2 + 3H2 ⇌ 2NH3 . (A) Increases (B) Decreases (C) Remains unchanged (D) Unpredictable from the data

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Last Answer : (A) Increases

The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and pressure. It is given by (A) (∂E/∂ni)S, v, nj (B) (∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj (C) (∂H/∂ni)S, P, nj (D) All (A), (B) and (C)

Description : The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and ... , nj (C) (∂H/∂ni)S, P, nj (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Use of catalyst is a must in the ammonia manufacture, because the reaction is reversible as well as the heat of dissociation of N2 & H2 is high. The presence of promoter along with the catalyst helps in __________ of the catalyst. (A) Stabilisation (B) Increasing the effectiveness (C) Improving the strength & heat resistance (D) All a, b & c

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Last Answer : (D) All a, b & c

Nickel is not used as a catalyst in the __________ reaction. (A) Shift conversion (B) Oil hydrogenation (C) Steaming reforming of naphtha (D) Ammonia cracking/dissociation

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Last Answer : (A) Shift conversion

In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = 0 (C) Addition of inert gas has no effect on the equilibrium constant at constant volume for any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'

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Last Answer : D) All 'a', 'b' & 'c'

A chemical reaction, A → 3B, is conducted in a constant pressure vessel. Starting with pure A, the volume of the reaction mixture increases 3 times in 6 minutes. The fractional conversion is (A) 0.33 (B) 0.5 (C) 1 (D) Data insufficient, can't be predicted

Description : A chemical reaction, A → 3B, is conducted in a constant pressure vessel. Starting with pure A, the volume of the reaction mixture increases 3 times in 6 minutes. The fractional conversion is (A) 0.33 (B) 0.5 (C) 1 (D) Data insufficient, can't be predicted

Last Answer : (C) 1

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Lime (CaCO3 ) is added to neutralize

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Last Answer : Ans. Acid soils

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Description : Keeping the pressure constant, to double the volume of a given mass of an ideal gas at 27°C, the temperature should be raised to __________ °C. (A) 270 (B) 327 (C) 300 (D) 540

Last Answer : (B) 327

Multistage operation (as in the case of catalytic oxidation of SO2 ) is not carried out for NH3 synthesis, because of (A) Comparatively higher pressure drop (B) High cost of the high pressure vessel used for the reactor (C) Higher pumping cost (D) Chances of entrainment and disturbance of catalyst bed

Description : Multistage operation (as in the case of catalytic oxidation of SO2 ) is not carried out for NH3 synthesis, because of (A) Comparatively higher pressure drop (B) High cost of the high pressure ... for the reactor (C) Higher pumping cost (D) Chances of entrainment and disturbance of catalyst bed

Last Answer : (B) High cost of the high pressure vessel used for the reactor

Pick out the correct statement. (A) A lower temperature favours the reaction of lower activation energy (B) The dispersion number for a reactor/vessel is uL/D (C) The rate controlling step in a reaction involving many steps is the fastest step (D) Pore volume and porosity of a catalyst is measured by Brunauer￾Emmett-Teller (BET) technique

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Last Answer : (A) A lower temperature favours the reaction of lower activation energy

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Description : Identify the type of reaction(s) in the following equations. (i)CH4 + 2O2 CO2 + 2 H2O (ii) Pb(NO3)2 + 2KI ——–>Pbl2 + 2KNOs (iii) CaO + H2O ——–> Ca(OH)2 (iv) CuSO4 + Zn ——–> ZnSO4 + Cu -Chemistry

Last Answer : Answer. (i) Combustion reaction and oxidation reaction. (ii)Double displacement reaction and precipitation reaction. (iii) Combination reaction. (iv) Displacement reaction.

Which one of the following is classified as a covalent network solid crystal? w) CaO x) SiO2 y) CO2 z) Pb

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A ⇌ 2B + Heat, the number of ‘A’ molecules increases if : a. volume is increased  b. temperature is increased 

Description : A ⇌ 2B + Heat, the number of ‘A’ molecules increases if : a. volume is increased  b. temperature is increased 

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__________ gas is normally employed in B.E.T. method of finding out the surface area of catalyst. (A) N2 (B) H2(C) CO2(D) He

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Last Answer : (A) N2

When a cylindrical vessel containing liquid is revolved about its vertical axis at a constant angular velocity, the pressure (A) Varies as the square of the radial distanceB) Increases linearly as its radial distance (C) Increases as the square of the radial distance (D) Decreases as the square of the radial distance

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Last Answer : Answer: Option A

In the ammonia synthesis reaction, N2 + 3H2 ⇌ 2NH3 + 22.4 kcal, the formation of NH3 will be favoured by (A) High temperature (B) Low pressure (C) Low temperature only (D) Both low temperature and high pressure

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Description : In the reaction, represented by, 2SO2 + O2 ⇌ 2SO3; ΔH = - 42 kcal; the forward reaction will be favoured by (A) Low temperature (B) High pressure (C) Both (A) and (B) (D) Neither (A) nor (B)

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Description : Formation of ammonium carbamate by reaction of NH3 with CO2 is a/an __________ reaction. (A) Catalytic (B) Exothermic (C) Endothermic (D) Reversible

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Description : The combustion reaction, C + O2 = CO2 , is (A) Exothermic (B) Endothermic (C) Autocatalytic (D) None of these

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