The electrophile, `E^((o+))` attacks the benzene ring to generate the intermediate `sigma`-complex. Of the following which `sigma`-complex is of lowes

The electrophile, `E^((o+))` attacks the benzene ring to generate the intermediate `sigma`-complex. Of the following which `sigma`-complex is of lowes
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The electrophile, `E^((o+))` attacks the benzene ring to generate the intermediate `sigma`-complex. Of the ... is of lowest energy? A. B. C. D.
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What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the chain reaction. (b) It functions by destabilizing the carbocationic intermediate and thereby increases the rate of H+ loss. (c) It serves as a Lewis base catalyst by reacting with Cl2 to generate chloride ions. (d) It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Description : What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the ... by reacting with the Cl2 and thereby activates it toward attack by benzene's π electrons.

Last Answer : It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Which of the following is not a correct statement concerning the FriedelCrafts acylation of benzene? (a) An alkyl group substitutes for a hydrogen. (b) The benzene ring attacks an acylium ion. (c) The acylium ion is resonance stabilized. (d) The acylium ion is often produced from an acyl chloride.

Description : Which of the following is not a correct statement concerning the FriedelCrafts acylation of benzene? (a) An alkyl group substitutes for a hydrogen. (b) The benzene ring attacks an acylium ion. (c) The acylium ion is resonance stabilized. (d) The acylium ion is often produced from an acyl chloride.

Last Answer : An alkyl group substitutes for a hydrogen

Electrophile `NO_(2)^(+)` attacks on the following: In which cases will `NO_(2)^(+)` be at meta-position?

Description : Electrophile `NO_(2)^(+)` attacks on the following: In which cases will `NO_(2)^(+)` be at meta-position?

Last Answer : Electrophile `NO_(2)^(+)` attacks on the following: In which cases will `NO_(2)^(+)` be at meta-position? ... I, II and III C. II and III D. I only

Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the rate-determining step. (c) The carbocation intermediate contains an sp3 hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Last Answer : The addition product is a frequently observed minor product.

Electron-withdrawing groups are meta directors because : (a) the carbonium ion intermediate has a negative charge on the meta position. (b) the more stable resonance hybrid occurs with meta attachment of the electrophile. (c) the less stable resonance hybrid occurs with meta attachment of the electrophile. (d) the carbonium ion intermediate has a positive charge on the meta position

Description : Electron-withdrawing groups are meta directors because : (a) the carbonium ion intermediate has a negative charge on the meta position. (b) the more stable resonance hybrid occurs with meta ... the electrophile. (d) the carbonium ion intermediate has a positive charge on the meta position

Last Answer : the more stable resonance hybrid occurs with meta attachment of the electrophile.

In the reaction of phenol with `CHCl_(3)` and aqueous `NaOH` at `70^(@)`, the electrophile attacking the ring is:

Description : In the reaction of phenol with `CHCl_(3)` and aqueous `NaOH` at `70^(@)`, the electrophile attacking the ring is:

Last Answer : In the reaction of phenol with `CHCl_(3)` and aqueous `NaOH` at `70^(@)`, the electrophile attacking the ring is: ... ` C. `:"CCl"_(2)` D. `COCl_(2)`

Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Description : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Last Answer : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the ... D. A is incorrect but R is correct

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the distance between adjacent carbon atoms is 1.39Å (intermediate between single and double bond lengths). The evidence suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Description : An organic compound (A) has a molecular weight 78 and an empirical formula CH. (A) is resistant to attack by oxidizing agents but undergoes substitution and addition reactions. X-ray analysis shows that the ... suggests that compound (A) is (a) Benzene (b) Cyclohexane (c) Toluene (d) n-Hexane

Last Answer : Benzene

A use computer to automatically generate process plans is? a.Lower-level strategies b.Intermediate strategies c.Higher-level strategies d.Morden-level strategies

Description : A use computer to automatically generate process plans is? a.Lower-level strategies b.Intermediate strategies c.Higher-level strategies d.Morden-level strategies

Last Answer : c.Higher-level strategies

. Operations Research involves _________ attacks of complex problems to arrive at the optimum solution a. Scientific b. Systematic c. Both a & b d. Statistical

Description : . Operations Research involves _________ attacks of complex problems to arrive at the optimum solution a. Scientific b. Systematic c. Both a & b d. Statistical

Last Answer : c. Both a & b

In Intermediate COCOMO the mode that represents complex products is referred to as a) Embedded b) Semidetached c) Organic d) Multiplicative e) onolithic.

Description : In Intermediate COCOMO the mode that represents complex  products is referred to as a) Embedded b) Semidetached c) Organic d) Multiplicative e) onolithic.

Last Answer : a) Embedded

The molecule of vitamin A1 contains (A) Benzene ring (B) β-Ionone ring (C) β-Carotene ring (D) None of these

Description : The molecule of vitamin A1 contains (A) Benzene ring (B) β-Ionone ring (C) β-Carotene ring (D) None of these

Last Answer : Answer : B

How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Description : How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Last Answer : The lone pair of electrons present on oxygen atom enter into resonance with the benzene ring. As a result, the electron density becomes higher at o- and p- position and due to higher electron density, the ring gets activated towards electrophilic substitution.

Benzene ring was proposed by

Description : Benzene ring was proposed by

Last Answer : Kekule.

How many isomers containing a benzene ring correspond to the formula C6H4(COOH)2? (a) 1 (b) 2 (c) 3 (d) 4

Description : How many isomers containing a benzene ring correspond to the formula C6H4(COOH)2? (a) 1 (b) 2 (c) 3 (d) 4

Last Answer : 3

The carbon atoms in a benzene ring are : (a) sp hybridized (b) sp3 hybridized (c) sp2 hybridized (d) None of these

Description : The carbon atoms in a benzene ring are : (a) sp hybridized (b) sp3 hybridized (c) sp2 hybridized (d) None of these

Last Answer : sp2 hybridized

Which statement about the structure of benzene is not true? (a) The two Kekule structures of benzene are in equilibrium. (b) The carbon-carbon bond lengths in benzene are greater than the carbon-carbon double bonds in aliphatic compounds. (c) The molecular geometry of benzene is best described as planar. (d) The stability of benzene ring is much greater than the stability of 1,3,5- cycloheptatriene

Description : Which statement about the structure of benzene is not true? (a) The two Kekule structures of benzene are in equilibrium. (b) The carbon-carbon bond lengths in benzene are greater than the carbon- ... (d) The stability of benzene ring is much greater than the stability of 1,3,5- cycloheptatriene

Last Answer : The two Kekule structures of benzene are in equilibrium

Pick out the wrong statement. (A) Catalytic hydrogenation of carbon monoxide produces methyl alcohol (B) In nylon-6, the number 6 represents the total number of carbon atoms in the ring (C) Raw materials for DDT manufacture are benzene and chlorine (D) Ethanolamines are produced by using ammonia and ethylene oxide as raw material

Description : Pick out the wrong statement. (A) Catalytic hydrogenation of carbon monoxide produces methyl alcohol (B) In nylon-6, the number 6 represents the total number of carbon atoms in the ring (C ... are benzene and chlorine (D) Ethanolamines are produced by using ammonia and ethylene oxide as raw material

Last Answer : (C) Raw materials for DDT manufacture are benzene and chlorine

How many carbon atoms are found in the benzene ring?

Description : How many carbon atoms are found in the benzene ring?  

Last Answer : ANSWER: 6 

A major problem with complex pricing structures is that they A)fail to generate the level of revenues needed by an organisation. B)confuse customers and lead to customer dissatisfaction. C)sometimes lead to regulation by governmental agencies. D)are almost always viewed as being deceptive by customers.

Description : A major problem with complex pricing structures is that they A)fail to generate the level of revenues needed by an organisation. B)confuse customers and lead to customer dissatisfaction. C) ... to regulation by governmental agencies. D)are almost always viewed as being deceptive by customers.

Last Answer : B)confuse customers and lead to customer dissatisfaction.

Fibrinolytic therapy is based on activation of plasminogen, the inactive proteolytic enzyme of plasma that binds to fibrin during the formation of thrombosis. Activation of plasminogen to plasmin results in selective thrombolysis at the fibrin clot surface. Which of the following statement(s) is/are true concerning agents used in thrombolytic therapy? a. Streptokinase is a bacterial protein which is antigenic in humans, resulting in allergic reactions in up to l5% of cases b. Tissue plasminogen activator acts directly on plasmin without an intermediate drug–plasmin complex c. The half-life of urokinase, streptokinase, and TPA all exceed 30 minutes d. Streptokinase is significantly cheaper than urokinase or TPA

Description : Fibrinolytic therapy is based on activation of plasminogen, the inactive proteolytic enzyme of plasma that binds to fibrin during the formation of thrombosis. Activation of plasminogen to plasmin results ... TPA all exceed 30 minutes d. Streptokinase is significantly cheaper than urokinase or TPA

Last Answer : Answer: a, b, d Streptokinase is a bacterial protein produced by group C b-hemolytic streptococci. It is therefore antigenic in humans and can be associated with allergic reaction in ... one agent over the other. Streptokinase however, is markedly less expensive than either urokinase or TPA

For a heterogeneous catalytic reaction (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction (B) A relatively small amount of catalyst can cause the conversion of large amount of reactants which does not mean that catalyst concentration is important (C) The catalyst does not form an intermediate complex with the reactant (D) The surface of the catalyst does not play an important role during reaction

Description : For a heterogeneous catalytic reaction (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction (B) A relatively small amount of catalyst ... with the reactant (D) The surface of the catalyst does not play an important role during reaction

Last Answer : (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction

The electrophile involved in the above reaction is:

Description : The electrophile involved in the above reaction is:

Last Answer : The electrophile involved in the above reaction is: A. Dichloromethyl cation `(overset(o+)(C)HCl_(2))` B. ... ` D. Formyl cation `(overset(o+)(C)HO)`

Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)=CH_(2))" "underset("(2)")(CH_(2)=

Description : Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)=CH_(2))" "underset("(2)")(CH_(2)=

Last Answer : Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)= ... and (4) D. (2), (3) and (4)

Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)=CH_(2))" "underset("(2)")(CH_(2)=

Description : Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)=CH_(2))" "underset("(2)")(CH_(2)=

Last Answer : Which among the following compounds behave both as an electrophile as well a nucleophile? `{:(underset("(1)")(CH_(2)= ... and (4) D. (2), (3) and (4)

Which of the following are electrophile?

Description : Which of the following are electrophile?

Last Answer : Which of the following are electrophile? A. `CN^(-)` B. `BF_(3)` C. `NO_(2)^(+)` D. `AlCl_(3)`

Least active electrophile is :

Description : Least active electrophile is :

Last Answer : Least active electrophile is : A. `CH_(3)-overset(O)overset(||)C-OCH_(3)` B. `CH_(3)-overset(O)overset( ... D. `CH_(3)-overset(O)overset(||)C-SCH_(3)`

Which one of the following characteristics belongs to an electrophile?

Description : Which one of the following characteristics belongs to an electrophile?

Last Answer : Which one of the following characteristics belongs to an electrophile? A. It is any species having electron ... in nature D. It is anionic in nature

In a Friedel-Crafts reaction, the electrophile is:

Description : In a Friedel-Crafts reaction, the electrophile is:

Last Answer : In a Friedel-Crafts reaction, the electrophile is: A. `Cl^(-) or X^(-)` B. `CH_(3)^(+)or CH_(3)CO^(+)` C. `CH_(3)Cl` D. `CH_(3)COCl`

Which one of the following behaves both as a nucleophile and an electrophile ?

Description : Which one of the following behaves both as a nucleophile and an electrophile ?

Last Answer : Which one of the following behaves both as a nucleophile and an electrophile ? A. `CH_(3)NH_(2)` B. `CH_(3)OH` C. `CH_(3)CN` D. `CH_(3)Cl`

`C_(6)H_(5)OH+CHCl_(3)+NaOH rarr` salicyladehyde The electrophile involved in the above reaction is.

Description : `C_(6)H_(5)OH+CHCl_(3)+NaOH rarr` salicyladehyde The electrophile involved in the above reaction is.

Last Answer : `C_(6)H_(5)OH+CHCl_(3)+NaOH rarr` salicyladehyde The electrophile involved in the above reaction is. A. ... ` D. formly cation `(overset(o+)(C)HO)`

Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an sp3 hybridized carbon undergo substitution and elimination reactions. (c) The electronegative atom is replaced by another atom or group in substitution reactions. (d) (a) and (b)

Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)

Last Answer : (a) and (b)

In the reaction of propene with HCl, H+ ion acts as the : (a) electrophile (b) carbonium ion (c) nucleophile (d) carbanion

Description : In the reaction of propene with HCl, H+ ion acts as the : (a) electrophile (b) carbonium ion (c) nucleophile (d) carbanion

Last Answer : electrophile

Which of the following statements is incorrect? (a) Electrons move toward positively charged locations. (b) An electron-rich atom is called an electrophile. (c) An electrophile is electron loving. (d) A nucleophile has a a pair of electrons it can share

Description : Which of the following statements is incorrect? (a) Electrons move toward positively charged locations. (b) An electron-rich atom is called an electrophile. (c) An electrophile is electron loving. (d) A nucleophile has a a pair of electrons it can share

Last Answer : An electron-rich atom is called an electrophile.

A nucleophile acts as a __________ when it reacts with an electrophile. (a) Bronsted-Lowry acid (b) Arrhenius base (c) Lewis acid (d) Lewis base

Description : A nucleophile acts as a __________ when it reacts with an electrophile. (a) Bronsted-Lowry acid (b) Arrhenius base (c) Lewis acid (d) Lewis base

Last Answer : Lewis base

An electrophile acts as a __________ when it reacts with a nucleophile. (a) Bronsted-Lowry base (b) Arrhenius base (c) Lewis acid(d) Lewis base

Description : An electrophile acts as a __________ when it reacts with a nucleophile. (a) Bronsted-Lowry base (b) Arrhenius base (c) Lewis acid (d) Lewis base

Last Answer : Lewis acid

Which of the following is not an electrophile? (a) NH3 (b) Br+ (c) AlCl3 (d) NO2+

Description : Which of the following is not an electrophile? (a) NH3 (b) Br+ (c) AlCl3 (d) NO2+

Last Answer : NH3

Which of the following solutions will follow Raoult's law most closely? (A) A solution of benzene, toluene and o-xylene (B) 35% solution of camphor in water (C) 35% solution of NH3 in water (D) A solution of polar organic compounds (not of homologue of a series)

Description : Which of the following solutions will follow Raoult's law most closely? (A) A solution of benzene, toluene and o-xylene (B) 35% solution of camphor in water (C) 35% solution of NH3 in water (D) A solution of polar organic compounds (not of homologue of a series)

Last Answer : (A) A solution of benzene, toluene and o-xylene

Cresols on distillation with zinc dust gives (a) o-Xylene(b) Benzene(c) o- plus p-Xylene(d) Toluene

Description : Cresols on distillation with zinc dust gives (a) o-Xylene (b) Benzene (c) o- plus p-Xylene (d) Toluene

Last Answer : Toluene

Which of the following can be made by the action of CH3Cl on benzene in the presence of aluminium chloride? (a) Ethylbenzene (b) o-Xylene (c) Chlorobenzene (d) m-Xylene

Description : Which of the following can be made by the action of CH3Cl on benzene in the presence of aluminium chloride? (a) Ethylbenzene (b) o-Xylene (c) Chlorobenzene (d) m-Xylene

Last Answer : o-Xylene

When acetylene is passed through hot iron tube at 400°C, it gives (a) Benzene (b) Toluene (c) o-Xylene (d) Mesitylene

Description : When acetylene is passed through hot iron tube at 400°C, it gives (a) Benzene (b) Toluene (c) o-Xylene (d) Mesitylene

Last Answer : Benzene

`{:(" "O^(16)),(" ||"),(CH_(3)-C-H overset(D_(2)O^(18))underset(D^(o+))to CH_(3)-C-H),(" ||"),(" "._(18)O):}` Give the following reaction intermediate

Description : `{:(" "O^(16)),(" ||"),(CH_(3)-C-H overset(D_(2)O^(18))underset(D^(o+))to CH_(3)-C-H),(" ||"),(" "._(18)O):}` Give the following reaction intermediate

Last Answer : `{:(" "O^(16)),(" ||"),(CH_(3)-C-H overset(D_(2)O^(18))underset(D^(o+))to CH_(3)-C-H),(" ||"),(" "._( ... ,(" |"),(CH_(3)-C-H),(" |"),(" "._(18)OD):}`

`{:(" "O^(16)),(" ||"),(CH_(3)-C-H overset(D_(2)O^(18))underset(D^(o+))to CH_(3)-C-H),(" ||"),(" "._(18)O):}` Give the following reaction intermediate

Description : `{:(" "O^(16)),(" ||"),(CH_(3)-C-H overset(D_(2)O^(18))underset(D^(o+))to CH_(3)-C-H),(" ||"),(" "._(18)O):}` Give the following reaction intermediate

Last Answer : `{:(" "O^(16)),(" ||"),(CH_(3)-C-H overset(D_(2)O^(18))underset(D^(o+))to CH_(3)-C-H),(" ||"),(" "._( ... ,(" |"),(CH_(3)-C-H),(" |"),(" "._(18)OD):}`

Assertion: The O - O bond lengths in ozone molecule are intermediate between single and double bonds. Reason: `O_(3)` molecule is a resonance hybrid.

Description : Assertion: The O - O bond lengths in ozone molecule are intermediate between single and double bonds. Reason: `O_(3)` molecule is a resonance hybrid.

Last Answer : Assertion: The O - O bond lengths in ozone molecule are intermediate between single and double bonds. ... I is not correct and Statement-II is correct

The brown ring test for `NO_(2)^(-)` and `NO_(3)^(-)` is due to the formation of complex ion with formula `:`

Description : The brown ring test for `NO_(2)^(-)` and `NO_(3)^(-)` is due to the formation of complex ion with formula `:`

Last Answer : The brown ring test for `NO_(2)^(-)` and `NO_(3)^(-)` is due to the formation of complex ion with formula `:` A. ... )` D. `[Fe(H_(2)O)(NO)_(5)]^(2+)`

Vitamin B12 has a complex ring structure (corrin ring) consisting of four (A) Purine rings (B) Pyrimidine rings (C) Pyrrole rings (D) Pteridine rings

Description : Vitamin B12 has a complex ring structure (corrin ring) consisting of four (A) Purine rings (B) Pyrimidine rings (C) Pyrrole rings (D) Pteridine rings

Last Answer : Answer : C

Which of the following is a quality management system that gives titles to specialists and requires a cost-benefit analysis? Select one: a. Lean accounting b. Business process re-engineering c. Kaizen d. Six Sigma e. Total Quality Management

Description : Which of the following is a quality management system that gives titles to specialists and requires a cost-benefit analysis? Select one: a. Lean accounting b. Business process re-engineering c. Kaizen d. Six Sigma e. Total Quality Management

Last Answer : d. Six Sigma

The TQM initiative reduces material costs and labor costs. a. Concurrent Engineering (CCE)/Six Sigma b. Benchmarking c. Continuous Product Improvement systems (CPI) d. Channel Support systems e. Quality Initiative Training (QIT)

Description : The TQM initiative reduces material costs and labor costs. a. Concurrent Engineering (CCE)/Six Sigma b. Benchmarking c. Continuous Product Improvement systems (CPI) d. Channel Support systems e. Quality Initiative Training (QIT)

Last Answer : a. Concurrent Engineering (CCE)/Six Sigma

These TQM initiatives reduce administrative overhead; reduces the R&D cycle time and enhances the effectiveness of the promotion and sales budget. a. Concurrent Engineering (CCE); Channel Support systems and Just-in-Time Inventory b. Quality Function Deployment and Benchmarking c. Continuous Product Improvement systems (CPI) and Just-in-Time Inventory d. Channel Support systems and Six Sigma e. Quality Initiative Training (QIT)

Description : These TQM initiatives reduce administrative overhead; reduces the R&D cycle time and enhances the effectiveness of the promotion and sales budget. a. Concurrent Engineering (CCE); Channel Support systems ... Inventory d. Channel Support systems and Six Sigma e. Quality Initiative Training (QIT)

Last Answer : b. Quality Function Deployment and Benchmarking