Description : In coordination chemistry there are a veriety of methods applied to find out the structure of complexes. One method involves treating the complex with
Last Answer : In coordination chemistry there are a veriety of methods applied to find out the structure of complexes. One method involves ... 0` C. `0.0` D. `3.0`
Last Answer : In coordination chemistry there are a veriety of methods applied to find out the structure of complexes. One method ... BM C. 4.9 BM D. 5.9 BM
Last Answer : In coordination chemistry there are a veriety of methods applied to find out the structure of complexes. One method ... BM C. 4.9 BM D. 1.73 BM
Last Answer : In coordination chemistry there are a veriety of methods applied to find out the structure of complexes. One method ... . `[CoBrCl(en)_(2)Cl.H_(2)O`
Description : When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex (ii) IUPAC name of the complex -Chemistry
Last Answer : i) Complex so formed is: CoCl3.6NH3 + AgNO3 → [Co(NH3)6]Cl3 (ii) IUPAC name of complex is: Hexaamminecobalt (III) chloride
Description : The ammonia prepared by treating ammonium sulphate with calcium hydroxide is completely used by `"NiCl"_(2).6H_(2)O` to form a stable coordination com
Last Answer : The ammonia prepared by treating ammonium sulphate with calcium hydroxide is completely used by `"NiCl"_(2).6H_(2)O` ... Cl = 35.5, Ca = 40, Ni = 59)
Description : Compare the following complexes’ with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : (i) [Ni(CN)4]2- (ii) [NiCl4]2- (iii) [CoF6]3- [At. Nos. : Ni = 28; Co = 27] -Chemistry
Last Answer : (i) [Ni(CN)4]2- Shape : Octahedral outer orbital complex Hybridisation : sp3d2 Magnetic behaviour : Paramagnetic (4 unpaired electrons)
Description : Explain the following : (i) Low spin octahedral complexes of nickel are not known. (ii) The π-complexes are known for transition elements only. (iii) CO is a stronger ligand than NTL, for many metals. -Chemistry
Last Answer : (i) The electronic configuration of Ni is [Ar] 3d8 4s2 which shows that it can only form two types of complexes i.e. square planar (dsp2) in presence of strong ligand and tetrahedral (sp3) in ... more splitting of d-orbitals and moreover it is also able to form π bond due to back bonding.
Description : Compare the following complexes with respect to structural shapes of units, magnetic behaviour and hybrid orbitals involved in units : [Co(NH3)6]+3, [Cr(NH3)6]3+, Ni(CO)4 (At. nos. : Co = 27, Cr = 24, Ni = 28) -Chemistry
Last Answer : (i) [Co(NH3)6]+3 → Octahedral shape, d2sp3 hybridisation, diamagnetic Formation of [Co(NH2)6]+3 → oxidation state of Co is +3.
Description : Compare the following complexes with respect to their shape, magnetic behaviour and the hybrid orbitals involved : (i) [CoF4]2- (ii) [Cr(H2O)2(C2O4)2]– (iii) [Ni(CO)4] (Atomic number : Co = 27, Cr = 24, Ni = 28) -Chemistry
Last Answer : (i) [COF4]2_ : Tetrafluorido cobalt (III) ion Coordination number = 4 Shape = Tetrahedral Hybridisation = sp3 Important Questions for Class 12 Chemistry Chapter 9 Coordination Compounds Class 12 Important Questions 7
Description : Describe the shape and magnetic behaviour of following complexes : (i) [CO(NH3)6]3+ (ii) [Ni(CN)4]2- (At. No. Co = 27, Ni = 28) -Chemistry
Last Answer : (i) [CO(NH3)6]3+ : Orbitals of CO3+ ion : Hybridization : d2sp3 Shape : Octahedral Magnetic behaviour : Diamagnetic (absence of unpaired electrons) (ii) [Ni(CN)4]2-
Description : Why are low spin tetrahedral complexes not formed? -Chemistry
Last Answer : Law spin tetrahedral complexes are rarely observed because orbital splitting energies for tetrahedral complexes are sufficiently large for forcing pairing.
Description : Which type of hypersensitivity reaction involves immune complexes formed when antigens bind to antibodies? a) Type III Type III hypersensitivity is associated with systemic lupus erythematosus, rheumatoid ... , or delayed-type, hypersensitivity occurs 24-72 hours after exposure to an allergen.
Last Answer : a) Type III Type III hypersensitivity is associated with systemic lupus erythematosus, rheumatoid arthritis, serum sickness, certain types of nephritis, and some types of bacterial endocarditis.
Description : Name the following coordination compounds according to IUPAC system of nomenclature :(i) [Co(NH3)4 (H2O)Cl]Cl2 (ii) [CrCl2(en)2]Cl, (en = ethane – 1, 2 – diamine) -Chemistry
Last Answer : (i) [CO(NH3)4 (H2O)Cl]Cl2 Tetraammine aquachlorido cobalt (III) chloride (ii) [CrCl2(en)2]Cl Dichlorobis (ethane-1, 2-diamine) chromium (III) chloride
Description : Write the IUPAC name of the following coordination compound [NiCl4]2-. -Chemistry
Last Answer : Tetrachloridonickelate (II) ion.
Description : Give two examples of ligands which form coordination compounds useful in analytical chemistry. -Chemistry
Last Answer : Examples : (i) EDTA (Ethylene diamine tetra-acetic acid) (ii) Dimethyl glyoxime (DMG)
Description : Give an example of coordination isomerism. -Chemistry
Last Answer : Example : [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [CO(CN)6]
Description : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero and 2.84 BM respectively. The second complex i
Last Answer : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2 ... . D. It produces three-fold freezing point depression.
Last Answer : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero and ... (H_(2)O)_(2)](NO_(3))_(2)`, octahedral
Description : In the complexes [SbF_(5)]^(2-),sp^(3)d` hybridisation is present. Geometry of the complex is:
Last Answer : In the complexes [SbF_(5)]^(2-),sp^(3)d` hybridisation is present. Geometry of the ... B. Square bipyramidal C. Tetrahedral D. square planar
Last Answer : The magnetic moment for two complexes of empirical formula `Ni(NH_(3))_(4)(NO_(3))_(2).2H_(2)O` is zero ... two B. zero, zero C. two, zero D. two ,two
Description : `NiCl_(2) overset(KCN)to "complex"A` `NiCl_(2) underset("excess") overset(KCl)to "complex"B` A & B complexes have the co-ordination number 4. The hybr
Last Answer : `NiCl_(2) overset(KCN)to "complex"A` `NiCl_(2) underset("excess") overset(KCl)to "complex"B` A & B complexes have ... ^(2) & sp^(3)` D. both `sp^(3)`
Description : A cationic complex has two isomers A & B. Each has one Co3+, five NH3 , one Br and one SO4 2 . A gives a white precipitate with BaCl2 solution while B gives a yellow precipitate with AgNO3 ... are the possible structures of the complexes A and B ? (a) Will the two complexes have same colour ?
Last Answer : (a) [CO (NH3 ) 5 Br] SO4 and [CO (NH3 ) 5 SO4 ] Br (b) NO
Description : A coordination complex of type `MX_(2)Y_(2)`[M=metal ion, X,Y=monodentata ligands ], can have either a tetrahedral of a square planar geometry. The ma
Last Answer : A coordination complex of type `MX_(2)Y_(2)`[M=metal ion, X,Y=monodentata ligands ], can have either a tetrahedral ... 2 and 1 C. 1 and 3 D. 3 and 2
Description : Consider the coordination compound , `[Co(NH_(3))_(6)]Cl_(3)`. In the formation of the complex, the species which acts as the Lewis acid is :
Last Answer : Consider the coordination compound , `[Co(NH_(3))_(6)]Cl_(3)`. In the formation of the complex, the species which ... -)` C. `Co^(3+)` D. `NH_(3)`
Description : The coordination number of a central metal atom in a complex is determined by:
Last Answer : The coordination number of a central metal atom in a complex is determined by: A. the number of ... ligands around a metal ion bonded by sigma bonds
Description : The pair of coordination complex exhibiting the same kind of isomerism is .
Last Answer : The pair of coordination complex exhibiting the same kind of isomerism is . A. `[Cr(NH_(3))_(5)Cl]C_(2) and [ ... NO_(3))]Cl and [Pt(NH_(3))_(3)Cl]Br`
Description : `Co^(2+)(aq.)+SCN^(-) (aq.) to "Complex"(X)` `Ni^(2+)(aq.) +"Dimethylglyoxime" overset(NH_(4)OH) to "Complex"(Y)` The coordination number of cobalt an
Last Answer : `Co^(2+)(aq.)+SCN^(-) (aq.) to "Complex"(X)` `Ni^(2+)(aq.) +"Dimethylglyoxime" overset(NH_ ... (Y) is diamagnetic D. (X) and (Y) both are diamagnetic.
Last Answer : `Co^(2+)(aq.)+SCN^(-) (aq.) to "Complex"(X)` `Ni^(2+)(aq.) +" ... both tetrahedral C. square planar and tetrahedral D. both square planar.
Last Answer : `Co^(2+)(aq.)+SCN^(-) (aq.) to "Complex"(X)` `Ni^(2+)(aq.) +" ... . tetrathiocyanoato-S-cobaltate(III) and bis(dimethylglyoximato) nickel (II).
Description : A complex anion is formed by Osmium ( in some oxidation state ) with ligands ( in proper number so that coordination number of osmium becomes six ). W
Last Answer : A complex anion is formed by Osmium ( in some oxidation state ) with ligands ( in proper number ... ) C. azidopentachloridoosmate(VI) D. None of these
Description : A complex cation is formed by Pt( in some oxidation state ) with ligands ( in proper number so that coordination number of Pt becomes six ). Which of
Last Answer : A complex cation is formed by Pt( in some oxidation state ) with ligands ( in proper number ... (ethylenediamine ) dithiocyanate -S- platinum (IV) ion
Description : The most common complex ions have octahedral geometry. What is the coordination number of the central ion in an octahedral complex?
Last Answer : ANSWER: SIX
Description : ………. Involves treating main memory as a resource to be allocated to and shared among a number of active processes. A) Partition management B) Memory management C) Disk management D) All of the above
Last Answer : B) Memory management
Description : What is the coordination number of an ion what is the coordination number of the cation (a) Na Cl structure and (b) Cs Cl structure explain the reason for this difference?
Last Answer : The coordination number is six for Na in NaCl.The coordination number is eight for Cs in CsCl. The accepted explanation is that the ionic radii of cesium and chloride are very similar.
Description : What is the coordination number of an cation in NaCl structure?
Last Answer : The coordination number is six for Na in NaCl.
Description : Which of the following problems is most likely to occur in a matrix structure? (a) Decreased employee motivation ; (b) Employees receiving conflicting directives (c) Decreased response to environmental change ; (d) Decreased coordination
Last Answer : (b) Employees receiving conflicting directives
Description : What is true in treating a patient with secondary herpes simplex:** A. Acyclovir inhibits viral transcription when applied in the prodromal phase B. Idoxuridine is better than acyclovir when applied topically C. Antivirals are contra indicated in immuno-compromised patient
Last Answer : A. Acyclovir inhibits viral transcription when applied in the prodromal phase
Description : Organic chemistry involves molecules that contain which element? a. carbon c. oxygen b. nitrogen d. calcium
Last Answer : a. carbon
Description : Pick out the wrong statement. (A) Pasteurisation of milk involves moderate heating followed by cooling (B) Bakeries and breweries make use of yeasts (C) Enzyme is a complex nitrogenous compound (D) Oils and fats are alkaloids
Last Answer : (D) Oils and fats are alkaloids
Description : For the complex [Fe(en)2Cl2], Cl, (en = ethylene diamine), identify (i) the oxidation number of iron, (ii) the hybrid orbitals and the shape of the complex, (iii) the magnetic behaviour of the complex, (iv) ... an optical isomer also, and (vi) name of the complex. (At. no. of Fe = 26) \ -Chemistry
Last Answer : i) [Fe(en)2Cl2] Cl or x + 0 + 2 (-1) + (-1) = 0 x + (- 3) = 0 or x = + 3 ∴ Oxidation number of iron, x = + 3 (ii) The complex has two bidentate ligands and two ... )2Cl2] Cl, only cis-isomer shows optical isomerism. (vi) Name of complex: Dichloridobis (ethane-1, 2- diamine) Iron (III) chloride
Description : When a co-ordination compound CrCl3.6H2O is mixed with AgNO3, 2 moles of AgCl are precipitated per mole of the compound. Write (i) Structural formula of the complex. (ii) IUPAC name of the complex. -Chemistry
Last Answer : (i) The complex formed on mixing a coordination compound CrCl3.6H2O with AgNO3 is as follows CrCl3.6H2O + AgNO3 → [Cr(H2O5)Cl]Cl2. H2O (ii) Pentaaquachloridochromium (III) chloride monohydrate
Description : (i) Write down the IUPAC name of the following complex : [CO(NH3)5Cl]2+ (ii) Write the formula for the following complex : Potassium tetrachloridonickelate (II) -Chemistry
Last Answer : i) [CO(NH3)5Cl]2+ IUPAC name : Pentaammine chlorido cobalt (III) ion (ii) Formula of the complex potassium tetrachloridonickelate (II) K2[NiCl4]
Description : (i) Write down the IUPAC name of the following complex : [Cr(NH3)2CI3(en)]Cl (en = ethylenediamine) (ii) Write the formula for the following complex : Pentaamminenitrito-o-Cobalt (III) -Chemistry
Last Answer : (I) [Cr(NH3)2Cl3(en)]Cl IUPAC name : Diammine dichlorido ethylenediamine chromium (III) chloride. (ii) [Co(NH3)5(ONO)]2+
Description : Write the IUPAC name of the complex [Cr(NH3)4Cl2]+. What type of isomerism does it exhibit? -Chemistry
Last Answer : IUPAC name : Tetraamine dichlorido chromium (III) ion. It exhibits geometrical isomerism.
Description : Explain why [Co(NH3)6]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital complex. (At. no. Co = 27, Ni = 28) -Chemistry
Last Answer : In [Co(NH3)6]3+, the d-electrons of Co3+ ([Ar]3d6 45°) get paired leaving behind two empty d-orbital and undergo d2sp3 hybridization and hence inner orbital complex, while in [Ni(NH3)6]2+ ... of Ni2+([Ar]3d8 45°) do not pair up and use outer 4d subshell hence outer orbital complex.
Description : How is the stability of a co-ordination compound in solution decided ? How is the dissociation constant of a complex defined? -Chemistry
Last Answer : Stability of a complex in solution means the measure of resistance to the replacement of a ligand by some other ligand. This stablility can be expressed in terms of equilibrium constant. Let the ... is its tendency to donate electron pair and therefore, more is the stability of the complex.
Description : Write IUPAC name of the complex: -Chemistry
Last Answer : Dichloridobis ethylenediamine cobalt (III) ion.
Description : Write IUPAC name of the complex: [CoCl2(en)2]+ -Chemistry
Last Answer : CoCl2(en)2]+: Dichloridobis(ethylenediamine)Cobalt(III)ion.
Description : Write the IUPAC name of the following complex : [CO(NH3)6]3+ -Chemistry
Last Answer : Hexaamminecobalt (III) ion.