Description : For a reversible process involving only pressure-volume work (A) (dF)T, p < 0 (B) (dF)T, p > 0 (C) (dF)T, p = 0 (D) (dA)T, v < 0
Last Answer : (C) (dF)T, p = 0
Description : ECE Board Exam April 1997 Sound intensity is given as A. df/dP B. dE/dp C. dA/dP D. dP/dA
Last Answer : D. dP/dA
Description : The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is (A) (∂T/∂V)S = - (∂P/∂S)V (B) (∂S/∂P)T = - (∂V/∂T)P (C) (∂V/∂S)P = (∂T/∂P)S (D) (∂S/∂V)T = (∂P/∂T)V
Last Answer : (D) (∂S/∂V)T = (∂P/∂T)V
Description : The volume (V) of a mass of gas varies directly as its absulute temperature (T) and iversely as the pressure (P) applied to it. The gas occupies a vol
Last Answer : The volume (V) of a mass of gas varies directly as its absulute temperature (T) and iversely as ... and pressure are 250 ml and 320 Pa respectively?
Description : The volume (V) of a mass of gas varies directly as its absolute temperature (T) and inversely as the pressure (P) applied to it. The gas occupies a vo
Last Answer : The volume (V) of a mass of gas varies directly as its absolute temperature (T) and inversely as ... and pressure are 200 ml and 250 Pa respectively?
Description : If air is at pressure, p, of 3200 lbf/ft2 , and at a temperature, T, of 800 ˚R, what is the specific volume, v? (R=5303 ft-lbf/lbm-˚R, and air can be modeled as an ideal gas.) A.9.8 ft^3/lbm B.11.2 ft^3/lbm C.13.33 ft^3/lbm D.14.2 ft^3/lbm Formula: pv = RT v = RT / p
Last Answer : 13.33 ft^3/lbm
Description : For a perfect gas, according to Boyle’s law (where p = Absolute pressure, v = Volume, and T = Absolute temperature) A. p v = constant, if T is kept constant B. v/T = constant, if p is kept constant C. p/T = constant, if v is kept constant D. T/p = constant, if v is kept constant
Last Answer : Answer: A
Description : The constant pressure, constant volume and constant pvn processes are regarded as irreversible process. A. True B. False
Description : In ΔABC and ΔDEF, AB = DE, AB || DE, BC = EF and BC || EF. Vertices A, B and C are joined to vertices D, E and F respectively (see Fig. 8.22). Show that (i) quadrilateral ABED is a parallelogram ( ... CF and AD = CF (iv) quadrilateral ACFD is a parallelogram (v) AC = DF (vi) ΔABC ≅ ΔDEF. -Maths 9th
Last Answer : . Solution: (i) AB = DE and AB || DE (Given) Two opposite sides of a quadrilateral are equal and parallel to each other. Thus, quadrilateral ABED is a parallelogram (ii) Again BC = EF and BC || EF ... (Given) BC = EF (Given) AC = DF (Opposite sides of a parallelogram) , ΔABC ≅ ΔDEF [SSS congruency]
Description : 3.0 lbm of air are contained at 25 psia and 100 ˚F. Given that Rair = 53.35 ft-lbf/lbm- ˚F, what is the volume of the container? A.10.7 ft^3 B.14.7 ft^3 C.15 ft^3 D.24.9 ft^3 Formula: use the ideal gas law pV = mRT T = (100 +460) ˚R V = mRT/p
Last Answer : 24.9 ft^3
Description : Internal energy of a gas obeying Van-Der-Waals equation of state, [p + (a/v2)] (V - b) = RT, depends upon its (A) Pressure & temperature (B) Pressure & specific volume (C) Temperature & specific volume (D) Temperature only
Last Answer : (A) Pressure & temperature
Description : The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and ... , nj (C) (∂H/∂ni)S, P, nj (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : Second order consecutive irreversible reaction as shown in the bellow figure, were carried out in a constant volume isothermal batch reactor with different initial feed compositions. Reactor temperature was same in all the cases. In experiments ... constants (k1 /k2 )? (A) 1/4 (B) 1/2 (C) 2 (D) 4
Last Answer : (A) 1/4
Description : In ball mill operation, the feed size (Df in meters) and the ball diameter (Db in metres) are related as (where, K = grindability constant (varying from 0.9 to 1.4 in increasing order of hardness)) (A) Db 2 = K.Df (B) Db = K.Df (C) Db 3 = K.Df (D) Db 2 = K.Df
Last Answer : (A) Db 2 = K.Df
Description : Which of the following relationship is valid for the equilibrium position of the float in a Rotameter? (Where, Df= Drag force on the float Bf = Buoyant force on the float Wf = Weight of the float). (A) Df + Bf = Wf (B) Df = Bf + Wf (C) Df + Bf + Wf =0 (D) None of these
Last Answer : (A) Df + Bf = Wf
Description : In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is (A) More (B) Less (C) Same (D) Unpredictable; depends on the particular reaction
Last Answer : (C) Same
Description : An ideal gas is heated at constant volume and then expanded isothermally. Show processes on P-V & T-S diagrams.
Last Answer : Process 1-2 : Constant volume process Process 2-3 : Constant temperature process (Isothermal process)
Description : An adsorption isotherm equation proposed by Langmuir is of the form `V = (V_(0)bPO)/((1 + bP))` where V is the volume of gas adsorbed at pressure P. F
Last Answer : An adsorption isotherm equation proposed by Langmuir is of the form `V = (V_(0)bPO)/((1 + bP))` where V is ... of V on P can be depicted as B. C. D.
Description : The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv ), depends upon its (A) Pressure (B) Volume (C) Temperature (D) All (A), (B) & (C)
Last Answer : (C) Temperature
Description : Work done may be calculated by the expression ∫ p dA for __________ processes. (A) Non-flow reversible (B) Adiabatic (C) Both (A) and (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) and (B)
Description : A change in state involving a decrease in entropy can be spontaneous, only if (A) It is exothermic (B) It is isenthalpic (C) It takes place isothermally (D) It takes place at constant volume
Last Answer : (A) It is exothermic
Description : Pick out the wrong statement: (A) The expansion of a gas in vacuum is an irreversible process (B) An isometric process is a constant pressure process (C) Entropy change for a reversible adiabatic process is zero (D) Free energy change for a spontaneous process is negative
Last Answer : (B) An isometric process is a constant pressure process
Description : . A first order irreversible reaction, A → B is carried out separately in a constant volume as well as in a variable volume reactor for a particular period. It signifies that __________ in the two ... be different (C) Both the conversion as well as concentrations will be different (D) None of these
Last Answer : (B) Conversion in both will be the same but concentrations will be different
Description : Pick out the wrong statemen (A) Autocatalytic reactions are exemplified by microbial fermentation reactions (B) The slowest step has the greatest influence on the overall reaction rate in case of an ... reaction (D) Hydrolysis of ester in presence of alkali or acid is a zero order reaction
Last Answer : (D) Hydrolysis of ester in presence of alkali or acid is a zero order reaction
Description : In case of the irreversible unimolecular type, first order reaction, the fractional conversion at any time for constant volume system as compared to variable volume system is (A) More (B) Less (C) Same (D) Either (A) or (B), depends on other factors
Description : An irreversible first order reaction is being carried out in a CSTR and PFR of same volume. The liquid flow rates are same. The relative conversion will (A) Be more in CSTR than in PFR (B) Be more in PFR than in CSTR (C) Be same in both cases (D) Depend on the temperature
Last Answer : (B) Be more in PFR than in CSTR
Description : Half the angle of nip, (α), for a roll crusher is given by (where, dr, dp and df are diameters of crushing rolls, feed particles and rolls gap respectively). (A) cos α = (dr + dp)/(dr + df) (B) cos α = (dr + df)/(dr + dp) (C) tan α = (dr + dp)/(dr + df) (D) sin α = (dr + dp)/(dr + df)
Last Answer : (A) cos α = (dr + dp)/(dr + df)
Description : The reduction ratio for grinders is defined as (where, Df and Dp are average diameters of feed and product respectively). (A) Df /Dp (B) Dp /Df (C) Df - Dp (D) None of these
Last Answer : (A) Df /Dp
Description : A pollutant P degrades according to first order kinetics. An aqueous stream containing P at 2 kmole/m3 and volumetric flow rate 1m3 /h requires a mixed flow reactor of volume V to bring down the pollutant level to 0.5 kmole/ ... reactor should be increased by a factor of: (A) 7 (B) 6 (C) 3 (D) 7/3
Last Answer : (A) 7
Description : The translocation of organic solutes in sieve tube members is supported by (a) cytoplasmic streaming (b) root pressure and transpiration pull (c) P-proteins (d) mass flow involving a carrier and ATP
Last Answer : (a) cytoplasmic streaming
Description : Gibbs-Helmholtz equation is (A) ∆F = ∆H + T [∂(∆F)/∂T]P (B) ΔF = ΔH - TΔT (C) d(E - TS) T, V < 0 (D) dP/dT = ∆Hvap/T.∆Vvap
Last Answer : (A) ∆F = ∆H + T [∂(∆F)/∂T]P
Description : With increase in the space time of an irreversible isothermal reaction being carried out in a P.F. reactor, the conversion will (A) Increase (B) Decrease (C) Remain same (D) Data in insufficient; can't be predicted
Last Answer : (A) Increase
Description : . An irreversible aqueous phase reaction, A + B → P, is carried out in an adiabatic mixed flow reactor. A feed containing 4kmole/m3 of each A and B enters the reactor at 8m3 /hr. If the temperature of ... be assumed to be independent of temperature and composition. (A) 190 (B) 290 (C) 390 (D) 490
Last Answer : (B) 290
Description : According to Bond crushing law, the work required to form particle of size 'D' from very large feed is (where (S/V)p and (S/V) f are surface to volume ratio of the product and feed respectively). (A) (S/V)p (B) √(S/V)p (C) (S/V) 2 p (D) (S/V) f
Last Answer : (B) √(S/V)
Description : In an irreversible process (A) Tds = dE - dW = 0 (B) dE - dW - Tds = 0 (C) Tds - dE + dW < 0 (D) Tds - dT + dW < 0
Last Answer : (C) Tds - dE + dW < 0
Description : Entropy change for an irreversible process taking system and surrounding together is (A) 0 (B) > 0 (C) < 0 (D) None of these
Last Answer : (B) > 0
Description : In a totally irreversible isothermal expansion process for an ideal gas, ΔE = 0, ΔH = 0. Then ΔQ and ΔS will be (A) ΔQ = 0, ΔS=0 (B) ΔQ = 0, ΔS = +ve (C) ΔQ = 0, ΔS = -ve (D) ΔQ = +ve, ΔS= +ve
Last Answer : (B) ΔQ = 0, ΔS = +ve
Description : Assertion (A): For a particular reaction, heat of combustion at constant pressure `(q_(P))` is always greater than that at constant volume `(q_(V))`.
Last Answer : Assertion (A): For a particular reaction, heat of combustion at constant pressure `(q_(P))` is ... False. D. If both Assertion & Reason are false.
Description : if pressure P is inversely proportional to volume (V) at constant temperature, then PV is constant (True/False)
Last Answer : if pressure P is inversely proportional to volume (V) at constant temperature, then PV is constant (True/False)
Description : Boyle's law states that A. pressure of a gas is inversely proportional to its volume i.e. P V = constant B. pressure of a gas is directly proportional to its volume i.e. P⁄V = constant C. ... of a gas is directly proportional to the square of its volume i.e. P ⁄ V² = constant
Last Answer : pressure of a gas is inversely proportional to its volume i.e. P × V = constant
Description : Van der Waals derived an expression for the pressure defect', if the observed pressure is denoted as p' and volume is denoted as V', the gas pressure in the bulk of the gas is equal to: A. p + ... a: constant for the particular gas D. p + (a V²); where a: constant for the particular gas
Last Answer : p + a/(V²); where a: constant for the particular gas
Description : The sum of internal energy (U) and the product of pressure and volume (p.v) is known as A. workdone B. entropy C. enthalpy D. none of these
Last Answer : Answer: C
Description : Pick out the correct statement. (A) The available energy in an isolated system for all irreversible (real) processes decreases (B) The efficiency of a Carnot engine increases, if the sink temperature is decreased ... condition is the change in Helmholtz free energy (D) All (A), (B) and (C)
Description : Pick out the correct statement. (A) If an insoluble gas is passed through a volatile liquid placed in a perfectly insulated container, the temperature of the liquid will increase (B) A ... compound is defined as the heat of reaction leading to the formation of the compound from its reactants
Last Answer : (D) The heat of formation of a compound is defined as the heat of reaction leading to the formation of the compound from its reactants
Description : An irreversible process (A) Is the analog of linear frictionless motion in machines (B) Is an idealised visualisation of behaviour of a system (C) Yields the maximum amount of work (D) Yields an amount of work less than that of a reversible process
Last Answer : (D) Yields an amount of work less than that of a reversible process
Description : Isometric process is a. T = P b. P = C c. V = C d. T = V
Last Answer : V = C
Description : Draw P-V and T-S diagram for isochoric process.
Last Answer : Isochoric Process:
Description : Represent Isobaric, Isochoric, Isothermal, Adiabatic process on P-V and T-S diagram.
Last Answer : Isobaric process Isothermal process Isochoric process Adiabatic process:
Description : Define isentropic process and plot it on, P-V and T-S diagram.
Last Answer : Isentropic Process: The process in which working substance neither receives nor rejects heat to its surrounding during expansion or compression is called as Isentropic process, it is also known as adiabatic ... is frictionless and the process is irreversible when it involves friction .