Equilibrium constant of a reaction varies with the (A) Initial concentration of the reactant (B) Pressure (C) Temperature (D) None of these

Equilibrium constant of a reaction varies with the
(A) Initial concentration of the reactant
(B) Pressure
(C) Temperature
(D) None of these
by

1 Answer

Answer :

C) Temperature
by

Related questions

Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is afunction of reaction temperature. In a chemical reaction, the time requiredto reduce the concentration of reactant from 100 gm moles/litre to 50 gmmoles/litre is same as that required to reduce it from 2 gm moles/litre to 1gm mole/litre in the same volume. Then the order of this reaction is:(A) 0(B) 1(C) 2(D) 3

Description : Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is afunction of reaction temperature. In a chemical reaction, the time required to ... Then the order of this reaction is: (A) 0 (B) 1 (C) 2 (D) 3

Last Answer : (B) 1

The irreversible reaction is a special case of reversible reaction, if the(A) Equilibrium constant is 1(B) Conversion of the reactant at equilibrium condition is zero(C) Reactant concentration at equilibrium condition is zero(D) All (A), (B) and (C)

Description : The irreversible reaction is a special case of reversible reaction, if the(A) Equilibrium constant is 1 (B) Conversion of the reactant at equilibrium condition is zero (C) Reactant concentration at equilibrium condition is zero (D) All (A), (B) and (C)

Last Answer : (C) Reactant concentration at equilibrium condition is zero

In the gaseous phase ammonia formation reaction (N2 + 3H2 ⇌ 2NH3 ), the value of the equilibrium constant depends on the (A) Total pressure of the system (B) Volume of the reactor (C) Temperature (D) Initial concentration of N2 and H2

Description : In the gaseous phase ammonia formation reaction (N2 + 3H2 ⇌ 2NH3 ), the value of the equilibrium constant depends on the (A) Total pressure of the system (B) Volume of the reactor (C) Temperature (D) Initial concentration of N2 and H2

Last Answer : (C) Temperature

Half-life period for a first order reaction is __________ the initial concentration of the reactant. (A) Directly proportional to (B) Inversely proportional to (C) Independent of(D) None of these

Description : Half-life period for a first order reaction is __________ the initial concentration of the reactant. (A) Directly proportional to (B) Inversely proportional to (C) Independent of (D) None of these

Last Answer : (C) Independent of

If the time required to change the concentration of reactant to half its original value is independent of the initial concentration, the order of reaction is: (A) Zero (B) One (C) Two (D) Three

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Last Answer : (B) One

For a __________ order chemical reaction as shown in the bellow figure, the half life period is independent of the initial concentration of the reactant A(A) Zero(B) First(C) Second(D) Third.

Description : For a __________ order chemical reaction as shown in the bellow figure, the half life period is independent of the initial concentration of the reactant A. (A) Zero (B) First (C) Second (D) Third

Last Answer : (B) First

Concentration of the limiting reactant (with initial concentration of a moles/litre) after time t is (a-x). Then 't' for a first order reaction is given by (A) k. t = ln a/(a - x) (B) k. t = x/a (a - x) (C) k. t = ln (a - x)/a (D) k. t = ln a (a - x)/x

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Last Answer : (A) k. t = ln a/(a - x)

The rate constant of a first order reaction depends on the (A) Concentration of the reactant (B) Temperature (C) Concentration of the product (D) Time

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Last Answer : (B) Temperature

Limiting reactant in a chemical reaction decides the (A) Rate constant (B) Conversion (C) Reaction speed (D) Equilibrium constant

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Last Answer : (B) Conversion

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Last Answer : (C) 0.4

Velocity of a chemical reaction (A) Decreases with increase in temperature (B) Increases with increase of pressure of reactants for all reactions (C) Decreases with increase of reactant concentration (D) None of these

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Last Answer : (D) None of these

A second order liquid phase reaction, A → B, is carried out in a mixed flow reactor operated in semi batch mode (no exit stream). The reactant A at concentration CAF is fed to the reactor at a volumetric flow rate of F. The volume of the reacting mixture is V and the density of the liquid mixture is constant. The mass balance for A is (A) d(VCA )/dt = -F (CAF - CA ) - kCA 2V (B) d(VCA )/dt = F (CAF - CA ) - kCA 2V (C) d(VCA )/dt = -FCA - kCA 2V (D) d(VCA )/dt = FCAF - kCA 2V

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Last Answer : (D) d(VCA )/dt = FCAF - kCA 2V

In an ideal P.F.R. at steady state conditions (A) The composition of reactants remains constant along a flow path (B) The conversion of the reactant varies from point to point along a flow path (C) There is no lateral mixing of fluid (D) There may be diffusion along the flow path

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Last Answer : (B) The conversion of the reactant varies from point to point along a flow path

Identify the INCORRECT statement below regarding chemical equilibrium. A All chemical reactions are, in principle, reversible. B Equilibrium is achieved when the forward reaction rate equals the reverse reaction rate. C Equilibrium is achieved when the concentrations of species become constant. D Equilibrium is achieved when the reaction quotient, Q, equals the equilibrium constant. E Equilibrium is achieved when reactant and product concentrations are equal.

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The rate constant of a reaction is a function of the (A) Time of reaction (B) Temperature of the system (C) Extent of reaction (D) Initial concentration of the reactants

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The rate constant of a reaction depends on the (A) Initial concentration of reactants (B) Time of reaction (C) Temperature of the system (D) Extent of reaction

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Last Answer : All of the carbon atoms are sp hybridized

The rate constant of a reaction depends on the (A) Initial concentration of reactants (B) Time of reaction (C) Temperature of the system (D) Extent of reaction

Description : The rate constant of a reaction depends on the (A) Initial concentration of reactants (B) Time of reaction (C) Temperature of the system (D) Extent of reaction

Last Answer : (C) Temperature of the system

The unit of equilibrium constant of a chemical reaction is the same as that of (A) Molar concentration (B) Temperature (C) Internal energy (D) None of these

Description : The unit of equilibrium constant of a chemical reaction is the same as that of (A) Molar concentration (B) Temperature (C) Internal energy (D) None of these

Last Answer : (D) None of these

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Last Answer : (B) Is the minimum energy which the molecules must have before the reaction can take place

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In a chemical reaction, represented by as shown in the bellow figure, it is observed that the (i) Rate of reaction increases by a factor of 4 on doubling the concentration of the reactant. (ii) Rate of reaction increases by a factor of 9 on trebling the concentration of the reactant. Then the rate of the reaction is proportional to(where, CA = concentration of the reactant) (A) CA (B) CA 2 (C) CA 3 (D) CA

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Last Answer : (B) CA 2

In a first order reaction, the time required to reduce the concentration of reactant from 1 mole/litre to 0.5 mole/litre will be __________ that requiredto reduce it from 10 moles/litre to 5 moles/litre in the same volume.(A) More than(B) Less than(C) Same as(D) Data insufficient; can't be predicted

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Last Answer : (C) Same as

first order chemical reaction, the concentration of the reactant decreases __________ with time. (A) Linearly (B) Exponentially (C) Logarithmically (D) Inversely

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In multistage equilibrium conversion of SO2 to SO3 (2SO2 + O2 ⇌ 2SO3 ), the reverse reaction becomes appreciable at a temperature of 550° C. The percentage equilibrium conversion of SO2 to SO3 can be increased by (A) Increasing the oxygen concentration (B) Putting more quantity of V2O5 catalyst in the converter (C) Removing some quantity of SO3 during intermediate stage (D) Maintaining low temperature & pressure in the converter

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Last Answer : (C) Removing some quantity of SO3 during intermediate stage

The knowledge of initial concentration and rate constant is necessary to determine the half life time of a reaction of __________ order. A) Zero (B) First (C) Second (D) None of these

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With increase in initial concentration, the fractional conversion of a first order reaction in a given time (A) Increases (B) Decreases (C) Remain constant (D) Unpredictable

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Which of the following is a controlling factor in very fast heterogeneous reaction? (A) Heat and mass transfer effects (B) Pressure (C) Temperature (D) Composition of reactant

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Last Answer : (A) Heat and mass transfer effects

In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled, then the equilibrium constant will (A) Remain the same (B) Be halved (C) Also be doubled (D) Become one fourth

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Last Answer : (A) Remain the same

A Catalyst (A) Increases the equilibrium concentration of the product (B) Changes the equilibrium constant of the reaction (C) Shortens the time to reach the equilibrium (D) None of these

Description : A Catalyst (A) Increases the equilibrium concentration of the product (B) Changes the equilibrium constant of the reaction (C) Shortens the time to reach the equilibrium (D) None of these

Last Answer : (C) Shortens the time to reach the equilibrium

According to the 'law of mass action', the rate of reaction is directlyproportional to the (A) Equilibrium constant (B) Volume of the reaction vessel (C) Nature of the reactants (D) Molar concentration of the reactants

Description : According to the 'law of mass action', the rate of reaction is directlyproportional to the (A) Equilibrium constant (B) Volume of the reaction vessel (C) Nature of the reactants (D) Molar concentration of the reactants

Last Answer : (D) Molar concentration of the reactants

Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an endothermic reaction (C) The rate constant for a first order reaction does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature

Description : Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an ... does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature

Last Answer : (C) The rate constant for a first order reaction does not change on changing the concentration units

The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)

Description : The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Two substances are in equilibrium in a reversible chemical reaction. If the concentration of each substance is doubled, then the value of the equilibrium constant will be (A) Same (B) Doubled (C) Halved (D) One fourth of its original value

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Last Answer : (A) Same

What is the unit of the rate constant in a chemical reaction in which 10% of the reactant decomposes in one hour, 20% in two hours, 30% in three hours and so on? (A) Litre/mole.second (B) Moles/litre.second (C) Litre/mole (D) Litre/second

Description : What is the unit of the rate constant in a chemical reaction in which 10% of the reactant decomposes in one hour, 20% in two hours, 30% in three hours and so on? (A) Litre/mole.second (B) Moles/litre.second (C) Litre/mole (D) Litre/second

Last Answer : (A) Litre/mole.second

The equilibrium constant for the reversible reaction as shown in the bellow figure, is affected by the (A) Temperature of the system (B) Presence or absence of inerts (C) Pressure of the system (D) Kinetics of the reaction

Description : The equilibrium constant for the reversible reaction as shown in the bellow figure, is affected by the (A) Temperature of the system (B) Presence or absence of inerts (C) Pressure of the system (D) Kinetics of the reaction

Last Answer : (C) Pressure of the system

The equilibrium constant ‘K’ of a chemical reaction depends on (A) Temperature only (B) Pressure only (C) Temperature and pressure (D) Ratio of reactants

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Pick out the wrong statement. (A) The conversion for a gas phase reaction increases with decrease in pressure, if there is an increase in volume accompanying the reaction (B) With increase in temperature, the equilibrium constant increases for an exothermic reaction (C) The equilibrium constant of a reaction depends upon temperature only (D) The conversion for a gas phase reaction increases with increase in pressure, if there is a decrease in volume accompanying the reaction

Description : Pick out the wrong statement. (A) The conversion for a gas phase reaction increases with decrease in pressure, if there is an increase in volume accompanying the reaction (B) With ... phase reaction increases with increase in pressure, if there is a decrease in volume accompanying the reaction

Last Answer : (B) With increase in temperature, the equilibrium constant increases for an exothermic reaction

Specific rate constant for a second order reaction (A) Is independent of temperature (B) Varies with temperature (C) Depends on the nature of the reactants (D) Both (B) and (C)

Description : Specific rate constant for a second order reaction (A) Is independent of temperature (B) Varies with temperature (C) Depends on the nature of the reactants (D) Both (B) and (C)

Last Answer : (D) Both (B) and (C)

For a zero order reaction, the concentration of product increases with the (A) Increase of reaction time (B) Increase in initial concentration (C) Total pressure (D) Decrease in total pressure

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Last Answer : (A) Increase of reaction time

Pick out the wrong statement: (A) Chemical reactions with high activation energy are very temperature sensitive (B) A flat velocity profile exists in a plug flow reactor (C) The residence time for all the elements of fluid in case of a P.F.R. need not be same (D) Half life of a reaction increases with increased initial concentration for reaction orders more than one

Description : Pick out the wrong statement: (A) Chemical reactions with high activation energy are very temperature sensitive (B) A flat velocity profile exists in a plug flow reactor (C) The residence ... D) Half life of a reaction increases with increased initial concentration for reaction orders more than one

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In a consecutive reaction system of the given figure bellow, when E1 is much greater than E2 , the yield of B increases with the (A) Increase of temperature (B) Decrease of temperature (C) Increase in initial concentration of A (D) Decrease in initial concentration of A

Description : In a consecutive reaction system of the given figure bellow, when E1 is much greater than E2 , the yield of B increases with the (A) Increase of temperature (B) Decrease of temperature (C) Increase in initial concentration of A (D) Decrease in initial concentration of A

Last Answer : (A) Increase of temperature

When sulphur is heated at 800 K, the initial pressure of 1 atm decreases by `20%` at equilibrium `K_(p)` of the reaction `S_(8)(g)rArr4S_(2)(g)` is :-

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Last Answer : When sulphur is heated at 800 K, the initial pressure of 1 atm decreases by `20%` at equilibrium `K_(p)` of the ... A. 0.2 B. 0.512 C. 1.51 D. 2

The rate constant of a chemical reaction decreases by decreasing the (A) Pressure (B) Concentration of reactants (C) Temperature (D) Duration of reaction

Description : The rate constant of a chemical reaction decreases by decreasing the (A) Pressure (B) Concentration of reactants (C) Temperature (D) Duration of reaction

Last Answer : (C) Temperature

Which of the following does not produce a change in the value of rate constant of a reaction? (A) Pressure (B) Temperature (C) Concentration and catalyst (D) None of these

Description : Which of the following does not produce a change in the value of rate constant of a reaction? (A) Pressure (B) Temperature (C) Concentration and catalyst (D) None of these

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The rate constant of a chemical reaction increases by increasing the (A) Temperature (B) Pressure (C) Reactant's concentration (D) None of these

Description : The rate constant of a chemical reaction increases by increasing the (A) Temperature (B) Pressure (C) Reactant's concentration (D) None of these

Last Answer : (A) Temperature

If the time required to complete a definite fraction of reaction varies inversely as the concentration of the reactants, then the order of reaction is (A) 1 (B) 2 (C) 3 (D) 4

Description : If the time required to complete a definite fraction of reaction varies inversely as the concentration of the reactants, then the order of reaction is (A) 1 (B) 2 (C) 3 (D) 4

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In a CSTR __________ varies with time. (A) Reaction rate (B) Concentration (C) Both (A) & (B) (D) Neither (A) nor (B)

Description : In a CSTR __________ varies with time. (A) Reaction rate (B) Concentration (C) Both (A) & (B) (D) Neither (A) nor (B)

Last Answer : (D) Neither (A) nor (B)