Identify the INCORRECT statement below regarding chemical equilibrium. A All chemical reactions are, in principle, reversible. B Equilibrium is achieved when the forward reaction rate equals the reverse reaction rate. C Equilibrium is achieved when the concentrations of species become constant. D Equilibrium is achieved when the reaction quotient, Q, equals the equilibrium constant. E Equilibrium is achieved when reactant and product concentrations are equal.

Identify the INCORRECT statement below regarding chemical equilibrium. A All chemical reactions are, in principle, reversible. B Equilibrium is achieved when the forward reaction rate equals the reverse reaction rate. C Equilibrium is achieved when the concentrations of species become constant. D Equilibrium is achieved when the reaction quotient, Q, equals the equilibrium constant. E Equilibrium is achieved when reactant and product concentrations are equal.
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1 Answer

Answer :

E Equilibrium is achieved when reactant and product concentrations are equal.
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Pick out the correct statement. (A) A catalyst speeds up the forward reaction but slows shown the reverse reaction (B) Addition of catalyst changes the equilibrium constant (C) Pressure changes do not change the equilibrium concentrations (D) The composition of equilibrium is changed by catalyst

Description : Pick out the correct statement. (A) A catalyst speeds up the forward reaction but slows shown the reverse reaction (B) Addition of catalyst changes the equilibrium constant (C) Pressure changes do not change the equilibrium concentrations (D) The composition of equilibrium is changed by catalyst

Last Answer : (C) Pressure changes do not change the equilibrium concentrations

Which one of the following statements regarding a catalyst is not correct? A An enzyme is a catalyst that only binds certain substrates. B An enzyme is a protein that is a highly efficient catalyst for one or more chemical reactions in a living system. C Catalysts increase the rate of a reaction by altering the mechanism, thereby increasing the activation energy. D Catalysts do not alter the equilibrium constant for a chemical reaction.

Description : Which one of the following statements regarding a catalyst is not correct? A An enzyme is a catalyst that only binds certain substrates. B An enzyme is a protein that is a highly ... increasing the activation energy. D Catalysts do not alter the equilibrium constant for a chemical reaction.

Last Answer : C Catalysts increase the rate of a reaction by altering the mechanism, thereby increasing the activation energy.

The irreversible reaction is a special case of reversible reaction, if the(A) Equilibrium constant is 1(B) Conversion of the reactant at equilibrium condition is zero(C) Reactant concentration at equilibrium condition is zero(D) All (A), (B) and (C)

Description : The irreversible reaction is a special case of reversible reaction, if the(A) Equilibrium constant is 1 (B) Conversion of the reactant at equilibrium condition is zero (C) Reactant concentration at equilibrium condition is zero (D) All (A), (B) and (C)

Last Answer : (C) Reactant concentration at equilibrium condition is zero

Pick out the wrong statement. (A) Catalytic activity of enzyme catalysed reactions which is affected by temperature, pH value & chemical agents, is maximum at a temperature of about 45°C(B) Most of the enzyme catalysed reactions involve at least two substrates (C) Enzymes help in increasing the activation energy of the reaction (D) Equilibrium concentrations in enzyme catalysed reactions can be calculated by using the thermodynamic properties of substrates & prod

Description : Pick out the wrong statement. (A) Catalytic activity of enzyme catalysed reactions which is affected by temperature, pH value & chemical agents, is maximum at a temperature of about 45°C ... in enzyme catalysed reactions can be calculated by using the thermodynamic properties of substrates & prod

Last Answer : (C) Enzymes help in increasing the activation energy of the reaction

In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = 0 (C) Addition of inert gas has no effect on the equilibrium constant at constant volume for any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'

Description : In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = ... any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'

Last Answer : D) All 'a', 'b' & 'c'

The equilibrium constant for the gas phase reactio A + B = C + D is 10-3. The rate of the forward reaction is 10-11 cubic centimeters per molecule per second. What is the rate constant of the reverse reaction? w) 10 cubic centimeters per molecule per second x) 10-8 cubic centimeters per molecule per second y) 10-10 cubic centimeters per molecule per second z) 10-14 cubic centimeters per molecule per second

Description : The equilibrium constant for the gas phase reactio A + B = C + D is 10-3. The rate of the forward reaction is 10-11 cubic centimeters per molecule per second. What is the rate constant of ... second y) 10-10 cubic centimeters per molecule per second z) 10-14 cubic centimeters per molecule per second

Last Answer : ANSWER: Z -- 10-14 CUBIC CENTIMETERS PER MOLECULE PER SECOND 

Limiting reactant in a chemical reaction decides the (A) Rate constant (B) Conversion (C) Reaction speed (D) Equilibrium constant

Description : Limiting reactant in a chemical reaction decides the (A) Rate constant (B) Conversion (C) Reaction speed (D) Equilibrium constant

Last Answer : (B) Conversion

Two half-reactions of an electrochemical cell are given below : MnO–4 (aq) + 8H+ (aq) + 5e– → Mn2+ (aq) + 4H2O (I), E° = 1.51 V Sn2+ (aq) → Sn4+ (aq) + 2e–, E° = + 0.15 V. Construct the redox equation from the standard potential of the cell and predict if the reaction is reactant favoured or product favoured. -Chemistry

Description : Two half-reactions of an electrochemical cell are given below : MnO-4 (aq) + 8H+ (aq) + 5e- → Mn2+ (aq) + 4H2O (I), E° = 1.51 V Sn2+ (aq) → Sn4+ (aq) + 2e- ... the redox equation from the standard potential of the cell and predict if the reaction is reactant favoured or product favoured. -Chemistry

Last Answer : The reactions can be represented at anode and at cathode in the following ways : At anode (oxidation) : Sn2+ → = Sn4+ (aq) + 2e- ] 5 E° = + 0.15 V At cathode (reduction) : MnO-4(aq) + 8H+ ... = E°cathode - E°anode = 1.51 - 0.15 = + 1.36 V ∴ Positive value of E°cell favours formation of product.

Two half-reactions of an electrochemical cell are given below : MnO–4 (aq) + 8H+ (aq) + 5e– → Mn2+ (aq) + 4H2O (I), E° = 1.51 V Sn2+ (aq) → Sn4+ (aq) + 2e–, E° = + 0.15 V. Construct the redox reaction equation from the two half-reactions and calculate the cell potential from the standard potentials and predict if the reaction is reactant or product favoured. -Chemistry

Description : Two half-reactions of an electrochemical cell are given below : MnO-4 (aq) + 8H+ (aq) + 5e- → Mn2+ (aq) + 4H2O (I), E° = 1.51 V Sn2+ (aq) → Sn4+ (aq) + ... -reactions and calculate the cell potential from the standard potentials and predict if the reaction is reactant or product favoured. -Chemistry

Last Answer : The reactions can be represented at anode and at cathode in the following ways : At anode (oxidation) : Sn2+ → Sn4+ (aq) + 2e- ] 5 E° = + 0.15 V Af cathode (reduction) : MnO-4(aq) + 8H+ ( ... = E°cathode - E°anode = 1.51 - 0.15 = + 1.36 V ∴ Positive value of E°cell favours formation of product.

In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled, then the equilibrium constant will (A) Remain the same (B) Be halved (C) Also be doubled (D) Become one fourth

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Last Answer : (A) Remain the same

Kinetics is the study of: (1) The rate of chemical reaction (2) How fast the reactions go (3) The mechanisms and paths of the molecules take in joining from one reactant to products (4) All of these are correct

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Last Answer : (4) All of these are correct Explanation: In chemistry, the study of rates and mechanisms of chemical processes and, of the factors on which they depend, is called kinetics. is the study of ... provides a very detailed picture of which bonds are broken and formed during the course of a reaction.

Kinetics is the study of: (1) The rate of chemical reaction (2) How fast the reactions go (3) The mechanisms and paths of the molecules take in joining from one reactant to products (4) All of these are correct

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Last Answer : All of these are correct

Answer: a, b, c, d Free oxygen radicals are chemical species that are intermediates in the normal process of cellular respiration. Oxidants that are free radicals have been implicated as initiators of reactions which lead to a variety of cellular injuries. Oxidants are derived from several sources, notably phagocytes. Among the effects of oxygen free radicals are membrane lipid peroxidation, DNA strand breaks, cytoskeletal disassembly and inhibition of glucose metabolism leading to decreased cellular ATP concentrations. (Figure 6-16) 187 Which of the following acute-phase protein levels are increased in human plasma following acute inflammation? a. C-reactive protein b. Serum amyloid c. a -Proteinase inhibitor d. Fibrinogen e. Albumin

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Last Answer : Answer: a, b, c, d The acute-phase response is a series of homeostatic responses of the organism to tissue injury in infection and inflammation. After an inflammatory stimulus occurs, a number ... 30% to 50% of the level before injury. The reason for the decrease in production is poorly understood

For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant(A) Is independent of pressure(B) Increases with pressure(C) Decreases with pressure(D) Increases /decreases with pressure depending on the stoichiometric co￾efficients of the reaction

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Last Answer : (B) Increases with pressure

Catalyst is a substance, which __________ chemical reaction. (A) Increases the speed of a (B) Decreases the speed of a (C) Can either increase or decrease the speed of a (D) Alters the value of equilibrium constant in a reversible

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Last Answer : (C) Can either increase or decrease the speed of a

Two substances are in equilibrium in a reversible chemical reaction. If the concentration of each substance is doubled, then the value of the equilibrium constant will be (A) Same (B) Doubled (C) Halved (D) One fourth of its original value

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Last Answer : (A) Same

The chemical reaction at one time the rate of forward and backward reaction becomes equal that state is called Equilibrium state. In a chemical equilibrium, the following properties remain unchanged with time. Pressure, Temperature, density, color Pressure, Temperature, density, color

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Last Answer : Who proposed law of mass action ?

The rate of forward reaction, at chemical equilibrium is _________the rate of backward reaction.(A) More than (B) Less than (C) Equal to (D) Either (B) or (C)

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Last Answer : (C) Equal to

If the forward rate constant of reversible reaction is 0.16 and backward rate constant is `4xx10^(4)` , then the equilibrum constant will be .

Description : If the forward rate constant of reversible reaction is 0.16 and backward rate constant is `4xx10^(4)` , then the equilibrum constant will be .

Last Answer : If the forward rate constant of reversible reaction is 0.16 and backward rate constant is `4xx10^(4)` , then the ... C. `4xx10^(-6)` D. `4xx10^(-5)`

Equilibrium constant of a reaction varies with the (A) Initial concentration of the reactant (B) Pressure (C) Temperature (D) None of these

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When a chemical reaction and it and reverse are occurring at the same time and at the same rate the reaction has achieved?

Description : When a chemical reaction and it and reverse are occurring at the same time and at the same rate the reaction has achieved?

Last Answer : equilibrium

In the reversible reaction of the type, A + B ⇌ AB, in general (A) Both forward and backward reactions will be exothermic (B) Neither of the reactions will be endothermic (C) The combination reaction will be exothermic, while the dissociation reaction will be endothermic (D) The combination reaction will be endothermic, while the dissociation reaction will be exothermic

Description : In the reversible reaction of the type, A + B ⇌ AB, in general (A) Both forward and backward reactions will be exothermic (B) Neither of the reactions will be endothermic (C) ... will be endothermic (D) The combination reaction will be endothermic, while the dissociation reaction will be exothermic

Last Answer : (C) The combination reaction will be exothermic, while the dissociation reaction will be endothermic

Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is afunction of reaction temperature. In a chemical reaction, the time requiredto reduce the concentration of reactant from 100 gm moles/litre to 50 gmmoles/litre is same as that required to reduce it from 2 gm moles/litre to 1gm mole/litre in the same volume. Then the order of this reaction is:(A) 0(B) 1(C) 2(D) 3

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Last Answer : (B) 1

What is the unit of the rate constant in a chemical reaction in which 10% of the reactant decomposes in one hour, 20% in two hours, 30% in three hours and so on? (A) Litre/mole.second (B) Moles/litre.second (C) Litre/mole (D) Litre/second

Description : What is the unit of the rate constant in a chemical reaction in which 10% of the reactant decomposes in one hour, 20% in two hours, 30% in three hours and so on? (A) Litre/mole.second (B) Moles/litre.second (C) Litre/mole (D) Litre/second

Last Answer : (A) Litre/mole.second

Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to iron catalyst in ammonia synthesis reaction (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction

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Last Answer : (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot

Pick out the wrong statement. (A) A catalyst does not alter the final position of equilibrium in a reversible reaction (B) A catalyst initiates a reaction (C) A catalyst is specific in reaction (D) A catalyst remains unchanged in chemical composition at the end the reaction

Description : Pick out the wrong statement. (A) A catalyst does not alter the final position of equilibrium in a reversible reaction (B) A catalyst initiates a reaction (C) A catalyst is specific in reaction (D) A catalyst remains unchanged in chemical composition at the end the reaction

Last Answer : (B) A catalyst initiates a reaction

Velocity of a chemical reaction (A) Decreases with increase in temperature (B) Increases with increase of pressure of reactants for all reactions (C) Decreases with increase of reactant concentration (D) None of these

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Last Answer : (D) None of these

The rate of an enzyme catalyzed reaction was measured using several substrate concentrations that were much lower than Km, the dependence of reaction velocity on substrate concentration can best be described as (A) Independent of enzyme concentration (B) A constant fraction of Vmax (C) Equal to Km (D) Proportional to the substrate concentration

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Last Answer : Answer : C

The rate constant of a first order reaction depends on the (A) Concentration of the reactant (B) Temperature (C) Concentration of the product (D) Time

Description : The rate constant of a first order reaction depends on the (A) Concentration of the reactant (B) Temperature (C) Concentration of the product (D) Time

Last Answer : (B) Temperature

For the reaction `a+brArrc+d`, initially concentrations of a and b are equal and at equilibrium the concentration of a . What will be the equilibrium

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Last Answer : For the reaction `a+brArrc+d`, initially concentrations of a and b are equal and at equilibrium the concentration of a ... ? A. 2 B. 9 C. 4 D. 3

Do Chemical reactions occur at the same rate no matter what the size of the reactant particles?

Description : Do Chemical reactions occur at the same rate no matter what the size of the reactant particles?

Last Answer : Need answer

Which one of the following statements is not correct? A Since voltage depends on concentrations, using standard conditions makes it easier to compare different electrochemical reactions. B We have to measure the cell potential to obtain the difference in potential energy because the potential of half-reactions cannot be measured directly. C The direction of a redox reaction can only be determined experimentally. D Half-cell potentials for half-reactions are determined by combining the relevant half-cell with a standardised half-cell.

Description : Which one of the following statements is not correct? A Since voltage depends on concentrations, using standard conditions makes it easier to compare different electrochemical reactions. B We have ... half-reactions are determined by combining the relevant half-cell with a standardised half-cell.

Last Answer : C The direction of a redox reaction can only be determined experimentally. 

Enzymes increases the rate of reactions by (A) Increasing the free energy of activation (B) Decreasing the energy of activation (C) Changing the equilibrium constant of the reaction (D) Increasing the free energy change of the reaction

Description : Enzymes increases the rate of reactions by (A) Increasing the free energy of activation (B) Decreasing the energy of activation (C) Changing the equilibrium constant of the reaction (D) Increasing the free energy change of the reaction

Last Answer : Answer : B

Enzymes accelerate the rate of reactions by (A) Increasing the equilibrium constant of reactions (B) Increasing the energy of activation (C) Decreasing the energy of activation (D) Decreasing the free energy change of the reaction

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Last Answer : Answer : C

if the equilibrium constant for the reaction is 4.0, what will be the equilibrium constant for the reverse reaction.

Description : if the equilibrium constant for the reaction is 4.0, what will be the equilibrium constant for the reverse reaction.

Last Answer : Ans. Kc=1/4

Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an endothermic reaction (C) The rate constant for a first order reaction does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature

Description : Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an ... does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature

Last Answer : (C) The rate constant for a first order reaction does not change on changing the concentration units

25. In a reaction, A + B  Product, rate is doubled when the concentration of B is doubled, and rate increases by a factor of 8 when the concentrations of both the reactants (A and B) are doubled, rate law for the reaction can be written as: (1) Rate = k[A]2 [B] (2) Rate = k[A] [B]2 (3) Rate = k[A]2 [B]2 (4) Rate = k[A] [B]

Description : 25. In a reaction, A + B  Product, rate is doubled when the concentration of B is doubled, and rate increases by a factor of 8 when the concentrations of both the reactants (A and B) are doubled, rate law for the reaction can be ... Rate = k[A] [B]2 (3) Rate = k[A]2 [B]2 (4) Rate = k[A] [B]

Last Answer : Rate = k[A]2 [B] (

The equilibrium constant for the reversible reaction as shown in the bellow figure, is affected by the (A) Temperature of the system (B) Presence or absence of inerts (C) Pressure of the system (D) Kinetics of the reaction

Description : The equilibrium constant for the reversible reaction as shown in the bellow figure, is affected by the (A) Temperature of the system (B) Presence or absence of inerts (C) Pressure of the system (D) Kinetics of the reaction

Last Answer : (C) Pressure of the system

The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)

Description : The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

For the reversible reaction A ⇌ 2B, if the equilibrium constant K is 0.05 mole/litre; starting from initially 2 moles of A and zero moles of B, how many moles will be formed at equilibrium? (A) 0.253 (B) 0.338 (C) 0.152 (D) 0.637

Description : For the reversible reaction A ⇌ 2B, if the equilibrium constant K is 0.05 mole/litre; starting from initially 2 moles of A and zero moles of B, how many moles will be formed at equilibrium? (A) 0.253 (B) 0.338 (C) 0.152 (D) 0.637

Last Answer : (B) 0.338

As the resources are reserved between two communicating end systems in circuit switching, ___________ is achieved. a) authentication b) guaranteed constant rate c) reliability d) store and forward

Description : As the resources are reserved between two communicating end systems in circuit switching, ___________ is achieved. a) authentication b) guaranteed constant rate c) reliability d) store and forward

Last Answer : b) guaranteed constant rate

Pick out the correct statement. (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state (C) A photochemical reaction is catalysed by light (D) A chemical reaction occurs when the energy of the reacting molecule is less than the activation energy of the reaction

Description : Pick out the correct statement. (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state (C) A photochemical reaction is catalysed by ... occurs when the energy of the reacting molecule is less than the activation energy of the reaction

Last Answer : (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state

Promoter (A) Initiates a chemical reaction and is a catalyst by itself (B) Alters the position of equilibrium in a reversible reaction (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals(D) All (A), (B) and (C)

Description : Promoter (A) Initiates a chemical reaction and is a catalyst by itself (B) Alters the position of equilibrium in a reversible reaction (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals (D) All (A), (B) and (C)

Last Answer : (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals

Which of the following statements is incorrect regarding a normal project? A. If the NPV of a project is greater than 0, then its PI will exceed 1. B. If the IRR of a project is 8%, its NPV, using a discount rate, k, greater than 8%, will be less than 0.C. If the PI of a project equals 0, then the project's initial cash outflow equals the PV of its cash flows. D. If the IRR of a project is greater than the discount rate, k, then its PI will be greater than 1.

Description : Which of the following statements is incorrect regarding a normal project? A. If the NPV of a project is greater than 0, then its PI will exceed 1. B. If the IRR of a project is 8%, its NPV, using ... the IRR of a project is greater than the discount rate, k, then its PI will be greater than 1.

Last Answer : D. If the IRR of a project is greater than the discount rate, k, then its PI will be greater than 1.

In an interphase heat transfer process, the equilibrium state corresponds to equality of temperature in the two phases, while the condition for equilibrium in an interphase mass transfer process is equality of (A) Concentrations (B) Chemical potentials (C) Activity co-efficients (D) Mass transfer co-efficients

Description : In an interphase heat transfer process, the equilibrium state corresponds to equality of temperature in the two phases, while the condition for equilibrium in an interphase mass transfer process is ... B) Chemical potentials (C) Activity co-efficients (D) Mass transfer co-efficients

Last Answer : (A) Concentrations

Pick out the wrong statement. (A) Visible radiation provides the necessary activation energy in photochemical reactions (B) The order and molecularity of a complex reaction may not be the same (C) For a second order reaction, the slope of the graph/plot between rate and (concentration) is equal to the rate constant (k) (D) Molecularity of the reaction is always a whole number greater than zero

Description : Pick out the wrong statement. (A) Visible radiation provides the necessary activation energy in photochemical reactions (B) The order and molecularity of a complex reaction may not be the same (C) For ... rate constant (k) (D) Molecularity of the reaction is always a whole number greater than zero

Last Answer : (B) The order and molecularity of a complex reaction may not be the same

When all the limiting reactant is consumed in the reaction, the operational yield __________ the relative yield. (A) Is greater than (B) Is smaller than (C) Equals (D) Can be either greater or smaller than (depends on the type of reaction)

Description : When all the limiting reactant is consumed in the reaction, the operational yield __________ the relative yield. (A) Is greater than (B) Is smaller than (C) Equals (D) Can be either greater or smaller than (depends on the type of reaction)

Last Answer : (C) Equals

The catalyst in a second order reversible reaction increases the rate of the forward reaction (A) And decreases that of backward reaction (B) And backward reaction equally (C) Only (D) To a greater extent than that of the backward reaction

Description : The catalyst in a second order reversible reaction increases the rate of the forward reaction (A) And decreases that of backward reaction (B) And backward reaction equally (C) Only (D) To a greater extent than that of the backward reaction

Last Answer : (B) And backward reaction equally

In a reversible reaction, a catalyst increases the rate of forward reaction (A) Only(B) To a greater extent than that of the backward reaction(C) And decreases that of the backward reaction(D) And the backward reaction equally

Description : In a reversible reaction, a catalyst increases the rate of forward reaction (A) Only (B) To a greater extent than that of the backward reaction (C) And decreases that of the backward reaction (D) And the backward reaction equally

Last Answer : (D) And the backward reaction equally