Description : Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is afunction of reaction temperature. In a chemical reaction, the time required to ... Then the order of this reaction is: (A) 0 (B) 1 (C) 2 (D) 3
Last Answer : (B) 1
Description : A second order liquid phase reaction, A → B, is carried out in a mixed flow reactor operated in semi batch mode (no exit stream). The reactant A at concentration CAF is fed to the reactor at a volumetric flow rate of F. The volume ... 2V (C) d(VCA )/dt = -FCA - kCA 2V (D) d(VCA )/dt = FCAF - kCA 2V
Last Answer : (D) d(VCA )/dt = FCAF - kCA 2V
Description : Equilibrium constant of a reaction varies with the (A) Initial concentration of the reactant (B) Pressure (C) Temperature (D) None of these
Last Answer : C) Temperature
Description : The irreversible reaction is a special case of reversible reaction, if the(A) Equilibrium constant is 1 (B) Conversion of the reactant at equilibrium condition is zero (C) Reactant concentration at equilibrium condition is zero (D) All (A), (B) and (C)
Last Answer : (C) Reactant concentration at equilibrium condition is zero
Description : The rate constant of a reaction depends on the (A) Initial concentration of reactants (B) Time of reaction (C) Temperature of the system (D) Extent of reaction
Last Answer : All of the carbon atoms are sp hybridized
Last Answer : (C) Temperature of the system
Description : Concentration of the limiting reactant (with initial concentration of a moles/litre) after time t is (a-x). Then 't' for a first order reaction is given by (A) k. t = ln a/(a - x) (B) k. t = x/a (a - x) (C) k. t = ln (a - x)/a (D) k. t = ln a (a - x)/x
Last Answer : (A) k. t = ln a/(a - x)
Description : In a first order reaction, the time required to reduce the concentration of reactant from 1 mole/litre to 0.5 mole/litre will be __________ that requiredto reduce it from 10 moles/litre to 5 moles/litre in the ... (A) More than (B) Less than (C) Same as (D) Data insufficient; can't be predicted
Last Answer : (C) Same as
Description : first order chemical reaction, the concentration of the reactant decreases __________ with time. (A) Linearly (B) Exponentially (C) Logarithmically (D) Inversely
Last Answer : (A) Linearly
Description : If the time required to change the concentration of reactant to half its original value is independent of the initial concentration, the order of reaction is: (A) Zero (B) One (C) Two (D) Three
Last Answer : (B) One
Description : Half-life period for a first order reaction is __________ the initial concentration of the reactant. (A) Directly proportional to (B) Inversely proportional to (C) Independent of (D) None of these
Last Answer : (C) Independent of
Description : For a __________ order chemical reaction as shown in the bellow figure, the half life period is independent of the initial concentration of the reactant A. (A) Zero (B) First (C) Second (D) Third
Last Answer : (B) First
Description : Identify the INCORRECT statement below regarding chemical equilibrium. A All chemical reactions are, in principle, reversible. B Equilibrium is achieved when the forward reaction rate equals the ... equilibrium constant. E Equilibrium is achieved when reactant and product concentrations are equal.
Last Answer : E Equilibrium is achieved when reactant and product concentrations are equal.
Description : In a chemical reaction, represented by as shown in the bellow figure, it is observed that the (i) Rate of reaction increases by a factor of 4 on doubling the concentration of the reactant. (ii) Rate of reaction increases ... where, CA = concentration of the reactant) (A) CA (B) CA 2 (C) CA 3 (D) CA
Last Answer : (B) CA 2
Description : Velocity of a chemical reaction (A) Decreases with increase in temperature (B) Increases with increase of pressure of reactants for all reactions (C) Decreases with increase of reactant concentration (D) None of these
Last Answer : (D) None of these
Description : What is the unit of the rate constant in a chemical reaction in which 10% of the reactant decomposes in one hour, 20% in two hours, 30% in three hours and so on? (A) Litre/mole.second (B) Moles/litre.second (C) Litre/mole (D) Litre/second
Last Answer : (A) Litre/mole.second
Description : Limiting reactant in a chemical reaction decides the (A) Rate constant (B) Conversion (C) Reaction speed (D) Equilibrium constant
Last Answer : (B) Conversion
Description : Second order consecutive irreversible reaction as shown in the bellow figure, were carried out in a constant volume isothermal batch reactor with different initial feed compositions. Reactor temperature was same in all the cases. In experiments ... constants (k1 /k2 )? (A) 1/4 (B) 1/2 (C) 2 (D) 4
Last Answer : (A) 1/4
Description : Specific rate constant for a second order reaction (A) Is independent of temperature (B) Varies with temperature (C) Depends on the nature of the reactants (D) Both (B) and (C)
Last Answer : (D) Both (B) and (C)
Description : In the gaseous phase ammonia formation reaction (N2 + 3H2 ⇌ 2NH3 ), the value of the equilibrium constant depends on the (A) Total pressure of the system (B) Volume of the reactor (C) Temperature (D) Initial concentration of N2 and H2
Last Answer : (C) Temperature
Description : A spherical porous catalyst particle of radius R is subjected to reactant A which reacts to form B by a zero order surface reaction A → B. Film mass transfer resistance is negligible and pore diffusion of A ... (D) Effectiveness factor for a zero order reaction cannot be 7/8 as it must always be 1
Last Answer : (A) Inner catalyst core of radius R/8 does not participate in reaction (
Description : When all the limiting reactant is consumed in the reaction, the operational yield __________ the relative yield. (A) Is greater than (B) Is smaller than (C) Equals (D) Can be either greater or smaller than (depends on the type of reaction)
Last Answer : (C) Equals
Description : For a heterogeneous catalytic reaction (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction (B) A relatively small amount of catalyst ... with the reactant (D) The surface of the catalyst does not play an important role during reaction
Last Answer : (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction
Description : Pick out the wrong statement. (A) In a batch reactor, which is exclusively used for liquid phase reactions; temperature pressure and composition may vary with time (B) In a semi-batch reactor, ... system (D) In a continuous flow reactor, both the reactants and the products flow out continuously
Last Answer : (C) In a continuous flow reactor, uniform concentration cannot be maintained throughout the vessel even in a well agitated system
Description : For a first order chemical reaction, the rate constant (A) Changes on changing the concentration units (B) Is not a function of the unit of time (C) Has unit of time -1 (D) None of these
Last Answer : (C) Has unit of time -1
Description : The knowledge of initial concentration and rate constant is necessary to determine the half life time of a reaction of __________ order. A) Zero (B) First (C) Second (D) None of these
Last Answer : (C) Second
Description : Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an ... does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature
Last Answer : (C) The rate constant for a first order reaction does not change on changing the concentration units
Description : Pick out the wrong statement. (A) Visible radiation provides the necessary activation energy in photochemical reactions (B) The order and molecularity of a complex reaction may not be the same (C) For ... rate constant (k) (D) Molecularity of the reaction is always a whole number greater than zero
Last Answer : (B) The order and molecularity of a complex reaction may not be the same
Description : For a __________ order chemical reaction as shown in the bellow figure, the fractional conversion of reactant 'A' is proportional to time. (A) Zero (B) First (C) Second (D) Third
Last Answer : (A) Zero
Description : The conversion of a reactant, undergoing a first order reaction, at a time equal to three times the half life of the reaction is: (A) 0.875 (B) 0.5 (C) 0.425 (D) Data insufficient to calculate
Last Answer : (A) 0.875
Description : The rate constant of a reaction is a function of the (A) Time of reaction (B) Temperature of the system (C) Extent of reaction (D) Initial concentration of the reactants
Last Answer : (B) Temperature of the system
Description : The conversion in a mixed reactor/accomplishing a reaction A → 3R is 50% when gaseous reactant 'A' is introduced at the rate of 1 litre/second and the leaving flow rate is 2 litres/second. The holding time for this operation is __________ second. (A) 0.5 (B) 1 (C) 2 (D) 3
Last Answer : (A) 0.5
Description : The rate constant of a chemical reaction decreases by decreasing the (A) Pressure (B) Concentration of reactants (C) Temperature (D) Duration of reaction
Description : If the rate of a chemical reaction becomes slower at a given temperature, then the (A) Initial concentration of the reactants remains constant (B) Free energy of activation is lower (C) Entropy changes (D) Free energy of activation is higher
Last Answer : (D) Free energy of activation is higher
Description : Which of the following does not produce a change in the value of rate constant of a reaction? (A) Pressure (B) Temperature (C) Concentration and catalyst (D) None of these
Last Answer : (C) Concentration and catalyst
Description : The rate constant of a chemical reaction increases by increasing the (A) Temperature (B) Pressure (C) Reactant's concentration (D) None of these
Last Answer : (A) Temperature
Description : If the time required for half change is inversely proportional to the square of initial concentration and the velocity depends on the units in which the concentration term is expressed, then the order of reaction is (A) 0 (B) 1 (C) 2 (D) 3
Last Answer : (D) 3
Description : Overall rate of reaction in a heterogeneous catalytic reaction depends upon the mass and energy transfer from the fluid to solid surface and its rate of reaction is usually __________ the concentration of ... to (B) Independent of (C) Inversely proportional to (D) Proportional to the square o
Last Answer : (A) Proportional to
Description : The most unsuitable reactor for carrying out reactions in which high reactant concentration favours high yields is (A) Backmix reactor (B) Plug flow reactor (C) Series of CSTR (D) PFR in series
Last Answer : A) Backmix reactor
Description : Which of the following is a controlling factor in very fast heterogeneous reaction? (A) Heat and mass transfer effects (B) Pressure (C) Temperature (D) Composition of reactant
Last Answer : (A) Heat and mass transfer effects
Description : Velocity of a reaction depends upon the (A) Nature of the reactants (B) Concentration of the reactants (C) Temperature at which the reaction is carried (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : In case of the irreversible unimolecular type, first order reaction, the fractional conversion at any time for constant volume system as compared to variable volume system is (A) More (B) Less (C) Same (D) Either (A) or (B), depends on other factors
Last Answer : (C) Same
Description : Two half-reactions of an electrochemical cell are given below : MnO-4 (aq) + 8H+ (aq) + 5e- → Mn2+ (aq) + 4H2O (I), E° = 1.51 V Sn2+ (aq) → Sn4+ (aq) + 2e- ... the redox equation from the standard potential of the cell and predict if the reaction is reactant favoured or product favoured. -Chemistry
Last Answer : The reactions can be represented at anode and at cathode in the following ways : At anode (oxidation) : Sn2+ → = Sn4+ (aq) + 2e- ] 5 E° = + 0.15 V At cathode (reduction) : MnO-4(aq) + 8H+ ... = E°cathode - E°anode = 1.51 - 0.15 = + 1.36 V ∴ Positive value of E°cell favours formation of product.
Description : Two half-reactions of an electrochemical cell are given below : MnO-4 (aq) + 8H+ (aq) + 5e- → Mn2+ (aq) + 4H2O (I), E° = 1.51 V Sn2+ (aq) → Sn4+ (aq) + ... -reactions and calculate the cell potential from the standard potentials and predict if the reaction is reactant or product favoured. -Chemistry
Last Answer : The reactions can be represented at anode and at cathode in the following ways : At anode (oxidation) : Sn2+ → Sn4+ (aq) + 2e- ] 5 E° = + 0.15 V Af cathode (reduction) : MnO-4(aq) + 8H+ ( ... = E°cathode - E°anode = 1.51 - 0.15 = + 1.36 V ∴ Positive value of E°cell favours formation of product.
Description : In a photosynthesis reaction, chlorophyll is: w) a reactant w) a product y) a catalyst z) an intermediate
Last Answer : ANSWER: Y -- A CATALYST
Description : With increase in initial concentration, the fractional conversion of a first order reaction in a given time (A) Increases (B) Decreases (C) Remain constant (D) Unpredictable
Last Answer : (C) Remain constant
Description : Kinetics is the study of: (1) The rate of chemical reaction (2) How fast the reactions go (3) The mechanisms and paths of the molecules take in joining from one reactant to products (4) All of these are correct
Last Answer : (4) All of these are correct Explanation: In chemistry, the study of rates and mechanisms of chemical processes and, of the factors on which they depend, is called kinetics. is the study of ... provides a very detailed picture of which bonds are broken and formed during the course of a reaction.
Last Answer : All of these are correct
Description : The order of reaction is the number of moles whose concentrations determine the rate of a reaction at a given temperature Give the integrated equation for first order reaction. K = (2.303 / t) * log (a ... a' is the initial concentration of reactants x' is the amount reacted in time t seconds
Last Answer : What is Threshold energy ?
Description : A Catalyst (A) Increases the equilibrium concentration of the product (B) Changes the equilibrium constant of the reaction (C) Shortens the time to reach the equilibrium (D) None of these
Last Answer : (C) Shortens the time to reach the equilibrium