Description : The irreversible reaction is a special case of reversible reaction, if the(A) Equilibrium constant is 1 (B) Conversion of the reactant at equilibrium condition is zero (C) Reactant concentration at equilibrium condition is zero (D) All (A), (B) and (C)
Last Answer : (C) Reactant concentration at equilibrium condition is zero
Description : Identify the INCORRECT statement below regarding chemical equilibrium. A All chemical reactions are, in principle, reversible. B Equilibrium is achieved when the forward reaction rate equals the ... equilibrium constant. E Equilibrium is achieved when reactant and product concentrations are equal.
Last Answer : E Equilibrium is achieved when reactant and product concentrations are equal.
Description : 6 gm of carbon is burnt with an amount of air containing 18 gm oxygen. The product contains 16.5 gms CO2 and 2.8 gms CO besides other constituents. What is the degree of conversion on the basis of disappearance of limiting reactant? (A) 100% (B) 95% (C) 75% (D) 20%
Last Answer : (B) 95%
Description : Equilibrium constant of a reaction varies with the (A) Initial concentration of the reactant (B) Pressure (C) Temperature (D) None of these
Last Answer : C) Temperature
Description : Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is afunction of reaction temperature. In a chemical reaction, the time required to ... Then the order of this reaction is: (A) 0 (B) 1 (C) 2 (D) 3
Last Answer : (B) 1
Description : What is the unit of the rate constant in a chemical reaction in which 10% of the reactant decomposes in one hour, 20% in two hours, 30% in three hours and so on? (A) Litre/mole.second (B) Moles/litre.second (C) Litre/mole (D) Litre/second
Last Answer : (A) Litre/mole.second
Description : For a __________ order chemical reaction as shown in the bellow figure, the fractional conversion of reactant 'A' is proportional to time. (A) Zero (B) First (C) Second (D) Third
Last Answer : (A) Zero
Description : When all the limiting reactant is consumed in the reaction, the operational yield __________ the relative yield. (A) Is greater than (B) Is smaller than (C) Equals (D) Can be either greater or smaller than (depends on the type of reaction)
Last Answer : (C) Equals
Description : Concentration of the limiting reactant (with initial concentration of a moles/litre) after time t is (a-x). Then 't' for a first order reaction is given by (A) k. t = ln a/(a - x) (B) k. t = x/a (a - x) (C) k. t = ln (a - x)/a (D) k. t = ln a (a - x)/x
Last Answer : (A) k. t = ln a/(a - x)
Description : The conversion in a mixed reactor/accomplishing a reaction A → 3R is 50% when gaseous reactant 'A' is introduced at the rate of 1 litre/second and the leaving flow rate is 2 litres/second. The holding time for this operation is __________ second. (A) 0.5 (B) 1 (C) 2 (D) 3
Last Answer : (A) 0.5
Description : Higher free energy of activation of a chemical reaction (at a given temperature) implies (A) Slower rate of reaction (B) Higher rate of reaction (C) Higher equilibrium conversion (D) Both (B) and (C)
Last Answer : (A) Slower rate of reaction
Description : In an ideal P.F.R. at steady state conditions (A) The composition of reactants remains constant along a flow path (B) The conversion of the reactant varies from point to point along a flow path (C) There is no lateral mixing of fluid (D) There may be diffusion along the flow path
Last Answer : (B) The conversion of the reactant varies from point to point along a flow path
Description : The rate constant of a first order reaction depends on the (A) Concentration of the reactant (B) Temperature (C) Concentration of the product (D) Time
Last Answer : (B) Temperature
Description : A second order liquid phase reaction, A → B, is carried out in a mixed flow reactor operated in semi batch mode (no exit stream). The reactant A at concentration CAF is fed to the reactor at a volumetric flow rate of F. The volume ... 2V (C) d(VCA )/dt = -FCA - kCA 2V (D) d(VCA )/dt = FCAF - kCA 2V
Last Answer : (D) d(VCA )/dt = FCAF - kCA 2V
Description : For a heterogeneous catalytic reaction (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction (B) A relatively small amount of catalyst ... with the reactant (D) The surface of the catalyst does not play an important role during reaction
Last Answer : (A) Free energy of activation is lowered in the presence of catalyst, which remains unchanged at the end of reaction
Description : The conversion of a reactant, undergoing a first order reaction, at a time equal to three times the half life of the reaction is: (A) 0.875 (B) 0.5 (C) 0.425 (D) Data insufficient to calculate
Last Answer : (A) 0.875
Description : In a chemical reaction, represented by as shown in the bellow figure, it is observed that the (i) Rate of reaction increases by a factor of 4 on doubling the concentration of the reactant. (ii) Rate of reaction increases ... where, CA = concentration of the reactant) (A) CA (B) CA 2 (C) CA 3 (D) CA
Last Answer : (B) CA 2
Description : Catalyst is a substance, which __________ chemical reaction. (A) Increases the speed of a (B) Decreases the speed of a (C) Can either increase or decrease the speed of a (D) Alters the value of equilibrium constant in a reversible
Last Answer : (C) Can either increase or decrease the speed of a
Description : With increase in temperature, the equilibrium __________ rises in case of endothermic reaction. (A) Constant (B) Conversion (C) Both (A) & (B) (D) Neither (A) nor (B)
Last Answer : (B) Conversion
Description : The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : Pick out the wrong statement. (A) The conversion for a gas phase reaction increases with decrease in pressure, if there is an increase in volume accompanying the reaction (B) With ... phase reaction increases with increase in pressure, if there is a decrease in volume accompanying the reaction
Last Answer : (B) With increase in temperature, the equilibrium constant increases for an exothermic reaction
Description : Pick out the correct statement. (A) A chemical reaction accompanied by absorption of heat is called an exothermic reaction (B) A chemical reaction accompanied by evolution of heat is called an ... does not change on changing the concentration units (D) Chemical equilibrium state is dynamic in nature
Last Answer : (C) The rate constant for a first order reaction does not change on changing the concentration units
Description : Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to ... Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction
Last Answer : (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot
Description : For the gaseous phase chemical reaction, C2H4(g) + H2O(g) ↔ C2H5OH(g), the equilibrium conversion does not depend on the (A) Steam to ethylene ratio (B) Temperature (C) Pressure (D) None of these
Last Answer : (D) None of these
Description : If 31.3 g of manganese(II) chloride 48.3 g of chlorine gas and 25.7 g of water react to produce manganese(IV) oxide and hydrochloric acid what is the limiting reactant and what mass of hydrochloric?
Last Answer : Need answer
Description : If 5.433 g of aluminum is burned with 8.834 g of oxygen gas what is the limiting reactant?
Last Answer : Aluminium (Al) + Oxygen (O) = Aluminium Oxide (Al2O3)Aluminium Atomic weight = about 27Oxygen Atomic weight = about) 16Proportion in Al203 = Aluminium 54, Oxygen 48Thus the ratio of weight ... will run out before the Oxygen as the reaction proceeds, making the Aluminium the limiting reactant.
Description : Kinetics is the study of: (1) The rate of chemical reaction (2) How fast the reactions go (3) The mechanisms and paths of the molecules take in joining from one reactant to products (4) All of these are correct
Last Answer : (4) All of these are correct Explanation: In chemistry, the study of rates and mechanisms of chemical processes and, of the factors on which they depend, is called kinetics. is the study of ... provides a very detailed picture of which bonds are broken and formed during the course of a reaction.
Last Answer : All of these are correct
Description : Though kinetics of ammonia synthesis dictates the use of low temperature for high equilibrium conversion, yet it is kept moderately high (550°C), because at low temperature (A) Rate of reaction is very low ... (C) Space velocity of gas is very low resulting in decreased conversion (D) None of these
Last Answer : (A) Rate of reaction is very low
Description : Which one of the following statements regarding a catalyst is not correct? A An enzyme is a catalyst that only binds certain substrates. B An enzyme is a protein that is a highly ... increasing the activation energy. D Catalysts do not alter the equilibrium constant for a chemical reaction.
Last Answer : C Catalysts increase the rate of a reaction by altering the mechanism, thereby increasing the activation energy.
Description : For a __________ order chemical reaction as shown in the bellow figure, the half life period is independent of the initial concentration of the reactant A. (A) Zero (B) First (C) Second (D) Third
Last Answer : (B) First
Description : Velocity of a chemical reaction (A) Decreases with increase in temperature (B) Increases with increase of pressure of reactants for all reactions (C) Decreases with increase of reactant concentration (D) None of these
Description : first order chemical reaction, the concentration of the reactant decreases __________ with time. (A) Linearly (B) Exponentially (C) Logarithmically (D) Inversely
Last Answer : (A) Linearly
Description : In the biosynthesis of testosterone the rate limiting step is conversion of (A) Cholesterol to pregnenolone (B) Pregnenolone to progesterone (C) Progesterone to 17 α-hydroxy progesterone (D) 17 α-Hydroxy progesterone to androstenedione
Last Answer : Answer : A
Description : A spherical porous catalyst particle of radius R is subjected to reactant A which reacts to form B by a zero order surface reaction A → B. Film mass transfer resistance is negligible and pore diffusion of A ... (D) Effectiveness factor for a zero order reaction cannot be 7/8 as it must always be 1
Last Answer : (A) Inner catalyst core of radius R/8 does not participate in reaction (
Description : In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled, then the equilibrium constant will (A) Remain the same (B) Be halved (C) Also be doubled (D) Become one fourth
Last Answer : (A) Remain the same
Description : The role of a catalyst in a chemical reaction is to change the (A) Equilibrium constant (B) Activation energy (C) Final products (D) Heat of reaction
Last Answer : (B) Activation energy
Description : Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the ... ) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions
Last Answer : (C) The intercept of the Arrhenius plot is called the 'activation energy
Description : Catalytic action in a catalytic chemical reaction follows from the ability of catalyst to change the (A) Activation energy (B) Equilibrium constant (C) Heat of reaction (D) None of these
Last Answer : (A) Activation energy
Description : For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant (A) Is independent of pressure (B) Increases with pressure (C) Decreases with pressure (D) Increases /decreases with pressure depending on the stoichiometric coefficients of the reaction
Last Answer : (B) Increases with pressure
Description : The catalyst in a first order chemical reaction changes the (A) Equilibrium constant (B) Activation energy (C) Heat of formation of the product (D) Heat of reaction
Description : The equilibrium constant ‘K’ of a chemical reaction depends on (A) Temperature only (B) Pressure only (C) Temperature and pressure (D) Ratio of reactants
Last Answer : (A) Temperature only
Description : The equilibrium constant of a catalytic chemical reaction __________ due to the presence of a catalyst. (A) Increases (B) Decreases (C) Remain unaffected (D) Unpredictable from the data
Last Answer : (C) Remain unaffected
Description : The equilibrium constant of chemical reaction __________ in the presence of catalyst. (A) Increases (B) Decreases (C) Remain unaffected (D) Can either increase or decrease (depends on the type of catalyst)
Description : The unit of equilibrium constant of a chemical reaction is the same as that of (A) Molar concentration (B) Temperature (C) Internal energy (D) None of these
Description : Two substances are in equilibrium in a reversible chemical reaction. If the concentration of each substance is doubled, then the value of the equilibrium constant will be (A) Same (B) Doubled (C) Halved (D) One fourth of its original value
Last Answer : (A) Same
Description : The free energy change for a chemical reaction is given by (where, K = equilibrium constant) (A) RT ln K (B) -RT ln K (C) -R ln K (D) T ln K
Last Answer : (B) -RT ln K
Description : In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = ... any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'
Last Answer : D) All 'a', 'b' & 'c'
Description : The equilibrium constant for a chemical reaction at two different temperatures is given by (A) Kp2/Kp1 = - (∆H/R) (1/T2- 1/T1) (B) Kp2/Kp1 = (∆H/R) (1/T2- 1/T1) (C) Kp2/Kp1 = ∆H (1/T2- 1/T1) (D) Kp2/Kp1 = - (1/R) (1/T2- 1/T1)
Last Answer : (A) Kp2/Kp1 = - (∆H/R) (1/T2- 1/T1)
Description : _________ explains the equilibrium constant for any chemical reaction. (A) Henry's law (B) Law of mass action (C) Hess's law (D) None of these
Last Answer : (B) Law of mass action