Description : At constant temperature and pressure, for one mole of a pure substance, the ratio of the free energy to the chemical potential is (A) Zero (B) One (C) Infinity (D) Negative
Last Answer : (B) One
Description : In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = ... any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'
Last Answer : D) All 'a', 'b' & 'c'
Description : What happens to the internal energy of water at reference temperature where enthalpy is zero? a. Becomes negative b. Becomes positive c. Remains constant d. Cannot be defined
Last Answer : Becomes negative
Description : Pick out the wrong statement: (A) The expansion of a gas in vacuum is an irreversible process (B) An isometric process is a constant pressure process (C) Entropy change for a reversible adiabatic process is zero (D) Free energy change for a spontaneous process is negative
Last Answer : (B) An isometric process is a constant pressure process
Description : Pressure-enthalpy chart is useful in refrigeration. The change in internal energy of an ideal fluid used in ideal refrigeration cycle is (A) Positive (B) Negative (C) Zero (D) Infinity
Last Answer : C) Zero
Description : Pick out the wrong statement. (A) α-particle emission from a radioactive element makes it electrically negative (B) β-particle emission from a radioactive element makes it electrically ... ) The disintegration constant of a radioactive isotope is independent of pressure, temperature or concentration
Last Answer : (C) A radioactive element having a half life period of 20 years will completely disintegrated in 40 years
Description : . Free energy change at equilibrium is (A) Zero (B) Positive (C) Negative (D) Indeterminate
Last Answer : (A) Zero
Description : The change in Gibbs free energy for vaporisation of a pure substance is (A) Positive (B) Negative (C) Zero (D) May be positive or negative
Last Answer : (C) Zero
Description : What chemical reaction is toxic hydrogen peroxide will spontaneously break down into water and oxygen?
Last Answer : The chemical reaction is:2 H2O2 = 2 H2O + O2
Description : The energy of activation of a chemical reaction: (A) Is same as heat of reaction at constant pressure (B) Is the minimum energy which the molecules must have before the reaction can take place (C) Varies as fifth power of the temperature (D) Both (B) and (C)
Last Answer : (B) Is the minimum energy which the molecules must have before the reaction can take place
Description : Gibbs free energy of a pure fluid approaches __________ as the pressure tends to zero at constant temperature. (A) Infinity (B) Minus infinity (C) Zero (D) None of these
Last Answer : (B) Minus infinity
Description : In frequency modulation, amplitude of modulated wave is A. positive B. negative C. constant D. zero
Last Answer : constant
Description : When total product remains constant the marginal product will be a. Zero b. Negative c. Positive d. Constant
Last Answer : a. Zero
Description : A constant potential difference is applied across the plates of a parallel-plate capacitor. Neglecting any edge effects, the electric field inside the capacitor is: w) constant x) varying as one over r squared y) decreasing as one moves from the positive to the negative plate z) zero
Last Answer : ANSWER: W -- CONSTANT
Description : If the rate of a chemical reaction becomes slower at a given temperature, then the (A) Initial concentration of the reactants remains constant (B) Free energy of activation is lower (C) Entropy changes (D) Free energy of activation is higher
Last Answer : (D) Free energy of activation is higher
Description : Pick out the wrong statement. (A) The vessel dispersion number (D/UL) for plug flow and mixed flow approaches zero and infinity respectively (B) Space time in a flow reactor is a ... ideal tubular flow reactor, mixing takes place in radial direction and there is no mixing in longitudinal direction
Last Answer : (C) Mixed reactor is always smaller than the plug flow reactor for all positive reaction orders for a particular duty
Description : Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance ... temperature and pressure is (A) 0 (B) 1 (C) ∞ (D) None of these
Last Answer : (B) 1
Description : If ΔG (free energy change) for a chemical reaction is very large and negative, then the reaction is (A) Not feasible (B) Just feasible (C) Very much feasible (D) Unpredictable as ΔG is no measure of feasibility of a reaction
Last Answer : (C) Very much feasible
Description : The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv ), depends upon its (A) Pressure (B) Volume (C) Temperature (D) All (A), (B) & (C)
Last Answer : (C) Temperature
Description : The rate constant of a chemical reaction decreases by decreasing the (A) Pressure (B) Concentration of reactants (C) Temperature (D) Duration of reaction
Description : The equilibrium constant ‘K’ of a chemical reaction depends on (A) Temperature only (B) Pressure only (C) Temperature and pressure (D) Ratio of reactants
Last Answer : (A) Temperature only
Description : The rate constant of a chemical reaction increases by increasing the (A) Temperature (B) Pressure (C) Reactant's concentration (D) None of these
Last Answer : (A) Temperature
Description : Pick out the wrong statement. (A) In a multistep reaction, the slowest step is the rate determining step (B) In general, the rate of a reaction becomes triple for every 10°C rise in temperature (C ... energy (D) Molecularity of a reaction cannot be zero but the order of a reaction can be zero
Last Answer : (B) In general, the rate of a reaction becomes triple for every 10°C rise in temperature
Description : Entropy of the system decreases, when (A) Snow melts into water (B) A gas expands spontaneously from high pressure to low pressure (C) Water is converted into ice (D) Both (B) & (C)
Last Answer : (D) Both (B) & (C)
Description : The total energy of revolving electron in an atom – (1) cannot be negative (2) can have any value above zero (3) can never be positive (4) will always be positive
Last Answer : (3) can never be positive Explanation: The total energy of a revolving electron in any orbit is the sum of its kinetic and potential energies. Energy of an electron at infinite distance from the ... and the energy of electron decreases and thus becomes negative. Thus, it can never be positive.
Description : For a missile launched with a velocity less than the earth’s escape velocity, the total energy is (1) either positive of negative (2) Negative (3) Zero (4) Positive
Last Answer : Negative
Description : The total energy of revolving electron in an atom (1) cannot be negative (2) can have any value above zero (3) can never be positive (4) will always be positive
Last Answer : can never be positive
Description : Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the ... ) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions
Last Answer : (C) The intercept of the Arrhenius plot is called the 'activation energy
Description : The unit of equilibrium constant of a chemical reaction is the same as that of (A) Molar concentration (B) Temperature (C) Internal energy (D) None of these
Last Answer : (D) None of these
Description : Pick out the wrong statement. (A) The integral method of analysing kinetic data is used when the data is scattered (B) The differential method of analysing kinetic data requires more accurate ... less than one for identical feed composition, flow rate, conversion and for all positive reaction orders
Last Answer : (C) When the reaction rate is independent of temperature, the reaction is said to be of zero order
Description : The free energy change for a chemical reaction is given by (where, K = equilibrium constant) (A) RT ln K (B) -RT ln K (C) -R ln K (D) T ln K
Last Answer : (B) -RT ln K
Description : The enthalpy change for a given reaction at `298 K` is `-x cal mol^(-1)`. If the reaction occurs spontaneously at `298 K`, the entropy change at that
Last Answer : The enthalpy change for a given reaction at `298 K` is `-x cal mol^(-1)`. If the reaction occurs ... (-1)` C. Cannot be negative D. Cannot be positive
Description : If `Delta H gt 0` and `Delta S gt 0`, the reaction proceeds spontaneously when :-
Last Answer : If `Delta H gt 0` and `Delta S gt 0`, the reaction proceeds spontaneously when :- A. `Delta H gt 0` B. ... Delta S` C. `Delta H = T Delta S` D. None
Description : The energy of activation of exothermic reaction is (A) Zero (B) Negative (C) Very large compared to that for endothermic reaction (D) Not possible to predict
Last Answer : (D) Not possible to predict
Description : For an exothermic reaction (A) Only enthalpy change (ΔH) is negative (B) Only internal energy change (ΔE) is negative (C) Both ΔH and ΔE are negative (D) Enthalpy change is zero
Last Answer : (C) Both ΔH and ΔE are negative
Description : Joule-Thomson co-efficient for a perfect gas is (A) Zero (B) Positive (C) Negative (D) None of these
Description : The cathode in an electrochemical cell always carries (A) Negative charge (B) Positive charge (C) Zero charge (D) Positive or negative charge depending upon the nature of the cell
Last Answer : (A) Negative charge
Description : Fenske equation for determining the minimum number of theoretical stages in distillation column holds good, when the (A) Relative volatility is reasonably constant (B) Mixture (to be separated) ... (to be separated) shows positive deviation from ideality (D) Multi-component distillation is involved
Last Answer : (A) Relative volatility is reasonably constant
Description : Which of the following is not a unit of the equilibrium constant Kp? (where, Δx = number of moles of products number of moles of reactants) (A) (atm)Δx, when Δx is negative (B) (atm)Δx, when Δx is positive (C) Dimensionless, when Δx = 0 (D) (atm)Δx2, when Δx > 0
Last Answer : (D) (atm)Δx2, when Δx > 0
Description : In maxilla fracture, if intra cranial pressure increases:** A. It is normal B. Typically associated with tachycardia C. Associated with blood pressure D. Usually subsides spontaneously E. Typically associated with constricted and un-reactive pupil
Last Answer : C. Associated with blood pressure
Description : ’Drying oil’, oxidized spontaneously by atmospheric oxygen at ordinary temperature and forms a hard water proof material is (A) Coconut oil (B) Peanut oil (C) Rape seed oil (D) Linseed oil
Last Answer : Answer : D
Description : If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as (A) Solubility increases as temperature ... (D) Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution
Last Answer : (B) Solubility increases as temperature decreases
Description : All of the following statements are true regarding risk events except which one? Choose the least correct answer. A. Project risks are uncertain events. B. If risks occur, they can ... that have more perceived rewards to the organization than the consequences of the risk should be accepted.
Last Answer : C. Unknown risks are threats to the project objectives, and nothing can be done to plan for them.
Description : Conjugation pili are found only on some ______ bacteria, though it may occur between cells of various bacteria. a. Gram-positive b. Gram-negative c. Acid-fast d. Capsule containing
Last Answer : b. Gram-negative
Description : A horn clause is ...................... (A) A clause in which no variables occur in the expression (B) A clause that has at least one negative literal (C) A disjunction of a number of literals (D) A clause that has at most one positive literal
Last Answer : (D) A clause that has at most one positive literal
Description : Pick out the wrong statement. (A) Visible radiation provides the necessary activation energy in photochemical reactions (B) The order and molecularity of a complex reaction may not be the same (C) For ... rate constant (k) (D) Molecularity of the reaction is always a whole number greater than zero
Last Answer : (B) The order and molecularity of a complex reaction may not be the same
Description : Pick out the wrong statement. (A) Enthalpies of all elements in their standard states are assumed to be zero (B) Combustion reactions are never endothermic in nature (C) Heat of reaction ... to the change in internal energy (D) Clausius-Clapeyron equation is not applicable to melting process
Last Answer : (D) Clausius-Clapeyron equation is not applicable to melting process
Description : In an incompressible flow of fluid, the fluid (A) Temperature remains constant (B) Compressibility is greater than zero (C) Density does not change with pressure & temperature (D) Is frictionless
Last Answer : (C) Density does not change with pressure & temperature
Description : Burning of Gasoline initially requires heat before it burns spontaneously. Which of the following does not give a good explanation of this phenomenon? a. the initial heat rises the enthalpy of the reactant ... of products. d. The enthalpy of the product is lower than the enthalpy of the reactant
Last Answer : the enthalpy of reactants is lower than the enthalpy of products.
Description : For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant (A) Is independent of pressure (B) Increases with pressure (C) Decreases with pressure (D) Increases /decreases with pressure depending on the stoichiometric coefficients of the reaction
Last Answer : (B) Increases with pressure