Chlorine free radicals react with methane by : (a) donating their free-radical electron to methane to form chloromethane. (b) abstracting a hydrogen atom from methane, and producing HCl and a methyl radical. (c) forming a carbanion intermediate that rapidly dissociates to produce chloromethane. (d) forming a carbonium ion intermediate that rapidly dissociates to form chloromethane

Chlorine free radicals react with methane by :
(a) donating their free-radical electron to methane to form chloromethane.
(b) abstracting a hydrogen atom from methane, and producing HCl and a methyl
radical.
(c) forming a carbanion intermediate that rapidly dissociates to produce
chloromethane.
(d) forming a carbonium ion intermediate that rapidly dissociates to form
chloromethane
by

1 Answer

Answer :

abstracting a hydrogen atom from methane, and producing HCl and a methyl
radical
by

Related questions

Homolytic fission of covalent bond between carbon atoms will produce : (a) Two carbonium ions (b) Two molecules (c) Free radicals (d) Carbonium ion and carbanion

Description : Homolytic fission of covalent bond between carbon atoms will produce : (a) Two carbonium ions (b) Two molecules (c) Free radicals (d) Carbonium ion and carbanion

Last Answer : Free radicals

In the reaction of propene with HCl, H+ ion acts as the : (a) electrophile (b) carbonium ion (c) nucleophile (d) carbanion

Description : In the reaction of propene with HCl, H+ ion acts as the : (a) electrophile (b) carbonium ion (c) nucleophile (d) carbanion

Last Answer : electrophile

An aqueous solution of glycine is neutral because of the formation of : (a) Carbanion (b) Zwitterion (c) Carbonium ions (d) Free radicals

Description : An aqueous solution of glycine is neutral because of the formation of : (a) Carbanion (b) Zwitterion (c) Carbonium ions (d) Free radicals

Last Answer : Zwitterion

What is the name given for a species that contains a positively charged carbon atom? (a) carbanion (b) carbocation (c) methyl radical (d) free radical

Description : What is the name given for a species that contains a positively charged carbon atom? (a) carbanion (b) carbocation (c) methyl radical (d) free radical

Last Answer : carbanion

Electron-withdrawing groups are meta directors because : (a) the carbonium ion intermediate has a negative charge on the meta position. (b) the more stable resonance hybrid occurs with meta attachment of the electrophile. (c) the less stable resonance hybrid occurs with meta attachment of the electrophile. (d) the carbonium ion intermediate has a positive charge on the meta position

Description : Electron-withdrawing groups are meta directors because : (a) the carbonium ion intermediate has a negative charge on the meta position. (b) the more stable resonance hybrid occurs with meta ... the electrophile. (d) the carbonium ion intermediate has a positive charge on the meta position

Last Answer : the more stable resonance hybrid occurs with meta attachment of the electrophile.

Which halogen does not appreciably react with methane in a free-radical substitution reaction? (a) chlorine (b) bromine (c) iodine (d) fluorine

Description : Which halogen does not appreciably react with methane in a free-radical substitution reaction? (a) chlorine (b) bromine (c) iodine (d) fluorine

Last Answer : iodine

Hydrogen and chlorine react vigorously in the presence of light (explosively) due to the formation of (a) Hydrogen-free radicals (b) Chlorine-free radicals (c) Hydrogen chloride molecule (d) Both hydrogen- and chlorine-free radicals

Description : Hydrogen and chlorine react vigorously in the presence of light (explosively) due to the formation of (a) Hydrogen-free radicals (b) Chlorine-free radicals (c) Hydrogen chloride molecule (d) Both hydrogen- and chlorine-free radicals

Last Answer : Ans:(b)

What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the chain reaction. (b) It functions by destabilizing the carbocationic intermediate and thereby increases the rate of H+ loss. (c) It serves as a Lewis base catalyst by reacting with Cl2 to generate chloride ions. (d) It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Description : What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the ... by reacting with the Cl2 and thereby activates it toward attack by benzene's π electrons.

Last Answer : It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

The mechanism of dehydration of an alcohol to give an ether involves formation of (a) Carbonium ions(b) Carbanions(c) Free radicals(d) Carbenes:

Description : The mechanism of dehydration of an alcohol to give an ether involves formation of : (a) Carbonium ions (b) Carbanions (c) Free radicals (d) Carbenes

Last Answer : Carbonium ions

The mechanism of dehydration of an alcohol to give an alkene involves formation of : (a) Carbonium ions (b) Carbanions (c) Free radicals (d) Carbenes

Description : The mechanism of dehydration of an alcohol to give an alkene involves formation of : (a) Carbonium ions (b) Carbanions (c) Free radicals (d) Carbenes

Last Answer : Carbonium ions

Homolytic fission of C–C bond leads to the formation of : (a) Free radicals (b) Carbonium ions (c) Carbanions (d) None of these

Description : Homolytic fission of C–C bond leads to the formation of : (a) Free radicals (b) Carbonium ions (c) Carbanions (d) None of these

Last Answer : Free radicals

Which of the following reagents will react with methyl group rather than thebenzene ring in methylbenzene?(a) Chlorine in the presence of uv light(b) CH3Cl in the presence of AlCl3(c) CH3COCl in the presence of AlCl3(d) Hydrogen in the presence of nickel

Description : Which of the following reagents will react with methyl group rather than the benzene ring in methylbenzene? (a) Chlorine in the presence of uv light (b) CH3Cl in the presence of AlCl3 (c) CH3COCl in the presence of AlCl3 (d) Hydrogen in the presence of nickel

Last Answer : Chlorine in the presence of uv light

Carbon atom in methyl carbocation and methyl carbanion is _____ and ______ hybridised :

Description : Carbon atom in methyl carbocation and methyl carbanion is _____ and ______ hybridised :

Last Answer : Carbon atom in methyl carbocation and methyl carbanion is _____ and ______ hybridised : A. `sp,sp^(2)` B. `sp^(3),sp ... 3),sp^(2)` D. `sp^(2),sp^(3)`

The greater acidity of carboxylic acids compared to alcohols arises primarily from : (a) the electron-donating effect of the hydroxyl group (b) the electron-withdrawing effect of the carboxyl oxygen (c) the acidity of α-hydrogens of carboxylic acids (d) the resonance stability associated with the carboxylate ion

Description : The greater acidity of carboxylic acids compared to alcohols arises primarily from : (a) the electron-donating effect of the hydroxyl group (b) the electron-withdrawing effect of the carboxyl ... of α-hydrogens of carboxylic acids (d) the resonance stability associated with the carboxylate ion

Last Answer : the resonance stability associated with the carboxylate ion

Which of the following would you expect to have the highest boiling point? w) methane x) carbon tetrachloride y) chloroform z) chloromethane

Description : Which of the following would you expect to have the highest boiling point? w) methane x) carbon tetrachloride y) chloroform z) chloromethane

Last Answer : ANSWER: X -- CARBON TETRACHLORIDE

Chlorine atom becomes a chloride ion by (a) Losing an electron (b) Gaining an electron (c) Sharing its electron with another element (d) Gaining a neutron

Description : Chlorine atom becomes a chloride ion by (a) Losing an electron (b) Gaining an electron (c) Sharing its electron with another element (d) Gaining a neutron

Last Answer : Ans:(b)

In order to become a/an ______, an atom of chlorine must ______ an electron. a. Ion; Gain b. Molecule; Lose c. Ion; Lose d. Molecule; Gain

Description : In order to become a/an ______, an atom of chlorine must ______ an electron. a. Ion; Gain b. Molecule; Lose c. Ion; Lose d. Molecule; Gain

Last Answer : a. Ion; Gain

Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an sp3 hybridized carbon undergo substitution and elimination reactions. (c) The electronegative atom is replaced by another atom or group in substitution reactions. (d) (a) and (b)

Description : Which of the following is not correct concerning substitution and elimination reactions of alkyl halides? (a) The electrophile replaces the leaving group. (b) Compounds containing electron-donating groups bonded to an ... replaced by another atom or group in substitution reactions. (d) (a) and (b)

Last Answer : (a) and (b)

The reaction between methane and chlorine in diffused sunlight is-----? A. Oxidation B. Reduction C. Polymerisation D. Radical substitution (Answer)

Description : The reaction between methane and chlorine in diffused sunlight is-----? A. Oxidation B. Reduction C. Polymerisation D. Radical substitution (Answer)

Last Answer : D. Radical substitution (Answer)

In the addition of hydrogen bromide to alkynes, which of the following species is believed to be an intermediate? (a) vinyl anion (b) vinyl cation (c) vinyl radical (d) carbene

Description : In the addition of hydrogen bromide to alkynes, which of the following species is believed to be an intermediate? (a) vinyl anion (b) vinyl cation (c) vinyl radical (d) carbene

Last Answer : vinyl cation

(A) Carbenes act as free radicals. (R) Only triplet carbenes act as biradical (divalent free radical).

Description : (A) Carbenes act as free radicals. (R) Only triplet carbenes act as biradical (divalent free radical).

Last Answer : (A) Carbenes act as free radicals. (R) Only triplet carbenes act as biradical (divalent free radical). A. ... IF (A) is incorrect but (R) is correct.

Which of the following statement(s) is/are true concerning ischemia reperfusion injury? a. During ischemia, ATP degradation results in increased plasma and intracellular levels of hypoxanthine and xanthene b. Oxygen free radicals such as the superoxide radical are involved in the expression of the proinflammatory phenotype of endothelial cells, macrophages and neutrophils c. The intracellular adhesion molecule-1 (ICAN-1) contributes to injury and disruption of the endothelial lining, with extensive capillary leak and resultant interstitial edema d. Animal models have demonstrated that passive immunization with antibodies to neutrophil adhesive complex lessen the ischemic/reperfusion microvascular injury

Description : Which of the following statement(s) is/are true concerning ischemia reperfusion injury? a. During ischemia, ATP degradation results in increased plasma and intracellular levels of ... immunization with antibodies to neutrophil adhesive complex lessen the ischemic/reperfusion microvascular injury

Last Answer : Answer: a, b, c, d During the ischemia and hypoperfusion phase, degradation of ATP stores essential to maintain cell integrity and significant loss of diffusible ... either the neutrophil adhesive complex or the endothelial selectins dramatically lessens ischemia/reperfusion microvascular injury

Addition polymerisation takes place either by a free radical mechanism or ionic mechanism depending on the reagents used. Free radical polymerisation is catalyzed by __________, which decompose to give free radicals. (A) Organic peroxides (B) Sulphuric acid (C) Hydrofluoric acid (D) None of these

Description : Addition polymerisation takes place either by a free radical mechanism or ionic mechanism depending on the reagents used. Free radical polymerisation is catalyzed by __________, which decompose to give free radicals. (A) Organic peroxides (B) Sulphuric acid (C) Hydrofluoric acid (D) None of these

Last Answer : (A) Organic peroxides

What is Carbonium Ion ?

Description : What is Carbonium Ion ?

Last Answer : Organic ions with positively charged carbon atoms are called 'carbonium' ions.

Why does a H+ ion attacking a carbon-carbon double bond add to the carbon with the least number of substituents? (a) the reaction is resonance stabilized. (b) the hybrid geometry favors this process. (c) nucleophile tends to attack stable centers of negative charge. (d) a more stable carbonium ion is generated.

Description : Why does a H+ ion attacking a carbon-carbon double bond add to the carbon with the least number of substituents? (a) the reaction is resonance stabilized. (b) the hybrid geometry favors this ... tends to attack stable centers of negative charge. (d) a more stable carbonium ion is generated.

Last Answer : a more stable carbonium ion is generated.

In the chlorination of alkanes, the first step in which chlorine free radicals are produced is called (a) initiation(b) activation(c) propagation(d) deactivation:

Description : In the chlorination of alkanes, the first step in which chlorine free radicals are produced is called : (a) initiation (b) activation (c) propagation (d) deactivation

Last Answer : initiation

Find the total number of acidic radical which produce volatile product with dil HCl : `(i) SO_(4)^(2-) " " (ii) I^(-) " " (iii) NO_(2)^(-) " " (iv) NO

Description : Find the total number of acidic radical which produce volatile product with dil HCl : `(i) SO_(4)^(2-) " " (ii) I^(-) " " (iii) NO_(2)^(-) " " (iv) NO

Last Answer : Find the total number of acidic radical which produce volatile product with dil HCl : `(i) SO_(4)^(2-) " " (ii) ... SO_(3)^(2-) " " (vi) HCO_(3)^(-)`

Arrange the following free radicals in order of decreasing stability: Methyl(I), Vinly(II), Allyl(III), Benzyl(IV)

Description : Arrange the following free radicals in order of decreasing stability: Methyl(I), Vinly(II), Allyl(III), Benzyl(IV)

Last Answer : Arrange the following free radicals in order of decreasing stability: Methyl(I), Vinly(II), Allyl(III), Benzyl(IV) ... gt III D. IV gt III gt I gt II

(A) Tertiary butyl carbonion is more stable than methyl carbanion. (R) `+I` effect of the three methyl groups in tertiary butyl carbanion tends to mak

Description : (A) Tertiary butyl carbonion is more stable than methyl carbanion. (R) `+I` effect of the three methyl groups in tertiary butyl carbanion tends to mak

Last Answer : (A) Tertiary butyl carbonion is more stable than methyl carbanion. (R) `+I` effect of the three methyl ... IF (A) is incorrect but (R) is correct.

What product is formed in the free-radical bromination of methane? (a) bromomethane (b) dibromomethane (c) tribromomethane (d) all of these

Description : What product is formed in the free-radical bromination of methane? (a) bromomethane (b) dibromomethane (c) tribromomethane (d) all of these

Last Answer : all of these

The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Description : The chlorination of methane to give CCl4 is an example of (a) an electrophilic addition (b) a free-radical substitution (c) a nucleophilic addition (d) an electrophilic substitution

Last Answer : a free-radical substitution

In which of the following compounds, the `C-Cl` bond ion-isation shall give most stable carbonium ion?

Description : In which of the following compounds, the `C-Cl` bond ion-isation shall give most stable carbonium ion?

Last Answer : In which of the following compounds, the `C-Cl` bond ion-isation shall give most stable carbonium ion? A. B. C. D.

The compound which give the most stable carbonium ion on dehydration is

Description : The compound which give the most stable carbonium ion on dehydration is

Last Answer : The compound which give the most stable carbonium ion on dehydration is A. `CH_(3) - underset(CH_(3)) ... underset(OH)underset(|)(CH)-CH_(2)CH_(3)`

The smallest particle of an element is called - (1) Ion (2) Electron (3) Atom (4) Molecule

Description : The smallest particle of an element is called - (1) Ion (2) Electron (3) Atom (4) Molecule

Last Answer : (3) Atom Explanation: An element is a substance completely made up of one atom. However, the atom itself is not the smallest known particle, but instead each atom is made up of three individual parts: electrons, protons and neutrons.

Which of the following is true when HCL is passed through water. (i) It does not ionize in the solution as it is a covalent compound (ii) It ionizes in the solution (iii) It gives both hydrogen and hydroxyl ions in the solution (iv) It forms hydronium ion in the solution due to the combination of hydrogen ion with water molecule. (a) (i) only (b) (iii) only (c) (ii) and (iv) only (d) (iii) and (iv)

Description : Which of the following is true when HCL is passed through water. (i) It does not ionize in the solution as it is a covalent compound (ii) It ionizes in the solution (iii) It gives both hydrogen and hydroxyl ions in the solution ... ) (i) only (b) (iii) only (c) (ii) and (iv) only (d) (iii) and (iv)

Last Answer : (c) (ii) and (iv) only

Due to the presence of an unpaired electron, free radicals are:

Description : Due to the presence of an unpaired electron, free radicals are:

Last Answer : Due to the presence of an unpaired electron, free radicals are: A. chemically reactive B. chemically inactive C. anions D. cations

When radiation breaks an electron pair bond in a molecule and each fragment of the molecule gets one of the bond electrons, the molecular fragments that are formed are called: w) ions x) free radicals y) stable molecules z) gases

Description : When radiation breaks an electron pair bond in a molecule and each fragment of the molecule gets one of the bond electrons, the molecular fragments that are formed are called: w) ions x) free radicals y) stable molecules z) gases

Last Answer : ANSWER: X -- FREE RADICALS

Which of the following statements describes the first step in the mechanism of the aldol condensation? (a) An alpha hydrogen is abstracted by the base to form an enolate anion. (b) A nucleophilic base attacks the carbonyl carbon atom. (c) The carbonyl oxygen is protonated by the base ion. (d) The alpha hydrogen is abstracted by an acid to the enolate anion.

Description : Which of the following statements describes the first step in the mechanism of the aldol condensation? (a) An alpha hydrogen is abstracted by the base to form an enolate anion. (b) A nucleophilic base attacks ... by the base ion. (d) The alpha hydrogen is abstracted by an acid to the enolate anion.

Last Answer : An alpha hydrogen is abstracted by the base to form an enolate anion

Mixing vessel used for the chlorination of methane to produce methyl chloride is made of (A) Copper (B) Cast iron (C) Aluminium (D) High carbon steel

Description : Mixing vessel used for the chlorination of methane to produce methyl chloride is made of (A) Copper (B) Cast iron (C) Aluminium (D) High carbon steel

Last Answer : (B) Cast iron

A chlorine atom reacts with a sodium atom to form sodium chloride, NaCl. A chlorine atom can also react with another chlorine atom to form a chlorine molecule, Cl2. Which statement BEST explains the behavior of chlorine in these two reactions?

Description : A chlorine atom reacts with a sodium atom to form sodium chloride, NaCl. A chlorine atom can also react with another chlorine atom to form a chlorine molecule, Cl2. Which statement BEST explains the behavior of chlorine in these two reactions?

Last Answer : A chlorine atom can form ionic bonds by accepting an electron and covalent bonds by sharing electrons.

Show diagrammatically the electron distributions in a sodium atom and a sodium ion and also give their atomic number. -Science

Description : Show diagrammatically the electron distributions in a sodium atom and a sodium ion and also give their atomic number. -Science

Last Answer : Atomic number of sodium (Z) =11 Mass number of sodium (A) = 23 Number of protons in the nucleus = 11 Number of neutrons in the nucleus =23-11 = 12 Number of electrons = 11 Electronic ... the electronic configuration is 2, 8(K, L). However, the number of protons and neutrons remains the same.

Which of the following hydrogen halides react with `AgNO_3` to give a precipitate that dissolves in hypo solution ? (I)HCl (II)HF (III)HI (IV)HBr

Description : Which of the following hydrogen halides react with `AgNO_3` to give a precipitate that dissolves in hypo solution ? (I)HCl (II)HF (III)HI (IV)HBr

Last Answer : Which of the following hydrogen halides react with `AgNO_3` to give a precipitate that dissolves in hypo solution ? (I) ... II),(I) D. (II),(IV),(III)

With hydrocarbons, is chlorine the ONLY atom powerful enough to remove a hydrogen atom from an alkane?

Description : With hydrocarbons, is chlorine the ONLY atom powerful enough to remove a hydrogen atom from an alkane?

Last Answer : (Disclaimer: I had organic chemistry 10 years ago, so you may want to back this up with some googling) Flourine reacts with alkanes, but it is so reactive it is unpredictable; you don't know ... . It seems like you can get the more powerful acids to react with alkanes under the right conditions.

Metronidazole is selectively active against anaerobic organisms because: A. Aerobes have an active transport mechanism to pump it out of their cell B. Only anaerobes reduce it to generate the reactive nitro radical C. It is rapidly inactivated in the presence of oxygen D. It binds to DNA of anaerobes with high affinity

Description : Metronidazole is selectively active against anaerobic organisms because: A. Aerobes have an active transport mechanism to pump it out of their cell B. Only anaerobes reduce it to generate the reactive ... inactivated in the presence of oxygen D. It binds to DNA of anaerobes with high affinity

Last Answer : B. Only anaerobes reduce it to generate the reactive nitro radical

If a chlorine atom were to attract an electron from sodium the chlorine atom would become?

Description : If a chlorine atom were to attract an electron from sodium the chlorine atom would become?

Last Answer : positively

If a chlorine atom were to attract an electron from sodium the chlorine atom would become blank charged?

Description : If a chlorine atom were to attract an electron from sodium the chlorine atom would become blank charged?

Last Answer : negative

Give reason: sodium has lower electron affinity than chlorine atom.

Description : Give reason: sodium has lower electron affinity than chlorine atom.

Last Answer : As electron affinity increases across a period (from left to right)

Which of the following compounds have highest dipole moment? (a) dichloromethane (b) chloroform (c) chloromethane (d) carbon tetrachloride

Description : Which of the following compounds have highest dipole moment? (a) dichloromethane (b) chloroform (c) chloromethane (d) carbon tetrachloride

Last Answer : dichloromethane

Which of the following compounds have lowest dipole moment? (a) carbon tetrachloride(b) chloromethane(c) dichloromethane(d) chloroform

Description : Which of the following compounds have lowest dipole moment? (a) carbon tetrachloride (b) chloromethane (c) dichloromethane (d) chloroform

Last Answer : carbon tetrachloride

How many electron lone pairs are on the central atom in Hydrogen Sulfide?

Description : How many electron lone pairs are on the central atom in Hydrogen Sulfide?

Last Answer : ANSWER: TWO