The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When `-NO_(2)` group is present at ortho

The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When `-NO_(2)` group is present at ortho
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The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When ` ... product (H) is : A. B. C. D.
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The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When `-NO_(2)` group is present at ortho

Description : The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When `-NO_(2)` group is present at ortho

Last Answer : The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When ` ... product (I) is : A. B. C. D.

The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When `-NO_(2)` group is present at ortho

Description : The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When `-NO_(2)` group is present at ortho

Last Answer : The `-NO_(2)` group in an aromatic ring deactivates the ortho and para positions for an electrophilic attack. When ` ... product (G) is : A. B. C. D.

Phenol is an ortho-para director because the hydroxyl group : (a) donates electrons that increase electron density at ortho and para positions favoring nucleophilic attack. (b) donates electrons that increase electron density at ortho and para positions favoring electrophilic attack. (c) donates electrons to the ortho and para positions and attracts electrons away from meta positions favoring nucleophilic attack of the ring. (d) donates electrons to the ortho and para positions and attracts electrons away from meta positions favoring electrophilic attack on the ring.

Description : Phenol is an ortho-para director because the hydroxyl group : (a) donates electrons that increase electron density at ortho and para positions favoring nucleophilic attack. (b) donates ... para positions and attracts electrons away from meta positions favoring electrophilic attack on the ring.

Last Answer : donates electrons that increase electron density at ortho and para positions favoring electrophilic attack.

Which of the following will undergo substitution in the ortho and para positions rather than in the meta position? (a) Nitrobenzene (b) Benzoic acid (c) Acetanilide (d) Benzaldehyde

Description : Which of the following will undergo substitution in the ortho and para positions rather than in the meta position? (a) Nitrobenzene (b) Benzoic acid (c) Acetanilide (d) Benzaldehyde

Last Answer : Acetanilide

Reimer-Tiemann reaction introduces an aldehyde group on to the aromatic ring of phenol, ortho to the hydroxyl group. This reacrtion involves electroph

Description : Reimer-Tiemann reaction introduces an aldehyde group on to the aromatic ring of phenol, ortho to the hydroxyl group. This reacrtion involves electroph

Last Answer : Reimer-Tiemann reaction introduces an aldehyde group on to the aromatic ring of phenol, ortho to the hydroxyl group. ... (I) is: A. B. C. D.

Reimer-Tiemann reaction introduces an aldehyde group on to the aromatic ring of phenol, ortho to the hydroxyl group. This reacrtion involves electroph

Description : Reimer-Tiemann reaction introduces an aldehyde group on to the aromatic ring of phenol, ortho to the hydroxyl group. This reacrtion involves electroph

Last Answer : Reimer-Tiemann reaction introduces an aldehyde group on to the aromatic ring of phenol, ortho to the hydroxyl group. This ... (2)` D. `.^(*)C Cl_(3)`

Reimer-Tiemann reaction introduces an aldehyde group on to the aromatic ring of phenol, ortho to the hydroxyl group. This reacrtion involves electroph

Description : Reimer-Tiemann reaction introduces an aldehyde group on to the aromatic ring of phenol, ortho to the hydroxyl group. This reacrtion involves electroph

Last Answer : Reimer-Tiemann reaction introduces an aldehyde group on to the aromatic ring of phenol, ortho to the hydroxyl group. ... ` D. aq. `NaOH + C Cl_(4)`

Which of the following substituents is an ortho and para director and ring deactivating? (a) –NH2 (b) –Cl (c) –OCH3 (d) –OH

Description : Which of the following substituents is an ortho and para director and ring deactivating? (a) –NH2 (b) –Cl (c) –OCH3 (d) –OH

Last Answer : –Cl

What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the chain reaction. (b) It functions by destabilizing the carbocationic intermediate and thereby increases the rate of H+ loss. (c) It serves as a Lewis base catalyst by reacting with Cl2 to generate chloride ions. (d) It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

Description : What purpose does FeCl3 serve in the electrophilic aromatic substitution reaction between chlorine and benzene? (a) It serves as a radical initiator to produce the chlorine radical needed to propagate the ... by reacting with the Cl2 and thereby activates it toward attack by benzene's π electrons.

Last Answer : It serves as a Lewis acid catalyst by reacting with the Cl2 and thereby activates it toward attack by benzene’s π electrons.

For reactions of ethylbenzene, the ethyl group is considered : (a) ortho director (b) ortho-para director (c) meta director (d) ortho-meta director

Description : For reactions of ethylbenzene, the ethyl group is considered : (a) ortho director (b) ortho-para director (c) meta director (d) ortho-meta director

Last Answer : ortho-para director

What is the balanced veratrole and nitric acid? Also, would you expect ortho-dimethoxybenzene or para-dimethoxybenzene to be nitrated more readily?

Description : What is the balanced veratrole and nitric acid? Also, would you expect ortho-dimethoxybenzene or para-dimethoxybenzene to be nitrated more readily?

Last Answer : answer:1. Are you asking for the balanced equation? 2. What determines how easily something is nitrated? Draw out the two structures and look at them.

The most suitable method of separation of a mixture of ortho and para nitrophenol in the ratio `1:1` is :

Description : The most suitable method of separation of a mixture of ortho and para nitrophenol in the ratio `1:1` is :

Last Answer : The most suitable method of separation of a mixture of ortho and para nitrophenol in the ... B. Distillation C. Sublimation D. Chromatography

Although — NH2 gp is an ortho and para directing gp, nitration of aniline gives along with ortho and para, meta derivatives also.

Description : Although — NH2 gp is an ortho and para directing gp, nitration of aniline gives along with ortho and para, meta derivatives also.

Last Answer : Nitration is carried out with a mixture of Conc. NO3 + Conc. H2 SO4 (nitrating mix). In the presence of these acids, most of aniline gets protonated to form anilinium ion. Therefore, in the ... is m-directing and deactivating hence a mixture of all three-ortho, para and meta derivatives is formed.

While separating a mixture of ortho and para-nitro phenols by steam distillation, name the isomer which will be steam volatile. Give reasons.

Description : While separating a mixture of ortho and para-nitro phenols by steam distillation, name the isomer which will be steam volatile. Give reasons.

Last Answer : In o-nitrophenol, there is intramolecular hydrogen bonding as follows : In p-nitrophenol, there is intramolecular hydrogen bonding as follows :   Due to intermolecular H ... -nitrophenol. Hence o-nitraphenol due to its lower b. p. is steam volatile while pnitrophenol is not.

Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with acidic KMnO4 solution. (c) on refluxing with concentrated H2SO4 gives a mixture of ortho and para toluenesulfonic acid. (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Description : Which of the following statements is false about toluene? (a) can be prepared by treating benzene with methyl chloride in the presence of AlCl3. (b) is converted to benzoic acid on refluxing with ... (d) can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene.

Last Answer : can be nitrated with concentrated nitric acid to give a mixture of ortho and meta nitrotoluene

Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ?

Description : Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ?

Last Answer : Arrange the following compound in reactivity towards EAS (Electrophilic aromatic substitution) reaction ? A. `A gt B gt ... A` D. `C gt B gt D gt A`

In electrophilic aromatic substitution reactions a chlorine substituent __________. (a) is a deactivator and a m-director (b) is a deactivator and an o,p-director (c) is an activator and a m-director (d) is an activator and an o,p-director

Description : In electrophilic aromatic substitution reactions a chlorine substituent __________. (a) is a deactivator and a m-director (b) is a deactivator and an o,p-director (c) is an activator and a m-director (d) is an activator and an o,p-director

Last Answer : is a deactivator and an o,p-director

How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Description : How an — OH group attached to carbon in the benzene ring activates benzene towards electrophilic substitution ?

Last Answer : The lone pair of electrons present on oxygen atom enter into resonance with the benzene ring. As a result, the electron density becomes higher at o- and p- position and due to higher electron density, the ring gets activated towards electrophilic substitution.

Peptizers like aromatic mercaptans (e.g. thiophenes) are added in rubber to (A) Protect rubber goods from attack by oxygen & ozone present in the atmosphere (B) Reduce its viscosity to permit easier processing (C) Reduce the time of vulcanisation and quantity of vulcanising agent (D) Increase its viscosity

Description : Peptizers like aromatic mercaptans (e.g. thiophenes) are added in rubber to (A) Protect rubber goods from attack by oxygen & ozone present in the atmosphere (B) Reduce its viscosity to ... processing (C) Reduce the time of vulcanisation and quantity of vulcanising agent (D) Increase its viscosity

Last Answer : (B) Reduce its viscosity to permit easier processing

The most favourable position (indicated by ) for an electrophilic attack is

Description : The most favourable position (indicated by ) for an electrophilic attack is

Last Answer : The most favourable position (indicated by ) for an electrophilic attack is A. B. C. D.

Which one of the following is most reactive towards electrophilic attack?

Description : Which one of the following is most reactive towards electrophilic attack?

Last Answer : Which one of the following is most reactive towards electrophilic attack? A. B. C. D.

Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the rate-determining step. (c) The carbocation intermediate contains an sp3 hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Description : Which of the following is not a correct statement about the electrophilic substitution mechanism of benzene? (a) Benzene functions as a nucleophile. (b) Formation of a carbocation intermediate is the ... hybridized carbon in the ring. (d) The addition product is a frequently observed minor product.

Last Answer : The addition product is a frequently observed minor product.

The brown ring test for `NO_(2)^(-)` and `NO_(3)^(-)` is due to the formation of complex ion with formula `:`

Description : The brown ring test for `NO_(2)^(-)` and `NO_(3)^(-)` is due to the formation of complex ion with formula `:`

Last Answer : The brown ring test for `NO_(2)^(-)` and `NO_(3)^(-)` is due to the formation of complex ion with formula `:` A. ... )` D. `[Fe(H_(2)O)(NO)_(5)]^(2+)`

Fluorination of an aromatic ring is easily accompolished by treating a diazonium salt with `HBF_4`. Which of the following conditions is correct about

Description : Fluorination of an aromatic ring is easily accompolished by treating a diazonium salt with `HBF_4`. Which of the following conditions is correct about

Last Answer : Fluorination of an aromatic ring is easily accompolished by treating a diazonium salt with `HBF_4`. Which of the ... O //H_(2)O` D. `NaF//Cu`

A major structural difference between estrogens and androgens is the fact that (A) The androgens are usually C21 steroids (B) The estrogens are usually digitonin - precipitable (C) The androgens have an aromatic ring (D) The estrogens have an aromatic ring

Description : A major structural difference between estrogens and androgens is the fact that (A) The androgens are usually C21 steroids (B) The estrogens are usually digitonin - precipitable (C) The androgens have an aromatic ring (D) The estrogens have an aromatic ring

Last Answer : Answer : D

Which of one ring in the structure of the following is aromatic? (A) Androgens (B) Estrogens (C) Cholesterol (D) Bile acids

Description : Which of one ring in the structure of the following is aromatic? (A) Androgens (B) Estrogens (C) Cholesterol (D) Bile acids

Last Answer : Answer : B

A coenzyme containing aromatic hetero ring is (A) TPP (B) Lipoic acid (C) Coenzyme Q (D) Biotin

Description : A coenzyme containing aromatic hetero ring is (A) TPP (B) Lipoic acid (C) Coenzyme Q (D) Biotin

Last Answer : Answer : A

A coenzyme containing non aromatic hetero ring is (A) ATP (B) NAD (C) FMN (D) Biotin

Description : A coenzyme containing non aromatic hetero ring is (A) ATP (B) NAD (C) FMN (D) Biotin

Last Answer : Answer : D

Cyclohexane does not belong to aromatic class even though it has a ring structure. How do you justify this?

Description : Cyclohexane does not belong to aromatic class even though it has a ring structure. How do you justify this?

Last Answer : Cyclohexane is a saturated hydrocarbon in which the carbon atoms are joined by single covalent bonds to form a ring where as in aromatic hydrocarbons have alternate single and double bonds. Hence Cyclohexane is does not belong to aromatic class.

Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ?

Description : Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ?

Last Answer : Can the amino group, in the aniline molecule, become meta-directing in an electrophilic substitution reaction ... D. Yes, in a non-polar solvent

Statement I: In strongly acidic solutions , anline becomes more reactive towards electrophilic reagents Statement II: The amino group being completely

Description : Statement I: In strongly acidic solutions , anline becomes more reactive towards electrophilic reagents Statement II: The amino group being completely

Last Answer : Statement I: In strongly acidic solutions , anline becomes more reactive towards electrophilic reagents ... Assertion is false but Reason is true.

Assertion: Phenol is more reactive than benzene towards electrophilic reactions. Reason : The +R effect of OH group increases the electron density on

Description : Assertion: Phenol is more reactive than benzene towards electrophilic reactions. Reason : The +R effect of OH group increases the electron density on

Last Answer : Assertion: Phenol is more reactive than benzene towards electrophilic reactions. Reason : The +R effect of ... D. A is incorrect but R is correct

Thermal pollution of water increases its toxicity and oxidation of oxygen demanding waste besides favouring bacterial growth. A rise in water temperature by 10°C, doubles the toxic effects of __________ present in it. (A) Coal ash (B) Potassium cyanide (C) Ortho-xylene (D) None of these

Description : Thermal pollution of water increases its toxicity and oxidation of oxygen demanding waste besides favouring bacterial growth. A rise in water temperature by 10°C, doubles the toxic effects of __________ present in it. (A) Coal ash (B) Potassium cyanide (C) Ortho-xylene (D) None of these

Last Answer : (B) Potassium cyanide

Assertion :- In `NH_(4)NO_(3)`, the oxidation number of the two N-atoms is not equal. Reason :- One N atom is present in the ammonium ion while the ot

Description : Assertion :- In `NH_(4)NO_(3)`, the oxidation number of the two N-atoms is not equal. Reason :- One N atom is present in the ammonium ion while the ot

Last Answer : Assertion :- In `NH_(4)NO_(3)`, the oxidation number of the two N-atoms is not equal. Reason : ... is False. D. If both Assertion & Reason are False.

The volume (in `mL`) of `0.1M Ag NO_(3)` required for complete precipitation of chloride ions present in `30 mL` of `0.01M` solution of `[Cr(H_(2)O)_(

Description : The volume (in `mL`) of `0.1M Ag NO_(3)` required for complete precipitation of chloride ions present in `30 mL` of `0.01M` solution of `[Cr(H_(2)O)_(

Last Answer : The volume (in `mL`) of `0.1M Ag NO_(3)` required for complete precipitation of chloride ions present ... Cl]Cl_(2)`, as silver chloride is close to:

With increase in the molecular weight of aromatic present in kerosene, its smoking tendency (A) Increases (B) Decreases (C) Remain same (D) Is unpredictable

Description : With increase in the molecular weight of aromatic present in kerosene, its smoking tendency (A) Increases (B) Decreases (C) Remain same (D) Is unpredictable

Last Answer : (A) Increases

When a group gives some of its leadership positions to the members of other group, it is (a) Contracting ; (b) Co-opting ; (c) Co-alition ; (d) Competition

Description : When a group gives some of its leadership positions to the members of other group, it is (a) Contracting ; (b) Co-opting ; (c) Co-alition ; (d) Competition

Last Answer : (b) Co-opting ; 

Which antibiotic contains NO2 group attached to aromatic nucleus in its structure ?

Description : Which antibiotic contains NO2 group attached to aromatic nucleus in its structure ?

Last Answer : Ans. Chloramphenicol. 

Which of the following amino acids has an aromatic R group? (a) Serine (b) Cysteine (c) Asparagine (d) Tyrosine

Description : Which of the following amino acids has an aromatic R group? (a) Serine (b) Cysteine (c) Asparagine (d) Tyrosine

Last Answer : Tyrosine

Toluene o/p orienting with respect to an electrophilic substitution reaction due to

Description : Toluene o/p orienting with respect to an electrophilic substitution reaction due to

Last Answer : Toluene o/p orienting with respect to an electrophilic substitution reaction due to A. `+I` effect of the ... ring D. `+M` effect to the methyl group.

The reactivity of compound `Z` with different halogens under appropriate conditions is gives below- The observed pattern of electrophilic substitution

Description : The reactivity of compound `Z` with different halogens under appropriate conditions is gives below- The observed pattern of electrophilic substitution

Last Answer : The reactivity of compound `Z` with different halogens under appropriate conditions is gives below- ... the electronic effect of the tert-butyl group

(A) Cation carriers, e.g., `H-Br,Cl-OH` and `Br-Br` and oxidising agents such as `O_(3)` and `R-O-O-R`, etc. act as electrophilic reagents. (R) Electr

Description : (A) Cation carriers, e.g., `H-Br,Cl-OH` and `Br-Br` and oxidising agents such as `O_(3)` and `R-O-O-R`, etc. act as electrophilic reagents. (R) Electr

Last Answer : (A) Cation carriers, e.g., `H-Br,Cl-OH` and `Br-Br` and oxidising agents such as `O_(3)` and ... incorrect. D. IF (A) is incorrect but (R) is correct.

Which of the following are examples of electrophilic addition?

Description : Which of the following are examples of electrophilic addition?

Last Answer : Which of the following are examples of electrophilic addition? A. `CH_(3)-HC=CH_(2)+H_(2)OrarrCH_(3)-overset(OH ... "| ")"CH"-CH_(3)` D. None of these

Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds:

Description : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds:

Last Answer : Identify the correct order of reactivity in electrophilic substitution reactions of the following ... C. `IIgtIgtIIIgtIV` D. `IIgtIIIgtIgtIV`

Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds :

Description : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds :

Last Answer : Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds : ... ` C. `2gt1gt3gt4` D. `2gt3gt1gt4`

Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is :

Description : Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is :

Last Answer : Among the following compounds, the decreasing order of reactivity towards electrophilic substitution is : ... C. `IVgtIgtIIgtIII` D. `IIIgtIgtIIgtIV`

An electrophilic reagent is:

Description : An electrophilic reagent is:

Last Answer : An electrophilic reagent is: A. electron-rich species B. electron-deficient spcies C. a Lewis base D. negatively charged species

Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Description : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the intermediate carbocation is more resonance st

Last Answer : Phenol is more reactive than benzene towards electrophilic substitution reaction. In case of Phenol, the ... D. A is incorrect but R is correct

What is electrophilic addition reaction ?

Description : What is electrophilic addition reaction ?

Last Answer : When the attacking species during the addition reaction is Electrophile, it is called electrophilic addition reaction. Ex; (+) (-) (+) (-) (+) (-) CH2Br-CH2BràH2C-CH2+BrBr-àH2C=CH2+Br2-

Give the example for electrophilic substitution reaction ?

Description : Give the example for electrophilic substitution reaction ?

Last Answer : The species, which accepts the electrons, are called Electrophilles (or) Electrophilic reagents. When the atom (or) group of atoms present in the organic compound is replaced by another atom (or) group of atoms (electrophilic) is called electrophilic substitution reaction.