According to Arrhenius equation of temperature dependency of rate
constant for an elementary reaction
(A) k ∝ √T
(B) k ∝ e
-E/RT
(C) k ∝ T e
-E/RT
(D) None of these

1 Answer

Answer :

(B) k ∝ e
-E/RT

Related questions

Description : Rate constant 'k' and absolute temperature 'T' are related by collision theory (for bimolecular) as (A) k ∝ T 1.5 (B) k ∝ exp(-E/RT) (C) k ∝ √T (D) k ∝ T

Last Answer : (C) k ∝ √T

Description : Transition state theory relates the above quantities as (A) k ∝ e -E/RT (B) k ∝ T.e E/RT (C) k ∝ √T (D) k ∝ T 1.5

Last Answer : (B) k ∝ T.e E/RT

Description : Collision theory gives the rate constant for bimolecular reaction as (A) K α √T.e -E/RT (B) K α e E/RT (C) K α e -E/RT (D) None of these

Last Answer : (C) K α e -E/RT

Description : From collision theory, the reaction rate constant is proportional to (A) exp (-E/RT) (B) exp (-E/2RT) (C) √T (D) T m exp (-E/RT)

Last Answer : (D) T m exp (-E/RT)

Description : Which of the following represents the Virial equation of state? (A) T = [RT/(V- b)] - [a/√T. V(V + b)] (B) PV/RT = 1 + (B/V) + (C/V2) + …… (C) n1u2 + μ2μ1 = 0 (D) None of these

Last Answer : (B) PV/RT = 1 + (B/V) + (C/V2) + ……

Description : The local surface conductance for laminar film condensation on vertical surface is (where, t = film thickness) (A) ∝ t (B) ∝ 1/t (C) ∝ √t (D) Independent of 't

Last Answer : (B) ∝ 1/t

Description : Arrhenius equation K = Ae-E a / R T In some reactions, Rate of reaction is directly proportional to. Concentration of catalyst Catalyst used in Bio-Chemical reactions is called. Enzymes Reactions catalyzed by light are called as. Photo catalyzed or Photosensitised reactions

Last Answer : Define order of reaction

Description : The units of frequency factor in Arrhenius equation (A) Are the same as those of the rate constant (B) Depend on the order of the reaction (C) Depend on temperature, pressure etc. of the reaction (D) Are cycles per unit time

Last Answer : (A) Are the same as those of the rate constant

Description : Arrhenius equation represents graphically the variation between the __________ and temperature. (A) Rate of reaction (B) Frequency factor (C) Rate constant (D) Activation energy

Last Answer : (C) Rate constant

Description : Arrhenius equation shows the variation of __________ with temperature. (A) Reaction rate (B) Rate constant (C) Energy of activation (D) Frequency factor

Last Answer : (B) Rate constant

Description : The free energy change for a chemical reaction is given by (where, K = equilibrium constant) (A) RT ln K (B) -RT ln K (C) -R ln K (D) T ln K

Last Answer : (B) -RT ln K

Description : Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the ... ) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions

Last Answer : (C) The intercept of the Arrhenius plot is called the 'activation energy

Description : With increase in temperature, the rate constant obeying Arrhenius equation (A) Increases (B) Decreases (C) Decreases exponentially (D) Can either increase or decrease; depends on the frequency factor

Last Answer : (C) Decreases exponentially

Description : The drying time between fixed moisture contents within the 'constant rate period' is proportional to (assuming that drying occurs from all surfaces of the solid) (where, T = thickness of the solid). (A) √T (B) T (C) T 1.5 (D) T

Last Answer : (B) T

Description : Pick out the wrong statement. (A) In a first order reaction, A → products; the reaction becomes slower as it proceeds, because the concentration of A decreases and the rate is proportional to the concentration ... irreversible reaction, A + B → 2C is k.CA .CB , then the reaction is always elementary

Last Answer : (C) According to the penetration theory, the mass transfer co-efficient decreases, if the exposure time of an eddy to the solute decreases

Description : The unit of frequency factor in Arrhenius equation is (A) Same as that of rate constant (B) Same as that of activation energy (C) Dimensionless (D) None of these

Last Answer : (A) Same as that of rate constant

Description : Pick out the Clausius-Clapeyron equation from the following: (A) dP/dT = ∆H/T∆V (B) ln P = - (∆H/RT) + constant (C) ∆F = ∆H + T [∂(∆F)/∂T]P (D) None of these

Last Answer : B) ln P = - (∆H/RT) + constant

Description : The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1is the activity co-efficient of component 1, is (A) A . x22 (B) Ax1 (C) Ax2 (D) Ax12

Last Answer : (A) A . x22

Description : Mass transfer co-efficient (K) and diffusivity (D) are related according to film theory as (A) K ∝ D (B) K ∝√D (C) K ∝ D1.5 (D) K ∝ D

Last Answer : (A) K ∝ D

Description : From Arrhenius law, a plot of loge K versus 1/T gives a straight line with a slope of (-E/R). The unit of E/R is (A) k cal (B) k cal/°K (C) °K (D) k cal. °K

Last Answer : (C) °K

Description : Charles' law for gases states that (A) V/T = Constant (B) V ∝ 1/T (C) V ∝ 1/P (D) PV/T = Constant

Last Answer : (A) V/T = Constant

Description : The value of Steric factor 'P' in the equation k = PZe E/RT usually ranges from (A) 1.0 to 10 -8 (B) 1.1 to 10 2 (C) 0.1 to 0.9 (D) None of these

Last Answer : (A) 1.0 to 10 -8

Description : The drying time between fixed moisture content within diffusion controlled 'falling rate period' is proportional to (assuming that drying occurs from all surfaces of the solid) (where, T = thickness of the solid). (A) √T (B) T (C) T 2 (D) T

Last Answer : (C) T

Description : Drag force on the float of a Rotameter is (where Q = flow rate of the) (A) ∝ Q (B) ∝ √Q (C) ∝ Q2 (D) Constant

Last Answer : (D) Constant

Description : What is the equation for the work done by a constant temperature system?  A. W = mRTln(V2-V1)  B. W = mR( T2-T1 ) ln( V2/V1)  C. W = mRTln (V2/V1)  D. W = RT ln (V2/V1) Formula : W=∫ pdV lim1,2 ∫ = mRT / V

Last Answer : W = mRTln (V2/V1)

Description : In case of liquids, the binary diffusivity is proportional to (where, T = temperature) (A) T (B) √T (C) T 2 (D) 1/T

Last Answer : (A) T

Description : The Knudsen diffusivity is proportional to (where, T = absolute temperature) (A) √T (B) T 2 (C) T (D) T 4

Last Answer : (A) √T

Description : In case of isentropic flow, the speed of sound in an ideal gas is proportional to (where, T = absolute temperature). (A) 1/√T (B) 1/T (C) √T (D) T

Last Answer : (C) √T

Description : Translational kinetic energy of molecules of an ideal gas is proportional to (where, T = absolute temperature of the gas) (A) T (B) √T (C) T2 (D) 1/√T

Last Answer : (A) T

Description : Velocity of a gas in sound is not proportional to (where, T = Absolute temperature of the gas. P = Absolute pressure of the gas. y = Ratio of specific heats (Cp/Cv) ρ = specific weight of the gas) (A) √T (B) 1/√P (C) √y (D) 1/√ρ

Last Answer : (B) 1/√P

Description : There is no correspondence between stoichiometric and the rate equation in case of a/an __________ reaction. (A) Elementary (B) Multiple (C) Autocatalytic (D) Non-elementary

Last Answer : (D) Non-elementary

Description : The reaction in which the rate equation corresponds to a stoichiometric equation, is called a/an __________ reaction. (A) Elementary (B) Non-elementary (C) Parallel (D) Autokinetic

Last Answer : (A) Elementary

Description : The diffusivity (D) in a binary gas mixture is related to the temperature (T) as (A) D ∝ T (B) D ∝ T 0.5 (C) D ∝ T 1.5 (D) D ∝ T

Last Answer : (C) D ∝ T 1.5

Description : The energy radiated from a surface Q at absolute temperature T is related as (A) Q ∝ T 2 (B) Q ∝ T 4 (C) Q ∝ T 3 (D) None of these

Last Answer : (B) Q ∝ T

Description : Boyle's law for gases states that (A) P ∝ 1/V, when temperature is constant (B) P ∝ 1/V, when temperature & mass of the gas remain constant (C) P ∝ V, at constant temperature & mass of the gas (D) P/V = constant, for any gas

Last Answer : (B) P ∝ 1/V, when temperature & mass of the gas remain constant

Description : The order of reaction is the number of moles whose concentrations determine the rate of a reaction at a given temperature Give the integrated equation for first order reaction. K = (2.303 / t) * log (a ... a' is the initial concentration of reactants x' is the amount reacted in time t seconds

Last Answer : What is Threshold energy ?

Description : At a given value of E/R (ratio of activation energy and gas constant), the ratio of the rate constants at 500°K and 400°K is 2, if Arrhenius law is used. What will be this ratio, if transition state theory is used with the same value of ‘E/R’? (A) 1.6 (B) 2 (C) 2.24 (D) 2.5

Last Answer : (D) 2.5

Description : he quantitative effect of temperature on chemical equilibrium is given by the (A) Van’t-Hoff equation (B) Le-Chatelier's principle (C) Arrhenius equation (D) None of these

Last Answer : (A) Van’t-Hoff equation

Description : In the equation Pv = RT, the constant of proportionality R is known as ______.  A. Universal gas constant  B. Gas constant  C. Ideal gas factor  D. Gas index

Last Answer : Gas constant

Description : Knudsen diffusion is directly proportional to (A) T (B) √T (C) 1/√T (D) T

Last Answer : (B) √T

Description : Internal energy of a gas obeying Van-Der-Waals equation of state, [p + (a/v2)] (V - b) = RT, depends upon its (A) Pressure & temperature (B) Pressure & specific volume (C) Temperature & specific volume (D) Temperature only

Last Answer : (A) Pressure & temperature

Description : Given that for a reaction of nth order, the integrated rate equation is: `K=1/(t(n-1))[1/C^(n-1)-1/C_(0)^(n-1)]`, where `C` and `C_(0)` are the concen

Last Answer : Given that for a reaction of nth order, the integrated rate equation is: `K=1/(t(n-1))[1/C^(n-1)-1/C_(0)^(n-1)] ... `t_(3//4)=t_(1//2) [2^((n-1))+1]`

Description : The compressibility factor, x, is used for predicting the behavior of nonideal gases. How is the compressibility ty factor defined relative to an ideal gas? (subscript c refers to critical value)  A. ... compressibility factor, x, is an dimensionless constant given by pV=zRT. Therefore z = pV / RT

Last Answer : z = pV/ RT

Description : The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv ), depends upon its (A) Pressure (B) Volume (C) Temperature (D) All (A), (B) & (C)

Last Answer : (C) Temperature

Description : Pick out the wrong statement. (A) The shear stress at the pipe (dia = D, length = L) wall in case of laminar flow of Newtonian fluids is (D/4L). ∆p (B) In the equation, T. gc = k. ... to motion (D) With increase in the Mach number >0.6, the drag co-efficient decreases in case of compressible fluids

Last Answer : (D) With increase in the Mach number >0.6, the drag co-efficient decreases in case of compressible fluids

Description : If air is at pressure, p, of 3200 lbf/ft2 , and at a temperature, T, of 800 ˚R, what is the specific volume, v? (R=5303 ft-lbf/lbm-˚R, and air can be modeled as an ideal gas.)  A.9.8 ft^3/lbm  B.11.2 ft^3/lbm  C.13.33 ft^3/lbm  D.14.2 ft^3/lbm Formula: pv = RT v = RT / p

Last Answer : 13.33 ft^3/lbm

Description : How degree of ionization effects the strength of an acid or base according to Arrhenius concept?

Last Answer : Ans: An acid or base which will ionize completely, having high degree of ionization, will give more H+ or –OH ions. And will be a strong acid or base.

Description : Which of the following holds good for an elementary reaction as shown in the bellow figure? (A) The rate of disappearance of 'Y' is equal to the rate of appearance of 'Z' (B) The rate of disappearance of 'Y ... of 'Z' (D) The rate of disappearance of 'X' is equal to the rate of appearance of 'Z

Last Answer : (C) Three times the rate of disappearance of 'X' is equal to the rate of appearance of 'Z

Description : Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to ... Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction

Last Answer : (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot

Description : My theory of electrolytic dissociation earned me t 1903 Nobel Prize in chemistry. My name is: w) Niels Bohr x) Svante Arrhenius y) Michael Faraday z) John Cavendish

Last Answer : ANSWER: X -- SVANTE ARRHENIUS